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1. 发明授权

US08076264B2 Conductive substance-adsorbing resin film, method for producing conductive substance-adsorbing resin film, metal layer-coated resin film using the same, and method for producing metal layer-coated resin film 有权
标题翻译：导电性物质吸附树脂膜，导电性物质吸附树脂膜的制造方法，使用该导电性物质吸附树脂膜的金属层被覆树脂膜以及金属层被覆树脂膜的制造方法
公开(公告)号：US08076264B2
公开(公告)日：2011-12-13
申请号：US12593922
申请日：2008-01-11
申请人： Mitsuyuki Tsurumi , Shiki Ueki
发明人： Mitsuyuki Tsurumi , Shiki Ueki
IPC分类号： B01J20/26 , B01J20/00 , B01J20/22
CPC分类号： H05K3/387 , C23C18/1641 , C23C18/1653 , C23C18/1658 , C23C18/206 , C23C18/208 , C23C18/2086 , C23C18/24 , C23C18/26 , C23C18/285 , C23C18/30 , C25D5/56 , H05K1/0393 , H05K3/105 , H05K3/426 , H05K2203/1105 , H05K2203/1157 , H05K2203/121 , Y10T156/1052 , Y10T156/1062
摘要： The invention provides a conductive substance-adsorbing resin film on which a conductive layer being excellent in adhesion to the resin film and having less unevenness at the interface with the resin film can easily be formed, a method for producing the same, a metal layer-coated resin film on which a high definition wiring excellent in adhesion to the insulating resin film can easily be formed, which is obtained by using the conductive substance-adsorbing resin film of the invention, and a method for producing a metal layer-coated resin film that is a material capable of easily producing a printed-wiring board having a high definition wiring. The invention also provides a conductive substance-adsorbing resin film including at least two resin layers, wherein at least one of the resin layers is an adsorbing resin layer having a property of adsorbing a conductive substance or a metal. This conductive substance-adsorbing resin film is allowed to adsorb a metal and subjected to plating, whereby a metal layer-coated resin film can be obtained.
摘要翻译：本发明提供一种导电性物质吸附树脂膜，其中可以容易地形成其与树脂膜的粘附性优异并且在与树脂膜的界面处具有较小不均匀性的导电层，其制造方法，金属层 - 通过使用本发明的导电性物质吸附树脂膜可以容易地形成具有优异的与绝缘树脂膜的粘附性的高分辨率布线的涂布树脂膜，以及金属层涂覆树脂膜的制造方法这是能够容易地制造具有高清晰度布线的印刷电路板的材料。本发明还提供一种包含至少两个树脂层的导电物质吸附树脂膜，其中至少一个树脂层是具有吸附导电物质或金属的吸附树脂层。使该导电性物质吸附树脂膜吸附金属并进行电镀，由此可以得到金属层被覆的树脂膜。

