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1. 发明授权

US08241742B2 Coated steel sheet comprising a composite coat containing compounded resin particles 有权
标题翻译：涂覆钢板包括含有复合树脂颗粒的复合涂层
公开(公告)号：US08241742B2
公开(公告)日：2012-08-14
申请号：US12303191
申请日：2006-06-15
申请人： Motohiro Sasaki , Junpei Karoji , Koichi Saito , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
发明人： Motohiro Sasaki , Junpei Karoji , Koichi Saito , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
IPC分类号： B32B5/16 , B32B15/18 , B32B15/095
CPC分类号： C09D123/0869 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G18/44 , C08G18/6662 , C08G18/758 , C08G2150/90 , C08L2666/20 , C09D123/04 , C09D175/04 , C09J123/0869 , C23C26/00 , C23C30/00 , Y10T428/25 , Y10T428/254 , Y10T428/259 , Y10T428/26 , Y10T428/273 , C08G18/3893 , C08L91/06 , C08L2666/04 , C08G18/3231
摘要： It is an object of the present invention to provide a coated steel sheet, properties of which such as tape peeling resistance, solvent resistance, alkali resistance and abrasion resistance are improved.A coated steel sheet coated with a composite coat, wherein said composite coat comprises a compounded resin (A) in which polyurethane resin particles (A-1) and ethylene-unsaturated carboxylic acid copolymerization resin particles (A-2), respectively having an average particle diameter of 20 to 100 nm and a silanol group and/or an alkoxysilyl, group, are contained in a mass ratio of 20:80 to 90:10 and silicon oxide particles (A-3) having an average particle diameter of 5 to 20 nm and an organic titanium compound (A-4) are compounded, polyolefin wax particles (B) having an average particle diameter of 0.5 to 4 μm and a softening point of 100 to 140° C., and silicon oxide particles (C) having an average particle diameter of 70 to 200 nm, and wherein an amount of a coat of said composite coat is 0.5 to 3 g/cm2.
摘要翻译：本发明的目的是提供一种涂层钢板，其性能如带剥离性，耐溶剂性，耐碱性和耐磨性得到改善。涂覆有复合涂层的涂覆钢板，其中所述复合涂层包括其中分别具有平均值的聚氨酯树脂颗粒（A-1）和乙烯 - 不饱和羧酸共聚树脂颗粒（A-2）的复合树脂（A） 20〜100nm的粒径和硅烷醇基和/或烷氧基甲硅烷基，以20:80〜90:10的质量比包含，平均粒径为5〜3的氧化硅粒子（A-3） 20nm的有机钛化合物（A-4），平均粒径为0.5〜4μm，软化点为100〜140℃的聚烯烃蜡粒子（B）和氧化硅粒子（C）平均粒径为70〜200nm，所述复合涂层的涂层量为0.5〜3g / cm 2。

2. 发明申请

US20080081196A1 Surface-treated metal sheet 有权
标题翻译：表面处理金属板
公开(公告)号：US20080081196A1
公开(公告)日：2008-04-03
申请号：US11540507
申请日：2006-10-02
申请人： Koichi Saito , Motohiro Sasaki , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
发明人： Koichi Saito , Motohiro Sasaki , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
IPC分类号： B32B15/08 , B32B27/18 , B32B15/085 , B32B15/09 , B32B15/092 , B32B15/095
CPC分类号： C23C26/00 , C09D5/084 , C23C30/00 , Y10T428/31511 , Y10T428/31529 , Y10T428/31551 , Y10T428/31605 , Y10T428/31678 , Y10T428/31681 , Y10T428/31692
摘要： It is an object of the present invention to provide an organic coating-treated metal sheet, having a coat capable of satisfying all the corrosion resistance, alkali resistance, solvent resistance, anti-scratch property and adhesion requirements which the conventional nonchromate type coating technologies have been difficult to meet.A surface-treated metal sheet with a coat comprising 50 to 90% by weight of a crosslinked resin matrix (A) and 10 to 50% by weight of an inorganic rust preventive (B) as formed on the metal sheet surface,wherein the crosslinked resin matrix (A) is formed by the reaction between a water-borne resin and a crosslinking agent and has an acid value of 0 to 30 due to carboxylic acid groups not neutralized by an alkali metal and a hydroxyl value of 5 to 50.
摘要翻译：本发明的目的是提供一种有机涂层处理的金属片，其具有能够满足常规非铬酸盐型涂覆技术具有的所有耐腐蚀性，耐碱性，耐溶剂性，抗划伤性和粘附要求的涂层很难见面。一种表面处理金属片，其具有在金属片表面上形成的包含交联树脂基体（A）50至90重量％和10至50重量％的无机防锈剂（B）的涂层，其中交联树脂基体（A）是由水性树脂与交联剂的反应形成的，由于未被碱金属中和且羟值为5〜50的羧酸基，酸值为0〜30。

