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1. 发明专利

JP2007177089A Polyethylene terephthalate resin composition and blow-molded container made therefrom 有权
标题翻译：聚乙烯三癸酸酯树脂组合物及其制成的发泡容器
公开(公告)号：JP2007177089A
公开(公告)日：2007-07-12
申请号：JP2005377616
申请日：2005-12-28
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： SUGIYAMA KAZUTO , KOREISHI HIROSHI
IPC分类号： C08L67/02 , B65D1/00
摘要： PROBLEM TO BE SOLVED: To provide a polyethylene terephthalate resin composition capable of obtaining blow-molded containers with high heat resistance and transparency in high productivity, and to provide such a blow-molded container using the above resin composition. SOLUTION: The polyethylene terephthalate resin composition comprises the components (A) and (B) described below, wherein the component (B) is contained at 0.1-10,000 ppb in the composition. The component (A) is a polyethylene terephthalate component consisting maily of recurring units derived from dicarboxylic acid(s) comprising terephthalic acid and/or its ester-forming derivative and diol(s) comprising ethylene glycol and/or its ester-forming derivative, wherein the proportion of diethylene glycol units is 0.5-2.0 wt.%. The component (B) is an ethylene-based polymer composition comprising (a) polyethylene and/or (b) an ethylene-(meth)acrylic acid copolymer, being greater than 45 in Shore D hardness. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供能够以高生产率获得高耐热性和透明性的吹塑容器的聚对苯二甲酸乙二醇酯树脂组合物，并使用上述树脂组合物提供这种吹塑容器。解决方案：聚对苯二甲酸乙二醇酯树脂组合物包含下述组分（A）和（B），其中组分（B）在组合物中的含量为0.1-10,000ppb。组分（A）是一种聚对苯二甲酸乙二醇酯组分，其由衍生自包含对苯二甲酸和/或其成酯衍生物的二羧酸的重复单元和包含乙二醇和/或其成酯衍生物的二醇组成，其中二甘醇单元的比例为0.5-2.0重量％。组分（B）是包含（a）聚乙烯和/或（b）乙烯 - （甲基）丙烯酸共聚物的乙烯基聚合物组合物，其肖氏D硬度大于45。版权所有（C）2007，JPO＆INPIT

2. 发明专利

JP2005272493A Method for producing polyester resin, polyester resin and blow molded product 审中-公开
标题翻译：生产聚酯树脂，聚酯树脂和吹塑产品的方法
公开(公告)号：JP2005272493A
公开(公告)日：2005-10-06
申请号：JP2004083775
申请日：2004-03-23
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： MAEDA KEN , HORI HIDESHI , HIRAOKA SHOJI , KOREISHI HIROSHI
IPC分类号： B65D1/00 , B65D1/09 , C08G63/86
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a polyester resin by which a container having excellent color tone can be produced with a small amount of produced cyclic trimers or acetaldehyde. SOLUTION: The method for producing the polyester resin is characterized as follows. A dicarboxylic acid or its ester-forming derivative and a diol or its ester-forming derivative are subjected to liquid-phase polycondensation in the presence of an aluminum compound to produce the polyester resin. A phosphorus compound is then added and contained in the resultant polyester resin. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种生产聚酯树脂的方法，通过该方法可以用少量的产生的环状三聚体或乙醛生产具有优异色调的容器。解决方案：聚酯树脂的制造方法的特征如下。二羧酸或其成酯衍生物和二醇或其成酯衍生物在铝化合物的存在下进行液相缩聚以制备聚酯树脂。然后将磷化合物加入并包含在所得聚酯树脂中。版权所有（C）2006，JPO＆NCIPI

