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    • 1. 发明授权
    • Electrophotographic sensitive materials containing disazo compounds
    • 含有双偶氮化合物的电子照相感光材料
    • US4314015A
    • 1982-02-02
    • US218382
    • 1980-12-19
    • Mitsuru HashimotoKiyoshi SakaiMasafumi OhtaAkio KozimaMasaomi SasakiKyoji Tsutsui
    • Mitsuru HashimotoKiyoshi SakaiMasafumi OhtaAkio KozimaMasaomi SasakiKyoji Tsutsui
    • C09B35/02C09B35/039G03G5/06
    • G03G5/0679C09B35/02C09B35/039G03G5/0681G03G5/0683
    • The present invention provides electrophotographic sensitive materials having a high sensitivity as well as a high flexibility which comprise a conductive support and a photosensitive layer formed thereon, said photosensitive layer containing one disazo pigment, as an effective ingredient, which is selected from the group consisting of disazo pigments expressed by the following general formulas I, II, III, and IV, ##STR1## [(wherein A is selected from the group consisting of ##STR2## is selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as indole ring, carbazole ring, benzofuran ring, etc. and their substituents, Ar.sub.1 is selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as dibenzofuran, etc. and their substituents, Ar.sub.2 and Ar.sub.3 are selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc. and their substituents, R.sub.1 and R.sub.3 are selected from the group consisting of hydrogen, lower alkyl radical or phenyl radical and their substituents and R.sub.2 is selected from the group consisting of lower alkyl radical, carboxyl radical and their esters)].
    • 本发明提供具有高灵敏度和高柔性的电子照相感光材料,其包含导电性支持体和形成在其上的感光层,所述感光层含有一种双偶氮颜料作为有效成分,其选自: 通式I表示的双偶氮颜料:通式I:通式II:通用化学式III:通式IV:其中A为 选自(其中X选自芳环如苯环,萘环等,杂环如吲哚环,咔唑环,苯并呋喃环等及其取代基 Ar1选自苯环,萘环等芳香环,二苯并呋喃等杂环及其取代基,Ar2和Ar3选自 由芳环如苯环,萘环等及其取代基组成的组,R 1和R 3选自氢,低级烷基或苯基及其取代基,R 2选自 低级烷基,羧基及其酯)]。
    • 3. 发明授权
    • Electrophotographic elements containing trisazo compounds
    • 含有三偶氮化合物的电子照相元件
    • US4279981A
    • 1981-07-21
    • US897508
    • 1978-04-18
    • Masafumi OhtaKiyoshi SakaiMitsuru HashimotoAkio KozimaMasaomi Sasaki
    • Masafumi OhtaKiyoshi SakaiMitsuru HashimotoAkio KozimaMasaomi Sasaki
    • C09B35/378G03G5/06
    • G03G5/0687C09B35/378
    • The present invention provides trisazo compounds expressed by the general formula I ##STR1## [wherein A represents ##STR2## (wherein R represents hydrogen, alkyl radical, alkoxy radical, nitro radical, dialkylamino radical or halogen, and n is an integer of 1, 2 or 3, R may be either identical or different when n is an integer of 2 or 3)]; a process for the preparation of said trisazo compounds; and electrophotographic sensitive materials having a high sensitivity as well as a high flexibility which comprise a conductive support and a photosensitive layer containing a trisazo compound, as an effective ingredient thereof, which is expressed by the general formula II ##STR3## [wherein A' represents ##STR4## (wherein Z represents aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as indole ring, carbazole ring, benzofuran ring, etc. or their substituents, Ar.sub.1 represents aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as dibenzofuran ring, etc. or their substituents, Ar.sub.2 and Ar.sub.3 represent aromatic rings such as benzene ring, naphthalene ring, etc. or their substituents, R.sub.1 and R.sub.3 represent hydrogen, lower alkyl radical, phenyl radical or their substituents, and R.sub.2 represents lower alkyl radical, carboxyl radical or their esters)].
