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1. 发明专利

JPS59213442A Preparation of denitration catalyst 失效
标题翻译：沥青催化剂的制备
公开(公告)号：JPS59213442A
公开(公告)日：1984-12-03
申请号：JP8501083
申请日：1983-05-17
申请人： Mitsubishi Heavy Ind Ltd , Mitsubishi Petrochem Co Ltd , Mitsubishi Yuka Eng Kk , Shokubai Kasei Kogyo Kk
发明人： IMANARI MAKOTO , OGAWA HIROSHI , HINO MASAO , KOBAYASHI TAKAFURU , MIYAKE JIYUNSUKE , FUSE MASAHIRO , NOZUE IKUTOSHI
IPC分类号： B01D53/94 , B01J23/30 , B01D53/36
摘要： PURPOSE: To obtain a catalyst having high activity for denitration and low activity for oxidation of SO
2 at relatively low temp. range by forming a ternary oxide of Ti, W, and Si previously, and adding a V compd. thereto.
CONSTITUTION: In a process for prepg. a denitration catalyst by reducing nitrogen oxides contained in waste gas in the presence of ammonia, a ternary oxide of Ti, W, and Si is previously formed, and a V compd. is added thereto. For example, silica sol and an aq. soln. of water-soluble tungsten salt are added to metatitanic acid; the mixture is kneaded and dried by evaporating water, and then calcined at 150W650°C. Aq. soln. of a V compd. is added to the obtd. powdery ternary oxide (TiO
2 .WO
2 .SiO
2 ); the mixture is kneaded and heated to evaporate water to prepare extrudable paste, which is extruded into an appropriate mold. The molded product is dried and calcined at 150W650°C in the air. The obtd. catalyst has high denitration activity and low oxidation activity for SO
2 at relatively low temp. range of 200W450°C.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：获得具有较高脱氮活性和较低氧化SO2活性的催化剂。预先通过形成Ti，W和Si的三元氧化物，并添加V化合物。于此。规定：在准备工作的过程中预先形成在氨的存在下还原废气中含有的氮氧化物，Ti，W和Si的三元氧化物的脱硝催化剂，加入其中。例如，硅溶胶和水溶液。 SOLN。的水溶性钨盐加入偏钛酸中; 将混合物通过蒸发水捏合并干燥，然后在150-650℃下煅烧。 AQ。 SOLN。的V compd 被添加到obtd。粉状三元氧化物（TiO 2·W 2 O·SiO 2）; 将混合物捏合并加热以蒸发水以制备可挤出的糊料，将其挤出成适当的模具。将成型产物干燥并在空气中在150-650℃下煅烧。有限公司催化剂在相对低的温度下具有较高的脱硝活性和低氧化活性。范围200-450摄氏度

2. 发明专利

JPS603859B2 失效
公开(公告)号：JPS603859B2
公开(公告)日：1985-01-31
申请号：JP14092775
申请日：1975-11-25
申请人： MITSUBISHI YUKA KK , SHOKUBAI KASEI KOGYO KK
发明人： WATANABE YOSHIHISA , IMANARI MAKOTO , ARIMA JUSAKU , TANAKA HIROKAZU
IPC分类号： B01D53/94 , B01D53/34 , B01J21/06 , B01J23/74 , B01J35/02

3. 发明专利

JPS6348584B2 失效
公开(公告)号：JPS6348584B2
公开(公告)日：1988-09-29
申请号：JP7217080
申请日：1980-05-31
申请人： MITSUBISHI YUKA KK , SHOKUBAI KASEI KOGYO KK , MITSUBISHI JUKOGYO KK
发明人： IMANARI MAKOTO , OSHIDA BUNJI , ARIMA JUSAKU , TANAKA HIROKAZU , TOFUJI YOSHINORI , KOBAYASHI TAKAFURU , SERA TOSHIKUNI
IPC分类号： B01D53/94 , B01J23/22 , B01J23/30 , B01J27/053

4. 发明专利

JPH0417091B2 失效
公开(公告)号：JPH0417091B2
公开(公告)日：1992-03-25
申请号：JP8501083
申请日：1983-05-17
申请人： MITSUBISHI YUKA KK , MITSUBISHI JUKOGYO KK , MITSUBISHI YUKA ENJINIARINGU KK , SHOKUBAI KASEI KOGYO KK
发明人： IMANARI MAKOTO , OGAWA HIROSHI , HINO MASAO , KOBAYASHI TAKAFURU , MYAKE JUNSUKE , FUSE MASAHIRO , NOZUE IKUTOSHI
IPC分类号： B01D53/94 , B01J23/30