2. 发明申请

US20100113264A1 CONDUCTIVE SUBSTANCE-ADSORBING RESIN FILM, METHOD FOR PRODUCING CONDUCTIVE SUBSTANCE-ADSORBING RESIN FILM, METAL LAYER-COATED RESIN FILM USING THE SAME, AND METHOD FOR PRODUCING METAL LAYER-COATED RESIN FILM 有权
标题翻译：导电性物质 - 吸附树脂膜，用于生产导电性物质 - 吸附树脂膜的方法，使用其的金属层涂覆树脂膜以及用于生产金属层涂树脂膜的方法
公开(公告)号：US20100113264A1
公开(公告)日：2010-05-06
申请号：US12593922
申请日：2008-01-11
申请人： Mitsuyuki Tsurumi , Shiki Ueki
发明人： Mitsuyuki Tsurumi , Shiki Ueki
IPC分类号： B01J20/26 , B32B37/14 , B32B38/04
CPC分类号： H05K3/387 , C23C18/1641 , C23C18/1653 , C23C18/1658 , C23C18/206 , C23C18/208 , C23C18/2086 , C23C18/24 , C23C18/26 , C23C18/285 , C23C18/30 , C25D5/56 , H05K1/0393 , H05K3/105 , H05K3/426 , H05K2203/1105 , H05K2203/1157 , H05K2203/121 , Y10T156/1052 , Y10T156/1062
摘要： The invention provides a conductive substance-adsorbing resin film on which a conductive layer being excellent in adhesion to the resin film and having less unevenness at the interface with the resin film can easily be formed, a method for producing the same, a metal layer-coated resin film on which a high definition wiring excellent in adhesion to the insulating resin film can easily be formed, which is obtained by using the conductive substance-adsorbing resin film of the invention, and a method for producing a metal layer-coated resin film that is a material capable of easily producing a printed-wiring board having a high definition wiring. The invention also provides a conductive substance-adsorbing resin film including at least two resin layers, wherein at least one of the resin layers is an adsorbing resin layer having a property of adsorbing a conductive substance or a metal. This conductive substance-adsorbing resin film is allowed to adsorb a metal and subjected to plating, whereby a metal layer-coated resin film can be obtained.
摘要翻译：本发明提供一种导电性物质吸附树脂膜，其中可以容易地形成其与树脂膜的粘附性优异并且在与树脂膜的界面处具有较小不均匀性的导电层，其制造方法，金属层 - 通过使用本发明的导电性物质吸附树脂膜可以容易地形成具有优异的与绝缘树脂膜的粘附性的高分辨率布线的涂布树脂膜，以及金属层涂覆树脂膜的制造方法这是能够容易地制造具有高清晰度布线的印刷电路板的材料。本发明还提供一种包含至少两个树脂层的导电物质吸附树脂膜，其中至少一个树脂层是具有吸附导电物质或金属的吸附树脂层。使该导电性物质吸附树脂膜吸附金属并进行电镀，由此可以得到金属层被覆的树脂膜。

3. 发明申请

US20090269599A1 MULTILAYER FILM FOR PLATING, METHOD OF MANUFACTURING METAL FILM-COATED MATERIAL AND METAL FILM-COATED MATERIAL 有权
标题翻译：多层薄膜，金属薄膜包覆材料和金属薄膜材料的制造方法
公开(公告)号：US20090269599A1
公开(公告)日：2009-10-29
申请号：US12427761
申请日：2009-04-22
申请人： Mitsuyuki Tsurumi
发明人： Mitsuyuki Tsurumi
IPC分类号： B32B15/08 , B05D3/00 , B32B27/00
CPC分类号： H05K3/387 , C23C18/1653 , C23C18/2086 , H05K2203/066 , Y10T428/31681 , Y10T428/31721
摘要： Disclosed is a multilayer film for plating comprising, on a surface of a first substrate, a plating receptive layer which contains a polymer having a polymerizable group and a functional group, wherein the plating receptive layer satisfies at least one of the following (1)-(4): (1) the saturated water absorption ratio is from 0.01 to 10% by mass in an environment of a temperature of 25° C. and relative humidity of 50%; (2) the saturated water absorption ratio is from 0.05 to 20% by mass in an environment of a temperature of 25° C. and relative humidity of 95%; (3) the water absorption ratio is from 0. 1 to 30% by mass after immersion in boiling water at 100° C. for one hour; and (4) the surface contact angle of distilled water is from 50° to 150° after 5 μl of the distilled water is dropped onto the plating receptive layer and allowed to stand for 15 seconds in an environment of a temperature of 25° C. and relative humidity of 50%.
摘要翻译：公开了一种用于电镀的多层膜，其包括在第一衬底的表面上含有具有聚合性基团和官能团的聚合物的电镀接受层，其中电镀接受层满足以下（1） - （4）：（1）在温度25℃，相对湿度50％的环境下，饱和吸水率为0.01〜10质量％（2）在温度25℃，相对湿度95％的环境下，饱和吸水率为0.05〜20质量％。（3）在100℃的沸水中浸渍1小时后，吸水率为0.1〜30质量％和（4）蒸馏水的表面接触角为50°〜150°，蒸馏水滴入镀层后，在25℃的温度环境下静置15秒。相对湿度为50％。