3. 发明专利

JP2008006626A Multilayer preform made of saturated polyester resin and multilayer bottle formed from the preform 有权
标题翻译：饱和聚酯树脂的多层预浸料和从预浸料制成的多层玻璃瓶
公开(公告)号：JP2008006626A
公开(公告)日：2008-01-17
申请号：JP2006177453
申请日：2006-06-28
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： YAMADA NAOHIRO , TSUGAWA MICHIO , KOREISHI HIROSHI
IPC分类号： B29C49/22 , B29B11/14 , B29K67/00 , B29K105/16 , B29L22/00 , B65D1/00 , B65D1/02
CPC分类号： B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/14113 , B29B2911/1412 , B29B2911/1414 , B29B2911/14146
摘要： PROBLEM TO BE SOLVED: To provide a polyester preform excellent in transparency and surface slidability and a hollow molding.
SOLUTION: The multilayer preform made of a saturated polyester resin is formed from a saturated polyester resin layer having at least two layers including a skin layer and a core layer. The saturated polyester resin forming the skin layer contains inert particles with a mean particle size of 5 μm or below. A multilayer saturated polyester resin bottle is obtained by extension-molding the preform.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供透明性和表面滑动性优异的中空成型的聚酯预成型体。解决方案：由饱和聚酯树脂制成的多层预制件由具有至少两层包括表层和芯层的饱和聚酯树脂层形成。形成表层的饱和聚酯树脂含有平均粒径为5μm以下的惰性粒子。通过对预成型件进行拉伸成型获得多层饱和聚酯树脂瓶。版权所有（C）2008，JPO＆INPIT

4. 发明专利

JP2006152066A Polyethylene terephthalate 有权
标题翻译：聚对苯二甲酸
公开(公告)号：JP2006152066A
公开(公告)日：2006-06-15
申请号：JP2004342284
申请日：2004-11-26
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： KOREISHI HIROSHI , YAMADA NAOHIRO , MAEDA KEN , MUKAI NOBUTADA
IPC分类号： C08L67/02 , C08K5/521
摘要： PROBLEM TO BE SOLVED: To provide a polyester resin in which the amount of a cyclic trimer or acetaldehyde produced during molding is small; corrosion of a molding and a polymerization apparatus is suppressed; and the reduction in quality due to inclusion of metal species is small.
SOLUTION: There is provided a polyethylene terephthalate having an intrinsic viscosity of 0.60 dl/g or more and containing a cyclic trimer (CT) in an amount of 0.55 wt% or less. When molded to a preform at a molding temperature of 280°C, the polyethylene terephthalate satisfies Formulas 1 and 2: ΔCT≤0.10 wt% (Formula 1), and Fe≤1.0 ppm (Formula 2), wherein ΔCT denotes the increased amount of the cyclic trimer contained in the polyethylene terephthalate during the molding; and Fe denotes the weight of the iron atom contained in the polyethylene terephthalate after molding.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种聚酯树脂，其中在模制过程中产生的环状三聚体或乙醛的量小; 模制品和聚合装置的腐蚀被抑制; 并且由于包含金属物质而导致的质量降低很小。解决方案：提供特性粘度为0.60dl / g以上且含有0.55重量％以下的环状三聚体（CT）的聚对苯二甲酸乙二醇酯。在模塑温度为280℃的模塑制品中，聚对苯二甲酸乙二醇酯满足式1和2：ΔCT≤0.10重量％（式1）和Fe≤1.0ppm（式2），其中ΔCT表示成型时聚对苯二甲酸乙二醇酯中包含的环状三聚体; Fe表示成型后的聚对苯二甲酸乙二醇酯中含有的铁原子的重量。版权所有（C）2006，JPO＆NCIPI

