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1. 发明公开

EP4083078A1 WATER REPELLENT COMPOSITION, METHOD FOR PRODUCING WATER REPELLENT COMPOSITION, AND TEXTILE PRODUCT 审中-实审转让
公开(公告)号：EP4083078A1
公开(公告)日：2022-11-02
申请号：EP20905561.5
申请日：2020-12-21
申请人： Mitsui Chemicals, Inc. , DAIKIN INDUSTRIES, LTD.
发明人： KOUDA, Chikako , FUKUDA, Kazuyuki , NAKAMURA, Keisuke , NOGUCHI, Daisuke , MIYAHARA, Masahiro , KAWABE, Rumi , MINAMI, Shinichi
IPC分类号： C08F16/28 , C08F20/68 , C08F20/70 , C08L29/10 , C08L33/04 , C08L75/04 , C09K3/18 , C08G18/28 , C08G18/36 , D06M15/21 , D06M15/263 , D06M15/564 , D06M15/643
摘要： A water repellent composition includes a polyurethane resin compound, a non-fluorine water repellent compound, a surfactant, and a liquid medium. The polyurethane resin compound includes at least one kind selected from the group consisting of a first polyurethane resin compound, a second polyurethane resin compound, and a third polyurethane resin compound:

2. 发明申请

WO2009122919A2 DISPERSION OF FLUOROSILICONES AND FLUORINE- AND SILICON-CONTAINING SURFACE TREATMENT AGENT 审中-公开
标题翻译：氟化硅和含氟和含硅表面处理剂的分散
公开(公告)号：WO2009122919A2
公开(公告)日：2009-10-08
申请号：PCT/JP2009/055381
申请日：2009-03-12
申请人： DAIKIN INDUSTRIES, LTD. , DOW CORNING CORPORATION , YAMAMOTO, Ikuo , MASUTANI, Tetsuya , MIYAHARA, Masahiro , ENOMOTO, Takashi , MINAMI, Shinichi , HUPFIELD, Peter, Cheshire , REED, Samantha , SURGENOR, Avril, E.
发明人： YAMAMOTO, Ikuo , MASUTANI, Tetsuya , MIYAHARA, Masahiro , ENOMOTO, Takashi , MINAMI, Shinichi , HUPFIELD, Peter, Cheshire , REED, Samantha , SURGENOR, Avril, E.
CPC分类号： C08F283/122 , C08F14/18 , C08F14/22 , C08F214/186 , C08F283/124 , C08J3/03 , C08J2383/10 , D06M15/277 , D06M15/3568 , D06M15/643 , D06M15/6436 , D06M15/657 , D06M2200/11 , D06M2200/12 , D06M2200/50 , C08F2/30
摘要： A fluorosilicone reaction product of a mercapto or vinyl functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH 2 =C(X)COOYRf, and (B) a mercapto or vinyl functional organopolysiloxane.
摘要翻译：公开了巯基或乙烯基官能的有机聚硅氧烷和含氟单体的氟硅酮反应产物，以及氟硅氧烷的制备方法。氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。氟化硅反应产物由（A）式为CH2 = C（X）COOYRf的含氟单体和（B）巯基或乙烯基官能的有机聚硅氧烷制备。

