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    • 1. 发明专利
    • Method for manufacturing polyimide film
    • 制备聚酰亚胺膜的方法
    • JP2012233021A
    • 2012-11-29
    • JP2011100333
    • 2011-04-28
    • Mitsui Chemicals Inc三井化学株式会社
    • MATSUDA TOSHINORIONO YOSUKEKAGAYAMA AKISHISAKATA YOSHIHIROYAMASHITA WATARUFUKUKAWA KENICHI
    • C08J5/18C08G73/10
    • PROBLEM TO BE SOLVED: To provide a method for manufacturing a polyimide film, which does not cause appearance defects and a decrease in strength, and whitening and the like involved in the imidization reaction.SOLUTION: The method for manufacturing a polyimide film includes: (a) a step of coating on a support a polyamic acid-containing solution obtained by reacting a specific tetracarboxylic dianhydride with a specific diamine in a solvent; (b) a step of drying the solvent in the polyamic acid-containing solution at a temperature of 150°C or lower until a polyamic acid-containing film composed of a coating film of the polyamic acid-containing solution becomes tack-free; (c) a step of peeling the polyamic acid-containing film from the support; and (d) a step of fixing and heating the polyamic acid-containing film while the temperature is being raised from 150°C or lower to imidize the polyamic acid to thereby obtain the polyimide film.
    • 要解决的问题:提供一种不引起外观缺陷和强度降低的方法,以及涉及酰亚胺化反应的美白等。 聚酰亚胺膜的制造方法包括:(a)在载体上涂布通过使特定的四羧酸二酐与特定的二胺在溶剂中反应得到的含聚酰胺酸的溶液的工序; (b)在150℃以下的温度下干燥含有聚酰胺酸的溶液中的溶剂,直到由含聚酰胺酸的溶液的涂膜组成的含聚酰胺酸的膜变得无粘性的步骤; (c)从载体剥离含聚酰胺酸的膜的步骤; 和(d)在将温度从150℃以上升温至聚酰胺酸酰亚胺化的同时,对含有聚酰胺酸的膜进行固定加热的步骤,得到聚酰亚胺膜。 版权所有(C)2013,JPO&INPIT
    • 2. 发明专利
    • Photosensitive resin composition for volume hologram recording and volume hologram using the same
    • 使用相同的体积卷曲记录和体积卷曲的感光树脂组合物
    • JP2005189256A
    • 2005-07-14
    • JP2003426712
    • 2003-12-24
    • Mitsui Chemicals Inc三井化学株式会社
    • TAKAMATSU YASUSHIONISHI HITOSHISAKATA YOSHIHIRO
    • G03F7/004G03F7/029G03H1/02
    • PROBLEM TO BE SOLVED: To provide a photosensitive resin composition for a volume hologram recording, the photosensitive resin composition having high sensitivity in a visible light region, in particular, to the second harmonic waves (at 532 nm) of a YAG laser which is a stable laser light source with high output, emission lines (at 458 nm, 488 nm and 514.5 nm) of an argon laser, or krypton ion laser light (647.1 nm), and having preferable compatibility with other resin compositions such as a photosensitizing agent.
      SOLUTION: The photosensitive resin composition for volume hologram recording contains a photo-cation polymerizable compound, a binder resin, a photo cation initiator and a specified dipyrromethene boron complex compound.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了提供用于体积全息图记录的感光性树脂组合物,在可见光区域中具有高灵敏度的感光性树脂组合物,特别是YAG激光器的第二谐波(532nm) 其是具有高输出的稳定的激光光源,氩激光器的发射线(在458nm,488nm和514.5nm)或氪离子激光(647.1nm),并且与其它树脂组合物 光敏剂。 解决方案:用于体积全息记录的感光性树脂组合物含有光阳离子聚合性化合物,粘合剂树脂,光阳离子引发剂和特定的二吡咯亚甲基硼络合物。 版权所有(C)2005,JPO&NCIPI
    • 3. 发明专利
    • Polyimide film and method for producing the same
    • 聚酰亚胺膜及其制造方法
    • JP2014034590A
    • 2014-02-24
    • JP2012175013
    • 2012-08-07
    • Mitsui Chemicals Inc三井化学株式会社
    • SAKATA YOSHIHIROFUKUKAWA KENICHIOKAZAKI MASAKIURAGAMI TATSUNOBUMATSUDA TOSHINORIONO YOSUKEYAMASHITA WATARU
    • C08J5/18B29C41/12C08G73/10G02B5/20G02F1/1333H01L51/50H05B33/02
    • PROBLEM TO BE SOLVED: To provide a polyimide film and a method for producing the same, the film having high optical transparency and a small in-plane retardation.SOLUTION: A production method is provided for a polyimide film having overall light transmittance of 80% or more and an in-plane retardation of 10 nm or less. The method includes steps of: (a) applying a polyimide precursor-containing solution containing a polyimide precursor on a substrate; (b) heating a polyimide precursor film comprising the coating film of the polyimide precursor-containing solution until an imidization rate of the polyimide precursor reaches 90% or more and the residual amount of the solvent is reduced to 1 mass% or less; (c) peeling off the film obtained in step (b) from the substrate; and (d) heating the film obtained in step (c) again. In the step (d), a heating temperature of the film obtained in step (c) is controlled to be equal to or lower than the glass transition temperature of the polyimide.
