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1. 发明申请

WO2011008492A2 SILICA-BASED PARTICLE COMPOSITION 审中-公开
公开(公告)号：WO2011008492A2
公开(公告)日：2011-01-20
申请号：PCT/US2010/040189
申请日：2010-06-28
申请人： NALCO COMPANY , KEISER, Bruce, A. , KEIZER, Timothy, S. , ADAIR, James, H.
发明人： KEISER, Bruce, A. , KEIZER, Timothy, S. , ADAIR, James, H.
IPC分类号： C01B33/141 , C09C1/28 , D21H21/10 , C09K11/02 , A61K8/25
CPC分类号： C01B33/18 , B82Y30/00 , C01B33/146 , C01B33/149 , C01P2002/84 , C01P2004/04 , C01P2004/62 , C01P2004/64 , C01P2006/12
摘要： The present invention relates to a method for forming a silica-based particle or composite consisting of a silica-based material, an active, with or without a surface modification, and the related composition. The silica-based particle is illustrated by the formula (SiO 2 ) x (OH) y R z S t , whereby R is an active or actives such as an organic or inorganic molecule that includes markers, amines, thiols, epoxies, organosilicones, organosilanes, and water soluble agents and, optionally, a surface modifier, S, which may be either organic, polymeric, or inorganic. Examples of a surface modifying material are inorganic salts of aluminum and boron or organic materials such as organosilanes or low molecular weight polymers. As such, the particle can be used in a variety of applications including any of a variety of high temperature, at acidic, neutral, or basic pH, or pressure environments. The composites have applications as diverse as papermaking, water treatment, chemical tracing, personal care, microbiological control, and delivery of polymers, for example. With regard to papermaking, the particle provides retention and drainage performance while delivering whitener, or OBA, other functional additives and serves an additive tracker.

2. 发明申请

WO2011008484A2 SILICA-BASED PARTICLE COMPOSITION 审中-公开
标题翻译：基于硅石的颗粒组合物
公开(公告)号：WO2011008484A2
公开(公告)日：2011-01-20
申请号：PCT/US2010/040132
申请日：2010-06-28
申请人： NALCO COMPANY , KEISER, Bruce, A. , KEIZER, Timothy, S. , ADAIR, James, H.
发明人： KEISER, Bruce, A. , KEIZER, Timothy, S. , ADAIR, James, H.
IPC分类号： C01B33/141 , C09C1/28 , D21H21/10 , C09K11/02
CPC分类号： C09K11/02 , C01P2002/84 , C01P2004/04 , C09B11/08 , C09B11/24 , C09B67/0007 , C09B67/0013 , C09B69/008 , C09B69/103 , C09C1/3063 , C09C1/3081 , C09C1/309 , C09K11/06 , Y10T428/2982
摘要： The present invention relates to a method for forming a silica-based particle or composite consisting of a silica-based material, an active, with or without a surface modification, and the related composition. The silica-based particle is illustrated by the formula (SiO 2 ) x (OH) y R z S t , whereby R is an active or actives such as an organic or inorganic molecule that includes markers, amines, thiols, epoxies, organosilicones, organosilanes, and water soluble agents and, optionally, a surface modifier, S, which may be either organic, polymeric, or inorganic. Examples of a surface modifying material are inorganic salts of aluminum and boron or organic materials such as organosilanes or low molecular weight polymers. As such, the particle can be used in a variety of applications including any of a variety of high temperature, at acidic, neutral, or basic pH, or pressure environments. The composites have applications as diverse as papermaking, water treatment, chemical tracing, personal care, microbiological control, and delivery of polymers, for example. With regard to papermaking, the particle provides retention and drainage performance while delivering whitener, or OBA, other functional additives and serves an additive tracker.
摘要翻译：本发明涉及一种形成二氧化硅基颗粒或复合物的方法，所述二氧化硅基颗粒或复合物由基于二氧化硅的材料，具有或不具有表面改性的活性物质以及相关组合物组成。基于二氧化硅的颗粒由下式表示（SiO 2）x（OH）y R z S S 其中R是活性或活性物质，例如包括标记物，胺，硫醇，环氧化物，有机硅氧烷，有机硅烷和水溶性试剂的有机或无机分子，以及任选的表面改性剂S ，它可以是有机的，聚合物的或无机的。表面改性材料的实例是铝和硼的无机盐或有机材料如有机硅烷或低分子量聚合物。这样，颗粒可用于各种应用，包括在酸性，中性或碱性pH或压力环境下的各种高温中的任何一种。例如，该复合材料具有多种应用，如造纸，水处理，化学追踪，个人护理，微生物控制和聚合物输送。关于造纸，颗粒在提供增白剂或OBA，其他功能性添加剂并提供添加剂追踪剂时提供保留和排水性能。

