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1. 发明授权

US5688985A Process for producing keto nitrile derivative 失效
标题翻译：制备酮腈衍生物的方法
公开(公告)号：US5688985A
公开(公告)日：1997-11-18
申请号：US590177
申请日：1996-01-23
申请人： Mitsuhiko Fujihara , Kenji Asahina , Toru Watanabe , Toshiyuki Takezawa , Seiji Watanabe
发明人： Mitsuhiko Fujihara , Kenji Asahina , Toru Watanabe , Toshiyuki Takezawa , Seiji Watanabe
IPC分类号： C07B53/00 , C07B49/00 , C07C221/00 , C07C225/14 , C07C225/16 , C07C253/30 , C07C255/42 , C07C253/00 , C07C225/00
CPC分类号： C07C221/00 , C07C253/30
摘要： A process for producing a (4S)-4-(N,N-dibenzyl)amino-5-phenyl-3-oxo-pentanenitrile derivative which comprises reacting a (2S)-2-(N,N-dibenzyl)aminophenylalanine ester derivative with acetonitrile in the presence of a lithium compound or a magnesium compound is disclosed, and a process for producing a (2S)-2-(N,N-dibenzyl)amino-5-amino-1,6-diphenyl-4-hexen-3-one derivative which comprises adding a benzylmagnesium halide or a benzyllithium to a reaction solution containing the (4S)-4-(N,N-dibenzyl)amino-5-phenyl-3-oxo-pentanenitrile derivative and reacting the derivative with the benzylmagnesium halide or the benzyllithium is also disclosed. According to these processes, optically pure (4S)-4-(N,N-dibenzyl)amino-5-phenyl-3-oxo-pentanenitrile derivative and (2S)-2-(N,N-dibenzyl)amino-5-amino-1,6-diphenyl-4-hexen-3-one derivative can be produced in a good yield on an industrial scale.
摘要翻译：一种（4S）-4-（N，N-二苄基）氨基-5-苯基-3-氧代 - 戊腈衍生物的制备方法，其包括使（2S）-2-（N，N-二苄基）氨基苯丙氨酸酯衍生物公开了在锂化合物或镁化合物存在下的乙腈，以及（2S）-2-（N，N-二苄基）氨基-5-氨基-1,6-二苯基-4-己烯的制备方法 -3-（N，N-二苄基）氨基-5-苯基-3-氧代 - 戊腈衍生物的反应溶液中加入苄基镁卤化物或苄基锂，并将该衍生物与还公开了苄基镁卤化物或苄基锂。根据这些方法，将光学纯的（4S）-4-（N，N-二苄基）氨基-5-苯基-3-氧代 - 戊腈衍生物和（2S）-2-（N，N-二苄基）氨基-5- 氨基-1,6-二苯基-4-己烯-3-酮衍生物可以以工业规模以良好的产率制备。

2. 发明授权

US10428268B2 Organic electroluminescence element 有权
公开(公告)号：US10428268B2
公开(公告)日：2019-10-01
申请号：US13522126
申请日：2010-12-28
申请人： Toshihiro Ise , Tetsu Kitamura , Toru Watanabe
发明人： Toshihiro Ise , Tetsu Kitamura , Toru Watanabe
IPC分类号： H01L51/50 , C09K11/06 , H01L51/00 , H05B33/14 , C07F15/00
摘要： A light emitting organic thin film including at least one compound represented by Formula (PQ-1) and at least one compound represented by Formula (BN-1). In Formula (PQ-1), each of Ra, Rb and Rc independently represents a hydrogen atom or an alkyl group, wherein any one of Ra, Rb and Rc represents a hydrogen atom and the remaining two represent an alkyl group. Each of R1 to R5 independently represents a hydrogen atom, an alkyl group, an aryl group, a fluorine atom or a cyano group. Each of Rx and Ry independently represents an alkyl group or a phenyl group. In Formula (BN-1), Ar1 represents an arylene group that may have a substituent Z. Ar2 represents a condensed hydrocarbyl group that may have a substituent Z. Each of R101 to R113 independently represents a phenyl group, or the like.

