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1. 发明授权

US08991039B2 Method for manufacturing flexible multilayer electrical articles with improved layer adhesion 有权
标题翻译：具有改善的层粘合性的柔性多层电气制品的制造方法
公开(公告)号：US08991039B2
公开(公告)日：2015-03-31
申请号：US13822083
申请日：2011-09-21
申请人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta
发明人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta
IPC分类号： H05K3/36 , H05K3/46 , B29C45/14 , B29K23/00
CPC分类号： H05K3/4644 , B29C45/14311 , B29C45/14467 , B29C45/14639 , B29C45/14778 , B29C2045/14532 , B29K2023/00 , B29K2023/083 , B29K2023/16 , B29K2995/0007 , Y10T29/49124 , Y10T29/49126 , Y10T29/49155 , Y10T29/49165
摘要： A process for manufacturing a multilayer article, the article comprising two crosslinked semiconductive layers separated by and bonded to an insulation layer, the semiconductive layers formed from a peroxide-crosslinkable olefin elastomer and the insulation layer comprising composition comprising a silane-grafted olefinic elastomer, the process comprises the steps of: (A) injecting the silane-grafted olefinic elastomer between the two crosslinked semiconductive layers so as to have direct contact with each semiconductive layer, and (B) crosslinking the silane-grafted olefinic elastomer in the absence of a peroxide catalyst.
摘要翻译：一种用于制造多层制品的方法，所述制品包含由绝缘层分隔并结合到其上的两个交联的半导体层，由过氧化物可交联的烯烃弹性体形成的半导体层和包含硅烷接枝的烯烃弹性体的组合物的绝缘层，方法包括以下步骤：（A）在两个交联的半导体层之间注入硅烷接枝的烯属弹性体以便与每个半导体层直接接触，和（B）在不存在过氧化物的情况下使硅烷接枝的烯属弹性体交联催化剂。

2. 发明申请

US20130174416A1 Method for Manufacturing Flexible Multilayer Electrical Articles with Improved Layer Adhesion 有权
标题翻译：制造具有改进层粘附性的柔性多层电气制品的方法
公开(公告)号：US20130174416A1
公开(公告)日：2013-07-11
申请号：US13822083
申请日：2011-09-21
申请人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta
发明人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta
IPC分类号： H05K3/46
CPC分类号： H05K3/4644 , B29C45/14311 , B29C45/14467 , B29C45/14639 , B29C45/14778 , B29C2045/14532 , B29K2023/00 , B29K2023/083 , B29K2023/16 , B29K2995/0007 , Y10T29/49124 , Y10T29/49126 , Y10T29/49155 , Y10T29/49165
摘要： A process for manufacturing a multilayer article, the article comprising two crosslinked semiconductive layers separated by and bonded to an insulation layer, the semiconductive layers formed from a peroxide-crosslinkable olefin elastomer and the insulation layer comprising composition comprising a silane-grafted olefinic elastomer, the process comprises the steps of: (A) injecting the silane-grafted olefinic elastomer between the two crosslinked semiconductive layers so as to have direct contact with each semiconductive layer, and (B) crosslinking the silane-grafted olefinic elastomer in the absence of a peroxide catalyst.
摘要翻译：一种用于制造多层制品的方法，所述制品包含由绝缘层分隔并结合到其上的两个交联的半导体层，由过氧化物可交联的烯烃弹性体形成的半导体层和包含硅烷接枝的烯烃弹性体的组合物的绝缘层，方法包括以下步骤：（A）在两个交联的半导体层之间注入硅烷接枝的烯属弹性体以便与每个半导体层直接接触，和（B）在不存在过氧化物的情况下使硅烷接枝的烯属弹性体交联催化剂。