    • 本发明提供由通式I表示的三偶氮化合物,其中A代表氢,烷基,烷氧基,硝基,二烷基氨基 或卤素,n为1,2或3的整数,当n为2或3的整数时,R可以相同或不同)。 一种制备所述三偶氮化合物的方法; 和具有高灵敏度的电子照相感光材料以及包含导电性支持体和含有三偶氮化合物的感光层作为其有效成分的高柔性,其由通式II表示[其中A'表示 (其中Z表示芳环如苯环,萘环等,杂环如吲哚环,咔唑环,苯并呋喃环等)或其取代基,Ar1表示芳环如苯环,萘环 等等,杂环如二苯并呋喃环等或其取代基,Ar 2和Ar 3表示芳环如苯环,萘环等或其取代基,R 1和R 3表示氢,低级烷基,苯基或 它们的取代基,R 2代表低级烷基,羧基或它们的酯)]。
    • 4. 发明授权
    • Electrophotographic material containing disazo compounds
    • 含有双偶氮化合物的电子照相材料
    • US4272598A
    • 1981-06-09
    • US898130
    • 1978-04-20
    • Masaomi SasakiKiyoshi SakaiMitsuru HashimotoMasafumi OhtaAkio Kozima
    • Masaomi SasakiKiyoshi SakaiMitsuru HashimotoMasafumi OhtaAkio Kozima
    • C09B35/215C09B56/06G03G5/06G03G13/22
    • G03G5/0683C09B35/215C09B56/06
    • The present invention provides disazo compounds expressed by the general formula I ##STR1## [wherein A represents ##STR2## (wherein R represents alkyl radical, alkoxy radical, nitro radical, dialkylamino radical or halogen, n is 0 or an integer of 1, 2 or 3, and R may be either identical or different when n is an integer of 2 or 3)]; a process for the preparation of said compounds; and electrophotographic sensitive materials having a high sensitivity as well as a high flexibility which comprise a conductive support and a photosensitive layer formed thereon, said photosensitive layer containing a disazo compound, as an effective ingredient, which is expressed by the general formula II ##STR3## [wherein A' represents ##STR4## (wherein X represents aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as indole ring, carbazole ring, benzofuran ring, etc. or their substituents, Ar.sub.1 represents aromatic rings such as benzene ring, naphthalene ring, etc., hetero rings such as dibenzofuran, etc. or their substituents, Ar.sub.2 and Ar.sub.3 represent aromatic rings such as benzene ring, naphthalene ring, etc. or their substituents, R.sub.1 and R.sub.3 represent respectively hydrogen, lower alkyl radical, phenyl radical or their substituents, and R.sub.2 represents lower alkyl radical, carboxyl radical or their esters)].
    • 本发明提供由通式I表示的双偶氮化合物[其中A表示(其中R表示烷基,烷氧基,硝基,二烷基氨基或卤素,n为0或 1或2或3的整数,当n为2或3的整数时,R可以相同或不同)。 一种制备所述化合物的方法; 和具有高灵敏度的电子照相感光材料以及包含导电性支持体和形成在其上的感光层的高柔性,所述感光层含有双偶氮化合物作为有效成分,其由通式II表示。 + TR 其中A'表示 + TR (其中X表示芳环如苯环,萘环等,杂环如吲哚环,咔唑环,苯并呋喃环等 或它们的取代基,Ar 1表示芳环如苯环,萘环等,杂环如二苯并呋喃等或其取代基,Ar2和Ar3表示芳环如苯环,萘环等或其取代基 ,R1和R3分别代表氢,低级烷基,苯基或它们的取代基,R2代表低级烷基,羧基或它们的酯)]。
    • 6. 发明授权
    • 3,6-Disazo-9-ethyl carbazole compounds
    • 3,6-二氮杂-9-咔唑化合物
    • US4426327A
    • 1984-01-17
    • US204150
    • 1980-11-05
    • Mitsuru HashimotoMasafumi OhtaAkio KozimaKiyoshi SakaiMasaomi Sasaki
    • Mitsuru HashimotoMasafumi OhtaAkio KozimaKiyoshi SakaiMasaomi Sasaki
    • C09B35/34G03G5/06C09B35/24C07D209/88
    • G03G5/0681C09B35/34
    • The present invention provides disazo compounds expressed by the general formula ##STR1## [wherein A represents ##STR2## (wherein R represents alkyl radical, alkoxy radical, nitro radical, dialkylamino radical or halogen, n is 0 or an integer ranging from 1 to 3, and R may be identical or different when n is an integer of 2 or 3)]; a process for the preparation of said compounds; and photosensitive materials having a high sensitivity as well as a high flexibility which comprises a conductive support and a photosensitive layer formed thereon, said photosensitive layer containing a disazo pigment, as an effective ingredient, which is expressed by the general formula ##STR3## [wherein R' represents a member selected from the group consisting of hydrogen, ethyl radical, chloroethyl radical and hydroxyethyl radical, A' represents a member selected from the group consisting of ##STR4## (wherein X represents a member selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc., heterocyclic rings such as indole ring, carbazole ring, benzofuran ring, etc. and their substituents, Ar.sub.1 represents a member selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc., heterocyclic rings such as dibenzofuran ring, etc. and their substituents, Ar.sub.2 and Ar.sub.3 represent respectively a member selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc. and their substituents, R.sub.1 and R.sub.3 represent respectively a member selected from the group consisting of hydrogen, lower alkyl radical or phenyl radical and their substituents, and R.sub.2 represents a member selected from the group consisting of lower alkyl radical, carboxyl radical and their esters)].
