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1. 发明授权

US06329049B1 Pressure-sensitive adhesive and surface protecting material 有权
标题翻译：压敏胶和表面保护材料
公开(公告)号：US06329049B1
公开(公告)日：2001-12-11
申请号：US09280676
申请日：1999-03-29
申请人： Mitsuyoshi Shirai , Isamu Teranishi , Hideki Mitsuda , Akira Taguchi , Kenji Sano , Komaharu Matsui , Takeshi Eda , Hiroshi Ueda
发明人： Mitsuyoshi Shirai , Isamu Teranishi , Hideki Mitsuda , Akira Taguchi , Kenji Sano , Komaharu Matsui , Takeshi Eda , Hiroshi Ueda
IPC分类号： C08L2322
CPC分类号： C08K5/14 , C08K5/05 , C08K5/09 , C08L2023/42 , C08L2666/28 , C09J123/22 , Y10T428/2839 , Y10T428/2857 , Y10T428/2883 , Y10T428/2891 , C08L23/22
摘要： A pressure-sensitive adhesive comprising 100 parts by weight of an isobutylene polymer having been masticated in an organic solvent with a radical generator and 0.001 to 5 parts by weight of at least one release control agent selected from the group consisting of an alcohol having a molecular weight of 90 to 300 and an oxygen atom content of 8.5% or more or a derivative thereof and a carboxylic acid having a molecular weight of 70 to 400 and an oxygen atom content of 11% or more or a derivative thereof; and a surface protecting material having a pressure-sensitive adhesive layer comprising the adhesive. The adhesive has well-balanced characteristics in initial adhesion, retention of initial adhesion, and weather resistance.
摘要翻译：一种压敏粘合剂，其包含100重量份的在有机溶剂中用自由基发生剂捏合的异丁烯聚合物和0.001至5重量份的选自以下的释放控制剂：具有分子重量为90〜300，氧原子含量为8.5％以上，或其衍生物和分子量为70〜400，氧原子含量为11％以上的羧酸或其衍生物; 以及具有包含所述粘合剂的压敏粘合剂层的表面保护材料。粘合剂在初始粘合性，初始粘合保持性和耐候性方面具有良好的平衡特性。

2. 发明授权

US06335090B1 Pressure-sensitive adhesive and surface protecting material comprising an isobutylene polymer 有权
标题翻译：包含异丁烯聚合物的压敏粘合剂和表面保护材料
公开(公告)号：US06335090B1
公开(公告)日：2002-01-01
申请号：US09277946
申请日：1999-03-29
申请人： Mitsuyoshi Shirai , Keiji Hayashi , Kenichi Shibata , Mitsuru Horada , Tsuyoshi Inoue , Kenji Sano , Komaharu Matsui , Takeshi Eda , Hiroshi Ueda
发明人： Mitsuyoshi Shirai , Keiji Hayashi , Kenichi Shibata , Mitsuru Horada , Tsuyoshi Inoue , Kenji Sano , Komaharu Matsui , Takeshi Eda , Hiroshi Ueda
IPC分类号： B32B706
CPC分类号： C08K5/09 , C08K5/05 , C08L2666/28 , C09J123/22 , Y10T428/28 , Y10T428/2852 , Y10T428/2857 , C08L23/22
摘要： A pressure-sensitive adhesive comprising 100 parts by weight of an isobutylene polymer and 0.001 to 5 parts by weight of at least one release control agent selected from the group consisting of an alcohol having a molecular weight of 90 to 300 and an oxygen atom content of 8.5% or more or a derivative thereof and a carboxylic acid having a molecular weight of 70 to 400 and an oxygen atom content of 11% or more or a derivative thereof; and a surface protecting material having a pressure-sensitive adhesive layer comprising the adhesive. The adhesive has well-balanced characteristics in initial adhesion, retention of initial adhesion, and weather resistance.
摘要翻译：一种压敏粘合剂，其包含100重量份的异丁烯聚合物和0.001至5重量份的至少一种脱模控制剂，其选自分子量为90至300的醇和氧原子含量为 8.5％以上或其衍生物和分子量为70〜400，氧原子含量为11％以上的羧酸或其衍生物; 以及具有包含所述粘合剂的压敏粘合剂层的表面保护材料。粘合剂在初始粘合性，初始粘合保持性和耐候性方面具有良好的平衡特性。

