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1. 发明专利

JP2010142809A Method for manufacturing zeolite membrane 有权
标题翻译：制备沸石膜的方法
公开(公告)号：JP2010142809A
公开(公告)日：2010-07-01
申请号：JP2010057286
申请日：2010-03-15
申请人： Mitsui Eng & Shipbuild Co Ltd , 三井造船株式会社
发明人： KONDO MASAKAZU , ABE ATSUSHI , SUGIMOTO ETSUO , YAMAMURA TADASHI
IPC分类号： B01D71/02 , B01D69/10 , B01D69/12 , C01B39/14 , C01B39/24 , C01B39/30
摘要： PROBLEM TO BE SOLVED: To easily form a zeolite membrane on the surface of a porous metal support. SOLUTION: A tubular porous metal support 1 having one end closed is pretreated with a nonvolatile cleaning agent. After being washed and dried, the porous metal support 1 is finally treated with an acid for functional group modification. Zeolite seed crystals are supported on or attached to the portion finally treated to form a zeolite membrane e. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：为了容易地在多孔金属载体的表面上形成沸石膜。解决方案：一端封闭的管状多孔金属支撑件1用不挥发性清洁剂预处理。洗涤并干燥后，最后用酸进行多孔金属载体1处理以进行官能团改性。沸石晶种负载在或最终处理以形成沸石膜的部分上。版权所有（C）2010，JPO＆INPIT

2. 发明专利

JP2006263561A Distillation-membrane separation hybrid apparatus and separation method in which distillation and membrane separation are combined 有权
标题翻译：蒸馏膜分离混合装置和分离方法，分离和膜分离组合
公开(公告)号：JP2006263561A
公开(公告)日：2006-10-05
申请号：JP2005084620
申请日：2005-03-23
申请人： Mitsui Eng & Shipbuild Co Ltd , 三井造船株式会社
发明人： KONDO MASAKAZU , SUGIMOTO ETSUO , YAMAMURA TADASHI , MATSUO YASUO
IPC分类号： B01D3/36 , B01D53/22 , C07B63/00 , C07C29/76 , C07C31/08
CPC分类号： Y02P20/126 , Y02P20/57 , Y02P20/572
摘要： PROBLEM TO BE SOLVED: To provide a separation apparatus for a liquid mixture with excellent separation performance and high energy efficiency while an installation space is compact in a separation operation of the liquid mixture in which it could not be separated only by a specific distillation method. SOLUTION: The separation device for the liquid mixture includes distillation means 3, 4 for separating the liquid mixture of two or more components; and a membrane separation means 13 having a zeolite membrane for separating the vapor mixture distilled from a column top of the distillation means. The device has a pressure control means comprising a pressure regulation valve 6 and two or more condensers 7, 8 arranged in a route for reflux of a part of the vapor mixture to an upper part of the distillation means; and an over-heating adjustment means 12 arranged between the column top of the distillation means 4 and the membrane separation means 13. The distillation vapor from the distillation means 4 is fed to the membrane separation means 13 while making it in the stable over-heating state. The separation performance is made high and reduction of energy consumption of the whole separation device and miniaturization of facility are realized. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种具有优异的分离性能和高能量效率的液体混合物的分离装置，而在液体混合物的分离操作中的安装空间紧凑的情况下，其不能仅由特定的蒸馏法。解决方案：液体混合物的分离装置包括用于分离两种或多种组分的液体混合物的蒸馏装置3,4; 以及膜分离装置13，其具有分离从蒸馏装置的塔顶馏出的蒸气混合物的沸石膜。该装置具有压力控制装置，该压力控制装置包括压力调节阀6和两个或更多个冷凝器7,8，该冷凝器7,8排列成一部分蒸汽混合物回流到蒸馏装置的上部的路线; 以及布置在蒸馏装置4的塔顶和膜分离装置13之间的过热调节装置12.来自蒸馏装置4的蒸馏蒸气被供给到膜分离装置13，同时使其处于稳定的过热州。分离性能提高，整个分离装置的能耗降低，设备小型化实现。版权所有（C）2007，JPO＆INPIT

