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1. 发明申请

WO2013030463A3 METHOD OF REFORMING GASIFICATION GAS 审中-公开
标题翻译：改善气化气体的方法
公开(公告)号：WO2013030463A3
公开(公告)日：2013-08-01
申请号：PCT/FI2012050851
申请日：2012-09-03
申请人： NESTE OIL OYJ , SIMELL PEKKA , KURKELA ESA , HILTUNEN ILKKA , TOPPINEN SAMI , EILOS ISTO
发明人： SIMELL PEKKA , KURKELA ESA , HILTUNEN ILKKA , TOPPINEN SAMI , EILOS ISTO
IPC分类号： C01B3/58 , B01J21/06 , B01J23/40 , C10K1/34 , C10K3/02
CPC分类号： C10K3/023 , C01B3/386 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0415 , C01B2203/0475 , C01B2203/062 , C01B2203/1058 , C01B2203/1064 , C01B2203/143 , C10J2300/092 , C10J2300/1846 , Y02P20/52
摘要： A method of reforming a gasification gas, in order to decompose the impurities comprised in it, and a new use of a precious metalcatalyst in the pre-reforming of gasification gas. In the present method, the gas is brought into contact with a metal catalyst in the presence of an oxidizing agent. According to the present invention, the reformation is carried out in several stages, in which case at least in one of the first catalytic zones a noble metal catalyst is used, and in a secondary reforming stage which follows the first, preliminary reforming zone,the catalyst used is a metal catalyst. Oxygen is fed separately into each of the catalyst zones. The use of a noble metalcatalyst reduces the risk of deactivation of the metal catalysts and thus increases the operating life of the catalyst.
摘要翻译：为了分解其中所含的杂质，重整气化气体的方法，以及气化气体的预重整中贵金属催化剂的新用途。在本方法中，在氧化剂存在下使气体与金属催化剂接触。根据本发明，重整是分几个阶段进行的，在这种情况下，至少在使用贵金属催化剂的第一催化剂区域中的至少一个中，在第一初级重整区之后的二次重整阶段，使用的催化剂是金属催化剂。氧分别进料到每个催化剂区域中。使用贵金属催化剂降低金属催化剂失活的风险，从而增加催化剂的使用寿命。

2. 发明公开

EP2542654A4 METHOD OF REFORMING GASIFICATION GAS 有权转让
标题翻译： PROCESS重整气化气
公开(公告)号：EP2542654A4
公开(公告)日：2014-12-03
申请号：EP11750242
申请日：2011-03-03
申请人： NESTE OIL OYJ
发明人： SIMELL PEKKA , KURKELA ESA , HILTUNEN ILKKA
IPC分类号： C10K1/34 , B01J21/06 , B01J23/38 , B01J23/40 , C10J3/00 , C10J3/48 , C10J3/84 , C10K3/02
CPC分类号： C10J3/00 , B01J21/066 , B01J23/40 , C10J3/482 , C10J3/84 , C10J2300/0916 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10K1/34 , C10K3/023 , Y02E20/18 , Y02P20/52

3. 发明专利

CA2787672C METHOD OF REFORMING GASIFICATION GAS 未知
公开(公告)号：CA2787672C
公开(公告)日：2018-09-18
申请号：CA2787672
申请日：2011-03-03
申请人： NESTE OIL OYJ
发明人： SIMELL PEKKA , KURKELA ESA , HILTUNEN ILKKA
IPC分类号： C10K1/34 , B01J23/38 , C10J3/84 , C10K3/02
摘要： A method of reforming gasification gas, in order to decompose organic impurities comprised in the gas. In the present method the gasification gas is contacted with at least one catalyst, in the presence of an oxidising agent. The reforming of the gasification gas is carried out in several stages. The method comprises a first stage with a noble metal catalyst stage wherein a noble metal catalyst is used, and a zirconium catalyst stage that is arranged in the direction of flow in a position before the noble metal catalyst stage. In a second stage, which follows the first stage, a metal catalyst is used. In the method, an oxidising agent is fed into the first stage. The use of noble metal catalyst reduce the risk of deactivation and increases the operating life of the metal catalyst.