3. 发明申请

US20120178867A1 Process for Producing Crosslinked, Melt-Shaped Articles 有权
标题翻译：生产交联，熔体制品的过程
公开(公告)号：US20120178867A1
公开(公告)日：2012-07-12
申请号：US13496410
申请日：2010-09-14
申请人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta
发明人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta
IPC分类号： C08L83/04
CPC分类号： B29C67/24 , B29C45/0001 , B29C45/16 , B29C70/88 , B29K2023/06 , B29K2023/0625 , B29K2023/18 , B29K2105/0014 , B29K2105/0067 , B29K2105/0085 , B29K2105/0088 , B29K2105/24 , B29K2995/0083 , B29K2995/0097 , B29L2009/00 , B29L2031/3462 , C08F220/10 , C08G77/16 , C08G77/442 , C08J3/24 , C08J3/244 , C08J3/246 , C08J2383/04 , C08J2423/04 , C08K5/57 , C08L23/04 , C08L23/08 , C08L43/04 , C08L51/06 , C08L83/04 , C08L83/06 , C08L2203/202 , C08L2207/322 , H01B3/22 , H01B3/307 , H01B3/46 , H01B7/00 , H01B19/00 , C08L83/00
摘要： Crosslinked, melt-shaped articles are manufactured by a process that does not require the use of post-shaping external heat or moisture, the process comprising the steps of: A. Forming a crosslinkable mixture of a 1. Organopolysiloxane containing one or more functional end groups; and 2. Silane-grafted or silane-copolymerized polyolefin; and B. Melt-shaping and partially crosslinking the mixture; and C. Cooling and continuing crosslinking the melt-shaped article. Crosslinking is promoted by the addition of a catalyst to the mixture before or during melt-shaping or to the melt-shaped article.
摘要翻译：交联的熔体状制品通过不需要使用后成形外部热或湿气的方法制造，该方法包括以下步骤：A.形成1.可交联的混合物1.含有一个或多个官能团的有机聚硅氧烷团体硅烷接枝或硅烷共聚聚烯烃; 和B.熔融成型并部分交联该混合物; 和C.冷却并持续交联熔体成型制品。通过在熔融成型之前或期间在熔融成型中向混合物中加入催化剂或熔融成型制品来促进交联。

4. 发明授权

US08835548B2 Process for producing crosslinked, melt-shaped articles 有权
标题翻译：交联的熔体制品的制造方法
公开(公告)号：US08835548B2
公开(公告)日：2014-09-16
申请号：US13496410
申请日：2010-09-14
申请人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta
发明人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta
IPC分类号： C08L83/04 , C08L51/06 , C08J3/24 , C08L23/04 , H01B7/00 , H01B3/46 , H01B3/44 , H01B3/30 , C08G77/442 , C08G77/16
CPC分类号： B29C67/24 , B29C45/0001 , B29C45/16 , B29C70/88 , B29K2023/06 , B29K2023/0625 , B29K2023/18 , B29K2105/0014 , B29K2105/0067 , B29K2105/0085 , B29K2105/0088 , B29K2105/24 , B29K2995/0083 , B29K2995/0097 , B29L2009/00 , B29L2031/3462 , C08F220/10 , C08G77/16 , C08G77/442 , C08J3/24 , C08J3/244 , C08J3/246 , C08J2383/04 , C08J2423/04 , C08K5/57 , C08L23/04 , C08L23/08 , C08L43/04 , C08L51/06 , C08L83/04 , C08L83/06 , C08L2203/202 , C08L2207/322 , H01B3/22 , H01B3/307 , H01B3/46 , H01B7/00 , H01B19/00 , C08L83/00
摘要： Crosslinked, melt-shaped articles are manufactured by a process that does not require the use of post-shaping external heat or moisture, the process comprising the steps of: A. Forming a crosslinkable mixture of a 1. Organopolysiloxane containing one or more functional end groups; and 2. Silane-grafted or silane-copolymerized polyolefin; and B. Melt-shaping and partially crosslinking the mixture; and C. Cooling and continuing crosslinking the melt-shaped article. Crosslinking is promoted by the addition of a catalyst to the mixture before or during melt-shaping or to the melt-shaped article.
摘要翻译：交联的熔体状制品通过不需要使用后整形外部热或湿气的方法制造，该方法包括以下步骤：A.形成1.可交联的混合物1.含有一个或多个官能团的有机聚硅氧烷团体硅烷接枝或硅烷共聚聚烯烃; 和B.熔融成型并部分交联该混合物; 和C.冷却并持续交联熔体成型制品。通过在熔融成型之前或期间在熔融成型中向混合物中加入催化剂或熔融成型制品来促进交联。