3. 发明申请

US20140239280A1 ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHT-EMITTING MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT, AND LIGHT-EMITTING DEVICE, DISPLAY DEVICE, AND ILLUMINATION DEVICE USING SAID ELEMENT 有权
标题翻译：有机电致发光元件，有机电致发光元件的发光材料，发光装置，显示装置和使用标准元件的照明装置
公开(公告)号：US20140239280A1
公开(公告)日：2014-08-28
申请号：US14238371
申请日：2012-08-06
申请人： Saki Takada , Yosuke Yamamoto , Toshihiro Ise , Tetsu Kitamura , Toru Watanabe , Wataru Sotoyama , Koji Takaku , Kimiatsu Nomura
发明人： Saki Takada , Yosuke Yamamoto , Toshihiro Ise , Tetsu Kitamura , Toru Watanabe , Wataru Sotoyama , Koji Takaku , Kimiatsu Nomura
IPC分类号： H01L51/00
CPC分类号： H01L51/0056 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1033 , C09K2211/1044 , C09K2211/1059 , C09K2211/1088 , C09K2211/1092 , H01L51/0052 , H01L51/0061 , H01L51/0071 , H01L51/0072 , H01L51/0073 , H01L51/0074 , H01L51/5012 , H01L51/5024 , H05B33/14
摘要： An organic electroluminescent element using a compound represented by the following general formula emits dark blue light and has a small change in the chromaticity during luminance modulation: wherein each of R1 to R8 represents a hydrogen atom or a substituent; A1 to A4 represent CR31 or N; L and X each independently represent any one of CR32R33, NR34, O, S, and SiR35R36; and each of R31 to R36 represents a hydrogen atom or a substituent.
摘要翻译：使用由以下通式表示的化合物的有机电致发光元件发出深蓝色光，并且在亮度调制期间具有小的色度变化：其中R1至R8各自表示氢原子或取代基; A1至A4表示CR31或N; L和X各自独立地表示CR32R33，NR34，O，S和SiR35R36中的任一个; R 31〜R 36表示氢原子或取代基。

4. 发明授权

US08614349B2 Oxidation catalyst and oxidation method 有权
标题翻译：氧化催化剂和氧化法
公开(公告)号：US08614349B2
公开(公告)日：2013-12-24
申请号：US11666240
申请日：2005-11-17
申请人： Koshiro Yokota , Tatsuo Yamaguchi , Toru Watanabe
发明人： Koshiro Yokota , Tatsuo Yamaguchi , Toru Watanabe
IPC分类号： C07C67/00 , C07C69/02
CPC分类号： C07C67/40 , B01J21/08 , B01J21/18 , B01J23/44 , B01J23/628 , B01J31/121 , B01J2231/70 , C07B41/00 , C07C27/12 , C07C29/50 , C07C45/33 , C07C45/38 , C07C45/39 , C07C67/39 , C07C69/54 , C07C69/14 , C07C69/06
摘要： The present invention provides a method for oxidizing a hydrocarbon, an alcohol or an aldehyde, which comprises: oxidizing a hydrocarbon, an alcohol or an aldehyde to an alcohol, an aldehyde, a carboxylic acid or a carboxylate ester corresponding thereto, in a liquid phase having: a region in which oxygen is substantially present; and a region in which oxygen is substantially absent, in the presence of a catalyst containing a palladium, wherein the region in which oxygen is substantially absent is 0.1 to 10% by volume with respect to a total of the region in which oxygen is substantially present and the region in which oxygen is substantially absent.
摘要翻译：本发明提供了一种用于氧化烃，醇或醛的方法，其包括：将烃，醇或醛氧化成液相中的醇，醛，羧酸或与其对应的羧酸酯具有：基本上存在氧的区域; 以及在含有钯的催化剂的存在下，基本上不存在氧的区域，其中基本上不存在氧的区域相对于基本上存在氧的区域的总和为0.1-10体积％和氧基本上不存在的区域。

