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    • 5. 发明公开
    • Beta-alumina solid electrolyte and process for production thereof
    • Festelektrolyt ausβ-aluminiumoxid和Verfahren zu seiner Herstellung。
    • EP0675558A1
    • 1995-10-04
    • EP95302058.3
    • 1995-03-28
    • NGK INSULATORS, LTD.
    • Kajita, MasaharuKajihara, TakehiroTotoki, Takao
    • H01M10/39C04B35/113
    • H01M10/3918C04B35/113
    • A beta-alumina solid electrolyte for use in sodium-sulfur battery is composed of the beta-alumina crystals having a degree of orientation toward C axis, of 0.2-0.4 and an aspect ratio of 4.0 or less. The beta-alumina solid electrolyte is composed of the beta-alumina crystals having a degree of orientation toward C axis, of 0.2-0.4 and has such a particle diameter distribution that the average particle diameter is 3 µm or less, the proportion of the particles having a particle diameter of 5 µm or less is 90% or more, and the maximum particle diameter is 300 µm or less. A process for producing a beta-alumina solid electrolyte using an alumina source material, a magnesium source material and a sodium source material has using a magnesium-aluminum spinel as the magnesium source material and subjecting all materials to mixing, granulation, molding and firing to obtain a beta-alumina solid electrolyte without subjecting the materials to calcination. The beta-alumina solid electrolyte has a low electrical resistance and a large strength to internal water pressure and exhibits excellent properties when used as a diaphragm for sodium-sulfur battery.
    • 用于钠硫电池的β-氧化铝固体电解质由具有朝向C轴的取向度为0.2-0.4且宽高比为4.0以下的β-氧化铝晶体组成。 β-氧化铝固体电解质由对C轴取向度为0.2-0.4的β-氧化铝晶体组成,具有平均粒径为3μm以下的粒径分布, 粒径为5μm以下的粒子为90%以上,最大粒径为300μm以下。 使用氧化铝源材料,镁源材料和钠源材料制造β-氧化铝固体电解质的方法使用镁 - 铝尖晶石作为镁源材料,并使所有材料进行混合,造粒,模塑和烧制 获得β-氧化铝固体电解质,而不对材料进行煅烧。 β-氧化铝固体电解质具有低电阻和较大的内部水压强度,并且在用作钠硫电池的隔膜时表现出优异的性能。