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1. 发明授权

US08598290B2 Method for producing fluorine-containing elastomer 有权
标题翻译：含氟弹性体的制造方法
公开(公告)号：US08598290B2
公开(公告)日：2013-12-03
申请号：US12307022
申请日：2007-06-29
申请人： Mitsuru Kishine , Masanori Kitaichi , Yousuke Nishimura , Manabu Fujisawa , Yoshiki Tanaka , Shintarou Ogata , Yutaka Ueta , Shigeru Morita
发明人： Mitsuru Kishine , Masanori Kitaichi , Yousuke Nishimura , Manabu Fujisawa , Yoshiki Tanaka , Shintarou Ogata , Yutaka Ueta , Shigeru Morita
IPC分类号： C08F14/18
CPC分类号： C08F214/18 , C08F14/18 , C08F2/22
摘要： The present invention provides a method of producing a fluoroelastomer excellent in dispersion stability at low cost, at a high rate of polymerization and in high yields. The present invention is a method of producing a fluoroelastomer comprising an emulsion polymerization of a fluorinated monomer in the presence of a water-soluble radical polymerization initiator, wherein the emulsion polymerization is carried out in the presence of a compound (1) containing a functional group reactive in radical polymerization and a hydrophilic group and a fluorinated compound (2) containing a fluorocarbon group comprising 1 to 6 continuously united carbon atom with fluorine atom directly bound to each of them as well as a hydrophilic group.
摘要翻译：本发明提供以低成本，高聚合速率和高产率制备分散稳定性优异的含氟弹性体的方法。本发明是一种在水溶性自由基聚合引发剂的存在下包含含氟单体的乳液聚合的含氟弹性体的方法，其中乳液聚合在含有官能团的化合物（1）的存在下进行，自由基聚合反应性和亲水性基团以及含有含有1〜6个连续碳原子的碳氟化合物的含氟化合物（2）和与其各自直接键合的氟原子以及亲水基团。

2. 发明申请

US20090234086A1 METHOD FOR PRODUCING FLUORINE-CONTAINING ELASTOMER 有权
标题翻译：生产含荧光弹性体的方法
公开(公告)号：US20090234086A1
公开(公告)日：2009-09-17
申请号：US12307022
申请日：2007-06-29
申请人： Mitsuru Kishine , Masanori Kitaichi , Yousuke Nishimura , Manabu Fujisawa , Yoshiki Tanaka , Shintarou Ogata , Yutaka Ueta , Shigeru Morita
发明人： Mitsuru Kishine , Masanori Kitaichi , Yousuke Nishimura , Manabu Fujisawa , Yoshiki Tanaka , Shintarou Ogata , Yutaka Ueta , Shigeru Morita
IPC分类号： C08F16/24 , C08F18/20
CPC分类号： C08F214/18 , C08F14/18 , C08F2/22
摘要： The present invention provides a method of producing a fluoroelastomer excellent in dispersion stability at low cost, at a high rate of polymerization and in high yields.The present invention is a method of producing a fluoroelastomer comprising an emulsion polymerization of a fluorinated monomer in the presence of a water-soluble radical polymerization initiator, wherein the emulsion polymerization is carried out in the presence of a compound (1) containing a functional group reactive in radical polymerization and a hydrophilic group and a fluorinated compound (2) containing a fluorocarbon group comprising 1 to 6 continuously united carbon atom with fluorine atom directly bound to each of them as well as a hydrophilic group.
摘要翻译：本发明提供以低成本，高聚合速率和高产率制备分散稳定性优异的含氟弹性体的方法。本发明是一种在水溶性自由基聚合引发剂的存在下包含含氟单体的乳液聚合的含氟弹性体的方法，其中乳液聚合在含有官能团的化合物（1）的存在下进行，自由基聚合反应性和亲水性基团以及含有含有1〜6个连续碳原子的碳氟化合物的含氟化合物（2）和与其各自直接键合的氟原子以及亲水基团。

3. 发明授权

US09273172B2 Method for producing a fluoroelastomer 有权
标题翻译：氟弹性体的制造方法
公开(公告)号：US09273172B2
公开(公告)日：2016-03-01
申请号：US12168454
申请日：2008-07-07
申请人： Mitsuru Kishine , Masanori Kitaichi , Shigeru Morita , Yoshiki Tanaka , Daisuke Ota
发明人： Mitsuru Kishine , Masanori Kitaichi , Shigeru Morita , Yoshiki Tanaka , Daisuke Ota
IPC分类号： C08F214/22 , C08F2/26 , C08F2/44
CPC分类号： C08F214/22 , C08F2/26
摘要： The present invention provides a method for producing a fluoroelastomer using an emulsifier which is inexpensive and hardly remains in product polymers. The present invention is related to a method for producing a fluoroelastomer, wherein vinylidene fluoride and at least one fluoroolefin monomer other than vinylidene fluoride are copolymerized in the manner of an emulsion polymerization in the presence of an emulsifier represented by C5F11COOM, wherein M represents H, NH4 or an alkali metal.
摘要翻译：本发明提供使用廉价且几乎不残留在产品聚合物中的乳化剂制备含氟弹性体的方法。本发明涉及一种含氟弹性体的制造方法，其中在由C5F11COOM表示的乳化剂的存在下，以偏二氟乙烯为单位，将聚偏二氟乙烯和至少一种氟烯烃单体以乳液聚合的方式共聚，其中M表示H， NH4或碱金属。