5. 发明申请

US20130020559A1 ORGANIC ELECTROLUMINESCENCE DEVICE 有权
标题翻译：有机电致发光器件
公开(公告)号：US20130020559A1
公开(公告)日：2013-01-24
申请号：US13522202
申请日：2010-12-28
申请人： Tetsu Kitamura , Toru Watanabe , Toshihiro Ise
发明人： Tetsu Kitamura , Toru Watanabe , Toshihiro Ise
IPC分类号： H01L51/54 , H01L27/32
CPC分类号： C07D209/86 , C07D221/06 , C07D235/18 , C07D403/12 , C07D487/22 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , H01L51/0054 , H01L51/0072 , H01L51/0085 , H01L51/0087 , H01L51/0094 , H01L51/5012 , H01L51/5268 , H05B33/10
摘要： Provided is an organic electroluminescence device including a pair of electrodes composed of an anode and a cathode, a light emitting layer between the electrodes and an organic layer which is adjacent to the light emitting layer between the light emitting layer and the cathode, on a substrate, and the light emitting layer contains at least one compound having a carbazole structure and the organic layer adjacent to the light emitting layer contains at least one hydrocarbon compound having a specific structure.
摘要翻译：本发明提供一种有机电致发光元件，其包括由阳极和阴极构成的一对电极，电极之间的发光层和与发光层和阴极之间的发光层相邻的有机层，在基板上并且发光层含有至少一种具有咔唑结构的化合物，并且与发光层相邻的有机层含有至少一种具有特定结构的烃化合物。

6. 发明申请

US20120298977A1 ORGANIC ELECTROLUMINESCENCE DEVICE 审中-公开
标题翻译：有机电致发光器件
公开(公告)号：US20120298977A1
公开(公告)日：2012-11-29
申请号：US13522162
申请日：2010-12-28
申请人： Tetsu Kitamura , Toru Watanabe , Toshihiro Ise
发明人： Tetsu Kitamura , Toru Watanabe , Toshihiro Ise
IPC分类号： H01L51/54
CPC分类号： C07C15/28 , C07C15/38 , C07D209/86 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , H01L51/0058 , H01L51/0072 , H01L51/0085 , H01L51/0087 , H01L51/5016 , H01L51/5088 , H01L51/5092 , H01L51/5268 , H05B33/14
摘要： Provided is an organic electroluminescence device including a pair of electrodes composed of an anode and a cathode, a light emitting layer between the electrodes and an organic layer which is adjacent to the light emitting layer between the light emitting layer and the cathode, on a substrate, the light emitting layer contains at least one compound having a carbazole structure and the organic layer adjacent to the light emitting layer contains at least one hydrocarbon compound which is composed only of carbon atoms and hydrogen atoms, has a molecular weight in a range of 400 to 1,200, and contains a condensed polycyclic structure with a total carbon number of 13 to 22.
摘要翻译：本发明提供一种有机电致发光元件，其包括由阳极和阴极构成的一对电极，电极之间的发光层和与发光层和阴极之间的发光层相邻的有机层，在基板上发光层含有至少一种具有咔唑结构的化合物，与发光层相邻的有机层含有至少一种仅由碳原子和氢原子构成的烃化合物，其分子量为400 至1200，并且含有总碳数为13至22的稠合多环结构。