4. 发明授权

US06864032B2 Method for forming azo colorant using diazo compound and coupler having leaving group and recording material using the coupler 失效
标题翻译：使用重氮化合物和具有离去基团的成色剂和使用该成色剂的记录材料形成偶氮着色剂的方法
公开(公告)号：US06864032B2
公开(公告)日：2005-03-08
申请号：US09836236
申请日：2001-04-18
申请人： Hisao Yamada , Mitsuyuki Tsurumi , Kazunori Nigorikawa
发明人： Hisao Yamada , Mitsuyuki Tsurumi , Kazunori Nigorikawa
IPC分类号： G11B7/12 , G11B7/135 , G11B7/22 , G03F7/021
CPC分类号： B82Y10/00 , G11B7/122 , G11B7/1353 , G11B7/1359 , G11B7/1384 , G11B7/1387 , G11B7/22
摘要： The present invention provides a method for forming an azo colorant by reaction of a diazo compound and a coupler. The coupler has a leaving group at the coupling position thereof, such that a coupling reaction rate is faster than it would be if the coupler did not have the leaving group. The coupling reaction rate constant k is preferably 0.1 (s−1) or more.
摘要翻译：本发明提供了通过重氮化合物和偶联剂的反应形成偶氮着色剂的方法。耦合器在其耦合位置处具有离去基团，使得耦合反应速率比如果耦合剂不具有离去基团时更快。偶合反应速度常数k优选为0.1（s -1）以上。

5. 发明授权

US06787502B2 Guanidine compound and heat sensitive recording material 失效
标题翻译：胍化合物和热敏记录材料
公开(公告)号：US06787502B2
公开(公告)日：2004-09-07
申请号：US09907566
申请日：2001-07-19
申请人： Naoto Yanagihara , Hisao Yamada , Mitsuyuki Tsurumi
发明人： Naoto Yanagihara , Hisao Yamada , Mitsuyuki Tsurumi
IPC分类号： B41M530
CPC分类号： B41M5/3375 , C07C279/18
摘要： An object of the present invention is to provide a heat sensitive recording material which can develop color at high density by the inclusion of a novel guanidine compound which is strongly basic and superior in diffusion resistance. The present invention for attaining the above-described object is a heat sensitive recording material comprising a substrate supporting thereon a heat sensitive recording layer containing a diazonium salt compound, a coupler which reacts with the diazonium salt compound when heated to develop color, and a base, wherein the heat sensitive recording layer includes as the base at least one of the guanidine compounds represented by the general formula (1): wherein, in the general formula (1), R1 and R2 represent an alkyl group or aryl group and may be the same or different, R3 and R4 represent a hydrogen atom, alkyl group or halogen atom and may be the same or different, and X represents a divalent connecting group.
摘要翻译：本发明的目的是提供一种热敏记录材料，其通过包含强碱性和优异的扩散阻力的新型胍化合物，可以以高密度显色。用于实现上述目的的本发明是一种热敏记录材料，其包括在其上支撑含有重氮盐化合物的热敏记录层的基底，加热显色时与重氮盐化合物反应的成色剂，以及碱其特征在于，所述热敏记录层包含由通式（1）表示的至少一种胍化合物作为碱的基：其中，在通式（1）中，R 1和R 2表示烷基或芳基，可以相同或不同，R 3和R 4表示氢原子，烷基或卤素原子，可以相同或不同，X表示二价连接基团。

6. 发明授权

US06348529B1 Guanidine compound and heat sensitive recording material 失效
标题翻译：胍化合物和热敏记录材料
公开(公告)号：US06348529B1
公开(公告)日：2002-02-19
申请号：US09477545
申请日：2000-01-04
申请人： Naoto Yanagihara , Hisao Yamada , Mitsuyuki Tsurumi
发明人： Naoto Yanagihara , Hisao Yamada , Mitsuyuki Tsurumi
IPC分类号： C07C27700
CPC分类号： B41M5/3375 , C07C279/18
摘要： An object of the present invention is to provide a heat sensitive recording material which can develop color at high density by the inclusion of a novel guanidine compound which is strongly basic and superior in diffusion resistance. The present invention for attaining the above-described object is a heat sensitive recording material comprising a substrate supporting thereon a heat sensitive recording layer containing a diazonium salt compound, a coupler which reacts with the diazonium salt compound when heated to develop color, and abase, wherein the heat sensitive recording layer includes as the base at least one of the guanidine compounds represented by the general formula (1): wherein, in the general formula (1), R1 and R2 represent an alkyl group or aryl group and may be the same or different, R3 and R4 represent a hydrogen atom, alkyl group or halogen atom and may be the same or different, and X represents a divalent connecting group.
摘要翻译：本发明的目的是提供一种热敏记录材料，其通过包含强碱性和优异的扩散阻力的新型胍化合物，可以以高密度显色。用于实现上述目的的本发明是一种热敏记录材料，其包括在其上支撑含有重氮盐化合物的热敏记录层的基底，加热显色时与重氮盐化合物反应的成色剂，其中，所述热敏记录层包含至少一种由通式（1）表示的胍化合物作为碱的基：其中，在通式（1）中，R 1和R 2表示烷基或芳基，可以是相同或不同，R 3和R 4表示氢原子，烷基或卤素原子，可以相同或不同，X表示二价连接基团。