4. 发明授权

US5717036A Fluororubber copolymer and curable composition thereof 失效
标题翻译：氟橡胶共聚物及其可固化组合物
公开(公告)号：US5717036A
公开(公告)日：1998-02-10
申请号：US687491
申请日：1996-10-07
申请人： Hideya Saito , Masanori Kitaichi , Yutaka Ueta , Mitsuru Kishine
发明人： Hideya Saito , Masanori Kitaichi , Yutaka Ueta , Mitsuru Kishine
IPC分类号： C08F2/38 , C08F14/22 , C08F16/14 , C08F214/22 , C08F216/14 , C08K5/04 , C08K5/14 , C08K5/17 , C08K5/3477 , C08L27/16 , C09K3/10 , C08F14/16 , C08F259/08
CPC分类号： C09K3/1009 , C08F214/222 , C08K5/14 , C08K5/3477
摘要： A copolymer comprising 0.005 to 1.5 mole % of repeating units derived from an iodine-containing fluorinated vinyl ether, 40 to 90 mole % of repeating units derived from vinylidene fluoride, 3 to 35 mole % of repeating units derived from perfluoro(methyl vinyl ether), optionally up to 25 mole % of repeating units derived from hexafluoropropylene and optionally up to 40 mole % of repeating units derived from tetrafluoroethylene, which is obtained by polymerizing the above monomers in the presence of a diiodide compound, contains iodine atoms introduced in the copolymer from the diiodide compound and the iodine-containing fluorinated vinyl ether in amounts of 0.01 to 1 wt. % and 0.01 to 2 wt. %, respectively, and has a Mooney viscosity of 20 to 150.
摘要翻译： PCT No.PCT / JP95 / 02497 Sec。 371日期1996年10月7日第 102（e）日期1996年10月7日PCT提交1995年12月6日PCT公布。第WO96 / 17877号公报日期：1996年6月13日共包含0.005〜1.5摩尔％的衍生自含碘氟化乙烯基醚的重复单元，40〜90摩尔％来源于偏二氟乙烯的重复单元，3〜35摩尔％来自全氟（甲基乙烯基醚），任意多达25摩尔％的衍生自六氟丙烯的重复单元和任意多至40摩尔％的衍生自四氟乙烯的重复单元，其通过在二碘化物化合物的存在下聚合上述单体而获得，含有碘从二碘化合物和含碘氟化乙烯基醚引入共聚物中的原子数为0.01〜1重量％％和0.01〜2wt。％，门尼粘度为20〜150。

5. 发明授权

US06509429B1 Process for preparing fluorine-containing polymer 有权
标题翻译：含氟聚合物的制备方法
公开(公告)号：US06509429B1
公开(公告)日：2003-01-21
申请号：US09743188
申请日：2001-01-05
申请人： Masanori Kitaichi , Hiroshi Aihara , Sadashige Irie , Mitsuru Kishine , Yutaka Ueta , Katsuhide Otani , Yoshiki Maruya , Hideya Saito , Mitsuo Tsukamoto
发明人： Masanori Kitaichi , Hiroshi Aihara , Sadashige Irie , Mitsuru Kishine , Yutaka Ueta , Katsuhide Otani , Yoshiki Maruya , Hideya Saito , Mitsuo Tsukamoto
IPC分类号： C08F1418
CPC分类号： C08F14/26 , C08F14/18 , C08F14/28 , C08F259/08 , C08F2/16 , C08F2/22 , C08F214/18
摘要： A process for preparing a fluorine-containing polymer through emulsion polymerization method which enhances productivity while maintaining excellent physical properties of the fluorine-containing polymer and comprises (a) a first polymerization step for emulsion-polymerizing a fluorine-containing monomer or a mixture of a fluorine-containing monomer and a non-fluorine-containing monomer in an aqueous medium in the presence of a radical polymerization initiator and an emulsifying agent, (b) a dilution step for diluting the obtained aqueous emulsion of polymer particles with water to reduce the number of emulsified polymer particles per unit amount of aqueous medium in the emulsion and a concentration of emulsifying agent, and (c) a second polymerization step for emulsion-polymerizing a fluorine-containing monomer and/or a non-fluorine-containing monomer in the obtained diluted emulsified solution.
摘要翻译：一种通过乳液聚合方法制备含氟聚合物的方法，其提高生产率同时保持含氟聚合物的优异物理性能，并且包括（a）第一聚合步骤，用于将含氟单体或在自由基聚合引发剂和乳化剂的存在下，在水性介质中含氟单体和非含氟单体，（b）稀释步骤，用水稀释所得聚合物颗粒的水乳液以减少数量乳液中的乳化聚合物粒子和乳化剂的浓度的乳化聚合物粒子，和（c）在所得到的乳液聚合物粒子中使含氟单体和/或非含氟单体乳化聚合的第二聚合步骤稀释乳化液。