7. 发明申请

US20120126692A1 ORGANIC ELECTROLUMINESCENCE DEVICE 审中-公开
标题翻译：有机电致发光器件
公开(公告)号：US20120126692A1
公开(公告)日：2012-05-24
申请号：US13388111
申请日：2010-07-28
申请人： Toshihiro Ise , Tetsu Kitamura , Toru Watanabe , Akira Takeda , Keiju Tonosaki
发明人： Toshihiro Ise , Tetsu Kitamura , Toru Watanabe , Akira Takeda , Keiju Tonosaki
IPC分类号： H05B33/14 , C09K11/06
CPC分类号： H01L51/0067 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H01L51/0072 , H01L51/0085 , H01L51/5016 , H05B33/14
摘要： An organic electroluminescence device which has on a substrate a pair of electrodes and a light emitting layer sandwiched between the electrodes, characterized by containing in the light emitting layer a compound represented by the following formula (1) and a particular indium complex; (Cz)p-L-(A)q (1) wherein Cz represents a substituted or unsubstituted arylcarbazolyl group or a substituted or unsubstituted carbazolylaryl group, L represents a single bond, a substituted or unsubstituted arylene group, a substituted or unsubstituted cycloalkylene group, or a group derived from a substituted or unsubstituted heteroaromatic ring, A represents a group derived from a substituted or unsubstituted nitrogen-containing heteroaromatic 6-membered ring, and each of p and q independently represents an integer from 1 to 6.
摘要翻译：一种有机电致发光元件，在基板上具有夹在电极之间的一对电极和发光层，其特征在于，在所述发光层中含有下述式（1）表示的化合物和特定的铟络合物; （Cz）pL-（A）q（1）其中Cz表示取代或未取代的芳基咔唑基或取代或未取代的咔唑基芳基，L表示单键，取代或未取代的亚芳基，取代或未取代的亚环烷基，或衍生自取代或未取代的杂芳族环的基团，A表示衍生自取代或未取代的含氮杂芳族六元环的基团，p和q各自独立地表示1〜6的整数。

8. 发明申请

US20120126690A1 ORGANIC ELECTROLUMINESCENCE DEVICE 有权
标题翻译：有机电致发光器件
公开(公告)号：US20120126690A1
公开(公告)日：2012-05-24
申请号：US13387847
申请日：2010-07-29
申请人： Toshihiro Ise , Tetsu Kitamura , Toru Watanabe , Akira Takeda , Keiju Tonosaki
发明人： Toshihiro Ise , Tetsu Kitamura , Toru Watanabe , Akira Takeda , Keiju Tonosaki
IPC分类号： H05B33/14 , C09K11/06
CPC分类号： C09K11/06 , C09K2211/1029 , C09K2211/1044 , C09K2211/1059 , C09K2211/185 , H01L51/0067 , H01L51/0072 , H01L51/0085 , H01L51/0087 , H01L51/5012 , H05B33/14 , H05B33/20
摘要： As an organic electroluminescence device that has an excellent emission characteristic, suppresses a change in chromaticity when driving at a high temperature and has excellent durability, the organic electroluminescence device includes on a substrate a pair of electrodes and a light emitting layer disposed between the electrodes, in which the light emitting layer contains a compound represented by the following Formula (1) and a specific metal complex is provided. (Cz)p-L-(A)q (1) (In Formula (1), Cz represents a substituted or unsubstituted arylcarbazolyl group or a substituted or unsubstituted carbazolylaryl group. L represents a single bond, a substituted or unsubstituted arylene group, a substituted or unsubstituted cycloalkylene group or a substituted or unsubstituted aromatic heterocyclic ring. A is a substituted or unsubstituted nitrogen-containing aromatic heterocyclic six-membered ring, and each of p and q independently represent an integer of 1 to 6.)
摘要翻译：作为具有优异的发光特性的有机电致发光元件，抑制高温驱动时的色度变化，耐久性优异，有机电致发光元件在基板上具有一对电极和位于电极之间的发光层，其中发光层含有由下式（1）表示的化合物和特定的金属络合物。（Cz）pL-（A）q（1）（在式（1）中，Cz表示取代或未取代的芳基咔唑基或取代或未取代的咔唑基芳基，L表示单键，取代或未取代的亚芳基，或未取代的亚环烷基或取代或未取代的芳族杂环，A为取代或未取代的含氮芳香族杂环六元环，p和q各自独立地表示1〜6的整数。