    • 要解决的问题:为了提供一种聚酰亚胺膜及其制造方法,该膜具有高的光学透明度和小的面内延迟。解决方案:提供了一种制备方法,该聚酰亚胺膜的总透光率为80% 以上,面内延迟为10nm以下。 该方法包括以下步骤:(a)在基材上涂布含有聚酰亚胺前体的含聚酰亚胺前体溶液; (b)加热含有聚酰亚胺前体的溶液的涂膜的聚酰亚胺前体膜,直到聚酰亚胺前体的酰亚胺化率达到90%以上,溶剂的残留量为1质量%以下。 (c)从基板剥离步骤(b)中获得的膜; 和(d)再次加热步骤(c)中获得的膜。 在步骤(d)中,将步骤(c)中获得的膜的加热温度控制在等于或低于聚酰亚胺的玻璃化转变温度。
    • 6. 发明专利
    • Novel polyimide and its use
    • 新型聚酰亚胺及其用途
    • JP2012251080A
    • 2012-12-20
    • JP2011125171
    • 2011-06-03
    • Mitsui Chemicals Inc三井化学株式会社
    • URAGAMI TATSUNOBUOKAZAKI MASAKIFUKUKAWA KENICHISAKATA YOSHIHIROYAMASHITA WATARU
    • C08G73/10
    • PROBLEM TO BE SOLVED: To provide a novel polyimide high in transparency and capable of being melt molded.SOLUTION: In the polyimide having a repeating unit derived from an acid anhydride component and a diamine component and represented by formula (1A), the acid anhydride component contains an alicyclic acid anhydride represented by formulae (2A) and/or (2B) as an essential component, which is contained in a ratio of 20 to 100 mol% in the whole acid anhydride; and the diamine component contains an aromatic diamine represented by formulae (3A) and/or (3B) as an essential component, which is contained in a ratio of 20 to 100 mol% in the whole diamine.
    • 要解决的问题:提供一种透明度高且能够熔融成型的新型聚酰亚胺。 解决方案:在具有由酸酐组分衍生的重复单元和由式(1A)表示的二胺组分的聚酰亚胺中,酸酐组分含有由式(2A)和/或(2B)表示的脂环酸酐 )作为必需成分,其在全部酸酐中的比例为20〜100摩尔% 二胺成分含有作为主要成分的式(3A)和/或(3B)所示的芳香族二胺,其比例在全部二胺中为20〜100摩尔%。 版权所有(C)2013,JPO&INPIT
    • 7. 发明专利
    • Photo-setting resin composition for sealing material
    • 用于密封材料的光固化树脂组合物
    • JP2003327951A
    • 2003-11-19
    • JP2002135756
    • 2002-05-10
    • Mitsui Chemicals Inc三井化学株式会社
    • YAMAMOTO YUGOTAKAMATSU YASUSHISAKATA YOSHIHIROKUWAZUKA TOSHIAKI
    • G02F1/1339C08G59/20C08G65/18C09K3/10
    • PROBLEM TO BE SOLVED: To obtain a photo-setting resin composition for a sealing material having excellent photo-setting properties and good adhesion and moisture permeation resistance. SOLUTION: This photo-setting resin composition for the sealing material comprises (A) a compound having an oxetane ring, (B) a polycyclic compound having at least one epoxy group and (C) a photocationic initiator and has a viscosity at 25°C within the range of 0.01-300 Pas. The photo-setting resin composition comprises (G) a cationic polymerizable compound and (C) the photocationic initiator and has the viscosity at 25°C within the range of 0.01-300 Pas. A cured product has 50-200 N/mm 2.5 film stiffness strength. COPYRIGHT: (C)2004,JPO
    • 要解决的问题:获得具有优异的光固化性和良好的粘合性和耐湿透性的密封材料的光固化树脂组合物。 解决方案:这种用于密封材料的光固化树脂组合物包括(A)具有氧杂环丁烷环的化合物,(B)具有至少一个环氧基的多环化合物和(C)光阳离子引发剂,并且在 25°C,范围为0.01-300 Pas。 光固性树脂组合物包含(G)阳离子可聚合化合物和(C)光阳离子引发剂,并且在25℃下的粘度在0.01-300Pa·s的范围内。 固化产品具有50-200N / mm 2.5 膜刚度强度。 版权所有(C)2004,JPO