6. 发明申请

US20070299207A1 Process for preparing vulcanizable fluorine-containing elastomer 有权
标题翻译：制备可硫化含氟弹性体的方法
公开(公告)号：US20070299207A1
公开(公告)日：2007-12-27
申请号：US11892702
申请日：2007-08-27
申请人： Yousuke Nishimura , Masaki Irie , Sadashige Irie , Manabu Fujisawa , Satoshi Tokuno , Mitsuru Kishine
发明人： Yousuke Nishimura , Masaki Irie , Sadashige Irie , Manabu Fujisawa , Satoshi Tokuno , Mitsuru Kishine
IPC分类号： C08L27/14
CPC分类号： C08F214/28 , C08F214/18 , C08F214/22
摘要： The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1·Ix wherein Rf1 is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon group having 1 to 16 carbon atoms, and x is the number of bonds of Rf1 and an integer of 1 to 4.
摘要翻译：本发明提供了一种通过在高压下进行碘转移聚合制备与非碘转移聚合方法相当的高生产率的含氟弹性体的方法。本发明还提供了通过该方法制备的含氟弹性体和含氟成型体。该方法是在临界常数降低至少为0.95，临界常数降低至少为0.80的条件下进行的间歇共聚方法，其中降低的温度和减压是使用Peng-Robinson公式在临界温度下，在具有下式的化合物的存在下，在反应容器中的气相中的每种单体的临界压力和组成比共聚，其中含有至少一个氟烯烃的烯键式不饱和化合物在具有下式的化合物的存在下共聚：其中R 1是饱和或不饱和的氟代烃或其中R 1，R 2，R 3，R 4，具有1至16个碳原子的氯氟烃基，x是R 1和...的整数1至4的整数。

7. 发明申请

US20080306196A1 Peroxide-Vulcanizable Fluorine-Containing Elastomer Composition 审中-公开
标题翻译：过氧化物可硫化含氟弹性体组合物
公开(公告)号：US20080306196A1
公开(公告)日：2008-12-11
申请号：US11658255
申请日：2005-07-28
申请人： Masaki Irie , Yousuke Nishimura , Manabu Fujisawa , Mitsuru Kishine , Daisuke Ota
发明人： Masaki Irie , Yousuke Nishimura , Manabu Fujisawa , Mitsuru Kishine , Daisuke Ota
IPC分类号： C08K5/14
CPC分类号： C08F214/26 , B82Y30/00 , C08F214/22 , C08K5/14 , C08L27/12
摘要： The present invention provides a peroxide-vulcanizable fluorine-containing elastomer composition which is remarkably improved in fluidity and thereby exhibits improved processability, though conventional fluorine-containing elastomer compositions could be molded only by a molding process having a problem in its productivity, for instance, compression molding or transfer molding which has been used so far as a general molding process. The present invention further provides a molded article obtained by vulcanizing the composition. The present invention also provides a fluorine-containing elastomer composition in which a large amount of a filler can be blended. Specifically, the present invention relates to the fluorine-containing elastomer composition comprising a fluorine-containing elastomer (A) composed of a structural unit derived from vinylidene fluoride and/or a structural unit of tetrafluoroethylene and a structural unit derived from at least one other monomer, and having (a) a number average molecular weight (Mn) of 30,000 to 70,000 g/mol, and (b) an iodine content of 0.3 to 1.0% by weight and an organoperoxide vulcanizing agent (B).
摘要翻译：本发明提供了一种过氧化物可硫化的含氟弹性体组合物，其流动性显着提高，从而表现出改进的加工性能，但是常规的含氟弹性体组合物可以仅通过其生产率问题的模制方法模制，压缩成型或传递模塑，其已经被用于一般的模塑工艺。本发明还提供通过硫化该组合物获得的模制品。本发明还提供了可以混合大量填料的含氟弹性体组合物。具体地说，本发明涉及包含由偏氟乙烯衍生的结构单元和/或四氟乙烯的结构单元构成的含氟弹性体（A）和来自至少一种其它单体的结构单元的含氟弹性体组合物（a）数均分子量（Mn）为30,000〜70,000g / mol，（b）碘含量为0.3〜1.0重量％和有机过氧化物硫化剂（B）。