3. 发明申请

WO2010030046A1 AQUEOUS POLYMER DISPERSION COMPOSITION AND SURFACE TREATMENT AGENT 审中-公开
标题翻译：水性聚合物分散体组合物和表面处理剂
公开(公告)号：WO2010030046A1
公开(公告)日：2010-03-18
申请号：PCT/JP2009/066325
申请日：2009-09-11
申请人： DAIKIN INDUSTRIES, LTD. , DOW CORNING CORPORATION , MOHARA, Kensuke , KISHIKAWA, Yousuke , TAKEUCHI, Rumi , MIYANAGA, Emi , MIYAHARA, Masahiro , KASHIWAGI, Masato , MINAMI, Shinichi , YAMAMOTO, Ikuo , HUPFIELD, Peter Cheshire
发明人： MOHARA, Kensuke , KISHIKAWA, Yousuke , TAKEUCHI, Rumi , MIYANAGA, Emi , MIYAHARA, Masahiro , KASHIWAGI, Masato , MINAMI, Shinichi , YAMAMOTO, Ikuo , HUPFIELD, Peter Cheshire
IPC分类号： C08F283/12 , C08L51/08 , C09D151/08 , D06M15/21 , D06M15/277 , D06M15/356
CPC分类号： D06M15/6436 , C08F283/122 , C08L51/085 , C09D151/085 , D06M15/277 , D06M15/3568 , C08F220/24 , C08L2666/04
摘要： A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from an aqueous dispersion water- and oil-repellent composition which contains: (I) a fluorine-containing polymer comprising repeating units derived from a monomer comprising a fluorine-containing monomer, wherein the fluorine-containing polymer has a silicone moiety possessed by a functional organopolysiloxane, and (II) a fluorine-free polymer comprising a vinyl monomer.
摘要翻译：可以从含水分散体防水斥油剂组合物中获得能够赋予基材优异的拒水拒油性，耐污性和感觉的表面处理剂，其包含：（I）含氟聚合物，其包含衍生自包含含氟单体的单体的重复单元，其中所述含氟聚合物具有由功能性有机聚硅氧烷占据的硅氧烷部分，和（II）包含乙烯基单体的无氟聚合物。

4. 发明申请

WO2010030044A3 WATER- AND OIL-REPELLENT COMPOSITION 审中-公开
公开(公告)号：WO2010030044A3
公开(公告)日：2010-03-18
申请号：PCT/JP2009/066323
申请日：2009-09-11
申请人： DAIKIN INDUSTRIES, LTD. , ENOMOTO, Takashi , YAMAMOTO, Ikuo , MIYAHARA, Masahiro , USUGAYA, Mitsuhiro , NANRI, Masashi , KUBOTA, Kouji , SAKASHITA, Hirotoshi , MINAMI, Shinichi , NAKAMURA, Hisako , TAKEUCHI, Rumi
发明人： ENOMOTO, Takashi , YAMAMOTO, Ikuo , MIYAHARA, Masahiro , USUGAYA, Mitsuhiro , NANRI, Masashi , KUBOTA, Kouji , SAKASHITA, Hirotoshi , MINAMI, Shinichi , NAKAMURA, Hisako , TAKEUCHI, Rumi
IPC分类号： C08F220/22 , C08L25/00 , D06M15/277
摘要： A fluorine-containing polymer comprising repeating units derived from: (A) a fluorine-containing monomer represented by the general formula: CH 2 =C(-X)-C(=O)-Y-Z-Rf wherein X is a hydrogen atom, a monovalent organic group or a halogen atom, Y is -O- or -NH-; Z is a direct bond or a divalent organic group; Rf is a fluoroalkyl group having 1 to 20 carbon atoms; and (B) a (meth)acrylate monomer having a cyclic hydrocarbon group provides a water- and oil-repellent agent which imparts excellent water repellency, oil repellency and stain-proofing properties to a substrate.