5. 发明申请

US20100159206A1 Method for the Delivery of a Multi-Component Reactive System to a Molding Operation 有权
标题翻译：将多部件反应系统运送到成型操作的方法
公开(公告)号：US20100159206A1
公开(公告)日：2010-06-24
申请号：US12630262
申请日：2009-12-03
申请人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta , Thomas J. Parsons
发明人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta , Thomas J. Parsons
IPC分类号： B32B3/30 , B29C65/00 , B29C47/06 , C08L83/00 , B32B27/32
CPC分类号： B29C47/0021 , B29C47/0019 , B29C47/065 , B32B3/08 , B32B7/12 , B32B27/08 , B32B27/18 , B32B27/20 , B32B27/283 , B32B27/32 , B32B27/327 , B32B2255/10 , B32B2270/00 , B32B2307/3065 , B32B2307/72 , B32B2307/744 , B32B2307/746 , Y10T428/1397 , Y10T428/24612 , Y10T428/31667
摘要： Tapes comprising (A) a first ribbon comprising (1)(a) a polyolefin containing at least one silane functionality, and (1)(b) a hydroxy-terminated silicone polymer, or (2) a blend of a vinyl silane, polyolefin, organic initiator, e.g., peroxide, and a hydroxy-terminated silicone polymer, and (B) a second ribbon comprising a catalyst masterbatch, the second ribbon carried on the first ribbon, allow for the delivery of a consistent mixture of resin and catalyst to an injection molding machine.
摘要翻译：包含（A）第一带的包括（1）（a）含有至少一种硅烷官能团的聚烯烃和（1）（b）羟基封端的有机硅聚合物的第一带，或（2）乙烯基硅烷，聚烯烃，有机引发剂，例如过氧化物和羟基封端的硅氧烷聚合物，和（B）包含催化剂母料的第二带，第一带上携带的第二带允许将一致的树脂和催化剂的混合物输送到注塑机。

6. 发明授权

US08586170B2 Method for the delivery of a multi-component reactive system to a molding operation 有权
标题翻译：用于将多组分反应体系输送到模制操作的方法
公开(公告)号：US08586170B2
公开(公告)日：2013-11-19
申请号：US12630262
申请日：2009-12-03
申请人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta , Thomas J. Parsons
发明人： Mohamed Esseghir , Jeffrey M. Cogen , Saurav S. Sengupta , Thomas J. Parsons
IPC分类号： B32B3/30
CPC分类号： B29C47/0021 , B29C47/0019 , B29C47/065 , B32B3/08 , B32B7/12 , B32B27/08 , B32B27/18 , B32B27/20 , B32B27/283 , B32B27/32 , B32B27/327 , B32B2255/10 , B32B2270/00 , B32B2307/3065 , B32B2307/72 , B32B2307/744 , B32B2307/746 , Y10T428/1397 , Y10T428/24612 , Y10T428/31667
摘要： Tapes comprising (A) a first ribbon comprising (1)(a) a polyolefin containing at least one silane functionality, and (1)(b) a hydroxy-terminated silicone polymer, or (2) a blend of a vinyl silane, polyolefin, organic initiator, e.g., peroxide, and a hydroxy-terminated silicone polymer, and (B) a second ribbon comprising a catalyst masterbatch, the second ribbon carried on the first ribbon, allow for the delivery of a consistent mixture of resin and catalyst to an injection molding machine.
摘要翻译：包含（A）第一带的包括（1）（a）含有至少一种硅烷官能团的聚烯烃和（1）（b）羟基封端的有机硅聚合物的第一带，或（2）乙烯基硅烷，聚烯烃，有机引发剂，例如过氧化物和羟基封端的硅氧烷聚合物，和（B）包含催化剂母料的第二带，第一带上携带的第二带允许将一致的树脂和催化剂的混合物输送到注塑机。