3. 发明授权

US06358600B1 Sheet for protecting paint film 失效
标题翻译：保护漆膜片
公开(公告)号：US06358600B1
公开(公告)日：2002-03-19
申请号：US09095894
申请日：1998-06-11
申请人： Keiji Hayashi , Tsuyoshi Inoue , Kenichi Shibata , Kenji Sano , Mitsuyoshi Shirai , Mitsuru Horada , Hiroshi Sugawa , Komaharu Matsui , Takeshi Eda , Hiroshi Ueda
发明人： Keiji Hayashi , Tsuyoshi Inoue , Kenichi Shibata , Kenji Sano , Mitsuyoshi Shirai , Mitsuru Horada , Hiroshi Sugawa , Komaharu Matsui , Takeshi Eda , Hiroshi Ueda
IPC分类号： B32B326
CPC分类号： B32B5/18 , C09J7/21 , C09J7/26 , C09J7/38 , C09J2203/306 , C09J2400/263 , C09J2400/283 , Y10T428/249982 , Y10T428/249983 , Y10T428/28 , Y10T428/2848 , Y10T428/2852 , Y10T442/2795
摘要： A sheet for protecting a paint film which does not deteriorate or discolor the paint film even when the sheet is adhered to protect the paint film under the condition containing acidic rainwater or detergent and can maintain the adhered state over an extended-period of time without peeling off is disclosed. The sheet for protecting a paint film comprises a porous substrate and a pressure-sensitive adhesive layer formed on one surface of the porous substrate. The sheet has an air permeability in a direction of sheet thickness of 20,000 sec/100 cc or more and a moisture permeability in a direction of sheet thickness of 2,000 g/m2·24 hr or more. The sheet for protecting a paint film further comprises a porous substrate and a pressure-sensitive adhesive layer formed on one surface of the porous substrate, wherein the porous substrate has an ultraviolet transmission of 10% or less at a wavelength of from 190 to 370 nm.
摘要翻译：用于保护即使粘合片材也不会使漆膜劣化或变色的漆膜的片材，以在含有酸性雨水或洗涤剂的条件下保护漆膜，并且可以在不剥离的情况下长时间保持粘附状态公开。用于保护漆膜的片材包括多孔基材和形成在多孔基材的一个表面上的压敏粘合剂层。片材的厚度方向的透气度为20,000秒/ 100cc以上，片材厚度方向的透湿性为2000g / m 2·24小时以上。用于保护漆膜的片材还包括多孔基材和形成在多孔基材的一个表面上的压敏粘合剂层，其中多孔基材在波长为190至370nm的紫外线透过率为10％以下。

4. 发明授权

US06083613A Sheet for protecting paint film 失效
标题翻译：保护漆膜片
公开(公告)号：US06083613A
公开(公告)日：2000-07-04
申请号：US084991
申请日：1998-05-28
申请人： Keiji Hayashi , Mitsuyoshi Shirai , Kenji Sano , Tsuyoshi Inoue , Kenichi Shibata , Mitsuru Horada , Komaharu Matsui , Takeshi Eda , Hiroshi Ueda
发明人： Keiji Hayashi , Mitsuyoshi Shirai , Kenji Sano , Tsuyoshi Inoue , Kenichi Shibata , Mitsuru Horada , Komaharu Matsui , Takeshi Eda , Hiroshi Ueda
IPC分类号： B32B27/32 , C09J7/02 , C09J123/22 , C09J153/00 , B32B7/12
CPC分类号： C09J7/0296 , B32B27/32 , C09J2201/162 , C09J2203/306 , C09J2400/263 , Y10T428/249979 , Y10T428/24998 , Y10T428/249983 , Y10T428/249985 , Y10T428/2883
摘要： A sheet for protecting a paint film is disclosed, which does not cause deterioration or discoloration the paint film even when the sheet is adhered to protect the paint film under the condition containing water or water vapor over a long period of time and thus can maintain the adhered state without peeled off the sheet. The sheet for protecting a paint film comprises a multi-layer substrate comprising a water or water vapor barrier layer as a surface layer and a water or water vapor-permeable layer as a back, and a pressure-sensitive adhesive layer formed on the water or water vapor-permeable layer.
摘要翻译：公开了一种用于保护漆膜的片材，即使在粘合片材以在长时间内含有水或水蒸汽的条件下保护漆膜也不会导致漆膜劣化或变色，因此可以保持粘附状态而不剥离片材。用于保护漆膜的片材包括多层基材，其包含作为表面层的水或水蒸气阻隔层和作为背面的水或水蒸气可透过层，以及形成在水或其上的压敏粘合剂层水蒸气透过层。

