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1. 发明授权

US08580896B2 Process for preparing fluorine-containing polymer 有权
标题翻译：含氟聚合物的制备方法
公开(公告)号：US08580896B2
公开(公告)日：2013-11-12
申请号：US12300252
申请日：2007-05-09
申请人： Mitsuru Kishine , Masanori Kitaichi , Daisuke Ota , Masahiko Oka
发明人： Mitsuru Kishine , Masanori Kitaichi , Daisuke Ota , Masahiko Oka
IPC分类号： C08F2/22 , C08F2/44 , C08F214/18 , C08F259/08
CPC分类号： C08F214/18 , C08F2/001 , C08F2/22 , C08F2/44 , C08F214/22
摘要： A process for preparing a fluorine-containing polymer which includes a first step for preparing a dispersion of fluorine-containing emulsified particles (A) having ionic functional groups where a fluorine-containing monomer mixture (i) is polymerized by using a water soluble radical polymerization initiator (a) without addition of an emulsifying agent, and a second step for preparing a fluorine-containing polymer (b) having a small amount of ionic functional groups where fluorine-containing monomers (ii) are emulsion-polymerized by using a radical polymerization initiator (b) in the presence of the fluorine-containing emulsified particles (A) having ionic functional groups without addition of an emulsifying agent.
摘要翻译：一种制备含氟聚合物的方法，其包括用于制备具有离子官能团的含氟乳化颗粒（A）的分散体的第一步骤，其中含氟单体混合物（i）通过使用水溶性自由基聚合不加乳化剂的引发剂（a），以及通过使用自由基聚合将含氟单体（ⅱ）进行乳液聚合的具有少量离子性官能团的含氟聚合物（b）的制备的第二工序在具有离子官能团的含氟乳化颗粒（A）的存在下，不添加乳化剂的引发剂（b）。

2. 发明申请

US20090215980A1 PROCESS FOR PREPARING FLUORINE-CONTAINING POLYMER 有权
标题翻译：制备含氟聚合物的方法
公开(公告)号：US20090215980A1
公开(公告)日：2009-08-27
申请号：US12300252
申请日：2007-05-09
申请人： Mitsuru Kishine , Masanori Kitaichi , Daisuke Ota , Masahiko Oka
发明人： Mitsuru Kishine , Masanori Kitaichi , Daisuke Ota , Masahiko Oka
IPC分类号： C08G61/12
CPC分类号： C08F214/18 , C08F2/001 , C08F2/22 , C08F2/44 , C08F214/22
摘要： The fluorine-containing polymer having a small number of ionic functional groups is prepared by a process, in which emulsion polymerization proceeds stably and produced polymer does not adhere to side walls of a polymerization reactor even without using an emulsifying agent, and the process comprises a first step for preparing a dispersion comprising fluorine-containing emulsified particles having ionic functional groups by polymerizing a fluorine-containing monomer mixture comprising a perhalo ethylenic monomer and a nonperhalo ethylenic monomer by using a water soluble radical polymerization initiator without adding an emulsifying agent, and a second step for preparing a fluorine-containing polymer having ionic functional groups in a small amount by emulsion polymerization of fluorine-containing monomers using a radical polymerization initiator in the presence of the fluorine-containing emulsified particles having ionic functional groups without adding an emulsifying agent, wherein the fluorine-containing emulsified particles having ionic functional groups prepared in the first step are used in an amount of from 0.01 to 5.0% by mass based on the fluorine-containing polymer to be obtained in the second step, and an amount of the water soluble radical polymerization initiator used in the first step is from 0.01 to 1,000% by mass based on the fluorine-containing emulsified particles having ionic functional groups prepared in the first step.
摘要翻译：具有少量离子官能团的含氟聚合物通过乳液聚合稳定进行并且生产的聚合物即使不使用乳化剂也不粘附到聚合反应器的侧壁的方法制备，并且该方法包括通过在不添加乳化剂的情况下使用水溶性自由基聚合引发剂使包含全卤乙烯性单体和非卤代乙烯性单体的含氟单体混合物聚合，制备包含具有离子性官能团的含氟乳化颗粒的分散体的第一步骤，在不添加乳化剂的情况下，在具有离子性官能团的含氟乳化粒子的存在下，使用自由基聚合引发剂使含氟单体进行乳液聚合，制备少量具有离子性官能团的含氟聚合物的第二工序，其中t 相对于第二工序中得到的含氟聚合物，第一工序中制备的具有离子性官能团的含氟乳化粒子的使用量为0.01〜5.0质量％，水溶性基于在第一步骤中制备的具有离子性官能团的含氟乳化颗粒，第一步中使用的自由基聚合引发剂为0.01〜1000质量％。