7. 发明申请

US20110147041A1 Medium Voltage Cable Insulation 有权
标题翻译：中压电缆绝缘
公开(公告)号：US20110147041A1
公开(公告)日：2011-06-23
申请号：US12966080
申请日：2010-12-13
申请人： Saurav S. Sengupta , Timothy J. Person , Jeffrey M. Cogen , Paul J. Caronia
发明人： Saurav S. Sengupta , Timothy J. Person , Jeffrey M. Cogen , Paul J. Caronia
IPC分类号： H01B3/30 , C08K5/34
CPC分类号： C08L23/06 , C08K5/14 , C08K5/34 , C08K5/375 , C08L23/0815 , C08L71/02 , H01B3/441 , C08L2666/02 , C08L2666/06
摘要： Compositions comprising: A. Ethylene-based polymer, e.g., LDPE; B. Polyalkylene glycol, e.g., PEG; C. Tertiary hindered amine stabilizer; D. Sulphur-containing hindered phenol antioxidant; E. Peroxide; and F. Optional coagent are useful in the preparation of TRXLPE insulation for medium voltage cable that exhibits a commercially desirable balance of long term heat aging retardancy and water-tree resistance.
摘要翻译：组合物包含：A.乙烯基聚合物，例如LDPE; B.聚亚烷基二醇，例如PEG; C.三级受阻胺稳定剂; D.含硫受阻酚抗氧化剂; 过氧化物和F.任选的助剂可用于制备用于中压电缆的TRXLPE绝缘体，其具有长期的热老化阻滞性和耐水树脂性的商业上期望的平衡。

8. 发明授权

US08460770B2 In situ moisture generation and use of polyfunctional alcohols for crosslinking of silane-functionalized resins 有权
标题翻译：用于交联硅烷官能化树脂的多官能醇的原位水分产生和使用
公开(公告)号：US08460770B2
公开(公告)日：2013-06-11
申请号：US12740838
申请日：2008-10-13
申请人： Bharat I. Chaudhary , Jeffrey M. Cogen , Saurav S. Sengupta
发明人： Bharat I. Chaudhary , Jeffrey M. Cogen , Saurav S. Sengupta
IPC分类号： B32B1/02 , B32B1/08 , C08F8/00 , C08F273/00 , C08F130/08 , C08G77/442
CPC分类号： C08K5/05 , C08K5/42 , Y10T428/1352 , Y10T428/139 , C08L43/04
摘要： Polymer compositions comprise a (i) silane-functionalized polymer, e.g., a polyethylene grafted with vinyl triethoxy silane, (H) polyfunctional alcohol e.g., α,α,α′,α′˜tetramethyl-I,3-benzenediethanol and, optionally, (iii) acid, e.g., an alkylated aryl disulfonic acid. The use of polyfunctional alcohols in the absence of a strong acid yields a light-crosslinking of the silane-functionalized polymer and this, in turn, provides a polymer melt with improved extensional properties such as elongational viscosity and melt strength. The use of a polyfunctional alcohol in combination with a blocked strong acid provides a slow rate of crosslinking during melt processing and a high degree of ultimate crosslinking after the polymer composition has been shaped or molded.
摘要翻译：聚合物组合物包含（i）硅烷官能化聚合物，例如用乙烯基三乙氧基硅烷接枝的聚乙烯，（H）多官能醇，例如α，α，α'，α'-四甲基-1,3-苯二甲醇，（iii）酸，例如烷基化芳基二磺酸。在不存在强酸的情况下使用多官能醇产生硅烷官能化聚合物的轻交联，这又提供具有改进的拉伸性能如伸长粘度和熔体强度的聚合物熔体。使用多官能醇与封闭的强酸组合提供了在熔融加工过程中缓慢的交联速率，以及在聚合物组合物成型或模制之后的高度极限交联。