5. 发明申请

WO2010030042A1 FLUOROSILICONE POLYMERS AND SURFACE TREATMENT AGENT 审中-公开
标题翻译：氟聚合物聚合物和表面处理剂
公开(公告)号：WO2010030042A1
公开(公告)日：2010-03-18
申请号：PCT/JP2009/066317
申请日：2009-09-11
申请人： DAIKIN INDUSTRIES, LTD. , DOW CORNING CORPORATION , MINAMI, Shinichi , ENOMOTO, Takashi , MASUTANI, Tetsuya , MIYAHARA, Masahiro , USUGAYA, Mitsuhiro , TAKEUCHI, Rumi , YAMAMOTO, Ikuo , HUPFIELD, Peter Cheshire
发明人： MINAMI, Shinichi , ENOMOTO, Takashi , MASUTANI, Tetsuya , MIYAHARA, Masahiro , USUGAYA, Mitsuhiro , TAKEUCHI, Rumi , YAMAMOTO, Ikuo , HUPFIELD, Peter Cheshire
IPC分类号： C08F283/12 , C08F290/06 , D06M15/277 , D06M15/356
CPC分类号： D06M15/6436 , C08F283/122 , C08F290/068 , D06M15/277 , D06M15/3568 , Y10T442/2172 , C08F220/24 , C08F220/68
摘要： A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH 2 =C(-X)-C(=O)-Y-Z-Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is -O- or -NH-, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.
摘要翻译：可以从含有以下的含氟聚合物获得能够赋予基材优异的防水拒油性，耐污性和感觉的表面处理剂：（A）包含以下物质的单体：（A1）下式的含氟单体：CH2 = C（-X）-C（= O）-YZ-Rf其中X是氢原子，一价有机基团或卤素原子，Y是-O - 或-NH-，Z为直接键或二价有机基团，Rf为碳原子数1〜20的氟代烷基，（A2）具有环状烃基的（甲基）丙烯酸酯单体，（B）至少一种选自巯基官能的有机聚硅氧烷，乙烯基官能的有机聚硅氧烷，（甲基）丙烯酰胺官能的有机聚硅氧烷和（甲基）丙烯酸酯官能团的官能的有机聚硅氧烷。

6. 发明申请

WO2010030041A1 FLUOROSILICONES AND SURFACE TREATMENT AGENT 审中-公开
标题翻译：氟化物和表面处理剂
公开(公告)号：WO2010030041A1
公开(公告)日：2010-03-18
申请号：PCT/JP2009/066316
申请日：2009-09-11
申请人： DAIKIN INDUSTRIES, LTD. , DOW CORNING CORPORATION , YAMAMOTO, Ikuo , MASUTANI, Tetsuya , ENOMOTO, Takashi , MIYAHARA, Masahiro , MINAMI, Shinichi , HUPFIELD, Peter Cheshire , SURGENOR, Avril E.
发明人： YAMAMOTO, Ikuo , MASUTANI, Tetsuya , ENOMOTO, Takashi , MIYAHARA, Masahiro , MINAMI, Shinichi , HUPFIELD, Peter Cheshire , SURGENOR, Avril E.
IPC分类号： C08F283/12 , C08F290/06 , C08L51/08 , D06M15/277 , D06M15/356
CPC分类号： D06M15/6436 , C08F283/122 , C08F283/124 , C08F290/068 , C08L51/085 , D06M15/277 , D06M15/3568 , C08F220/24 , C08F220/16
摘要： A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (a) a fluorine-containing monomer of the formula: CH 2 =C(-X)-C(=O)-Y-Z-Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is -O- or -NH-, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 8 to 12 carbon atoms, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a meth(acrylate) functional organopolysiloxane.
摘要翻译：可以从含有以下的含氟聚合物获得能够赋予基材优异的防水拒油性，耐污性和感觉的表面处理剂：（A）包含以下物质的单体：（a）下式的含氟单体：CH2 = C（-X）-C（= O）-YZ-Rf其中X是氢原子，一价有机基团或卤素原子，Y是-O - 或-NH-，Z是直接键或二价有机基团，Rf是具有8至12个碳原子的氟烷基，和（B）至少一种选自巯基官能的有机聚硅氧烷，乙烯基官能的有机聚硅氧烷，（甲基）丙烯酰胺官能的有机聚硅氧烷和（甲基）丙烯酸酯官能的有机聚硅氧烷。

7. 发明授权

EP3015480B1 SURFACE TREATMENT AGENT 有权
公开(公告)号：EP3015480B1
公开(公告)日：2019-11-06
申请号：EP14817619.1
申请日：2014-06-18
申请人： Daikin Industries, Ltd.
发明人： UEHARA, Tetsuya , MIYAHARA, Masahiro , FUKUMORI, Masaki , FUKUMOTO, Kanako , YAMAMOTO, Ikuo
IPC分类号： C08F220/22 , C09K3/18