9. 发明申请

US20120044140A1 INFORMATION DISPLAY SYSTEM AND PROGRAM, AND OPTICAL INPUT SYSTEM, PROJECTION-TYPE IMAGES AND DISPLAY APPARATUS 审中-公开
标题翻译：信息显示系统和程序，光输入系统，投影类型图像和显示设备
公开(公告)号：US20120044140A1
公开(公告)日：2012-02-23
申请号：US13211642
申请日：2011-08-17
申请人： Tadahisa KOYAMA , Kazuo Ishimoto , Toru Watanabe , Miwa Yoneda
发明人： Tadahisa KOYAMA , Kazuo Ishimoto , Toru Watanabe , Miwa Yoneda
IPC分类号： G06F3/033
CPC分类号： G06F3/04883 , G06F3/0325 , G06F3/03542 , G06F3/03545 , G06F3/0425
摘要： An information display system includes a pointing device and a control apparatus for detecting the locus of tip of the pointing device. The pointing device includes a light emitting part for irradiating the radiated light that radiates with the tip of the pointing device as the center on a predetermined plane. A camera captures images of a region including the radiated light on the predetermined plane. A radiated light detector detects the radiated light from the images captured by the camera. An estimation unit estimates the position of the tip of the pointing device from the radiated light detected by the radiated light detector.
摘要翻译：信息显示系统包括指示装置和用于检测指示装置的尖端轨迹的控制装置。指示装置包括用于照射以指示装置的尖端照射的辐射光作为中心的发光部分在预定平面上。摄像机拍摄包含预定平面上的辐射光的区域的图像。辐射光检测器检测由相机拍摄的图像的辐射光。估计单元从由辐射光检测器检测到的辐射光估计指示设备的尖端的位置。

10. 发明授权

US08071126B2 Percutaneous absorption type patch 有权
标题翻译：经皮吸收型贴片
公开(公告)号：US08071126B2
公开(公告)日：2011-12-06
申请号：US12666435
申请日：2008-03-19
申请人： Toru Sekiguchi , Kaname Nakahara , Toru Watanabe
发明人： Toru Sekiguchi , Kaname Nakahara , Toru Watanabe
IPC分类号： A61F13/00 , A61F13/02 , A61F15/00 , B23B9/00
CPC分类号： A61K9/703 , A61F2013/00646 , A61K9/7038 , A61K9/7084 , A61L15/44 , A61L15/58 , A61L2300/256 , A61L2300/406 , A61L2300/41 , A61L2300/428 , A61L2300/608 , A61M35/006 , Y10T428/1495
摘要： A percutaneous absorption type patch adapted to be applied to a skin surface of a patient. The percutaneous absorption type patch comprises: a stratum-corneum release member constituted from a sheet-like first supporting substrate and a pressure-sensitive adhesive layer laminated on the first supporting member; a medicinal-components administration member constituted from a sheet-like second supporting substrate, a medicinal-components retention layer laminated on the second supporting substrate, and a protect layer laminated on the medicinal-components retention layer; and a sheet-like handling member interposed between the stratum-corneum release member and the medicinal-components administration member. An edge portion of the handling member is coupled to or integrated with both the first supporting substrate and the protect layer. Operations of peeling the stratum-corneum release member from the skin surface of the patient and peeling the protect layer from the medicinal-components retention layer are carried out at a time by pulling the handling member toward an operating direction.
摘要翻译：适合施用于患者皮肤表面的经皮吸收型贴剂。经皮吸收型贴片包括：由片状第一支撑基板和层叠在第一支撑部件上的压敏粘合剂层构成的角质层释放部件; 由片状第二支撑基板，层叠在第二支撑基板上的药物保持层和层叠在药剂保持层上的保护层构成的药物成分给药部件，以及插入在角质层释放构件和药物成分给药构件之间的片状处理构件。处理构件的边缘部分与第一支撑衬底和保护层两者耦合或一体化。通过沿着操作方向拉动处理构件，一次执行从患者皮肤表面剥离角质层释放构件并从保护层剥离保护层的操作。

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