3. 发明授权

US09273172B2 Method for producing a fluoroelastomer 有权
标题翻译：氟弹性体的制造方法
公开(公告)号：US09273172B2
公开(公告)日：2016-03-01
申请号：US12168454
申请日：2008-07-07
申请人： Mitsuru Kishine , Masanori Kitaichi , Shigeru Morita , Yoshiki Tanaka , Daisuke Ota
发明人： Mitsuru Kishine , Masanori Kitaichi , Shigeru Morita , Yoshiki Tanaka , Daisuke Ota
IPC分类号： C08F214/22 , C08F2/26 , C08F2/44
CPC分类号： C08F214/22 , C08F2/26
摘要： The present invention provides a method for producing a fluoroelastomer using an emulsifier which is inexpensive and hardly remains in product polymers. The present invention is related to a method for producing a fluoroelastomer, wherein vinylidene fluoride and at least one fluoroolefin monomer other than vinylidene fluoride are copolymerized in the manner of an emulsion polymerization in the presence of an emulsifier represented by C5F11COOM, wherein M represents H, NH4 or an alkali metal.
摘要翻译：本发明提供使用廉价且几乎不残留在产品聚合物中的乳化剂制备含氟弹性体的方法。本发明涉及一种含氟弹性体的制造方法，其中在由C5F11COOM表示的乳化剂的存在下，以偏二氟乙烯为单位，将聚偏二氟乙烯和至少一种氟烯烃单体以乳液聚合的方式共聚，其中M表示H， NH4或碱金属。

4. 发明授权

US08450423B2 Fluorine-containing elastomer mixture, method for producing same, composition for vulcanizing peroxide, and molded article 有权
标题翻译：含氟弹性体混合物，其制造方法，硫化过氧化物的组合物和成型体
公开(公告)号：US08450423B2
公开(公告)日：2013-05-28
申请号：US13260913
申请日：2010-03-30
申请人： Shoji Fukuoka , Keiko Washino , Shuumi Nishii , Daisuke Ota , Mitsuru Kishine
发明人： Shoji Fukuoka , Keiko Washino , Shuumi Nishii , Daisuke Ota , Mitsuru Kishine
IPC分类号： C08F8/00 , C08L23/00 , C08L23/04 , C08L23/10 , C08K5/17 , C08K5/18 , A01N33/06
CPC分类号： C08L27/16 , C08J3/24 , C08J2327/16 , C08K5/14 , C08L27/18 , C08L2205/02
摘要： A fluoroelastomer mixture, including: a peroxide-vulcanizable fluoroelastomer (A) containing an iodine atom; and a peroxide-vulcanizable fluoroelastomer (B) containing an iodine atom. The fluoroelastomer (A) is a copolymer (a1) consisting of 50 to 85 mol % of a vinylidene fluoride unit and 15 to 50 mol % of a perfluoro(alkyl vinyl ether) unit, or a copolymer (a2) consisting of 45 to 85 mol % of a vinylidene fluoride unit, 1 to 30 mol % of a tetrafluoroethylene unit, and 14 to 30 mol % of a perfluoro(alkyl vinyl ether) unit. Further the fluoroelastomer (B) has a fluorine content of 70.0% or more. Also disclosed is a composition for peroxide vulcanization containing the above fluoroelastomer composition (i), a polyfunctional unsaturated compound (ii) and a peroxide (iii), as well as a method for producing the fluoroelastomer mixture.
摘要翻译：一种含氟弹性体混合物，包括：含有碘原子的过氧化物可硫化的含氟弹性体（A）和含有碘原子的过氧化物可硫化的含氟弹性体（B）。含氟弹性体（A）是由50〜85摩尔％的偏氟乙烯单元和15〜50摩尔％的全氟（烷基乙烯基醚）单元组成的共聚物（a1），或由45〜85组成的共聚物（a2）偏二氟乙烯单元的摩尔％，四氟乙烯单元为1〜30摩尔％，全氟（烷基乙烯基醚）单元为14〜30摩尔％。此外，含氟弹性体（B）的氟含量为70.0％以上。还公开了含有上述含氟弹性体组合物（i），多官能不饱和化合物（ⅱ）和过氧化物（ⅲ）的过氧化物硫化的组合物，以及含氟弹性体混合物的制造方法。

