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    • 8. 发明公开
    • METHOD FOR PRODUCING POLYACRYLIC ACID (SALT)-BASED WATER ABSORBENT RESIN POWDER
    • VERFAHREN ZUR HERSTELLUNG EINES WASSERABSERBIERENDEN HARZPULVERS AUFPOLYACRYLSÄURE(SALZ)BASIS
    • EP2565219A4
    • 2014-04-02
    • EP11775082
    • 2011-04-27
    • NIPPON CATALYTIC CHEM IND
    • WATANABE YUSUKETORII KAZUSHINOGI KOZOISHIZAKI KUNIHIKONAKATSURU REIKOSAKAMOTO SHIGERU
    • C08J3/12
    • C08J3/12C08F6/008C08F122/105C08F220/06C08J3/122C08J3/245C08J2333/02C08L33/02
    • A water absorbent resin having less fine powder or powdery dust and a controlled particle size is provided, and the water absorption rate of the water absorbent resin is increased by a simple method at low cost, while maintaining or improving other physical properties such as liquid permeability. Disclosed is a method for producing a polyacrylic acid (salt)-type water absorbent resin powder, which includes, in sequence, a step of polymerizing an aqueous solution of acrylic acid (salt)-type monomer; a step of gel-crushing a gel of a water-containing gel-like crosslinked polymer during polymerization or after polymerization; a step of drying the water-containing gel-like crosslinked polymer; and a step of pulverizing and classifying the dried polymer, wherein water absorbent resin fine particles having a particle size of less than 150 µm or a hydrated-particles thereof is added to a step prior to the drying step, and in the drying step, hot air drying is carried out with a hot air having an average flow velocity of 1.0 to 3.0 [m/s], a dew point of 30°C to 100°C, and a hot air temperature of 140°C to 235°C.
    • 提供具有较少细粉末或粉末粉尘和受控粒度的吸水性树脂,并且通过简单的方法以低成本提高吸水性树脂的吸水率,同时保持或改善其它物理性能如液体渗透性 。 本发明公开了一种聚丙烯酸(盐)型吸水性树脂粉末的制造方法,其中,依次包括使丙烯酸(盐)型单体的水溶液聚合的工序; 在聚合过程中或聚合后凝胶化凝胶状凝胶状交联聚合物凝胶的步骤; 干燥含水凝胶状交联聚合物的工序; 以及将干燥聚合物粉碎并分级的步骤,其中在干燥步骤之前的步骤中加入粒径小于150μm的吸水性树脂细颗粒或其水合颗粒,并且在干燥步骤中,热 用平均流速为1.0〜3.0 [m / s],露点为30〜100℃,热风温度为140〜235℃的热风进行空气干燥。