3. 发明专利

JP2005066473A Membrane separation method, membrane separation apparatus and membrane module 审中-公开
标题翻译：膜分离方法，膜分离装置和膜模块
公开(公告)号：JP2005066473A
公开(公告)日：2005-03-17
申请号：JP2003300002
申请日：2003-08-25
申请人： Mitsui Eng & Shipbuild Co Ltd , 三井造船株式会社
发明人： KONDO MASAKAZU , ABE ATSUSHI , SUGIMOTO ETSUO , YAMAMURA TADASHI
IPC分类号： B01D61/36 , B01D53/22
摘要： PROBLEM TO BE SOLVED: To provide a membrane separation method in which a vapor-liquid fluid mixture can be controlled easily and problems such as concentration polarization and temperature drop can be solved, and to provide a membrane separation apparatus and a membrane module. SOLUTION: A liquid mixture 1a is made to be the vapor-liquid fluid mixture 1d having a vapor phase the temperature of which is higher than that of a liquid phase. the vapor-liquid fluid mixture 1d is supplied to the primary side of a separation membrane 31 and the pressure of the secondary side is made negative so that an impure component in the liquid mixture 1a can be permeated into the secondary side of the separation membrane 31. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种能够容易地控制气液混合物的膜分离方法，并且可以解决诸如浓度偏振和温度下降的问题，并且提供膜分离装置和膜组件。解决方案：将液体混合物1a制成汽相液体混合物1d，其气相的温度高于液相。气液流体混合物1d被供给到分离膜31的一次侧，二次侧的压力为负，使得液体混合物1a中的不纯成分能够渗透到分离膜31的二次侧（C）2005，JPO＆NCIPI

4. 发明专利

JP2006263574A Double-cylinder heating type membrane module 有权
标题翻译：双缸加热型膜模块
公开(公告)号：JP2006263574A
公开(公告)日：2006-10-05
申请号：JP2005085146
申请日：2005-03-24
申请人： Mitsui Eng & Shipbuild Co Ltd , 三井造船株式会社
发明人： KONDO MASAKAZU , SUGIMOTO ETSUO , YAMAMURA TADASHI , ABE ATSUSHI
IPC分类号： B01D61/36 , B01D63/06 , B01D65/00 , B01D71/02
摘要： PROBLEM TO BE SOLVED: To optimize a required membrane area by preventing reduction of a temperature of a fed liquid (liquid to be treated) in a module or condensation of a fed vapor (vapor to be treated).
SOLUTION: The double-cylinder heating type membrane module is provided with a cylinder type body 14; a pipe plate 15 attached to an opening end of the body; and a channel 17 covering the pipe plate, closing the opening of the body and having a permeation vapor taking out port 16. In the membrane module, an opening end of a tubular separation membrane body 18 is attached to the pipe plate in the cantilever form. The tubular separation membrane body 18 is covered with a sleeve pipe 23 to form a double pipe shape and a heating medium b is fed into the body 14 to heat a mixture a fed into the sleeve pipe.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：通过防止在模块中供给的液体（待处理液体）的温度降低或进料的蒸汽（待处理的蒸气）的冷凝来优化所需的膜面积。解决方案：双缸加热型膜组件设有气缸体14; 附接到主体的开口端的管板15; 以及覆盖管板的通道17，封闭主体的开口并具有透过蒸气取出口16.在膜组件中，管状分离膜体18的开口端以悬臂形式附接到管板。管状分离膜体18被套筒管23覆盖以形成双管状，并且将加热介质b供给到主体14中以加热供给到套管中的混合物。版权所有（C）2007，JPO＆INPIT

