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    • 2. 发明专利
    • Catalyst for use in polymerization of ethylenically unsaturated monomer, and method of polymerizing ethylenically unsaturated monomer using the catalyst
    • 用于乙烯基不饱和单体聚合的催化剂,以及使用催化剂聚合乙烯不饱和单体的方法
    • JP2007126686A
    • 2007-05-24
    • JP2007038420
    • 2007-02-19
    • Mitsui Chemicals Inc三井化学株式会社
    • DOI YASUSHIMAKIO HARUYUKIFUJITA TERUNORITSUTSUI TOSHIYUKI
    • C08F4/60
    • PROBLEM TO BE SOLVED: To provide a catalyst comprising a novel catalyst component and a transition metal compound, and a polymerization method using the catalyst. SOLUTION: The catalyst for use in polymerization of an ethylenically unsaturated monomer comprises (A) a compound of a transition metal selected from those belonging to the groups 3 to 12 in the periodic table, (B) a catalyst component, and (C) a specific organic aluminum compound, wherein component (B) is a catalyst component obtained by reacting, in any order, (i) a specific organic aluminum compound, (ii) H 2 O, R 4 NH 2 , etc. (R 4 represents a halogenated hydrocarbon group), and (iv) R 10 X, R 10 H, R 10 OH or R 10 COOH (R 10 represents a halogenated hydrocarbon group, and X represents a halogen atom), and then reacting the reaction product with (iii) triphenyl chloromethane, bis(η-cyclopentadienyl)iron-sulfate, N,N-dimethyl anilinium chloride or triethyl ammonium chloride. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供包含新型催化剂组分和过渡金属化合物的催化剂和使用该催化剂的聚合方法。 解决方案:用于烯键式不饱和单体聚合的催化剂包含(A)选自元素周期表中第3至12族的过渡金属化合物,(B)催化剂组分和( C)特定有机铝化合物,其中组分(B)是通过以任何顺序使(i)特定的有机铝化合物,(ii)H 2 SBO,R 2, SP> 4 NH 2 等(R 4 表示卤代烃基),和(iv)R 10 ,R 10,R 10,R 10,R 10,R 10,R 10,R 10,R 10, X表示卤素原子),然后使反应产物与(iii)三苯基氯甲烷,双(η-环戊二烯基)硫酸铁,N,N-二甲基苯胺氯化物或三乙基氯化铵反应。 版权所有(C)2007,JPO&INPIT
    • 3. 发明专利
    • Polymer containing functional group of vicinal substitution type and use thereof
    • 含有取代类型功能组的聚合物及其用途
    • JP2006307191A
    • 2006-11-09
    • JP2006090003
    • 2006-03-29
    • Mitsui Chemicals Inc三井化学株式会社
    • AITHA V PRASADMAKIO HARUYUKIISOGAWA SOROMATOISHI KAORIFUJITA TERUNORI
    • C08F8/00C08F10/00C08L27/06G03G9/08
    • PROBLEM TO BE SOLVED: To provide a new polymer containing a functional group of vicinal substitution type and the use thereof.