3. 发明申请

US20100233469A1 COATED STEEL SHEET 有权
标题翻译：涂层钢板
公开(公告)号：US20100233469A1
公开(公告)日：2010-09-16
申请号：US12303191
申请日：2006-06-15
申请人： Motohiro Sasaki , Junpei Karoji , Koichi Saito , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
发明人： Motohiro Sasaki , Junpei Karoji , Koichi Saito , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
IPC分类号： B32B5/16 , B32B15/06 , B32B15/095 , B32B15/18
CPC分类号： C09D123/0869 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G18/44 , C08G18/6662 , C08G18/758 , C08G2150/90 , C08L2666/20 , C09D123/04 , C09D175/04 , C09J123/0869 , C23C26/00 , C23C30/00 , Y10T428/25 , Y10T428/254 , Y10T428/259 , Y10T428/26 , Y10T428/273 , C08G18/3893 , C08L91/06 , C08L2666/04 , C08G18/3231
摘要： It is an object of the present invention to provide a coated steel sheet, properties of which such as tape peeling resistance, solvent resistance, alkali resistance and abrasion resistance are improved.A coated steel sheet coated with a composite coat, wherein said composite coat comprises a compounded resin (A) in which polyurethane resin particles (A-1) and ethylene-unsaturated carboxylic acid copolymerization resin particles (A-2), respectively having an average particle diameter of 20 to 100 nm and a silanol group and/or an alkoxysilyl, group, are contained in a mass ratio of 20:80 to 90:10 and silicon oxide particles (A-3) having an average particle diameter of 5 to 20 nm and an organic titanium compound (A-4) are compounded, polyolefin wax particles (B) having an average particle diameter of 0.5 to 4 μm and a softening point of 100 to 140° C., and silicon oxide particles (C) having an average particle diameter of 70 to 200 nm, and wherein an amount of a coat of said composite coat is 0.5 to 3 g/cm2.
摘要翻译：本发明的目的是提供一种涂层钢板，其性能如带剥离性，耐溶剂性，耐碱性和耐磨性得到改善。涂覆有复合涂层的涂覆钢板，其中所述复合涂层包括其中分别具有平均值的聚氨酯树脂颗粒（A-1）和乙烯 - 不饱和羧酸共聚树脂颗粒（A-2）的复合树脂（A） 20〜100nm的粒径和硅烷醇基和/或烷氧基甲硅烷基，以20:80〜90:10的质量比包含，平均粒径为5〜3的氧化硅粒子（A-3） 20nm的有机钛化合物（A-4），平均粒径为0.5〜4μm，软化点为100〜140℃的聚烯烃蜡粒子（B）和氧化硅粒子（C）平均粒径为70〜200nm，所述复合涂层的涂层量为0.5〜3g / cm 2。