5. 发明专利

DE3781373T2 未知
公开(公告)号：DE3781373T2
公开(公告)日：1993-07-29
申请号：DE3781373
申请日：1987-11-17
申请人： MITSUBISHI PETROCHEMICAL CO , MITSUBISHI HEAVY IND LTD , CATALYSTA & CHEMICALS IND CO , MITSUBISHI PETROCHEM ENG
发明人： IMANARI MAKOTO , KOSHIKAWA TAKEO , YAMAUCHI AKIHIRO , HANADA MASAYUKI , FUKUDA MORIO , NAGANO KIYOSHI
IPC分类号： B01D53/94 , B01D53/86 , B01J21/06 , B01J23/22 , B01J23/30 , B01J35/10 , B01D53/36
摘要： A denitration catalyst comprising an oxide of titanium, an oxide of tungsten and an oxide of vanadium as catalytically active ingredients and having a specific surface area, measured by the BET method, of 80 to 200 m /g and a pore volume, measured by the mercury penetration method, of 0.1 to 0.5 cc/g.

8. 发明专利

DE3781373D1 未知
公开(公告)号：DE3781373D1
公开(公告)日：1992-10-01
申请号：DE3781373
申请日：1987-11-17
申请人： MITSUBISHI PETROCHEMICAL CO , MITSUBISHI HEAVY IND LTD , CATALYSTA & CHEMICALS IND CO , MITSUBISHI PETROCHEM ENG
发明人： IMANARI MAKOTO , KOSHIKAWA TAKEO , YAMAUCHI AKIHIRO , HANADA MASAYUKI , FUKUDA MORIO , NAGANO KIYOSHI
IPC分类号： B01D53/94 , B01D53/86 , B01J21/06 , B01J23/22 , B01J23/30 , B01J35/10 , B01D53/36
摘要： A denitration catalyst comprising an oxide of titanium, an oxide of tungsten and an oxide of vanadium as catalytically active ingredients and having a specific surface area, measured by the BET method, of 80 to 200 m /g and a pore volume, measured by the mercury penetration method, of 0.1 to 0.5 cc/g.

9. 发明专利

CA1295598C PROCESS FOR REMOVING NITROGEN OXIDES FROM EXHAUST GASES 未知
公开(公告)号：CA1295598C
公开(公告)日：1992-02-11
申请号：CA543123
申请日：1987-07-28
申请人： MITSUBISHI PETROCHEMICAL CO , MITSUBISHI HEAVY IND LTD , CATALYSTS & CHEM IND CO , MITSUBISHI PETROCHEM ENG
发明人： IMANARI MAKOTO , KOSHIKAWA TAKEO , YAMAUCHI AKIHIRO , HANADA MASAYUKI , FUKUDA MORIO , NAGANO KIYOSHI
IPC分类号： B01D53/86 , B01J23/24 , B01J29/076 , B01D53/36 , B01J27/053
摘要： A process for removing nitrogen oxides from an exhaust gas containing the nitrogen oxides and an arsenic compound, which comprises bringing said exhaust gas into contact with a reducing gas in the presence of a catalyst to reduce the nitrogen oxides in the exhaust gas and render them nontoxic. There are disclosed two types of catalysts: (1) a catalyst comprising (A) an oxide of titanium, (B) an oxide of at least one metal selected from tungsten and molybdenum, (C) an oxide of vanadium, and (D) an oxide and/or a sulfate of at least one metal selected from the group consisting of yttrium, lanthanum, cerium and neodymium, and (2) the above (A), (B), (C) components and (D)' at least one metal selected from the group consisting of yttrium, lanthanum, cerium, neodymium, copper, cobalt, manganese and iron, the component (D)' being deposited on zeolite.

10. 发明专利

CA1291743C CATALYST FOR REMOVING NITROGEN OXIDES IN EXHAUST GASES 未知
公开(公告)号：CA1291743C
公开(公告)日：1991-11-05
申请号：CA542974
申请日：1987-07-24
申请人： MITSUBISHI PETROCHEMICAL CO , MITSUBISHI HEAVY IND LTD , SAKAI CHEMICAL INDUSTRY CO , CATALYSTS & CHEM IND CO , MITSUBISHI PETROCHEM ENG
发明人： IMANARI MAKOTO , KOSHIKAWA TAKEO , YAMAUCHI AKIHIRO , HANADA MASAYUKI , FUKUDA MORIO , NAGANO KIYOSHI
IPC分类号： B01D53/86 , B01J21/06 , B01J23/22 , B01J23/24 , B01J35/10 , B01D53/36
摘要： Title of the Invention: CATALYST FOR REMOVING NITROGEN OXIDES IN EXHAUST GASES A catalyst for removing nitrogen oxides in an exhaust gas, said catalyst containing a first group of many pores having a diameter of 1 x 102 .ANG. to less than 1 x 103 .ANG. and a second group of many pores having a diameter of 1 x 103 .ANG. to 1.2 x 105 .ANG., the pore volume of the first group being at least 10% based on the total pore volume of the first group and the second group, and said catalyst comprising titanium and at least one metal selected from molybdenum, tungsten and vanadium as metal elements of catalytically active ingredients.

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