3. 发明申请

WO2007112407A2 METHOD OF STABILIZING SILICA-CONTAINING ANIONIC MICROPARTICLES IN HARD WATER 审中-公开
标题翻译：在硬水中稳定含二氧化硅阳离子微生物的方法
公开(公告)号：WO2007112407A2
公开(公告)日：2007-10-04
申请号：PCT/US2007/065270
申请日：2007-03-27
申请人： NALCO COMPANY , KEISER, Bruce, A. , MILLER, Raymond, D. , Jr. , STRYSIK, Linda, S. , GRATTAN, David, A.
发明人： KEISER, Bruce, A. , MILLER, Raymond, D. , Jr. , STRYSIK, Linda, S. , GRATTAN, David, A.
IPC分类号： A61K8/89 , A61K8/81
CPC分类号： C01B33/1485 , C01P2006/12 , C09C1/3072 , C09C1/309 , D21H17/68 , D21H21/10
摘要： A method of stabilizing silica-containing anionic microparticles upon mixing of the silica-containing anionic microparticles with hard water comprising adding one or more hardness-abating additives to the hard water prior to mixing of the hard water and the silica-containing anionic microparticles; or adding an effective stabilizing amount of one or more hardness-abating agents to the silica-containing anionic microparticles prior to mixing of the hard water with the silica-containing anionic microparticles and a stabilized composition comprising silica-containing anionic microparticles and an effective stabilizing amount of one or more hardness-abating additives.
摘要翻译：在含有二氧化硅的阴离子微粒与硬水混合的同时稳定含二氧化硅的阴离子微粒的方法，包括在混合硬水和含二氧化硅的阴离子微粒之前向硬水中加入一种或多种减硬添加剂; 或者在将硬水与含二氧化硅的阴离子性微粒混合之前，向含二氧化硅的阴离子性微粒中添加有效稳定量的一种或多种减硬剂，以及含有二氧化硅的阴离子性微粒和稳定化的组合物，的一种或多种降低硬度的添加剂。

4. 发明申请

WO2007040735A2 USE OF SYNTHETIC METAL SILICATES FOR DECREASING THE DEPOSITION OF CONTAMINANTS DURING A PAPERMAKING PROCESS 审中-公开
标题翻译：合成金属硅酸盐用于降低造纸过程中污染物的沉积
公开(公告)号：WO2007040735A2
公开(公告)日：2007-04-12
申请号：PCT/US2006/028812
申请日：2006-07-25
申请人： NALCO COMPANY , GRAY, Ross, T. , SHERMAN, Laura, M. , KEISER, Bruce, A.
发明人： GRAY, Ross, T. , SHERMAN, Laura, M. , KEISER, Bruce, A.
IPC分类号： D21H17/68 , D21H21/02
CPC分类号： D21H17/68 , D21H11/14 , D21H21/02 , D21H23/04
摘要： A method for decreasing the amount of contaminants in a papermaking a process is disclosed. The method involves adding an effective amount of SMS to said papermaking process.
摘要翻译：公开了一种用于减少造纸工艺中污染物的量的方法。该方法涉及在所述造纸过程中添加有效量的SMS。

