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    • 2. 发明专利
    • Detection method for chemical substance and detection device therefor
    • 化学物质检测方法及其检测装置
    • JP2003279543A
    • 2003-10-02
    • JP2002081606
    • 2002-03-22
    • Mitsubishi Heavy Ind Ltd三菱重工業株式会社
    • YAMAKOSHI HIDEOFUTAMI HIROSHIDANNO MINORUTSURUGA SHIGENORIKURIBAYASHI SHIZUMA
    • G01N27/62G01N27/64G01N33/00
    • PROBLEM TO BE SOLVED: To selectively detect an isomer with high correlation with dioxins from among precursors of the dioxins.
      SOLUTION: The detection device 100 for this chemical substance with a vacuum ultraviolet light lamp 3 ionizes TCB of the precursor of the dioxins in an exhaust gas Gs with this vacuum ultraviolet light lamp 3. Then a TCB ion is fragmentized by providing energy to the TCB ion with a TICKLE waveform having a frequency component corresponding to the orbit resonance frequency of the TCB ion. Thereafter, the mass of a fragment thereof is measured with a mass spectrometer 4 and a fragment pattern is determined. The isomer concentration of the TCB contained in the exhaust gas Gs is determined with mathematical calculation based on the predetermined fragment pattern of the TCB, by utilizing that the fragment pattern is different by the isomer when the isomer of the TCB is fragmentized.
      COPYRIGHT: (C)2004,JPO
    • 要解决的问题:选择性地检测与二恶英前体中二恶英高度相关的异构体。 解决方案:使用真空紫外光灯3的该化学物质的检测装置100利用该真空紫外线灯3将废气Gs中的二恶英前体的TCB离子化。然后通过提供能量来分离TCB离子 具有具有对应于TCB离子的轨道共振频率的频率分量的TICKLE波形的TCB离子。 此后,用质谱仪4测定其片段的质量,并确定片段图案。 排气Gs中含有的TCB的异构体浓度通过利用TCB的异构体断裂时该异构体的片段图案不同而基于TCB的预定片段图案的数学计算来确定。 版权所有(C)2004,JPO