5. 发明授权

US6037054A Sheet for protecting paint film 失效
标题翻译：保护漆膜片
公开(公告)号：US6037054A
公开(公告)日：2000-03-14
申请号：US948785
申请日：1997-10-10
申请人： Mitsuyoshi Shirai , Tomohide Bamba , Keiji Hayashi , Isao Hirose , Kenji Sano , Toshiyuki Umehara , Komaharu Matsui , Takeshi Eda , Hiroshi Ueda
发明人： Mitsuyoshi Shirai , Tomohide Bamba , Keiji Hayashi , Isao Hirose , Kenji Sano , Toshiyuki Umehara , Komaharu Matsui , Takeshi Eda , Hiroshi Ueda
IPC分类号： C08L23/22 , C09J7/02 , C09J123/22 , B32B7/12
CPC分类号： C09J123/22 , C09J7/0246 , C08L23/22 , C09J2203/306 , Y10T428/14 , Y10T428/1452 , Y10T428/1471 , Y10T428/2852 , Y10T428/2857 , Y10T428/2878 , Y10T428/2883
摘要： A sheet for protecting paint film comprising a support having formed thereon a rubber adhesive layer comprising an isobutylene polymer having a degree of dispersion of from 1 to 2.3 and a weight average molecular weight of 300,000 to 600,000 (the domain A in the FIGURE) as the base polymer.The paint film protecting sheet has the compatibility of the prevention of the occurrence of a microdeformation and a good peelability. That is, when an article such as automobiles having a paint film applied with the protecting sheet is placed outdoors for a long period of time at high temperature, the paint film is hard to deform and the sheet can be easily peeled even after adhering for a long period of time.
摘要翻译：一种用于保护涂膜的片材，其包括其上形成有橡胶粘合剂层的载体，所述橡胶粘合剂层包含分散度为1至2.3，重均分子量为300,000至600,000的异丁烯聚合物（图中的域A）为基础聚合物。涂膜保护片具有防止微变形发生和良好剥离性的相容性。也就是说，当具有涂有保护片的涂膜的汽车的物品在高温下长时间放置在室外时，漆膜难以变形，即使在粘附后也可以容易地剥离片材很长一段时间

6. 发明授权

US6030702A Sheet for protecting paint films of automobiles 失效
标题翻译：用于保护汽车漆膜的片材
公开(公告)号：US6030702A
公开(公告)日：2000-02-29
申请号：US728900
申请日：1996-10-10
申请人： Komaharu Matsui , Takeshi Eda , Hiroshi Ueda , Mitsuyoshi Shirai , Kenji Sano , Mitsuru Horada , Naoyuki Nishiyama
发明人： Komaharu Matsui , Takeshi Eda , Hiroshi Ueda , Mitsuyoshi Shirai , Kenji Sano , Mitsuru Horada , Naoyuki Nishiyama
IPC分类号： C08L23/20 , C09J7/02 , C09J123/20
CPC分类号： C09J7/0246 , C08L23/20 , C09J2203/306 , Y10T428/28 , Y10T428/2883
摘要： A sheet for protecting paint films of automobiles for adhering to the incompletely cured paint films of automobiles comprising two pack urethane paint, the sheet comprising a support and a pressure-sensitive adhesive layer formed thereon, wherein the sheet has a Young's modulus E of at least 75 N/mm.sup.2 and a coefficient of flexural stress k represented by the formula k=Eh.sup.3 wherein h is a thickness of the support, of 0.035 or less. The protective sheet can uniformly protect the paint films and easily be peeled and removed therefrom without causing environmental problems and adhesive remaining of the pressure-sensitive adhesive layer. Even when the sheet is adhered to incompletely cured paint films of automobiles and they are allowed to stand for a long period of time under an outside high temperature in summer, the sheet does not cause the deformation of the paint film and the microdeformations by the deformation of the paint film at the edge portion of the pressure-sensitive adhesive layer. The protective sheet can be reserved in a roll state without causing the change of form by, for example, a telescope phenomenon.
摘要翻译：一种用于保护汽车漆膜以粘附到不完全固化的汽车漆膜的片材，其包括两个包装氨基甲酸酯涂料，该片材包含支撑体和形成在其上的压敏粘合剂层，其中该片材的杨氏模量E至少为 75N / mm 2，并且由公式k = Eh3表示的弯曲应力k，其中h是载体的厚度，为0.035或更小。保护片可以均匀地保护漆膜，并且容易地剥离并除去，而不会引起环境问题，并且粘合剂层残留粘合剂。即使当片材附着在汽车的未完全固化的漆膜上，并且在夏天的外部高温下允许长时间放置时，片材不会引起漆膜的变形和变形的微变形在压敏粘合剂层的边缘部分处的漆膜。保护片可以保持在滚动状态，而不会由于例如望远镜现象而导致形状的改变。