5. 发明专利

JP2005154655A Polyester and blow molded article made therefrom 审中-公开
标题翻译：聚酯和吹塑制品
公开(公告)号：JP2005154655A
公开(公告)日：2005-06-16
申请号：JP2003397948
申请日：2003-11-27
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： KOREISHI HIROSHI , YAMADA NAOHIRO , HAMA TAKASHI , MUKAI NOBUTADA
IPC分类号： C08G63/181
摘要： PROBLEM TO BE SOLVED: To obtain a polyester resin generating little acetaldehyde in the molding of a preform or a bottle.
SOLUTION: The polyester is formed from terephthalic acid and/or isophthalic acid and ethylene glycol. It has an intrinsic viscosity of ≥0.60 [dl/g] and a density of ≥1,390 kg/m
3 and satisfies the formula 1: (AA
4h -AA
1h )≤1.0 ppm wherein AA
1h is the weight ratio of AA (acetaldehyde) extracted in hot water under the condition of 120°C×1hr and AA
4h is the weight ratio of AA extracted in hot water under the condition of 120°C×4hr.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：为了获得在预成型件或瓶子的成型中产生很少乙醛的聚酯树脂。解决方案：聚酯由对苯二甲酸和/或间苯二甲酸和乙二醇形成。它具有≥0.60[dl / g]的特性粘度和≥1,390kg/ m 3的密度，满足式1：（AA 4h -AA 1h ）≤1.0ppm其中AA 1h 是在120℃×1小时和AA 4小时的条件下在热水中提取的AA（乙醛）的重量比， SB>是在120℃×4小时的条件下在热水中提取的AA的重量比。版权所有（C）2005，JPO＆NCIPI

6. 发明专利

JP2004307559A Modified polyethylene terephthalate 审中-公开
公开(公告)号：JP2004307559A
公开(公告)日：2004-11-04
申请号：JP2003099520
申请日：2003-04-02
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： NAKAMACHI KOJI , KOREISHI HIROSHI , KARAIWA MASATO
IPC分类号： C08L67/02 , C08G63/183
摘要： PROBLEM TO BE SOLVED: To provide a modified polyethylene terephthalate readily controlling the crystallization rate, having excellent stability of the crystallization rate and improving the crystallization rate from a low-temperature state.
SOLUTION: The modified polyethylene terephthalate comprises polyethylene terephthalate and a crystalline resin (0.1-10,000 ppb) other than the polyethylene terephthalate. The crystallization temperature Tcc (°C) of a molded product measured with a differential scanning calorimeter during temperature rising and the semicrystallization time t1/2 (s) of the molded product at 180°C satisfy formula (I)Tcc≤0.2×(t1/2)+139 (I).
COPYRIGHT: (C)2005,JPO&NCIPI

7. 发明专利

JP2004131118A Single-layer container made from polyethylene terephthalate 有权
公开(公告)号：JP2004131118A
公开(公告)日：2004-04-30
申请号：JP2002296317
申请日：2002-10-09
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： SASAKI TOYOAKI , KOREISHI HIROSHI , KARAIWA MASATO
IPC分类号： B65D1/00 , B65D1/09 , B65D65/02 , B65D81/26 , C08K3/00 , C08K5/00 , C08L67/02
摘要： PROBLEM TO BE SOLVED: To provide a single-layer container made from polyethylene terephthalate, which has excellent oxygen barrier properties and wherein a volatile constituent quantity is made small. SOLUTION: This single-layer container made from the polyethylene terephthalate contains: the polyethylene terephthalate (A); an oxygen absorbent (B) which is composed of an aromatic polyester, polyolefine and a transition-metal catalyst; and an antioxidant (C). COPYRIGHT: (C)2004,JPO