4. 发明授权

US07476445B2 Surface-treated metal sheet 有权
标题翻译：表面处理金属板
公开(公告)号：US07476445B2
公开(公告)日：2009-01-13
申请号：US11540507
申请日：2006-10-02
申请人： Koichi Saito , Motohiro Sasaki , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
发明人： Koichi Saito , Motohiro Sasaki , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
IPC分类号： B32B15/082 , B32B15/085 , B32B15/092 , B32B15/095 , B32B27/18
CPC分类号： C23C26/00 , C09D5/084 , C23C30/00 , Y10T428/31511 , Y10T428/31529 , Y10T428/31551 , Y10T428/31605 , Y10T428/31678 , Y10T428/31681 , Y10T428/31692
摘要： It is an object of the present invention to provide an organic coating-treated metal sheet, having a coat capable of satisfying all the corrosion resistance, alkali resistance, solvent resistance, anti-scratch property and adhesion requirements which the conventional nonchromate type coating technologies have been difficult to meet. A surface-treated metal sheet with a coat comprising 50; to 90% by weight of a crosslinked resin matrix (A) and 10 to 50% by weight of an inorganic rust preventive (B) as formed on the metal sheet surface, wherein the crosslinked resin matrix (A) is formed by the reaction between a water-borne resin and a crosslinking agent and has an acid value of 0 to 30 due to carboxylic acid groups not neutralized by an alkali metal and a hydroxyl value of 5 to 50.
摘要翻译：本发明的目的是提供一种有机涂层处理的金属片，其具有能够满足常规非铬酸盐型涂覆技术具有的所有耐腐蚀性，耐碱性，耐溶剂性，抗划伤性和粘附要求的涂层很难见面。具有包含50的涂层的表面处理金属片; 至90重量％的交联树脂基体（A）和10〜50重量％的形成在金属板表面上的无机防锈剂（B），其中交联树脂基质（A）通过水性树脂和交联剂，并且由于未被碱金属中和且羟值为5〜50的羧酸基，其酸值为0〜30。

5. 发明授权

US08349446B2 Coated steel sheet 有权
标题翻译：涂层钢板
公开(公告)号：US08349446B2
公开(公告)日：2013-01-08
申请号：US12303195
申请日：2006-06-15
申请人： Motohiro Sasaki , Koichi Saito , Atsushi Morishita , Akira Takahashi
发明人： Motohiro Sasaki , Koichi Saito , Atsushi Morishita , Akira Takahashi
IPC分类号： B32B5/16 , B32B15/08
CPC分类号： C09D123/0853 , C08K3/36 , C08K5/0091 , C09J123/0869 , Y10T428/254
摘要： A coated steel sheet coated with a composite coat, wherein said composite coat is a coat formed by compounding ethylene-unsaturated carboxylic acid copolymerization resin particles (A) having an average particle diameter of 20 to 100 nm and a silanol group and/or an alkoxysilyl group, silicon oxide particles (B) having an average particle diameter of 5 to 50 nm and an organic titanium compound (C), and wherein an amount of a coat of said composite coat is 0.5 to 3 g/m2.
摘要翻译：涂覆有复合涂层的涂覆钢板，其中所述复合涂层是通过将平均粒径为20-100nm的乙烯 - 不饱和羧酸共聚树脂颗粒（A）与硅烷醇基和/或烷氧基甲硅烷基基团，平均粒径为5〜50nm的氧化硅粒子（B）和有机钛化合物（C），其中所述复合涂层的涂层量为0.5〜3g / m 2。