8. 发明公开

EP3015480A1 SURFACE TREATMENT AGENT 有权
标题翻译： OBERFLÄCHENBEHANDLUNGSMITTEL
公开(公告)号：EP3015480A1
公开(公告)日：2016-05-04
申请号：EP14817619.1
申请日：2014-06-18
申请人： Daikin Industries, Ltd.
发明人： UEHARA, Tetsuya , MIYAHARA, Masahiro , FUKUMORI, Masaki , FUKUMOTO, Kanako , YAMAMOTO, Ikuo
IPC分类号： C08F220/22 , C09K3/18
摘要： The present invention provides a fluorine-containing polymer having (a) a repeating unit derived from a fluorine-containing monomer indicated by the formula CH 2 =C(-X)-C(=O)-Y Z-Rf, (b) a repeating unit derived from a cyclic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH 2 =CQ 11 -C(=O)-O-Q 12 , and (c) a repeating unit derived from an aliphatic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH 2 =CQ 21 -C(=O)-O-Q 22 , wherein the fluorine-containing polymer is produced by polymerizing in the presence of one or both of (d) a silicon-containing monomer and a silicon-containing chain transfer agent. The fluorine-containing polymer provides a surface treatment agent that has superior water repellency and oil repellency, and that is such that the fluorine-containing polymer has superior solubility in the surface treatment agent.
摘要翻译：本发明提供具有（a）由式CH 2 = C（-X）-C（= O）-Y Z-Rf表示的含氟单体衍生的重复单元的含氟聚合物，（b）由式CH 2 = CQ 11 -C（= O）-OQ 12表示的含环状烃基的丙烯酸酯单体的重复单元，（c）衍生自脂肪族烃基的重复单元由式CH 2 = CQ 21 -C（= O）-OQ 22表示的丙烯酸酯单体，其中所述含氟聚合物通过在（d）含硅单体中的一种或两种的存在下聚合来制备，和含硅链转移剂。含氟聚合物提供了具有优异的拒水性和拒油性的表面处理剂，并且使得含氟聚合物在表面处理剂中具有优异的溶解性。

9. 发明公开

EP4116342A1 DISPERSION 审中-实审转让
公开(公告)号：EP4116342A1
公开(公告)日：2023-01-11
申请号：EP21764613.2
申请日：2021-03-05
申请人： Daikin Industries, Ltd.
发明人： YAMAMOTO, Ikuo , MIYAHARA, Masahiro , MINAMI, Shinichi
IPC分类号： C08F220/22 , C08K5/02 , C08L27/04 , C08L33/04 , C08L33/16 , D06M15/277
摘要： Provided is a dispersion having both product stability and water repellency and/or oil repellency, and comprising a fluorine-containing polymer and a liquid medium, wherein: the fluorine-containing polymer has a Q value of at least 2.0 and contains a repeating unit derived from a fluorine-containing monomer (a) containing a fluoroalkyl group, and a repeating unit derived from a chloride monomer (b), which is at least one selected from among vinyl chloride and vinylidene chloride; and the concentration of the unreacted chloride monomer (b) is at most 2.0 ppm.

10. 发明授权

EP2331595B1 FLUOROSILICONE POLYMERS AND SURFACE TREATMENT AGENT 有权
标题翻译： FLUOR硅聚合物和表面处理剂
公开(公告)号：EP2331595B1
公开(公告)日：2016-05-18
申请号：EP09788070.2
申请日：2009-09-11
申请人： Daikin Industries, Ltd. , Dow Corning Corporation
发明人： MINAMI, Shinichi , ENOMOTO, Takashi , MASUTANI, Tetsuya , MIYAHARA, Masahiro , USUGAYA, Mitsuhiro , TAKEUCHI, Rumi , YAMAMOTO, Ikuo , HUPFIELD, Peter Cheshire
IPC分类号： C08F283/12 , C08F290/06 , D06M15/356 , D06M15/643 , D06M15/277
CPC分类号： D06M15/6436 , C08F283/122 , C08F290/068 , D06M15/277 , D06M15/3568 , Y10T442/2172 , C08F220/24 , C08F220/68
摘要： A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH2═C(—X)—C(═O)—Y—Z—Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or —NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.

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