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    • 7. 发明专利
    • METHOD OF FORMATION FOR INDIUM ARSENIDE LAYER
    • JPH0376217A
    • 1991-04-02
    • JP21229389
    • 1989-08-18
    • NEC CORP
    • SHIMAWAKI HIDENORIKATOU YOSHITAKE
    • H01L21/205
    • PURPOSE:To alleviate the substrate temperature dependency of growth speed and to contrive improvement in film thickness controllability by a method wherein a first raw gas, containing a group III element, contains an In chloride, a second raw gas, containing a group V element, contains As, and the (111) B face is used as the crystal face orientation of the substrate. CONSTITUTION:A (111) B face (group V element stabilized face) is used as the crystal face orientation of a substrate, and the growth of a mono-molecular layer is made possible by using an In chloride for raw gas. The In chloride, generated by the reaction of an In source and an HC1, and the As compound, generated by the thermal decomposition of AsH, are used for raw gas, the temperature of In source is set at 650 deg.C, the partial pressure of the HC1 to be fed to the In source and AsH3 feeding partial pressure are set at 7.5X10 atm and 1.4X10 atm. By using the (111) B substrate, the growth of film thick ness per cycle is made uniform in the temperature region of 375 deg.C or lower irrespective of substrate temperature. When an InAs layer is formed, the region where growth speed becomes constant irrespective of substrate temperature is expanded, and stabilized InAs can be grown for almost every molecular layer in the above-mentioned temperature region.
    • 8. 发明专利
    • SEMICONDUCTOR LAMINATED STRUCTURE AND SEMICONDUCTOR DEVICE INCLUDING SAME
    • JPH02271669A
    • 1990-11-06
    • JP9455589
    • 1989-04-13
    • NEC CORP
    • SHIMAWAKI HIDENORI
    • C30B23/08C30B29/40H01L21/20H01L21/203H01L29/201
    • PURPOSE:To form a graded junction type hetero junction type hetero junction by forming a graded layer into a periodic laminate structure of two or more kinds of a binary compound semiconductor layers each of which takes as ingredients constituent elements of a semiconductor layer A and a semiconductor layer B, and altering the period of the periodic laminate structure. CONSTITUTION:For an InAs layer 2 and a GaAs layer 3, lattice matching with InP is taken into consideration, and the ratio of the layer number therebetween is kept at a predetermined one (1:1) such that they exhibit an equivalent crystal layer to In0.5As. More specifically, the layer number ratio in the In0.5Ga0.5As layer in which the InP layer, the InAs layer, and the GaAs layer are laminated, is progressively altered, whereby there is formed a graded layer in which the composition is changed from the InP to In0.5Ga0.5As. Further, a tetra mixed crystal semiconductor layer can be formed, which has a composition corresponding to In0.6Ga0.4As0.8P0.2, by alternately laminating three InP layers, one InAs layer, and one GaAs layer and by alternately laminating In0.8Ga0.2As0.6P0.6, or InP layer, two InAs layers, and two GaAs layer. Hereby, a graded junction type hetero junction improved in composition uniformity is yielded.
    • 9. 发明专利
    • HETEROJUNCTION BIPOLAR TRANSISTOR AND ITS MANUFACTURE
    • JPH0278226A
    • 1990-03-19
    • JP23034288
    • 1988-09-13
    • NEC CORP
    • TANAKA SHINICHISHIMAWAKI HIDENORI
    • H01L29/73H01L21/331H01L29/205H01L29/737
    • PURPOSE:To form a fine structure of high reliability by a method wherein a difference in height between an upper end face of an outer base layer in an external transistor region and a base-emitter junction face inside an intrinsic transistor region is made smaller than a thickness of an intrinsic base layer. CONSTITUTION:A collector contact layer (n GaAs) 2 and a collector layer (n GaAs) 3 are formed one after another on a semiinsulating substrate 1. Then, a protective film 81 composed of SiO2 is formed in a prescribed region; the layer 3 is etched by making use of the protective film as a mask; a high- resistance layer (mi-GaAs Iayer) 3i is filled in such a way that a semiconductor crystal plane of an outer base layer (p GaAs) 4c is nearly flat. Then, a protective film 82 composed of an SiO2 film is grown on the whole surface; the film is coated with a photoresist as a protective film 9; this film is flattened; the film 9 is etched; the exposed films 82, 81 are etched; the remaining film 9 is removed; a base layer 4 (p-GaAs), an emitter layer 5 (n-Al0.3Ga0.7As) and a contact layer (n GaAS) are grown again.