5. 发明专利

JP2005313156A Vacuum maintaining device and vacuum maintaining method 有权
标题翻译：真空维护装置和真空维护方法
公开(公告)号：JP2005313156A
公开(公告)日：2005-11-10
申请号：JP2005094154
申请日：2005-03-29
申请人： Mitsui Eng & Shipbuild Co Ltd , New Energy & Industrial Technology Development Organization , Wave Engineering:Kk , 三井造船株式会社 , 株式会社ウエイブエンジニアリング , 独立行政法人新エネルギー・産業技術総合開発機構
发明人： TOMISHIGE TOSHIRO , HIGUCHI HIROFUMI , NISHINO YUKIO , KONDO MASAKAZU , SUGIMOTO ETSUO , YAMAMURA TADASHI , SHIBATA KINICHI
IPC分类号： F16J15/08 , B01D63/00 , B01D63/06 , B01D71/02 , B01J3/00 , F16J15/06
CPC分类号： B01D63/06 , B01D2313/04
摘要： PROBLEM TO BE SOLVED: To provide a vacuum maintaining device that blocks both ends of a permeable component separation cylindrical member by allowing a predetermined component contained in a mixed substance in the exterior of a cylinder to pass through a cylindrical wall for separation with the interior of the cylinder kept at a negative pressure.
SOLUTION: The vacuum maintaining device is provided with sealing instruments that are each mounted on both cylindrical ends and seal the cylindrical ends, and the sealing instruments are each provided with a plurality of stepped sealing sections comprising a cylindrical end fixing member that is fixed to the cylindrical end, a spiral member that is spirally bonded to the cylindrical end fixing member in the axial direction of a cylinder, an annular accommodating section formed between the cylindrical end fixing member and the spiral member and cylindrical internal peripheral surfaces or cylindrical external peripheral surfaces on the cylindrical ends, a plurality of annular sealing members that are fitted into the annular accommodating section, and annular interposing members that are interposed between the annular sealing members and are slidable in the axial direction of the cylinder, and the annular sealing member is elastically deformed by a pinching pressure in response to the screwing of the spiral member into the cylindrical fixing end member and corresponds to the number of the annular sealing members over the axial direction of the cylinder.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种真空保持装置，其通过使包含在气缸外部的混合物质中的预定成分通过圆筒壁分离，从而阻挡可渗透部件分离圆柱形部件的两端，气缸的内部保持在负压。解决方案：真空保持装置设置有密封装置，每个密封装置安装在两个圆柱形端部上并密封圆柱形端部，并且密封装置均设置有多个阶梯式密封部分，其包括圆柱形端部固定构件固定到圆筒形端部，螺旋形构件，其在圆柱体的轴向方向上螺旋地结合到圆筒形端部固定构件，形成在圆柱形端部固定构件和螺旋构件之间的环形容纳部分和圆柱形内周面或圆柱形外部圆筒端部的圆周表面，与环形容纳部分相配合的多个环形密封构件和插入在环形密封构件之间并且可在气缸轴向滑动的环形介入构件，环形密封构件由于受到压力的弹性变形将螺旋构件拧入圆筒形固定端构件中，并且对应于环形密封构件在圆柱体的轴向方向上的数量。版权所有（C）2006，JPO＆NCIPI

6. 发明专利

JP2005074382A Mixture separation membrane and mixture separation method 审中-公开
标题翻译：混合分离膜和混合分离方法
公开(公告)号：JP2005074382A
公开(公告)日：2005-03-24
申请号：JP2003310935
申请日：2003-09-03
申请人： Mitsui Eng & Shipbuild Co Ltd , 三井造船株式会社
发明人： KONDO MASAKAZU , ABE ATSUSHI , SUGIMOTO ETSUO , YAMAMURA TADASHI
IPC分类号： B01D71/02 , B01D61/36
摘要： PROBLEM TO BE SOLVED: To provide a mixture separation membrane having an excellent separation performance by grasping a zeolite membrane from the side surface of the fine structure.
SOLUTION: The mixture separation membrane has the zeolite membrane deposited on a porous substrate. The zeolite membrane is constituted of assembly of fine agglomerates where the proportion of apertures of crystalline agglomerates falling into the range of Kelvin diameter within 4A nm occupies 99% or more of the whole of apertures of crystalline agglomerates, when the Kelvin diameter of frequency peak in aperture distribution of the crystalline agglomerates calculated according to the Kelvin equation 1 based on the wet gas permeation dynamic method is made to be A nm : RTln(P/P
sat )=-ν×2σcosθ/r
p (1), wherein P is vapor pressure in supply gas, P
sat is the saturated vapor pressure, R is the gas constant, T is a temperature, ν is the molecular volume of a condensate, σ is an interfacial force between the condensate and inactive gas, θ is a contact angle and r
p is a capillary condensation diameter.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：通过从精细结构的侧表面抓住沸石膜来提供具有优异分离性能的混合物分离膜。解决方案：混合物分离膜具有沉积在多孔基材上的沸石膜。沸石膜由细小团聚体组成，其中结晶聚集体的孔径在4Anm以内的开尔文直径范围内的比例占整个结晶聚集体孔径的99％以上，当开尔文直径的频率峰值在将基于湿气渗透动力学方法的开尔文方程式1计算出的结晶聚集体的孔径分布设为A nm：RTln（P / P sat ）=-ν×2σcosθ/ SB> p （1）其中P是供应气体中的蒸汽压，P sat 是饱和蒸气压，R是气体常数，T是温度，ν是分子冷凝物的体积，σ是冷凝物和惰性气体之间的界面力，θ是接触角，r p 是毛细管冷凝直径。版权所有（C）2005，JPO＆NCIPI