8. 发明申请

US20060052548A1 Method for producing vulcanizable fluorine-containing elastomer 有权
标题翻译：可硫化含氟弹性体的制造方法
公开(公告)号：US20060052548A1
公开(公告)日：2006-03-09
申请号：US10542545
申请日：2004-01-22
申请人： Yousuke Nishimura , Masaki Irie , Sadashige Irie , Manabu Fujisawa , Satoshi Tokuno , Mitsuru Kishine
发明人： Yousuke Nishimura , Masaki Irie , Sadashige Irie , Manabu Fujisawa , Satoshi Tokuno , Mitsuru Kishine
IPC分类号： C08C19/20
CPC分类号： C08F214/28 , C08F214/18 , C08F214/22
摘要： The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1·Ix wherein Rf1 is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon group having 1 to 16 carbon atoms, and x is the number of bonds of Rf1 and an integer of 1 to 4.
摘要翻译：本发明提供了一种通过在高压下进行碘转移聚合制备与非碘转移聚合方法相当的高生产率的含氟弹性体的方法。本发明还提供了通过该方法制备的含氟弹性体和含氟成型体。该方法是在临界常数降低至少为0.95，临界常数降低至少为0.80的条件下进行的间歇共聚方法，其中降低的温度和减压是使用Peng-Robinson公式从临界温度，临界压力和反应容器中气相中各单体的组成比

9. 发明授权

US07375171B2 Process for preparing vulcanizable fluorine-containing elastomer 有权
标题翻译：制备可硫化含氟弹性体的方法
公开(公告)号：US07375171B2
公开(公告)日：2008-05-20
申请号：US10542545
申请日：2004-01-22
申请人： Yousuke Nishimura , Masaki Irie , Sadashige Irie , Manabu Fujisawa , Satoshi Tokuno , Mitsuru Kishine
发明人： Yousuke Nishimura , Masaki Irie , Sadashige Irie , Manabu Fujisawa , Satoshi Tokuno , Mitsuru Kishine
IPC分类号： C08F14/18
CPC分类号： C08F214/28 , C08F214/18 , C08F214/22
摘要： The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1.Ix wherein Rf1 is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon group having 1 to 16 carbon atoms, and x is the number of bonds of Rf1 and an integer of 1 to 4.
摘要翻译：本发明提供了一种通过在高压下进行碘转移聚合制备与非碘转移聚合方法相当的高生产率的含氟弹性体的方法。本发明还提供了通过该方法制备的含氟弹性体和含氟成型体。该方法是在临界常数降低至少为0.95，临界常数降低至少为0.80的条件下进行的间歇共聚方法，其中降低的温度和减压是使用Peng-Robinson公式在临界温度下，在具有下式的化合物的存在下，在反应容器中的气相中的每种单体的临界压力和组成比共聚，其中含有至少一个氟烯烃的烯键式不饱和化合物在具有下式的化合物的存在下共聚：其中R 1是饱和或不饱和的氟代烃或其中R 1，R 2，R 3，R 4，R 5，具有1至16个碳原子的氯氟烃基，x是R 1和...的整数1至4的整数。

10. 发明授权

US08247505B2 Process for preparing vulcanizable fluorine-containing elastomer 有权
标题翻译：制备可硫化含氟弹性体的方法
公开(公告)号：US08247505B2
公开(公告)日：2012-08-21
申请号：US11892702
申请日：2007-08-27
申请人： Yousuke Nishimura , Masaki Irie , Sadashige Irie , Manabu Fujisawa , Satoshi Tokuno , Mitsuru Kishine
发明人： Yousuke Nishimura , Masaki Irie , Sadashige Irie , Manabu Fujisawa , Satoshi Tokuno , Mitsuru Kishine
IPC分类号： C08F14/18
CPC分类号： C08F214/28 , C08F214/18 , C08F214/22
摘要： The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1·Ix wherein Rf1 is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon group having 1 to 16 carbon atoms, and x is the number of bonds of Rf1 and an integer of 1 to 4.
摘要翻译：本发明提供了一种通过在高压下进行碘转移聚合制备与非碘转移聚合方法相当的高生产率的含氟弹性体的方法。本发明还提供了通过该方法制备的含氟弹性体和含氟成型体。该方法是在临界常数降低至少为0.95，临界常数降低至少为0.80的条件下进行的间歇共聚方法，其中降低的温度和减压是使用Peng-Robinson公式在临界温度下，在具有下式的化合物的存在下共聚反应容器中气相中各单体的临界压力和组成比：Rf1· 其中Rf1是具有1至16个碳原子的饱和或不饱和的氟代烃或氯氟烃基，x是Rf1的键数和1至4的整数。

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