4. 发明专利

BR112012021962A2 método de reforma de gás de gasificação 未知
公开(公告)号：BR112012021962A2
公开(公告)日：2016-06-07
申请号：BR112012021962
申请日：2011-03-03
申请人： NESTE OIL OYJ
发明人： KURKELA ESA , HILTUNEN ILKKA , SIMELL PEKKA
IPC分类号： B01J23/38 , C10J3/84 , C10K1/34 , C10K3/02
摘要： método de reforma de gás de gasificação. a presente invenção refere-se a um método de reforma de um gás de gaseificação, de forma a decompor as impurezas compreendidas no mesmo e um novo uso de um catalisador de metal nobre pré-reforma de gás de gasificação. no presente método, o gás é mantido em contato com um catalisador de metal na presença de um agente de oxidação. de acordo com a presente invenção, a reforma é realizada em vários estágios, caso no qual pelo menos em um dos primeiros estágios, um catalisador de metal nobre é usado e, em um segundo estágio o qual segue o primeiro estágio, o catalisador usado é um catalisador de metal. o uso de um catalisador de metal nobre reduz o risco de desativação dos catalisadores de metal, e assim, aumenta a vida operacional do catalisador.

5. 发明专利

CA2787672A1 METHOD OF REFORMING GASIFICATION GAS 未知
公开(公告)号：CA2787672A1
公开(公告)日：2011-09-09
申请号：CA2787672
申请日：2011-03-03
申请人： NESTE OIL OYJ
发明人： SIMELL PEKKA , KURKELA ESA , HILTUNEN ILKKA
IPC分类号： C10K1/34 , B01J23/38 , C10J3/84 , C10K3/02
摘要： A method of reforming a gasification gas, in order to decompose the impurities comprised in it, and a new use of a noble metal catalyst in the pre-reforming of gasification gas. In the present method, the gas is brought into contact with a metal catalyst in the presence of an oxidising agent. According to the present invention, the reformation is carried out in several stages, in which case at least in one of the first stages a noble metal catalyst is used, and in a second stage which follows the first stage the catalyst used is a metal catalyst. The use of a noble metal catalyst reduces the risk of deactivation of the metal catalysts and thus increases the operating life of the catalyst.

6. 发明专利

EA024259B1 СПОСОБ РИФОРМИНГА ГАЗА, ПОЛУЧЕННОГО ГАЗИФИКАЦИЕЙ 未知
公开(公告)号：EA024259B1
公开(公告)日：2016-08-31
申请号：EA201490510
申请日：2012-09-03
申请人： NESTE OIL OYJ
发明人： SIMELL PEKKA , KURKELA ESA , HILTUNEN ILKKA , TOPPINEN SAMI , EILOS ISTO
IPC分类号： C01B3/58 , B01J21/06 , B01J23/40 , C10K1/34 , C10K3/02
摘要： Визобретениипредставленспособриформингагаза, полученногогазификацией, дляразложениясодержащихсяв немзагрязненийи новоеприменениекатализаторанаосноведрагоценногометаллаприпредриформингегаза, полученногогазификацией. Вспособегазприводятв контактс металлическимкатализаторомв присутствииокислителя. Согласноизобретениюриформингосуществляютв несколькостадий, причемпоменьшеймерев однойизпервыхкаталитическихзониспользуюткатализаторнаосновеблагородногометалла, анавторойстадиириформинга, котораяследуетзапервой, используемымкатализаторомявляетсяметаллическийкатализатор. Кислородподаютраздельнов каждуюизкаталитическихзон. Использованиекатализаторанаосновеблагородногометалласнижаетрискдеактивацииметаллическихкатализаторови поэтомуувеличиваетсрокслужбыкатализатора.