      SOLUTION: The present invention provides a polymer containing a functional group of vicinal substitution type represented by Formula (I): wherein A represents a group formed by the polymerization of ethylene or the like which has a weight average molecular weight of 400 to 500,000 as measured by GPC; Z represents a hydrogen atom, an alkyl group or the like; and one of X and Y represents a hydroxy group, a polyalkylene glycol group or the like and another of X and Y represents a specified functional group. Also provided are a releasing agent for a toner, a pigment dispersing agent and a lubricant for a vinyl chloride resin which comprise the polymer containing a functional group of vicinal substitution type.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 待解决的问题:提供一种含有邻位取代型官能团的新型聚合物及其用途。 解决方案:本发明提供一种含有式(I)所示的邻位取代型官能团的聚合物:其中A表示通过乙烯等的聚合形成的基团,其重均分子量为400〜 通过GPC测量的500,000; Z表示氢原子,烷基等; X和Y中的一个表示羟基,聚亚烷基二醇基等,X和Y中的另一个表示规定的官能团。 还提供了一种用于调色剂的脱模剂,颜料分散剂和用于氯乙烯树脂的润滑剂,其包含含有邻位取代型官能团的聚合物。 版权所有(C)2007,JPO&INPIT
    • 5. 发明专利
    • One-terminal-functional polyolefin
    • 单末端功能聚烯烃
    • JP2005097587A
    • 2005-04-14
    • JP2004247319
    • 2004-08-26
    • Mitsui Chemicals Inc三井化学株式会社
    • MAKIO HARUYUKIFUJITA TERUNORI
    • C08F8/00
    • PROBLEM TO BE SOLVED: To provide a one-terminal-functional polyolefin useful in various applications.
      SOLUTION: The one-terminal-functional polyolefin is represented by general formula (I) (wherein X is a group containing at least one kind of element selected from among oxygen, sulfur, nitrogen, phosphor, and halogens; P is a polymer chain formed by using, as the main component, an olefin composed of only carbon atoms and hydrogen atoms; and X is bonded to a terminal of P) and its molecular weight distribution (Mw/Mn) obtained by gel permeation chromatography (GPC) is 1.0-1.5.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 待解决的问题:提供可用于各种应用的单末端官能聚烯烃。 解决方案:一末端官能聚烯烃由通式(I)表示(其中X是含有选自氧,硫,氮,磷和卤素中的至少一种元素的基团; P是 通过使用仅由碳原子和氢原子组成的烯烃形成的聚合物链; X键合到P的末端,其通过凝胶渗透色谱法(GPC)获得的分子量分布(Mw / Mn) 是1.0-1.5。 版权所有(C)2005,JPO&NCIPI
    • 8. 发明专利
    • One-terminal-functional polyolefin
    • 单末端功能聚烯烃
    • JP2009155655A
    • 2009-07-16
    • JP2009096994
    • 2009-04-13
    • Mitsui Chemicals Inc三井化学株式会社
    • MAKIO HARUYUKIFUJITA TERUNORI
    • C08F10/00C08F4/642C08F8/00
    • C08F10/00C08F8/00C08F8/20C08F110/02C08F110/06C08F4/64048
    • PROBLEM TO BE SOLVED: To provide a method for producing a one-terminal-functional polymer useful in various uses.
      SOLUTION: This method for producing the one-terminal-functional polyolefin obtained by performing the following process 1 and process 2 in the presence of an olefin polymerization catalyst containing (A) the Groups 4 to 5 transition metal-containing compound and then performing the process 3 as necessary, and having a 1.0 to 1.5 molecular weight distribution (Mw/Mn) obtained by gel permeation chromatography (GPC) is provided. [Process 1] The process of contact-mixing (C) a polar group-containing olefin. [Process 2] The process of catalytically mixing ethylene and (D) at least 1 kind olefin selected from 3-20C olefins by n-times (wherein, (n) is an integer of ≥1). Provided that, when the (n) is an integer of ≥2, the kind or composition of the olefin (D) used in each of the times is different. [Process 3] The chemical conversion process.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 待解决的问题:提供一种可用于各种用途的单末端官能聚合物的制备方法。 解决方案:通过在含有(A)第4〜5族过渡金属的化合物的烯烃聚合催化剂的存在下进行以下的方法1和方法2而得到的单末端官能聚烯烃的制造方法, 根据需要进行工序3,提供通过凝胶渗透色谱法(GPC)得到的1.0〜1.5的分子量分布(Mw / Mn)。 [方法1]接触混合(C)含极性基团的烯烃的方法。 [方法2]将乙烯和(D)至少1种选自3-20℃烯烃的烯烃催化混合n次(其中,(n)为≥1)的整数的方法。 假设当(n)为≥2的整数时,每次使用的烯烃(D)的种类或组成不同。 [工艺3]化学转化过程。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • Both-terminal-functional polyolefin
    • 双端功能聚烯烃
    • JP2005097588A
    • 2005-04-14
    • JP2004247320
    • 2004-08-26
    • Mitsui Chemicals Inc三井化学株式会社
    • MAKIO HARUYUKIFUJITA TERUNORI
    • C08F8/00C08F10/00
    • PROBLEM TO BE SOLVED: To provide a both-terminal-functional polyolefin useful in various applications.