5. 发明申请

WO2007040736A1 USE OF SYNTHETIC METAL SILICATES FOR INCREASING RETENTION AND DRAINAGE DURING A PAPERMAKING PROCESS 审中-公开
标题翻译：合成金属硅酸盐在造纸过程中增加保持和排水的使用
公开(公告)号：WO2007040736A1
公开(公告)日：2007-04-12
申请号：PCT/US2006/028814
申请日：2006-07-25
申请人： NALCO COMPANY , KEISER, Bruce, A. , SHERMAN, Laura, M.
发明人： KEISER, Bruce, A. , SHERMAN, Laura, M.
IPC分类号： D21H21/10
CPC分类号： D21H17/28 , D21H17/68 , D21H21/10
摘要： A paper or paperboard produced from a slurry that includes cellulose fibers and synthetic metal silicates is disclosed. A method for increasing retention and dewatering during the papermaking process is also disclosed. The method involves the addition of an effective amount of synthetic metal silicates to a slurry in the papermaking process. Certain embodiments of the process also include the use of anionic, cationic, non-ionic, zwitterionic and amphoteric polymers as processing aids.
摘要翻译：公开了由包括纤维素纤维和合成金属硅酸盐的浆料制成的纸或纸板。还公开了一种在造纸过程中增加保留和脱水的方法。该方法涉及在造纸过程中向浆液中加入有效量的合成金属硅酸盐。该方法的某些实施方案还包括使用阴离子，阳离子，非离子，两性离子和两性聚合物作为加工助剂。

6. 发明申请

WO2011127230A3 SULFUR CONTAINING SILICA PARTICLE 审中-公开
公开(公告)号：WO2011127230A3
公开(公告)日：2011-10-13
申请号：PCT/US2011/031496
申请日：2011-04-07
申请人： NALCO COMPANY , KEISER, Bruce, A. , ERGANG, Nicholas, S. , MIMNA, Richard
发明人： KEISER, Bruce, A. , ERGANG, Nicholas, S. , MIMNA, Richard
IPC分类号： C01B33/20 , C01B33/18 , C09C1/30 , B01J20/10 , B01J21/08
摘要： A silica containing composition is disclosed. The composition comprises a compound having the following formula: (SiO 2 ) x (OH) y M z S a F: wherein M is at least one of the following metal or metalloid cations: boron, magnesium, aluminum, calcium, titanium, vanadium, manganese, iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, palladium, silver, cadmium, tin, platinum, gold, and bismuth; wherein S is a sulfur-based species selected from at least one of the following: sulfide salts, dithiocarbamates, polymer-based dithiocarbamates, and polysulfide salts;wherein F optionally exists and said F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of 0.01 100 %; and wherein the molar ratio of y/x is equal to 0.01 0.5, the molar ratio of x/z is equal to 3 300, and the molar ratio of a/z is 1 5.

7. 发明申请

WO2015069403A1 METHOD OF HEAVY METAL REMOVAL FROM WASTE WATER STREAMS 审中-公开
标题翻译：从废水流中去除金属重金属的方法
公开(公告)号：WO2015069403A1
公开(公告)日：2015-05-14
申请号：PCT/US2014/059353
申请日：2014-10-06
申请人： NALCO COMPANY
发明人： MUSALE, Deepak, A. , SCHWARZ, Daniel, E. , ZINN, Paul, J. , KEISER, Bruce, A. , SHAH, Jitendra, T.
IPC分类号： C02F1/62 , C02F1/52 , B01D61/00
CPC分类号： C02F9/00 , B01D61/025 , B01D61/027 , B01D61/14 , B01D2311/04 , B01D2311/2642 , B01D2311/2665 , B01D2311/2688 , C02F1/285 , C02F1/441 , C02F1/442 , C02F1/444 , C02F1/5236 , C02F1/56 , C02F1/683 , C02F2101/103 , C02F2101/106 , C02F2101/20 , C02F2101/203
摘要： The invention provides methods and compositions for separating metals from a liquid medium, the method uses a copolymer derived from at least two monomers: acrylic-x and an alkylamine, wherein said polymer is modified to contain a functional group capable of scavenging one or more compositions containing one or more metals are disclosed. The treated liquid is then passed through a filtration system. The scavenging effect of the combination of the treatment with the filtration is unexpectedly greater than the sum of its parts. MS
摘要翻译：本发明提供用于从液体介质中分离金属的方法和组合物，该方法使用衍生自至少两种单体的共聚物：丙烯酸-X和烷基胺，其中所述聚合物被改性为含有能够清除一种或多种组合物的官能团含有一种或多种金属。然后将处理过的液体通过过滤系统。处理与过滤的组合的清除效果意外地大于其部分的总和。女士

