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    • 2. 发明授权
    • Apparatus for the zone-annealing of a workpiece consisting of a
high-temperature material
    • 用于由高温材料组成的工件进行区域退火的装置
    • US4583720A
    • 1986-04-22
    • US664389
    • 1984-10-24
    • Roland KunzliGunther SchroderRobert Singer
    • Roland KunzliGunther SchroderRobert Singer
    • C21D9/28C21D1/26C21D1/44C21D1/46C22F1/00C22F1/10C21D9/00
    • C21D1/46C21D1/26
    • An apparatus and a process for the zone-annealing of a workpiece (1) consisting of a high-temperature material, in which the workpiece (1) is hung on a suspension device (2) actuated via a roller (3) driven by a drive motor (4) and is provided with a plate-shaped covering screen (10) having an orifice. For the dipping of the workpiece (1), there is underneath the latter a salt bath (5) which is enclosed in an insulating vessel (6) and is provided with a heating system (7) with centrally symmetrical guide plates (8) and which is closed off at the top by means of a floating insulating cover (9). The cooling of the part of the workpiece (1) which is not immersed is guaranteed by a cooling body (11) through which cooling air (14) flows and which has a central passage (12) and, at the lower end of the passage (12), a projecting edge (13) serving as a stop for the covering screen (10). The intended grain structure can be adjusted when the feed speed of the workpiece (1) is varied in portions by means of a drive motor (4) and the amount of cooling air (14). The lateral heat flux is reduced by means of jacket-like heat-insulating cladding of the workpiece (1).
    • 一种用于由高温材料组成的工件(1)的区域退火的装置和方法,其中工件(1)悬挂在经由由(3)驱动的辊(3)致动的悬挂装置(2)上, 驱动马达(4),并且设置有具有孔口的板状覆盖屏(10)。 对于工件(1)的浸渍,在其下方具有封闭在绝缘容器(6)中的盐浴(5),并且设置有具有中心对称导向板(8)的加热系统(7)和 其通过浮动绝缘盖(9)在顶部封闭。 通过冷却空气(14)流过冷却空气(14)并具有中心通道(12)的冷却体(11)和通道的下端来保证工件(1)未被浸没的部分的冷却 (12),用作覆盖屏(10)的止挡件的突出边缘(13)。 当通过驱动马达(4)和冷却空气(14)的量部分地改变工件(1)的进给速度时,可以调整预期的晶粒结构。 通过工件(1)的护套状绝热包层来减小横向热通量。
    • 4. 发明授权
    • Process for the production of oxalic acid diesters
    • 草酸二酯生产工艺
    • US4713483A
    • 1987-12-15
    • US849858
    • 1986-04-09
    • Klaus LangerbeinsGunther SchroderHans-Peter Boehm
    • Klaus LangerbeinsGunther SchroderHans-Peter Boehm
    • C07B61/00B01J27/00C07C69/36C07C67/36
    • C07C69/36
    • A process for the production of diesters of oxalic acid by oxidative carbonylation of alcohols with carbon monoxide and oxygen as oxidizer at pressures of 1 to 700 atmospheres and in a temperature range between 20.degree. and 250.degree. C. in a reaction phase containing the alcohol and, as catalyst, palladium and at least one metal halide in catalytically effective amounts, whereby a catalyst system is used which consists of palladium, at least one metal halide, and an activated carbon which has been pretreated before use by heating to 200.degree.-1,500.degree. C. in a gas atmosphere G, differing from air.The gas atmosphere G, differing from air, consists, preferably, of at least one of the gases (a) nitrogen; (b) nitrogen compounds, except those with nitrogen-oxygen bonds; or (c) carbon monoxide; and may optionally contain an accompanying gas.
    • 在含有醇的反应相中,在1〜700个大气压和20〜250℃的压力下,一氧化碳和氧气作为氧化剂的醇的氧化羰基化生产草酸的方法, 作为催化剂,钯和至少一种金属卤化物具有催化有效量,由此使用由钯,至少一种金属卤化物和活性炭组成的催化剂体系,其在使用前通过加热至200-1,500 在气体气氛G中,与空气不同。 不同于空气的气体气氛G优选由气体(a)中的至少一种构成氮气; (b)除氮氧键外的氮化合物; 或(c)一氧化碳; 并且可以任选地含有伴随的气体。