6. 发明申请

US20100233470A1 COATED STEEL SHEET 有权
标题翻译：涂层钢板
公开(公告)号：US20100233470A1
公开(公告)日：2010-09-16
申请号：US12303195
申请日：2006-06-15
申请人： Motohiro Sasaki , Koichi Saito , Atsushi Morishita , Akira Takahashi
发明人： Motohiro Sasaki , Koichi Saito , Atsushi Morishita , Akira Takahashi
IPC分类号： B32B5/16 , B32B15/08
CPC分类号： C09D123/0853 , C08K3/36 , C08K5/0091 , C09J123/0869 , Y10T428/254
摘要： It is an object of the present invention to provide a coated steel sheet, properties of which such as an adhesion property to a substrate and press oil resistance are improved.A coated steel sheet coated with a composite coat, wherein said composite coat is a coat formed by compounding ethylene-unsaturated carboxylic acid copolymerization resin particles (A) having an average particle diameter of 20 to 100 nm and a silanol group and/or an alkoxysilyl group, silicon oxide particles (B) having an average particle diameter of 5 to 50 nm and an organic titanium compound (C), and wherein an amount of a coat of said composite coat is 0.5 to 3 g/m2.
摘要翻译：本发明的目的是提供一种涂层钢板，其特性如对基材的粘合性能和耐压油性提高。涂覆有复合涂层的涂覆钢板，其中所述复合涂层是通过将平均粒径为20-100nm的乙烯 - 不饱和羧酸共聚树脂颗粒（A）与硅烷醇基和/或烷氧基甲硅烷基基团，平均粒径为5〜50nm的氧化硅粒子（B）和有机钛化合物（C），其中所述复合涂层的涂层量为0.5〜3g / m 2。

7. 发明授权

US08263232B2 Composite coated zinc-containing plated steel material superior in corrosion resistance, blackening resistance, coating adhesion, and alkali resistance 有权
标题翻译：耐腐蚀性，耐黑变性，涂层附着力和耐碱性优异的复合涂层含锌电镀钢材
公开(公告)号：US08263232B2
公开(公告)日：2012-09-11
申请号：US12226388
申请日：2007-04-20
申请人： Yoshio Kimata , Atsushi Morishita , Akira Takahashi , Toshikazu Amemiya , Takayuki Kuwagaki , Hidetoshi Shindo , Ikuo Kikuchi
发明人： Yoshio Kimata , Atsushi Morishita , Akira Takahashi , Toshikazu Amemiya , Takayuki Kuwagaki , Hidetoshi Shindo , Ikuo Kikuchi
IPC分类号： B32B15/04 , B32B15/18
CPC分类号： C22C21/10 , C22C38/00 , C23C22/60 , C23C22/66 , C23C28/321 , C23C28/3225 , C23C28/345 , Y10T428/12556 , Y10T428/1266 , Y10T428/12757 , Y10T428/12799 , Y10T428/12819 , Y10T428/12937 , Y10T428/12972 , Y10T428/27
摘要： The present invention provides a composite coated zinc-containing plated steel material different from the plated steel materials treated by conventional chromate replacement technologies and superior in all of corrosion resistance, blackening resistance, coating adhesion, and alkali resistance. The composite coated zinc-containing plated steel material of the present invention is characterized by having a composite coating formed by coating and drying on the surface of a plated steel material a treatment solution containing a basic zirconium compound, vanadyl (VO2+)-containing compound, phosphoric acid compound, cobalt compound, organic acid, and water and having a pH 7 to 14, the composite coating containing, with respect to the Zr element as 100 parts by mass, V in an amount of 10 to 45 parts by mass, P in 5 to 100 parts by mass, Co in 0.1 to 20 parts by mass, and an organic acid in 10 to 90 parts by mass.
摘要翻译：本发明提供一种与通过常规的铬酸盐替代技术处理的镀覆钢材不同的复合涂覆的含锌镀钢材料，并且具有优异的耐腐蚀性，耐黑变性，涂层粘附性和耐碱性。本发明的复合镀覆含锌镀覆钢材的特征在于，在电镀钢材的表面上涂布并干燥含有碱性锆化合物，含氧化钒（VO2 +）的化合物，磷酸化合物，钴化合物，有机酸和水，并且pH为7〜14，所述复合涂层相对于Zr元素为100质量份，V为10〜45质量份，P为相对于5〜100质量份，Co为0.1〜20质量份，有机酸为10〜90质量份。