5. 发明授权

US09045614B2 Fluororubber composition 有权
标题翻译：氟橡胶组成
公开(公告)号：US09045614B2
公开(公告)日：2015-06-02
申请号：US13217436
申请日：2011-08-25
申请人： Daisuke Ota , Yutaka Ueta , Masanori Kitaichi , Shoji Fukuoka
发明人： Daisuke Ota , Yutaka Ueta , Masanori Kitaichi , Shoji Fukuoka
IPC分类号： C08K3/04 , C08L27/12 , C08K5/00 , C08K5/14
CPC分类号： C08K5/0025 , C08K3/04 , C08K5/14 , C08L27/12
摘要： The present invention provides a fluororubber composition that has excellent heat resistance and excellent mechanical properties at high temperatures. The fluororubber composition comprises a peroxide cross-linkable fluororubber (A); a carbon black (B); a peroxide cross-linking agent (C); and a low-self-polymerizing cross-linking accelerator (D), wherein to 100 parts by mass of the fluororubber (A), the amount of the carbon black (B) is 5 to 50 parts by mass, the amount of the cross-linking agent (C) is 0.01 to 10 parts by mass, and the amount of the cross-linking accelerator (D) is 2.5 parts by mass or smaller.
摘要翻译：本发明提供一种在高温下具有优异的耐热性和优异的机械性能的氟橡胶组合物。氟橡胶组合物包含过氧化物可交联的氟橡胶（A）; 炭黑（B）; 过氧化物交联剂（C）; 和低自聚合交联促进剂（D），其中对于100质量份的氟橡胶（A），炭黑（B）的量为5〜50质量份，交联量交联剂（C）的含量为0.01〜10质量份，交联促进剂（D）的量为2.5质量份以下。

6. 发明申请

US20120029152A1 FLUORINE-CONTAINING ELASTOMER MIXTURE, METHOD FOR PRODUCING SAME, COMPOSITION FOR VULCANIZING PEROXIDE, AND MOLDED ARTICLE 有权
标题翻译：含氟的弹性体混合物，其生产方法，过氧化物的组合物和成型品
公开(公告)号：US20120029152A1
公开(公告)日：2012-02-02
申请号：US13260913
申请日：2010-03-30
申请人： Shoji Fukuoka , Keiko Washino , Shuumi Nishii , Daisuke Ota , Mitsuru Kishine
发明人： Shoji Fukuoka , Keiko Washino , Shuumi Nishii , Daisuke Ota , Mitsuru Kishine
IPC分类号： C08L27/20
CPC分类号： C08L27/16 , C08J3/24 , C08J2327/16 , C08K5/14 , C08L27/18 , C08L2205/02
摘要： A fluoroelastomer mixture, including: a peroxide-vulcanizable fluoroelastomer (A) containing an iodine atom; and a peroxide-vulcanizable fluoroelastomer (B) containing an iodine atom. The fluoroelastomer (A) is a copolymer (a1) consisting of 50 to 85 mol % of a vinylidene fluoride unit and 15 to 50 mol % of a perfluoro(alkyl vinyl ether) unit, or a copolymer (a2) consisting of 45 to 85 mol % of a vinylidene fluoride unit, 1 to 30 mol % of a tetrafluoroethylene unit, and 14 to 30 mol % of a perfluoro(alkyl vinyl ether) unit. Further the fluoroelastomer (B) has a fluorine content of 70.0% or more. Also disclosed is a composition for peroxide vulcanization containing the above fluoroelastomer composition (i), a polyfunctional unsaturated compound (ii) and a peroxide (iii), as well as a method for producing the fluoroelastomer mixture.
摘要翻译：一种含氟弹性体混合物，包括：含有碘原子的过氧化物可硫化的含氟弹性体（A）和含有碘原子的过氧化物可硫化的含氟弹性体（B）。氟弹性体（A）是由50〜85摩尔％的偏氟乙烯单元和15〜50摩尔％的全氟（烷基乙烯基醚）单元构成的共聚物（a1），或由45〜85组成的共聚物（a2）偏二氟乙烯单元的摩尔％，四氟乙烯单元为1〜30摩尔％，全氟（烷基乙烯基醚）单元为14〜30摩尔％。此外，含氟弹性体（B）的氟含量为70.0％以上。还公开了含有上述含氟弹性体组合物（i），多官能不饱和化合物（ⅱ）和过氧化物（ⅲ）的过氧化物硫化的组合物，以及含氟弹性体混合物的制造方法。

