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    • 6. 发明专利
    • MASS SPECTROGRAPH OF LASER IONIZATION TYPE
    • JPH11329344A
    • 1999-11-30
    • JP13887898
    • 1998-05-20
    • NIPPON KOKAN KK
    • MIYAZAWA KUNIONAGANO HIDEKIKONDO TAKAAKI
    • G01N27/62G01N27/64H01J27/24H01J49/10
    • PROBLEM TO BE SOLVED: To ensure an automatic correction to a set wavelength by comparing the wavelength of reference beam detected by a spectrum measurement unit with the wavelength of an ionizing laser beam, and controlling a wavelength converter in a pulse laser beam oscillator when there is a difference between them and the preliminarily input wavelengths thereof. SOLUTION: Light of a specified wavelength emitted from a mercury hollow cathode lamp 7 serving as a correction light source is led to a line photosensor 12 via a changeover mirror 8 and a refraction lattice 10, and the position of specified wavelength is confirmed. The pulse light generated by a pulse laser 2 is led to a titanium saphire laser wavelength converter 1, and further led to a second high frequency and a third high frequency converter 3, then it is projected into an ionization chamber as an ionization laser beam 6. A part of output of the converter 3 is taken out by a half mirror 5, and the refraction lattice in the laser oscillator of the converter 1 is controlled in rotation by a controller 20 so that it comes to a position confirmed by a sensor 12, and further an angle of wavelength selection element of the high frequency converter 3 is controlled.
    • 9. 发明专利
    • METHOD FOR RAPIDLY ANALYZING DIOXIN
    • JPH1114596A
    • 1999-01-22
    • JP17022397
    • 1997-06-26
    • NIPPON KOKAN KK
    • MIYAZAWA KUNIONAGANO HIDEKIMIYAMOTO HITOSHIKONDO TAKAAKI
    • G01N27/62G01N27/64
    • PROBLEM TO BE SOLVED: To permit an analysis rapidly by obtaining the concentration of the alternative index compound of dioxin using a laser multiple photon ionization mass spectrograph and obtaining dioxin concentration according to the correlation with the concentration. SOLUTION: With an exhaust gas sample, an alternative index compound is measured by a laser multiple photon ionization mass spectrograph. First, the exhaust gas sample is introduced into an ionization room from a sample- introducing part and laser beams are applied to an exhaust gas in molecular jet shape. When the alternative index compound in the exhaust sample gas is ionized, the mass spectrograph detects molecular ions and determine the number of masses and determines the alternative index compound and obtains the concentration. The correlation between the alternative index compound concentration and dioxin concentration is obtained in advance and the dioxin concentration is obtained from the actually measured value of the alternative index compound concentration based on the correlation. Chlorobenzofuran compound such as 2-chlorodibenzofuran is preferable as the alternative index compound.
    • 10. 发明专利
    • ANALYZER FOR CHLOROBENZENES
    • JPH10332656A
    • 1998-12-18
    • JP14140497
    • 1997-05-30
    • NIPPON KOKAN KK
    • MIYAZAWA KUNIONAGANO HIDEKI
    • G01N30/08B01D8/00B01D53/02G01N30/14G01N30/88
    • PROBLEM TO BE SOLVED: To provide an analyzer by which chlorobenzenes can be automatically analyzed with high accuracy by a method wherein dust particles are removed by a dust collector in which a calcium carbonate layer is formed, an adsorbent is used at a concentrator and the chlorobenzene, etc., are concentrated by a cold trap injector. SOLUTION: An exhasust gas 21 is sucked, by using a pump 10, to a concentrator 3, which is kept at room temperature or lower, via a dust collector 1 in which a calicium carbonate layer is formed and which is provided with a filter and via a dehumidifier 2 which is cooled electronically to about 2 deg.C or lower. A cold trap injector 4 is set at about -40 deg.C or lower by means of carbon diode from a carbon diode cylinder 80. Helium is sent to the concentrator 3 from a helium cylinder 60, a heater is warmed, and adsorbed chlorobenzene, etc., are desorbed so as to be condensed and reconcentrated by the injector 4. When the concentrator 3 becomes about 280 deg.C, the injection of the helium is changed over to the injector 4 from the concentrator 3, and the temperature of the injector 4 is raised. Thereby, the chlorobenzene, etc., are sent to a gas chromatograph 5 and a mass spectrometer 6, and ananalyzed value is output from a data processor 8.