9. 发明申请

US20100297374A1 In Situ Moisture Generation and Use of Polyfunctional Alcohols for Crosslinking of Silane-Functionalized Resins 有权
标题翻译：多官能醇的原位水分产生和使用用于硅烷官能化树脂的交联
公开(公告)号：US20100297374A1
公开(公告)日：2010-11-25
申请号：US12740838
申请日：2008-10-13
申请人： Bharat I. Chaudhary , Jeffrey M. Cogen , Saurav S. Sengupta
发明人： Bharat I. Chaudhary , Jeffrey M. Cogen , Saurav S. Sengupta
IPC分类号： B32B1/08 , C08G77/00 , C08F30/08 , B05D5/12 , H01B3/00
CPC分类号： C08K5/05 , C08K5/42 , Y10T428/1352 , Y10T428/139 , C08L43/04
摘要： Polymer compositions comprise a (i) silane-functionalized polymer, e.g., a polyethylene grafted with vinyl triethoxy silane, (H) polyfunctional alcohol e.g., α,α,α′,α′˜tetramethyl-I,3-benzenediethanol and, optionally, (iii) acid, e.g., an alkylated aryl disulfonic acid. The use of polyfunctional alcohols in the absence of a strong acid yields a light-crosslinking of the silane-functionalized polymer and this, in turn, provides a polymer melt with improved extensional properties such as elongational viscosity and melt strength. The use of a polyfunctional alcohol in combination with a blocked strong acid provides a slow rate of crosslinking during melt processing and a high degree of ultimate crosslinking after the polymer composition has been shaped or molded.
摘要翻译：聚合物组合物包含（i）硅烷官能化聚合物，例如用乙烯基三乙氧基硅烷接枝的聚乙烯，（H）多官能醇，例如α，α，α'，α'-四甲基-1,3-苯二甲醇，（iii）酸，例如烷基化芳基二磺酸。在不存在强酸的情况下使用多官能醇产生硅烷官能化聚合物的轻交联，这又提供具有改进的拉伸性能如伸长粘度和熔体强度的聚合物熔体。使用多官能醇与封闭的强酸组合提供了在熔融加工过程中缓慢的交联速率，以及在聚合物组合物成型或模制之后的高度极限交联。

10. 发明申请

US20120175809A1 Process for Making Crosslinked Injection Molded Articles 审中-公开
标题翻译：制造交联注塑制品的工艺
公开(公告)号：US20120175809A1
公开(公告)日：2012-07-12
申请号：US13496523
申请日：2010-09-14
申请人： Mohamed Esseghir , Saurav S. Sengupta
发明人： Mohamed Esseghir , Saurav S. Sengupta
IPC分类号： B29C45/00 , B29C45/72
CPC分类号： C08J3/244 , C08J2351/06
摘要： An injection molding process for making a plastic article, the process comprising the steps of: A. Forming a moisture-curable composition comprising a 1. Silane-functionalized polyethylene, 2. Moisture source, e.g., a moisture-containing filler, wherein the moisture source excludes alcohols, and 3. Condensation catalyst; B. Injecting the composition into a mold; C. Subjecting the composition to conditions sufficient to 1. Release moisture from the moisture source, and 2. Partially cure the composition; D. Removing the partially cured composition from the mold; and E. Continuing the cure of the composition outside of the mold. The process is particularly well suited for the manufacture of thick parts, such as wire and cable elastomeric connectors.
摘要翻译：一种用于制造塑料制品的注射成型方法，该方法包括以下步骤：A.形成包含1.硅烷官能化聚乙烯的湿气固化组合物，2.水分源，例如含水分的填料，其中水分来源不包括醇类，和3.缩合催化剂; B.将组合物注入模具; C.使组合物达到足以从水分源释放水分的条件，和2.部分固化组合物; D.从模具中取出部分固化的组合物; 和E.继续固化组合物在模具外面。该方法特别适用于制造厚部件，例如电线和电缆弹性体连接器。

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