7. 发明申请

US20110112265A1 CURABLE COMPOSITION AND MOLDED ARTICLE MADE OF SAME 审中-公开
标题翻译：可固化组合物和成型品
公开(公告)号：US20110112265A1
公开(公告)日：2011-05-12
申请号：US13002016
申请日：2009-06-29
申请人： Keiko Washino , Shoji Fukuoka , Daisuke Ota , Mitsuru Kishine
发明人： Keiko Washino , Shoji Fukuoka , Daisuke Ota , Mitsuru Kishine
IPC分类号： C08F4/00 , C08F2/38
CPC分类号： C09K3/1009 , C08K5/16 , C08L27/16
摘要： A curable composition comprising (A) a vinylidene fluoride type elastomer which is a copolymer of vinylidene fluoride (a1), at least one perfluoroolefin (a2) selected from the group consisting of tetrafluoroethylene, hexafluoropropylene and perfluoro(alkyl vinyl ether) and a cyano group-containing monomer (a3) (the proportion of vinylidene fluoride exceeds 20% by mole), and (B) a compound generating ammonia at 40° to 330° C. alone as a curing agent. The present invention can provide a curable composition of a vinylidene fluoride type elastomer assuring improved crosslinking speed and making it possible to use a cheap curing agent, and a molded article obtained from the curable composition. Physical properties under normal conditions can also be improved by the presence of the solvent having affinity for the compound generating ammonia.
摘要翻译：一种可固化组合物，其包含（A）偏二氟乙烯类弹性体，其是偏二氟乙烯（a1），至少一种选自四氟乙烯，六氟丙烯和全氟（烷基乙烯基醚）的全氟烯烃（a2）的共聚物和氰基（a3）（偏二氟乙烯的比例超过20摩尔％），（B）仅在40〜330℃产生氨的化合物作为固化剂。本发明可以提供一种偏二氟乙烯类弹性体的固化性组合物，其确保交联速度提高，并且可以使用廉价的固化剂，以及由可固化组合物获得的成型体。在正常条件下的物理性能也可以通过对产生氨的化合物具有亲和性的溶剂的存在来改善。

8. 发明申请

US20110151164A1 CURABLE COMPOSITION AND MOLDED ARTICLE MADE OF SAME 审中-公开
标题翻译：可固化组合物和成型品
公开(公告)号：US20110151164A1
公开(公告)日：2011-06-23
申请号：US13060646
申请日：2009-09-18
申请人： Keiko Washino , Shoji Fukuoka , Daisuke Ota , Mitsuru Kishine
发明人： Keiko Washino , Shoji Fukuoka , Daisuke Ota , Mitsuru Kishine
IPC分类号： C08K5/00 , C08F4/00 , B32B1/08
CPC分类号： C08K5/0025 , C08K5/18 , C08K5/21 , Y10T428/139 , C08L27/16
摘要： A curable composition comprising (A) a vinylidene fluoride elastomer which is a copolymer of vinylidene fluoride (a1), at least one kind of perfluoroolefin (a2) selected from the group consisting of tetrafluoroethylene, hexafluoropropylene and perfluoro(alkyl vinyl ether) and a cyano group-containing monomer (a3) (a proportion of the vinylidene fluoride exceeds 20% by mole), (B) a specific curing agent and (C) a compound generating ammonia at 40° to 330° C. The present invention can provide a curable composition of a vinylidene fluoride elastomer assuring improved crosslinking speed, and a molded article obtained from the curable composition. Physical properties under normal conditions are improved by the presence of a solvent having affinity for the compound generating ammonia.
摘要翻译：一种可固化组合物，其包含（A）偏二氟乙烯弹性体，其是偏氟乙烯（a1）的共聚物，选自四氟乙烯，六氟丙烯和全氟（烷基乙烯基醚）的至少一种全氟烯烃（a2）和氰基含有基团的单体（a3）（偏二氟乙烯的比例超过20摩尔％），（B）特定的固化剂和（C）在40〜330℃产生氨的化合物。本发明可以提供确保改善交联速度的偏二氟乙烯弹性体的可固化组合物和由可固化组合物获得的模塑制品。通过存在对产生氨的化合物具有亲和性的溶剂来改善在正常条件下的物理性能。