    • 本发明提供由通式 [其中A表示“(其中R表示烷基,烷氧基,硝基,二烷基氨基或卤素,n为0或1至3的整数)表示的双偶氮化合物 当n为2或3的整数时,R可以相同或不同)]; 一种制备所述化合物的方法; 以及具有高灵敏度的感光材料以及包含导电性支持体和形成在其上的感光层的高柔性,所述感光层含有双偶氮颜料作为有效成分,其通过通式[表示] [其中 R'表示选自氢,乙基,氯乙基和羟乙基的成员,A'表示选自下列的成员:其中X表示选自 芳环如苯环,萘环等杂环,吲哚环,咔唑环,苯并呋喃环等杂环及其取代基,Ar1表示选自芳香环如苯的成员 环,萘环等杂环,二苯并呋喃环等杂环及其取代基,Ar2和Ar3分别表示成员选择 由芳环如苯环,萘环等及其取代基组成,R1和R3分别表示选自氢,低级烷基或苯基及其取代基的成员,R2表示 选自低级烷基,羧基及其酯的成员)]。
    • 7. 发明授权
    • Electrophotographic elements containing disazo compounds
    • 含有双偶氮化合物的电子照相元件
    • US4293628A
    • 1981-10-06
    • US872679
    • 1978-01-26
    • Mitsuru HashimotoMasafumi OhtaAkio KozimaKiyoshi SakaiMasaomi Sasaki
    • Mitsuru HashimotoMasafumi OhtaAkio KozimaKiyoshi SakaiMasaomi Sasaki
    • C09B35/34G03G5/06
    • C09B35/34G03G5/0681
    • The present invention provides disazo compounds expressed by the general formula ##STR1## [wherein A represents ##STR2## (wherein R represents alkyl radical, alkoxy radical, nitro radical, dialkylamino radical or halogen, n is 0 or an integer ranging from 1 to 3, and R may be identical or different when n is an integer of 2 or 3)]; a process for the preparation of said compounds; and photosensitive materials having a high sensitivity as well as a high flexibility which comprises a conductive support and a photosensitive layer formed thereon, said photosensitive layer containing a disazo pigment, as an effective ingredient, which is expressed by the general formula ##STR3## [wherein R' represents a member selected from the group consisting of hydrogen, ethyl radical, chloroethyl radical and hydroxyethyl radical, A' represents a member selected from the group consisting of ##STR4## (wherein X represents a member selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc., heterocyclic rings such as indole ring, carbazole ring, benzofuran ring, etc. and their substituents, Ar.sub.1 represents a member selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc., heterocyclic rings such as dibenzofuran ring, etc. and their substituents, Ar.sub.2 and Ar.sub.3 represent respectively a member selected from the group consisting of aromatic rings such as benzene ring, naphthalene ring, etc. and their substituents, R.sub.1 and R.sub.3 represent respectively a member selected from the group consisting of hydrogen, lower alkyl radical or phenyl radical and their substituents, and R.sub.2 represents a member selected from the group consisting of lower alkyl radical, carboxyl radical and their esters)].
    • 本发明提供由通式 [其中A表示“(其中R表示烷基,烷氧基,硝基,二烷基氨基或卤素,n为0或1至3的整数)表示的双偶氮化合物 当n为2或3的整数时,R可以相同或不同)]; 一种制备所述化合物的方法; 以及具有高灵敏度的感光材料以及包含导电性支持体和形成在其上的感光层的高柔性,所述感光层含有双偶氮颜料作为有效成分,其通过通式[表示] [其中 R'表示选自氢,乙基,氯乙基和羟乙基的成员,A'表示选自下列的成员:其中X表示选自芳环的成员 苯环,萘环等杂环,吲哚环,咔唑环,苯并呋喃环等杂环及其取代基,Ar1表示选自苯环,萘环等芳香族的基团, 等等,杂环如二苯并呋喃环等及其取代基,Ar2和Ar3分别表示选自 由苯环,萘环等芳香环和它们的取代基组成的基团,R1和R3分别表示选自氢,低级烷基或苯基及其取代基的成员,R2表示选自 由低级烷基,羧基和它们的酯组成的组)]。