7. 发明专利

FI20105201A 未知
公开(公告)号：FI20105201A
公开(公告)日：2011-09-04
申请号：FI20105201
申请日：2010-03-03
申请人： NESTE OIL OYJ
发明人： SIMELL PEKKA , KURKELA ESA , HILTUNEN ILKKA
IPC分类号： C10K1/34 , B01D53/86 , B01J23/38 , C10G47/14 , C10J3/84 , C10K3/02
摘要： A method of reforming a gasification gas, in order to decompose the impurities contained therein, and a use of a noble metal catalyst in the pre-reforming of gasification gas. The gas is brought into contact with a metal catalyst in the presence of an oxidizing agent. The reformation is carried out in several stages, wherein in at least one of the first stages a noble metal catalyst is used, and in a second stage which follows the first stage the catalyst used is a metal catalyst. The use of a noble metal catalyst can reduce the risk of deactivation of the metal catalysts and can increase the operating life of the catalyst.

8. 发明专利

FI20105201A0 未知
公开(公告)号：FI20105201A0
公开(公告)日：2010-03-03
申请号：FI20105201
申请日：2010-03-03
申请人： NESTE OIL OYJ
发明人： SIMELL PEKKA , KURKELA ESA , HILTUNEN ILKKA
IPC分类号： C10K20100101
摘要： A method of reforming a gasification gas, in order to decompose the impurities contained therein, and a use of a noble metal catalyst in the pre-reforming of gasification gas. The gas is brought into contact with a metal catalyst in the presence of an oxidizing agent. The reformation is carried out in several stages, wherein in at least one of the first stages a noble metal catalyst is used, and in a second stage which follows the first stage the catalyst used is a metal catalyst. The use of a noble metal catalyst can reduce the risk of deactivation of the metal catalysts and can increase the operating life of the catalyst.

9. 发明专利

CA2846936C METHOD OF REFORMING GASIFICATION GAS 未知
公开(公告)号：CA2846936C
公开(公告)日：2021-05-04
申请号：CA2846936
申请日：2012-09-03
申请人： NESTE OIL OYJ
发明人： SIMELL PEKKA , KURKELA ESA , HILTUNEN ILKKA , TOPPINEN SAMI , EILOS ISTO
IPC分类号： C10K1/34 , B01J21/06 , B01J23/40 , C10K3/02
摘要： A method of reforming a gasification gas, in order to decompose the impurities comprised in it, and a new use of a precious metalcatalyst in the pre-reforming of gasification gas. In the present method, the gas is brought into contact with a metal catalyst in the presence of an oxidizing agent. According to the present invention, the reformation is carried out in several stages, in which case at least in one of the first catalytic zones a noble metal catalyst is used, and in a secondary reforming stage which follows the first, preliminary reforming zone,the catalyst used is a metal catalyst. Oxygen is fed separately into each of the catalyst zones. The use of a noble metalcatalyst reduces the risk of deactivation of the metal catalysts and thus increases the operating life of the catalyst.

10. 发明专利

CA2837418C METHOD OF PRODUCING A HYDROCARBON COMPOSITION 未知
公开(公告)号：CA2837418C
公开(公告)日：2020-08-25
申请号：CA2837418
申请日：2012-05-30
申请人： NESTE OIL OYJ
发明人： EILOS ISTO , JOHANSSON SEBASTIAN , TOPPINEN SAMI , HILTUNEN ILKKA , KURKELA ESA , SIMELL PEKKA
IPC分类号： C10G2/00 , C01B3/48 , C01B3/50 , C10J3/00 , C10K3/06
摘要： Method of producing a hydrocarbon composition. In the method a biomass raw-material is gasified produce a raw syngas containing carbon monoxide, carbon dioxide and hydrogen, the hydrogen-to-carbon monoxide ratio being about 0.5 to 1.7. A part of the impurities is removed to produce a clean syngas which is fed into a Fischer-Tropsch reactor where a significant part of the carbon monoxide and hydrogen is converted to a hydrocarbon composition containing C4-C90 hydrocarbons. From the Fischer-Tropsch reactor a hydrocarbon composition is recovered which mainly contains hydrocarbons which are solid or semisolid at ambient temperature and pressure and an off-gas of the Fischer- Tropsch reactor, comprising hydrocarbons which are gaseous at ambient temperature and pressure, is used for producing hydrogen gas; and the hydrogen thus produced is fed into the clean syngas. By introducing hydrogen into the clean syngas, the hydrogen to carbon monoxide ratio can be increased and by using off-gas-produced hydrogen, the capacity of the process is significantly improved.

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