8. 发明申请

US20090110921A1 Chromate-Free Surface Treated Metal Material with Excellent Corrosion Resistance, Heat Resistance, Fingermark Resistance, Conductivity, Coatability, and Blackening Resistance at the Time of Working 审中-公开
标题翻译：无铬酸盐表面处理金属材料，具有优良的耐腐蚀性，耐热性，抗水印性，电导率，可涂敷性和耐黑化性
公开(公告)号：US20090110921A1
公开(公告)日：2009-04-30
申请号：US11989096
申请日：2006-07-14
申请人： Taihei Kaneto , Atsushi Morishita , Yoshio Kimata , Akira Takahashi , Ikuo Kikuchi , Shinji Nomura , Hidehiro Yamaguchi
发明人： Taihei Kaneto , Atsushi Morishita , Yoshio Kimata , Akira Takahashi , Ikuo Kikuchi , Shinji Nomura , Hidehiro Yamaguchi
IPC分类号： B32B9/04
CPC分类号： C23C22/44 , C08G77/14 , C08G77/26 , C09D5/084 , C23C2222/20 , Y10T428/273 , Y10T428/31663
摘要： The present invention provides a metal material given a chrome-free surface treatment satisfying all of the requirements of corrosion resistance, heat resistance, fingermark resistance, conductivity, coatability, and blackening resistance at the time of working, which was difficult to achieve with conventional chromate-free technology. The chromate-free surface treated metal material of the present invention is comprised of a metal material on the surface of which is coated and dried an aqueous metal surface treatment agent comprising an organic silicon compound (W), obtained by blending a silane coupling agent (A) containing one amino group in its molecule and a silane coupling agent (B) containing one glycidyl group in its molecule in a solid weight ratio [(A)/(B)] of 0.5 to 1.7, at least one type of fluorocompound (X) selected from fluorotitanic acid or fluorozirconic acid, phosphoric acid (Y), and a vanadium compound (Z) so as to form a composite coating containing the different ingredients.
摘要翻译：本发明提供了赋予无铬表面处理的金属材料，其满足了常规铬酸盐难以达到的耐蚀性，耐热性，防水印性，导电性，可涂布性和耐黑变性的所有要求免费技术。本发明的无铬酸盐表面处理金属材料由金属材料构成，其表面涂覆并干燥含有金属表面处理剂，其含有有机硅化合物（W），其通过将硅烷偶联剂（ A），其分子中含有一个氨基和其分子中含有一个缩水甘油基的硅烷偶联剂（B），其固体重量比[（A）/（B）]为0.5至1.7，至少一种氟化合物 X）选自氟钛酸或氟锆酸，磷酸（Y）和钒化合物（Z），以形成含有不同成分的复合涂层。

