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    • 2. 发明申请
    • NETWORK COPOLYMER CROSSLINKED EMULSIONS AND DEMULSIFYING COMPOSTIONS COMPRISE THE SAME
    • 网络共聚物交联乳液和分解组合物
    • WO2011079014A2
    • 2011-06-30
    • PCT/US2010/060716
    • 2010-12-16
    • MOMENTIVE PERFORMANCE MATERIALS INC.LU, NingGONZALEZ, SigfredoSILVESTRE, Emie, M.WANG, Geng
    • LU, NingGONZALEZ, SigfredoSILVESTRE, Emie, M.WANG, Geng
    • C08K5/541C08L43/02
    • C08F220/26A61K8/8152A61K2800/54A61Q1/02A61Q5/12C08F220/38C08F230/02
    • The present invention is directed to a network composition the reaction product of: (I) at least one anionic polymerizable ethylenically unsaturated monomer (I) selected from the group consisting of [CH 2 =C(R 3 )C(O)OX 3 (C 2 H 4 O)b(C 3 H 6 O) c .(C 4 H 8 ,O) d ] p P(O)(OY) q (OZ) r where R3= H or alkyl of 1 to about 6 carbon atoms; X= alkyl, aryl or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a is 0 to about 100;b is 0 to about 100;c is 0 to about 100; d is 0 to about 100;q is 0 to about 2; r is 0 to about 2; p is 1 to about 3 subject to the limitation that p +q +r= 3; and Y and Z is H, or metal ion; and CH 2 =C(R 3 )C(O)OX a' (C 2 H 4 O) b' (C 3 H 6 O) c' (C 4 H 8 ,O) d' -SO 3 -Y) where R3 = H or alkyl of from 1 to about 6 carbon atoms; X= alky!, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a' is 0 to about 100;b' is 0 to about 100;c' is 0 to about 100; d' is 0 to about 100;Y is H, or metal ion; and (ii) one or more additional monomers (H) selected from the group consisting of acrylic acid/acrylate, methacrylic acid/methacrylate, acrylamides, vinyl acetate and styrene, which are copolymerizable with (I); and (iii) a cross-linking agent (III), capable of copolymerizing with (I) and (II).
    • 本发明涉及一种网络组合物,其反应产物为:(I)选自[CH 2 = C(R 3)C(O)OX 3(C 2 H 4 O)b的至少一种阴离子可聚合烯属不饱和单体(I) (C 3 H 6 O)c。(C 4 H 8,O)d] pP(O)(OY)q(OZ)r其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a为0至约100; b为0至约100; c为0至约100; d为0至约100; q为0至约2; r为0〜2; p为1至约3,但受限于p + q + r = 3; Y和Z是H或金属离子; 其中R 3 = H或具有1至约6个碳原子的烷基;和(C 1 -C 4) X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a'为0至约100; b'为0至约100; c'为0至约100; d'为0至约100; Y为H或金属离子; 和(ii)可与(I)共聚的一种或多种选自丙烯酸/丙烯酸酯,甲基丙烯酸/甲基丙烯酸酯,丙烯酰胺,乙酸乙烯酯和苯乙烯的另外的单体(H)。 和(iii)能够与(I)和(II)共聚的交联剂(III)。
    • 4. 发明申请
    • CLARIFYING AGENTS FOR ORGANOMODIFIED SILICONES
    • 用于有机硅的澄清剂
    • WO2012170606A1
    • 2012-12-13
    • PCT/US2012/041213
    • 2012-06-07
    • MOMENTIVE PERFORMANCE MATERIALS INC.FALK, BenjaminGONZALEZ, Sigfredo
    • FALK, BenjaminGONZALEZ, Sigfredo
    • C08G77/388C08G77/46C08L83/08C08L83/12A61K8/894A61K8/898C08J3/09
    • C08L83/12A61K8/894A61K8/898A61K2800/10A61K2800/262A61Q19/00C08G77/388C08G77/46C08L83/08
    • There is provided herein a composition comprising a silicone copolymer of the general formula (I) M a M E c D d D E e T f TE g Q h where M = R 1 R 2 R 3 SiO 1/2 ; M E = R 4 R 5 R E SiO 1/2 ; D = R 6 R 7 Si0 2/2 ; D E = R 8 R E Si0 2/2 ; T = R 9 Si0 3/2 ; T E = R E Si0 2/2 ; and Q = Si0 4/2 ; where R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , and R 9 are each independently selected from the group of monovalent hydrocarbon radicals optionally containing heteroatoms, carbonyl groups, and hydroxyl groups, each independently having from about 1 to about 20 carbon atoms; RE is a monovalent radical defined as: - R 10 O-(C 2 H 4 O) h (C 3 H 6 O) i (C 4 H 8 O) j -R 11 or -R 12 with the provision that the copolymer must contain at least one R E group; R 10 is a linear or branched divalent hydrocarbon radical containing from 3 to about 10 carbon atoms; R 11 is H or -C(=0)CH 3 or a monovalent saturated or unsaturated hydrocarbon radical, optionally containing heteroatoms and hydroxyl groups, containing from 1 to about 30 carbon atoms; R 12 is a hydrocarbon radical, containing from 2 to about 30 carbon atoms and at least 1 hydroxyl group, optionally containing heteroatoms; subscripts a, b, c, d, e, f, and g are 0 or positive subject to the limitation a + b + c + d + e + f + g D H ρ
    • 本文提供了包含通式(I)MaME cDdDE eTfTEgQh的硅氧烷共聚物的组合物,其中M = R 1 R 2 R 3 SiO 1/2; ME = R4R5RESiO1 / 2; D = R6R7SiO2 / 2; DE = R8RESi02 / 2; T = R9SiO 3/2; TE = RESi02 / 2; 和Q = SiO 4/2; 其中R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8和R 9各自独立地选自任选含有杂原子,羰基和羟基的一价烃基,其各自独立地具有约1至约20 碳原子 RE是被定义为:R10O-(C2H4O)h(C3H6O)i(C4H8O)j -R11或-R12的一价基团,条件是共聚物必须含有至少一个RE基团; R 10是含有3至约10个碳原子的直链或支链二价烃基; R 11是H或-C(= O)CH 3或任选含有1至约30个碳原子的杂原子和羟基的一价饱和或不饱和烃基; R 12是含有2至约30个碳原子和至少1个羟基,任选地含有杂原子的烃基; 下标a,b,c,d,e,f和g分别为0或正,受限于a + b + c + d + e + f + g <1000; 下标h,i和j为0或正数,受限于h + i + j小于100; 和b)含有至少1个酯基-C(= O)0 - 的有机油,其显示出Hansen溶解度参数为14DH 3。 <15,并且其中所述组合物的粘度小于20,000cps。 还提供含有该组合物的硅氧烷乳液,含有所述硅氧烷乳液的个人护理组合物,以及处理含硅氧烷表面活性剂的方法,包括混合组合物的内容物。