7. 发明授权

US06346359B1 Pyrrolopyrimidineone compound and heat-sensitive recording material using the same 失效
标题翻译：吡咯并嘧啶酮化合物和使用其的热敏记录材料
公开(公告)号：US06346359B1
公开(公告)日：2002-02-12
申请号：US09557871
申请日：2000-04-24
申请人： Hisao Yamada , Mitsuyuki Tsurumi , Kazunori Nigorikawa
发明人： Hisao Yamada , Mitsuyuki Tsurumi , Kazunori Nigorikawa
IPC分类号： G03C172
CPC分类号： C07D487/04 , B41M5/287 , G03C1/58
摘要： Disclosed are a pyrrolopyrimidineone compound represented by the following general formula (1) and a heat-sensitive recording material using the pyrrolopyrimidineone compound as a coupler: General formula (1) wherein R1 and R2 each independently represents a hydrogen atom, a halogen atom, an aryl group, an alkyl group, a cyano group, an acyl group, a carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylsulfonyl group, or an arylsulfonyl group; R3 represents an amino group, a substituted amino group, a hydroxyl group, an acyloxy group, an arylcarboxyl group, an alkoxy group, an aryloxy group, an alkylthio group, or an arylthio group; R4 represents a hydrogen atom, a halogen atom, or an electron attracting group whose Hammett substituent constant &sgr;p is 0.2 or more; and L represents a substituent group which can leave when the compound reacts with a diazonium salt. The pyrrolopyrimidineone compound produces a good purple to cyan color hue and a sufficient color density.
摘要翻译：公开了由以下通式（1）表示的吡咯并嘧啶酮化合物和使用吡咯并嘧啶酮化合物作为偶联剂的热敏记录材料：通式（1）其中R 1和R 2各自独立地表示氢原子，卤素原子，芳基，烷基，氰基，酰基，氨基甲酰基，烷氧基羰基，芳氧基羰基，烷基磺酰基或芳基磺酰基; R3表示氨基，取代氨基，羟基，酰氧基，芳基羧基，烷氧基，芳氧基，烷硫基或芳硫基; R4表示氢原子，卤素原子或哈米特取代基常数sigmap为0.2以上的吸电子基团; L表示当化合物与重氮盐反应时可以离开的取代基。吡咯并嘧啶酮化合物产生良好的紫色至青色色调和足够的色密度。

8. 发明授权

US06228553B1 Pyrrolo [1,2-A] pyrimidine compound and heat-sensitive recording material using the same 失效
标题翻译：吡咯并[1,2-A]嘧啶化合物和使用其的热敏记录材料
公开(公告)号：US06228553B1
公开(公告)日：2001-05-08
申请号：US09349364
申请日：1999-07-08
申请人： Tetsunori Matsushita , Naoto Yanagihara , Masanobu Takashima , Mitsuyuki Tsurumi
发明人： Tetsunori Matsushita , Naoto Yanagihara , Masanobu Takashima , Mitsuyuki Tsurumi
IPC分类号： G03C158
CPC分类号： C07D487/04 , G03C1/002 , G03C1/54
摘要： A pyrrolo[1,2-a]pyrimidine compound providing an excellent color-forming property is provided. Further, a novel cyan color-forming type diazo heat-sensitive recording material having excellent shelf life, image light-resistance and image fixing property is provided. The pyrrolo[1,2-a]pyrimidine compound is represented by following general formula (1). The heat-sensitive recording material comprises a substrate, and on the substrate, a heat-sensitive recording layer containing a diazonium salt compound and a coupler. The coupler contains at least one of pyrrolo[1,2-a]pyrimidine compounds represented by following general formula (1). In the formula, R1 represents an aryl group or the like, R2 represents an alkoxycarbonyl group or the like, R3 and R4 represent an acyl group or the like, and R5 represents a hydrogen atom or the like.
摘要翻译：提供了提供优异的成色性能的吡咯并[1,2-a]嘧啶化合物。此外，提供了具有优异的保存期限，图像耐光性和图像定影性的新型青色成色型重氮感光记录材料。吡咯并[1,2-a]嘧啶化合物由以下通式（1）表示。热敏记录材料包括基底，并且在基底上，含有重氮盐化合物和成色剂的热敏记录层。成色剂含有由以下通式（1）表示的吡咯并[1,2-a]嘧啶化合物中的至少一种。在该式中，R 1表示芳基等，R 2表示烷氧基羰基等，R 3和R 4表示酰基等，R 5表示氢原子等。