9. 发明申请

US20140050939A1 SURFACE-TREATED METAL MATERIAL AND AQUEOUS METAL SURFACE-TREATMENT AGENT 审中-公开
标题翻译：表面处理金属材料和水性金属表面处理剂
公开(公告)号：US20140050939A1
公开(公告)日：2014-02-20
申请号：US14113502
申请日：2012-04-26
申请人： Atsushi Morishita , Taihei Kaneto , Yoshio Kimata , Akira Takahashi , Ikuo Kikuchi , Hidehiro Yamaguchi , Shinji Nomura
发明人： Atsushi Morishita , Taihei Kaneto , Yoshio Kimata , Akira Takahashi , Ikuo Kikuchi , Hidehiro Yamaguchi , Shinji Nomura
IPC分类号： C09D7/12
CPC分类号： C09D7/63 , C23C22/361 , C23C22/44 , C23C2222/20 , Y10T428/12569 , Y10T428/273 , Y10T428/31663
摘要： A surface-treated metal material of the present invention has a composite film on the surface of a metal material. The composite film includes an organic silicon compound (W) having cyclic siloxane bonds, at least one metal compound (X) selected from a group consisting of a titanium compound and a zirconium compound, a phosphate compound (Y) and a fluorine compound (Z). In each of the components of the composite film, the ratio of XS/WS is from 0.06 to 0.16, where WS is a solid mass of Si derived from the organic silicon compound (W) and XS is a solid mass of at least one metal component selected from a group consisting of Ti and Zr included in the metal compound (X); the ratio of YS/WS is from 0.15 to 0.31, where WS is the solid mass of Si and YS is a solid mass of P derived from the phosphate compound (Y); and the ratio of ZS/WS is from 0.08 to 0.50, where WS is the solid mass of Si and ZS is a solid mass of F derived from the fluorine compound (Z).
摘要翻译：本发明的表面处理金属材料在金属材料的表面具有复合膜。复合膜包括具有环状硅氧烷键的有机硅化合物（W），选自由钛化合物和锆化合物组成的组中的至少一种金属化合物（X），磷化合物（Y）和氟化合物（Z ）。在复合膜的每个组分中，XS / WS的比例为0.06至0.16，其中WS是来自有机硅化合物（W）的Si的固体质量，XS是至少一种金属的固体质量选自金属化合物（X）中所含的由Ti和Zr组成的组的组分; YS / WS的比例为0.15〜0.31，其中WS是Si的固体质量，YS是来自磷酸盐化合物（Y）的P的固体质量; 并且ZS / WS的比例为0.08〜0.50，其中WS为Si的固体质量，ZS为来自氟化合物（Z）的F的固体质量。

10. 发明申请

US20110027611A1 ZINC-BASED PLATED STEEL SHEET EXCELLENT IN SURFACE ELECTRICAL CONDUCTIVITY HAVING PRIMARY RUST PREVENTIVE THIN FILM LAYER 有权
标题翻译：基于ZINC的镀层钢板表面电导率优于主要防腐薄膜层
公开(公告)号：US20110027611A1
公开(公告)日：2011-02-03
申请号：US12735628
申请日：2008-02-15
申请人： Akira Takahashi , Atsushi Morishita
发明人： Akira Takahashi , Atsushi Morishita
IPC分类号： B32B15/04 , B05D3/00 , C25D5/00 , B82Y30/00
CPC分类号： C23C2/26 , C25D5/48 , Y10T428/12472 , Y10T428/12535 , Y10T428/12799 , Y10T428/12993
摘要： A zinc or zinc alloy plated steel sheet expressing a performance provided with both corrosion resistance and surface conductivity is provided. The zinc or zinc alloy plated steel sheet of the present invention is a zinc or zinc alloy plated steel sheet having an arithmetic average roughness Ra of a zinc-plated layer surface defined by JIS B 0601, obtained by a stylus-type surface roughness meter defined by JIS B 0651, of 0.3 μm to 2.0 μm and a maximum peak height Rp of 4.0 μm to 20.0 μm, wherein the arithmetic average roughness Ra (peak) obtained by measuring a range of evaluation length of 20 μm of peak parts of 80% or more of the Rp by an electron beam 3D roughness analyzer is 70% or more of the arithmetic average roughness Ra (average) obtained by measuring a range of evaluation length of 20 μm of parts of a height of ±20% about an average line, obtained by a stylus-type surface roughness meter, by an electron beam 3D roughness analyzer.
摘要翻译：提供了表现出具有耐腐蚀性和表面电导率的性能的锌或锌合金镀覆钢板。本发明的锌或锌合金镀覆钢板是由JIS B 0601规定的镀锌层表面的算术平均粗糙度Ra为规定的触针式表面粗糙度计得到的锌或锌合金镀覆钢板通过JIS B 0651为0.3μm〜2.0μm，最大峰高Rp为4.0μm〜20.0μm，其中通过测定峰值部分的评价长度的范围为80％而得到的算术平均粗糙度Ra（峰值）通过电子束3D粗糙度分析器的Rp以上的算术平均粗糙度Ra（平均值）为70％以上，通过将平均线的高度为±20％的部分的评价长度的范围测定为20μm ，由电子束3D粗糙度分析仪由触针式表面粗糙度仪获得。

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