7. 发明授权

US5612135A Paint-film protective sheet 失效
标题翻译：油漆膜保护片
公开(公告)号：US5612135A
公开(公告)日：1997-03-18
申请号：US396725
申请日：1995-03-01
申请人： Komaharu Matsui , Takeshi Eda , Mitsuo Wakimoto , Kenichi Shibata , Toshitaka Suzuki , Mitsuyoshi Shirai , Kenichi Okada , Tsuyoshi Inoue , Hiroyoshi Onishi , Taiki Kusaka
发明人： Komaharu Matsui , Takeshi Eda , Mitsuo Wakimoto , Kenichi Shibata , Toshitaka Suzuki , Mitsuyoshi Shirai , Kenichi Okada , Tsuyoshi Inoue , Hiroyoshi Onishi , Taiki Kusaka
IPC分类号： A01N25/34 , C09J7/02 , C09J11/06 , C09J121/00
CPC分类号： C09J7/0246 , A01N25/34 , C09J11/06 , C09J2203/306 , Y10T428/28 , Y10T428/2857 , Y10T428/31851
摘要： A paint film-protective sheet comprising a supporting substrate having formed thereon a rubber-based pressure-sensitive adhesive layer containing a fatty acid glycerol ester and an antifungal agent.
摘要翻译：一种漆膜保护片，其包括在其上形成有含有脂肪酸甘油酯和抗真菌剂的橡胶系压敏粘合剂层的支撑基材。

8. 发明授权

US08901242B2 Composite film 有权
标题翻译：复合膜
公开(公告)号：US08901242B2
公开(公告)日：2014-12-02
申请号：US12678442
申请日：2009-04-08
申请人： Hidenori Suzuki , Masanori Uesugi , Makoto Kai , Mitsuyoshi Shirai
发明人： Hidenori Suzuki , Masanori Uesugi , Makoto Kai , Mitsuyoshi Shirai
IPC分类号： B32B27/00 , B32B27/40 , C03C25/10 , C08F2/50 , C08G18/08 , C08G18/28 , C08G73/10 , C08K5/34 , C08K5/48 , C08K5/3435 , C08L75/00 , C09J151/08 , C08G18/48 , C08G18/75 , C08L51/08 , C08F283/00
CPC分类号： C08G18/4854 , C08F283/006 , C08G18/757 , C08G2270/00 , C08L51/08 , C08L2666/02 , C09J151/08 , Y10T428/28 , Y10T428/31551
摘要： [Problem] To provide a composite film having light-curing property and weather resistance.[Means for solving] A composite film is one that comprises at least a urethane polymer, wherein both an initial b* value of the composite film measured by a spectrocolorimeter (value at an angle of 15 degrees) and a b* value after performing an accelerated weathering test for 120 hours (value at an angle of 15 degrees) are 4.0 or less, and a non-volatile component after heating the composite film at 130° C. for two hours is 96% or more.
摘要翻译：提供具有光固化性和耐候性的复合膜。 [解决方案]复合膜是至少包含氨基甲酸酯聚合物的复合膜，其中通过分光色差计测量的复合膜的初始b *值（15度角）和执行加速后的ab *值 120小时的风化试验（15度的角度）为4.0以下，在130℃下加热复合膜2小时后的非挥发性成分为96％以上。