      SOLUTION: The both-terminal-functional polyolefin, useful in various applications, is represented by general formula (I) (wherein X and Y are each a group containing at least one kind of element selected from among oxygen, sulfur, nitrogen, phosphor, and halogens, provided X and Y may be the same or different; P is a polymer chain formed by using, as the main component, an olefin composed of only carbon atoms and hydrogen atoms; and X is bonded to one terminal of P, and Y, to the other terminal) and its molecular weight distribution (Mw/Mn) obtained by gel permeation chromatography (GPC) is 1.0-1.5.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供可用于各种应用的双末端官能聚烯烃。 解决方案:可用于各种应用的双末端官能聚烯烃由通式(I)表示(其中X和Y各自是含有选自氧,硫,氮中的至少一种元素的基团 荧光体和卤素,X和Y可以相同或不同; P是通过使用仅由碳原子和氢原子组成的烯烃作为主要成分形成的聚合物链; X键合到 P和Y),通过凝胶渗透色谱法(GPC)得到的分子量分布(Mw / Mn)为1.0〜1.5。 版权所有(C)2005,JPO&NCIPI
    • 10. 发明专利
    • Both-terminals-functional polyolefin
    • 两端 - 功能性聚烯烃
    • JP2009155656A
    • 2009-07-16
    • JP2009096995
    • 2009-04-13
    • Mitsui Chemicals Inc三井化学株式会社
    • MAKIO HARUYUKIFUJITA TERUNORI
    • C08F8/00C08F4/642C08F10/00
    • C08F10/00C08F8/00C08F8/20C08F110/02C08F110/06C08F4/64048
    • PROBLEM TO BE SOLVED: To provide a both-terminals-functional polyolefin useful in various uses.
      SOLUTION: This method for producing both-terminals-functional polyolefin obtained by performing the following process 1, process 2 and process 1 in this order in the presence of an olefin polymerization catalyst containing (A) the Grups 4 to 5 transition metal-containing compound, and then performing the process 3 as necessary and having a 1.0 to 1.5 molecular weight distribution (Mw/Mn) obtained by gel permeation chromatography (GPC) is provided. [Process 1] The process of contact-mixing (C) a polar group-containing olefin. [Process 2] The process of catalytically mixing ethylene and (D) at least 1 kind olefin selected from 3-20C olefins by n-times (wherein, (n) is an integer of ≥1). Provided that, when the (n) is an integer of ≥2, the kind or composition of the olefin (D) used in each of the times is different. [Process 3] The chemical conversion process.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供可用于各种用途的双末端官能聚烯烃。 解决方案:通过在含有(A)Grups 4至5过渡金属的烯烃聚合催化剂存在下,依次进行以下方法1,方法2和方法1而获得的双末端官能聚烯烃的制造方法 并且然后根据需要进行方法3,并且提供通过凝胶渗透色谱法(GPC)获得的1.0至1.5分子量分布(Mw / Mn)。 [方法1]接触混合(C)含极性基团的烯烃的方法。 [方法2]将乙烯和(D)至少1种选自3-20℃烯烃的烯烃催化混合n次(其中,(n)为≥1)的整数的方法。 假设当(n)为≥2的整数时,每次使用的烯烃(D)的种类或组成不同。 [工艺3]化学转化过程。 版权所有(C)2009,JPO&INPIT