9. 发明授权

US06749908B2 Multicolor heat-sensitive recording material 失效
标题翻译：多色热敏记录材料
公开(公告)号：US06749908B2
公开(公告)日：2004-06-15
申请号：US10201493
申请日：2002-07-24
申请人： Mitsuyuki Tsurumi
发明人： Mitsuyuki Tsurumi
IPC分类号： B41M526
CPC分类号： G03C1/52 , B41M5/30 , B41M5/34
摘要： Disclosed is a multicolor heat-sensitive recording material at least having a yellow-forming heat-sensitive recording material, a cyan-forming heat-sensitive recording material, and a magenta-forming heat-sensitive recording material disposed on a support, characterized in that, if laminates are made of a transparent support, a single layer of these heat-sensitive recording layers, and a protective layer in the order listed, the haze values of the laminates are all not greater than 40.
摘要翻译：公开了一种多色热敏记录材料，其至少具有黄色形成的热敏记录材料，形成青色的热敏记录材料和设置在支撑体上的品红成型热敏记录材料，其特征在于：如果层压体由透明支撑体，这些热敏记录层的单层和按照列出的顺序制成保护层，则层压体的雾度值均不大于40。

10. 发明授权

US5683850A Diazo heat-sensitive recording material comprising hydroxy coumarin as a coupler 失效
标题翻译：包含羟基香豆素作为成色剂的重氮热敏记录材料
公开(公告)号：US5683850A
公开(公告)日：1997-11-04
申请号：US753886
申请日：1996-12-02
申请人： Tetunori Matushita , Hiroshi Sato , Sadao Ishige , Kimiatsu Nomura , Mitsuyuki Tsurumi
发明人： Tetunori Matushita , Hiroshi Sato , Sadao Ishige , Kimiatsu Nomura , Mitsuyuki Tsurumi
IPC分类号： B41M5/323 , B41M5/28 , B41M5/30 , G03C1/52 , G03C1/54 , G03C1/58 , G03F7/021
CPC分类号： G03C1/54 , G03C1/58 , G03C1/52
摘要： A diazo heat-sensitive recording material having excellent raw stock storability and image storage characteristics, which comprises a support having thereon a recording layer comprising a diazo compound, a coupling component and an organic base. The diazo compound is a 4-disubstituted amino-2-alkoxybenzenediazonium salt and the coupling component is a compound represented by the following general formula: ##STR1## wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 each represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, an alkyloxy group, an aryloxy group, an alkylthio group, an arylthio group, an acyl group, an alkoxycarbonyl group, an acyloxy group, a carbamoyl group, a sulfamoyl group, a halogen atom, a cyano group or a nitro group.
摘要翻译：一种具有优良原始储存性和图像保存特性的重氮热敏记录材料，其包括其上具有包含重氮化合物，偶联组分和有机碱的记录层的载体。重氮化合物是4-二取代的氨基-2-烷氧基苯并重氮盐，偶联组分是由以下通式表示的化合物：其中R 4，R 5，R 6和R 7各自表示氢原子，烷基，芳基，芳烷基，烷氧基，芳氧基，烷硫基，芳硫基，酰基，烷氧基羰基，酰氧基，氨基甲酰基，氨磺酰基，卤素原子，氰基或硝基。

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