9. 发明申请

US20080306196A1 Peroxide-Vulcanizable Fluorine-Containing Elastomer Composition 审中-公开
标题翻译：过氧化物可硫化含氟弹性体组合物
公开(公告)号：US20080306196A1
公开(公告)日：2008-12-11
申请号：US11658255
申请日：2005-07-28
申请人： Masaki Irie , Yousuke Nishimura , Manabu Fujisawa , Mitsuru Kishine , Daisuke Ota
发明人： Masaki Irie , Yousuke Nishimura , Manabu Fujisawa , Mitsuru Kishine , Daisuke Ota
IPC分类号： C08K5/14
CPC分类号： C08F214/26 , B82Y30/00 , C08F214/22 , C08K5/14 , C08L27/12
摘要： The present invention provides a peroxide-vulcanizable fluorine-containing elastomer composition which is remarkably improved in fluidity and thereby exhibits improved processability, though conventional fluorine-containing elastomer compositions could be molded only by a molding process having a problem in its productivity, for instance, compression molding or transfer molding which has been used so far as a general molding process. The present invention further provides a molded article obtained by vulcanizing the composition. The present invention also provides a fluorine-containing elastomer composition in which a large amount of a filler can be blended. Specifically, the present invention relates to the fluorine-containing elastomer composition comprising a fluorine-containing elastomer (A) composed of a structural unit derived from vinylidene fluoride and/or a structural unit of tetrafluoroethylene and a structural unit derived from at least one other monomer, and having (a) a number average molecular weight (Mn) of 30,000 to 70,000 g/mol, and (b) an iodine content of 0.3 to 1.0% by weight and an organoperoxide vulcanizing agent (B).
摘要翻译：本发明提供了一种过氧化物可硫化的含氟弹性体组合物，其流动性显着提高，从而表现出改进的加工性能，但是常规的含氟弹性体组合物可以仅通过其生产率问题的模制方法模制，压缩成型或传递模塑，其已经被用于一般的模塑工艺。本发明还提供通过硫化该组合物获得的模制品。本发明还提供了可以混合大量填料的含氟弹性体组合物。具体地说，本发明涉及包含由偏氟乙烯衍生的结构单元和/或四氟乙烯的结构单元构成的含氟弹性体（A）和来自至少一种其它单体的结构单元的含氟弹性体组合物（a）数均分子量（Mn）为30,000〜70,000g / mol，（b）碘含量为0.3〜1.0重量％和有机过氧化物硫化剂（B）。

10. 发明授权

US09068653B2 Sealing material 有权
标题翻译：密封材料
公开(公告)号：US09068653B2
公开(公告)日：2015-06-30
申请号：US13217769
申请日：2011-08-25
申请人： Junpei Terada , Daisuke Ota , Masanori Kitaichi , Yutaka Ueta , Shigeru Morita , Kazuyoshi Kawasaki , Tatsuya Morikawa , Shoji Fukuoka
发明人： Junpei Terada , Daisuke Ota , Masanori Kitaichi , Yutaka Ueta , Shigeru Morita , Kazuyoshi Kawasaki , Tatsuya Morikawa , Shoji Fukuoka
IPC分类号： F16J15/10 , C09K3/10 , C08K3/04 , C08K5/00 , C08L27/12 , C08L27/16 , C08L27/20
CPC分类号： F16J15/102 , C08K3/04 , C08K5/0025 , C08L27/12 , C08L27/16 , C08L27/20 , C09K3/1009
摘要： To provide a sealing material which is excellent in sealability under high-temperature conditions as well as crack resistance at high temperatures and high compression. A sealing material comprising a cross-linked fluororubber layer obtainable by cross-linking a fluororubber composition containing a fluororubber (A) and a carbon black (B), the cross-linked fluororubber layer having a loss modulus E″ of 600 kPa or higher and 6,000 kPa or lower determined by a dynamic viscoelasticity test under conditions of measurement temperature: 160° C., tensile strain: 1%, initial force: 157 cN, and frequency: 10 Hz.
摘要翻译：提供一种密封材料，其在高温条件下的密封性优异，并且在高温和高压缩下具有抗裂性。一种密封材料，其包含通过交联含有氟橡胶（A）和炭黑（B）的氟橡胶组合物而获得的交联氟橡胶层，所述交联氟橡胶层的损耗模量E“为600kPa以上，通过动态粘弹性试验，在测量温度：160℃，拉伸应变：1％，初始力：157cN，频率：10Hz的条件下测定。

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