8. 发明专利

DE69622487T2 未知
公开(公告)号：DE69622487T2
公开(公告)日：2003-04-03
申请号：DE69622487
申请日：1996-04-05
申请人： MITSUI CHEMICALS INC
发明人： KOREISHI HIROSHI , TANAKA YASUHIRO , MIURA KIMIYOSHI
IPC分类号： C08G63/183 , C08G63/78 , C08G63/80 , C08G63/88
摘要： A process for producing a polyethylene terephthalate in which the amount of the oligomers, such as cyclic trimer etc., is lower and which causes metal mold staining to occur difficultly. The process comprises an esterification stage in which dicarboxylic acids including mainly terephthalic acid or ester-forming derivatives of such acids are esterified with glycols including mainly ethylene glycol or with ester-forming derivatives of such glycols; a liquid phase polycondensation stage in which the esterified product obtained in the esterification stage is subjected to a polycondensation in a liquid phase containing a polycondensation catalyst and having a content of an alkaline solubilizing agent of 0.4 mole or less per mole of the polycondensation catalyst with heating; a solid phase polycondensation stage in which the polycondensation product obtained in the liquid phase polycondensation stage is heated at a temperature below the melting point of the product in an inert atmosphere; and an aqua-treatment stage in which the polycondensation catalyst is deactivated by contacting the polycondensation product obtained in the solid phase polycondensation stage with water. The polyethylene terephthalate obtained by this process is suitable as the material for containers to be charged with drinks.

9. 发明专利

DE69622487D1 未知
公开(公告)号：DE69622487D1
公开(公告)日：2002-08-29
申请号：DE69622487
申请日：1996-04-05
申请人： MITSUI CHEMICALS INC
发明人： KOREISHI HIROSHI , TANAKA YASUHIRO , MIURA KIMIYOSHI
IPC分类号： C08G63/183 , C08G63/78 , C08G63/80 , C08G63/88
摘要： A process for producing a polyethylene terephthalate in which the amount of the oligomers, such as cyclic trimer etc., is lower and which causes metal mold staining to occur difficultly. The process comprises an esterification stage in which dicarboxylic acids including mainly terephthalic acid or ester-forming derivatives of such acids are esterified with glycols including mainly ethylene glycol or with ester-forming derivatives of such glycols; a liquid phase polycondensation stage in which the esterified product obtained in the esterification stage is subjected to a polycondensation in a liquid phase containing a polycondensation catalyst and having a content of an alkaline solubilizing agent of 0.4 mole or less per mole of the polycondensation catalyst with heating; a solid phase polycondensation stage in which the polycondensation product obtained in the liquid phase polycondensation stage is heated at a temperature below the melting point of the product in an inert atmosphere; and an aqua-treatment stage in which the polycondensation catalyst is deactivated by contacting the polycondensation product obtained in the solid phase polycondensation stage with water. The polyethylene terephthalate obtained by this process is suitable as the material for containers to be charged with drinks.

10. 发明专利

JP2002302555A METAL COMPOUND-CONTAINING POLYESTER RESIN COMPOSITION, METHOD FOR PRODUCING THE SAME, PREFORM FOR HOLLOW MOLDED PRODUCT, HOLLOW MOLDED PRODUCT AND METHOD FOR PRODUCING THE PREFORM AND MOLDED PRODUCT 失效
公开(公告)号：JP2002302555A
公开(公告)日：2002-10-18
申请号：JP2001106918
申请日：2001-04-05
申请人： MITSUI CHEMICALS INC
发明人： KIYOMIYA TATSUYA , KOREISHI HIROSHI , NAKAMACHI KOJI , TSUGAWA MICHIO
IPC分类号： B65D1/00 , B29B11/08 , B29C49/06 , B29C49/08 , B29K67/00 , B29L22/00 , B65D1/09 , C08J3/22 , C08J5/00 , C08K3/00 , C08K5/09 , C08L67/02
摘要： PROBLEM TO BE SOLVED: To provide a metal compound-containing polyester resin composition homogeneously containing a metal compound, and further to provide a method for stably producing the composition, a perform for a hollow molded product and the hollow molded product produced from the composition, and a method for producing the perform and the hollow molded product. SOLUTION: This metal compound-containing polyester resin composition is obtained by bringing a chip-shaped polyester resin into contact with a member comprising a polyester resin containing the metal compound under a fluidized condition. The method for producing the metal compound-containing polyester resin composition comprises bringing the chip-shaped polyester resin into contact with a member comprising the polyester containing the metal compound under the fluidized condition to provide the polyester resin containing the metal compound.

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