7. 发明专利

JP2004148208A Membrane separation method and apparatus for the same 审中-公开
标题翻译：膜分离方法及其设备
公开(公告)号：JP2004148208A
公开(公告)日：2004-05-27
申请号：JP2002316423
申请日：2002-10-30
申请人： Mitsui Eng & Shipbuild Co Ltd , 三井造船株式会社
发明人： YAMAMURA TADASHI
IPC分类号： H05B6/64 , B01D61/36 , B01D71/02 , C12G3/10 , H05B6/74 , H05B6/80
摘要： PROBLEM TO BE SOLVED: To provide a membrane separation method which efficiently separates one composition in a liquid mixture, and an apparatus for the same.
SOLUTION: In the membrane separation method, the liquid mixture b is fed to a primary side 8a of the separation membrane 8, and on the other hand, the one composition in the liquid mixture b is permeated to a secondary side 8b of the separation membrane 8 by generating a negative pressure in the secondary side 8b of the separation membrane 8, so that the concentration of the liquid mixture b on the primary side 8a of the separation membrane 8 is increased, wherein a separation membrane 8 is directly heated.
COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供一种有效分离液体混合物中的一种组合物的膜分离方法及其装置。解决方案：在膜分离方法中，将液体混合物b进料到分离膜8的一次侧8a，另一方面，将液体混合物b中的一种组分渗透到二次侧8b 分离膜8通过在分离膜8的次级侧8b产生负压，使得分离膜8的初级侧8a上的液体混合物b的浓度增加，其中分离膜8被直接加热。版权所有（C）2004，JPO

8. 发明专利

JP2004123457A Synthesizing method of zeolite film 审中-公开
公开(公告)号：JP2004123457A
公开(公告)日：2004-04-22
申请号：JP2002290704
申请日：2002-10-03
申请人： Mitsui Eng & Shipbuild Co Ltd , 三井造船株式会社
发明人： YAMAMURA TADASHI , NAMETAKE TOMOMI , MORIGAMI YOSHIO
IPC分类号： B01D67/00 , B01D69/10 , B01D71/02 , C01B39/00
摘要： PROBLEM TO BE SOLVED: To provide a synthesizing method of a zeolite film by which surface treatment of the supporting body can be done in an easy procedure.
SOLUTION: The synthesizing method for a zeolite film includes a surface treatment process of a supporting body to subject the supporting body for the formation of a zeolite film to the surface treatment followed by a zeolite film forming process to form the zeolite film. The surface treatment process on the supporting body is carried out by applying ultrasonic waves to the supporting body for the formation of the zeolite film. By this method, unnecessary substances depositing on the supporting body surface can be removed by the eroding effect, and a fragile part of the surface is eroded to reveal a new surface. The pore diameter and roughness of the supporting body surface can be controlled. Since the process is easy and surface treatment of the supporting body is efficiently performed, the method is suitable for mass treatment. The amount of the consumed materials necessary for the surface treatment can be significantly decreased.
COPYRIGHT: (C)2004,JPO

9. 发明专利

JP2004188353A Evaluation method of membrane characteristics of pervaporation membrane 审中-公开
标题翻译：渗透膜膜特性评价方法
公开(公告)号：JP2004188353A
公开(公告)日：2004-07-08
申请号：JP2002361395
申请日：2002-12-12
申请人： Mitsui Eng & Shipbuild Co Ltd , 三井造船株式会社
发明人： YAMAMURA TADASHI
IPC分类号： G01M3/00 , B01D61/36 , B01D65/10 , B01D71/02
摘要： PROBLEM TO BE SOLVED: To provide an evaluation method of evaluating characteristics of a separation pipe using a zeolite membrane in a short time.
SOLUTION: The method of evaluating the characteristics of a pervaporation membrane element 20 made by depositing a separation film of zeolite on a surface of a porous substrate comprises the steps of measuring the weight of the separation element 20 in the dry state, adsorbing a matter to be separated on the separation membrane by bringing the element 20 into contact with a solution to be treated or the saturated vapor of the solution to be treated and measuring the weight of the matter adsorbed by measuring the weight of the element 20 on which the matter is adsorbed.
COPYRIGHT: (C)2004,JPO&NCIPI

10. 发明专利

JP2004148209A Pervaporation membrane and method for manufacturing the same 审中-公开
公开(公告)号：JP2004148209A
公开(公告)日：2004-05-27
申请号：JP2002316430
申请日：2002-10-30
申请人： Mitsui Eng & Shipbuild Co Ltd , 三井造船株式会社
发明人： YAMAMURA TADASHI
IPC分类号： B01D69/10 , B01D61/36 , B01D71/02
摘要： PROBLEM TO BE SOLVED: To provide a pervaporation membrane which has high durability while having a permeation performance equal to that heretofore and a method for manufacturing the same.
SOLUTION: The pervaporation membrane consists of a porous support 2 and a separation membrane 3 deposited on the support 2. The separation membrane 3 comprises an A type zeolite membrane 4 having a membrane separation function and a protective layer 5 which is deposited on the A type zeolite membrane 4 and has a density coarser than the density of the A type zeolite membrane 4.
COPYRIGHT: (C)2004,JPO

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