9. 发明申请

US20100112346A1 ACRYLIC PRESSURE-SENSITIVE ADHESIVE TAPE OR SHEET AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：丙烯酸压敏胶带或其制造方法
公开(公告)号：US20100112346A1
公开(公告)日：2010-05-06
申请号：US12450136
申请日：2008-02-28
申请人： Takashi Kondou , Mitsuyoshi Shirai , Masanori Uesugi , Masayuki Okamoto , Kazuhisa Maeda
发明人： Takashi Kondou , Mitsuyoshi Shirai , Masanori Uesugi , Masayuki Okamoto , Kazuhisa Maeda
IPC分类号： B32B15/082 , B05D5/10
CPC分类号： C09J133/02 , C08K7/22 , C08L2205/20 , C08L2312/06 , C08L2666/04 , C09J7/29 , C09J7/385 , C09J2201/162 , C09J2205/106 , C09J2205/11 , C09J2433/00 , Y10T428/2809
摘要： Provided is an acrylic pressure-sensitive adhesive tape or sheet highly adhesive to hard-to-adhere adherends such as coatings having the surface control agent bleeding thereon.The acrylic pressure-sensitive adhesive tape or sheet, according to the present invention, having a viscoelastic layer (X) containing microspheres and an acrylic polymer containing an alkyl (meth)acrylate as the principal monomer component as the base polymer and a pressure-sensitive adhesive layer (Y) formed at least on one side of the viscoelastic layer (X) by irradiation of an acrylic monomer mixture or a prepolymer of the acrylic monomer mixture with active energy ray, wherein the amount of acrylic acid in the acrylic monomer mixture for the pressure-sensitive adhesive layer (Y) or a prepolymer of the acrylic monomer mixture is 6 to 12 wt % with respect to all monomer components and the amount of n-butyl acrylate is 35 to 65 wt % with respect to the total amount of 2-ethylhexyl acrylate and n-butyl acrylate.
摘要翻译：提供了一种与表面控制剂在其上渗色的诸如涂层之类的难以粘附的被粘物高度粘合的丙烯酸类压敏粘合带或片。根据本发明的丙烯酸类压敏粘合带或片材具有含有微球的粘弹性层（X）和含有（甲基）丙烯酸烷基酯作为主要单体成分的丙烯酸类聚合物作为基础聚合物，并具有压敏性通过丙烯酸类单体混合物或丙烯酸类单体混合物的预聚物与活性能量射线照射而形成在粘弹性层（X）的至少一侧上的粘合剂层（Y），其中丙烯酸类单体混合物中的丙烯酸用量丙烯酸系单体混合物的粘合剂层（Y）或预聚物相对于所有单体成分为6〜12重量％，丙烯酸正丁酯的含量相对于丙烯酸系单体的总量为35〜65重量％丙烯酸2-乙基己酯和丙烯酸正丁酯。

10. 发明申请

US20100080990A1 SHEET FOR PROTECTING COATINGS 审中-公开
标题翻译：防护涂料表
公开(公告)号：US20100080990A1
公开(公告)日：2010-04-01
申请号：US12450551
申请日：2008-03-31
申请人： Mitsuyoshi Shirai , Masanori Uesugi , Takashi Kondou , Masayuki Okamoto , Masahito Niwa
发明人： Mitsuyoshi Shirai , Masanori Uesugi , Takashi Kondou , Masayuki Okamoto , Masahito Niwa
IPC分类号： B32B27/32 , B32B27/06
CPC分类号： C09J153/00 , C08F293/00 , C08F293/005 , C08L33/06 , C08L2666/02 , C08L2666/04 , C09D153/00 , C09D153/02 , C09D153/025 , C09J7/381 , C09J121/00 , C09J123/22 , C09J153/02 , C09J153/025 , C09J2203/306 , C09J2409/00 , C09J2433/00 , C09J2453/00 , Y10T428/2852 , Y10T428/2878
摘要： Provided is a sheet for protecting coatings that shows superior adhesiveness even to coatings often causing low adhesive by bleeding for example of leveling agent and others without a washing treatment and the like, retains its preferable adhesion state for an extended period of time, and is easily releasable when separated even after being bonded for an extended period of time.The sheet for protecting coatings according to the present invention is characterized by including a supporting substrate and a pressure-sensitive adhesive layer formed at least on one side thereof, containing a rubber-based polymer and an aliphatic (meth)acrylic oligomer having a glass transition temperature of 30 to 100° C. and a weight-average molecular weight of 1000 to 20,000, wherein the blending amount of the (meth)acrylic oligomer is 0.02 to 1 wt part with respect to 100 wt parts of the rubber-based polymer.
摘要翻译：提供了一种用于保护涂层的片材，即使对于通常通过例如流平剂等流平剂而导致低粘合剂的涂层也没有洗涤处理等而具有优异的粘合性，在较长时间内保持其优选的粘附状态，并且容易即使在长时间粘合后也可分离。根据本发明的用于保护涂层的片材的特征在于包括支撑基材和至少一面形成的压敏粘合剂层，其包含橡胶基聚合物和具有玻璃化转变的脂族（甲基）丙烯酸低聚物温度为30〜100℃，重均分子量为1000〜20,000，其中，相对于100重量份的橡胶系聚合物，（甲基）丙烯酸系低聚物的配合量为0.02〜1重量份。

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