8. 发明公开

EP2448864A2 SILICA-BASED PARTICLE COMPOSITION 审中-公开
标题翻译：颗粒组成FOR硅基
公开(公告)号：EP2448864A2
公开(公告)日：2012-05-09
申请号：EP10800262.7
申请日：2010-06-28
申请人： Nalco Company
发明人： KEISER, Bruce, A. , KEIZER, Timothy, S. , ADAIR, James, H.
IPC分类号： C01B33/141 , C09C1/28 , D21H21/10 , C09K11/02
CPC分类号： C09K11/02 , C01P2002/84 , C01P2004/04 , C09B11/08 , C09B11/24 , C09B67/0007 , C09B67/0013 , C09B69/008 , C09B69/103 , C09C1/3063 , C09C1/3081 , C09C1/309 , C09K11/06 , Y10T428/2982
摘要： The present invention relates to a method for forming a silica-based particle or composite consisting of a silica-based material, an active, with or without a surface modification, and the related composition. The silica-based particle is illustrated by the formula (SiO2)x(OH)yRzSt, whereby R is an active or actives such as an organic or inorganic molecule that includes markers, amines, thiols, epoxies, organosilicones, organosilanes, and water soluble agents and, optionally, a surface modifier, S, which may be either organic, polymeric, or inorganic. Examples of a surface modifying material are inorganic salts of aluminum and boron or organic materials such as organosilanes or low molecular weight polymers. As such, the particle can be used in a variety of applications including any of a variety of high temperature, at acidic, neutral, or basic pH, or pressure environments. The composites have applications as diverse as papermaking, water treatment, chemical tracing, personal care, microbiological control, and delivery of polymers, for example. With regard to papermaking, the particle provides retention and drainage performance while delivering whitener, or OBA, other functional additives and serves an additive tracker.

9. 发明授权

EP1189689B1 PROCESS FOR PREPARING STABLE SILICA SOLS OF HIGH SURFACE AREA AND IMPROVED ACTIVITY 有权
标题翻译：方法稳定KIESELSOL高比和改进的活性的
公开(公告)号：EP1189689B1
公开(公告)日：2008-04-16
申请号：EP99973881.8
申请日：1999-06-02
申请人： Ondeo Nalco Company
发明人： KEISER, Bruce, A. , NUNN, Maureen, B. , HUANG, Cheng-Sung , MACDONALD, Dennis, L.
IPC分类号： B01J13/00 , C01B33/142 , C01B33/143 , D21H21/10
CPC分类号： B01J13/0008 , C01B33/143 , D21H17/29 , D21H17/68 , D21H21/10
摘要： Disclosed are stable, aqueous colloidal silicas having surface area of greater than 700m /g and S-values of from 20-50. These colloidal silicas do not require treatment with a surface treating agent such as aluminium to achieve stability. These colloidal silica aquasols can be produced and stored at concentrations greater than 7 percent by weight SiO2 solids, and even as high as 15 percent by weight solids or higher, and remain stable at room temperature for at least 30 days. These colloidal silica sols are useful as drainage and retention agents in papermaking processes. Also disclosed are processes for making aqueous colloidal silica o f the invention and papermaking processes employing the colloidal silica sols.

10. 发明授权

EP1999069B1 METHOD OF STABILIZING SILICA-CONTAINING ANIONIC MICROPARTICLES IN HARD WATER 有权
标题翻译：稳定含二氧化硅的阴离子微粒在硬水中的方法
公开(公告)号：EP1999069B1
公开(公告)日：2018-03-14
申请号：EP07759498.4
申请日：2007-03-27
申请人： Nalco Company
发明人： KEISER, Bruce, A. , MILLER, Raymond, D. , Jr. , STRYSIK, Linda, S. , GRATTAN, David, A.
IPC分类号： C01B33/143 , C09C1/30 , C01B33/148 , D21H17/68 , D21H21/10
CPC分类号： C01B33/1485 , C01P2006/12 , C09C1/3072 , C09C1/309 , D21H17/68 , D21H21/10
摘要： A method of stabilizing silica-containing anionic microparticles upon mixing of the silica-containing anionic microparticles with hard water comprising adding one or more hardness-abating additives to the hard water prior to mixing of the hard water and the silica-containing anionic microparticles; or adding an effective stabilizing amount of one or more hardness-abating agents to the silica-containing anionic microparticles prior to mixing of the hard water with the silica-containing anionic microparticles and a stabilized composition comprising silica-containing anionic microparticles and an effective stabilizing amount of one or more hardness-abating additives.

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