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    • 4. 发明专利
    • Solid oxide cell
    • 固体氧化物
    • JP2009152014A
    • 2009-07-09
    • JP2007327970
    • 2007-12-19
    • Mitsubishi Chemicals CorpTokyo Institute Of Technology三菱化学株式会社国立大学法人東京工業大学
    • IHARA MANABUTAGAWA HIROKIYAMAHARA KEIJI
    • H01M4/86B01J19/08H01M8/06H01M8/12
    • Y02E60/525
    • PROBLEM TO BE SOLVED: To provide an easily miniaturizable solid oxide cell which prevents deterioration of an electrode, especially an anode (fuel electrode), during operation, improves oxidation-reduction cycle property and in which function does not deteriorate even when activation and power generation are repeated and stably maintains high power. SOLUTION: The solid oxide cell at least includes the anode with anode material, a cathode with cathode material and electrolyte composed of ion conductive solid oxide arranged between the anode and the cathode. When activated, solid carbon is carried on the anode material. In power generation, at least reaction formulas; CO 2 +C→2CO and CO+O 2- →CO 2 +2e - are used in the anode. The solid oxide cell, power generation method for the same solid oxide cell and electrochemistry reactor are characterized by the anode material composed of composite metal oxide with electrical conductivity. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供一种容易小型化的固体氧化物电池,其防止电极,特别是阳极(燃料电极)在运行期间的劣化,提高氧化还原循环性能,即使在激活时功能也不劣化 重复发电并稳定地维持高功率。 解决方案:固体氧化物电池至少包括具有负极材料的阳极,具有阴极材料的阴极和布置在阳极和阴极之间的离子导电固体氧化物组成的电解质。 当活化时,固体碳承载在阳极材料上。 在发电方面,至少有反应式; CO 2 + / C→2CO和CO + O 2 - →CO 2 + 2e - 阳极。 固体氧化物电池,相同固体氧化物电池和电化学反应器的发电方法的特征在于由具有导电性的复合金属氧化物组成的负极材料。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • Negative electrode material for nonaqueous secondary battery, negative electrode for nonaqueous secondary battery, and nonaqueous secondary battery
    • 非水性二次电池用负极材料,非水性二次电池负极和非电解二次电池
    • JP2013225502A
    • 2013-10-31
    • JP2013060925
    • 2013-03-22
    • Mitsubishi Chemicals Corp三菱化学株式会社
    • ASAMI HARUHIROKIMURA TAKAHIDENAKAMURA KENICHIYAMAHARA KEIJI
    • H01M4/587C01B31/02C01B31/04C01B33/113H01M4/36H01M4/48H01M10/0525
    • Y02E60/122Y02T10/7011
    • PROBLEM TO BE SOLVED: To provide a negative electrode material for a nonaqueous secondary battery that has both high capacity and high cycle characteristics, a negative electrode for the nonaqueous secondary battery, and the nonaqueous secondary battery.SOLUTION: There is provided a negative electrode material for a nonaqueous secondary battery that includes carbonaceous particles (A) and silicon oxide particles (B), the carbonaceous particles (A) being approximate ellipsoids having an ellipticity (f) of 0.38-0.68 represented by expression (1) of f=1-b/a(1) calculated from a major diameter (a) and a minor diameter (b) found in the following measuring method, where approximate ellipsoid sections are obtained through image analyzing software from respective sectional ellipses of 100 carbonaceous particles in an image of an electrode section photographed by a scanning type electron microscope after an electrode of 6-20 mg/cmin weight of an active material layer obtained by mixing only carbonaceous particles (A) and a binding resin is cut by a cross section polisher while pressed to an active material density of 1.2 to 1.8 g/cmor not pressed, average values of respective major diameters and minor diameters which are thus measured being a major diameter (a) and a minor diameter (b).
    • 要解决的问题:提供一种具有高容量和高循环特性的非水二次电池用负极材料,非水系二次电池用负极和非水系二次电池。提供一种负极材料 对于包含碳质颗粒(A)和氧化硅颗粒(B)的非水二次电池,碳质颗粒(A)是具有由式(1)表示的f = 1〜1的椭圆率(f)为0.38〜0.68的近似椭圆体, 从以下测量方法中发现的大直径(a)和小直径(b)计算出的b / a(1),其中通过来自100个碳质颗粒的相应截面椭圆的图像分析软件获得近似椭圆体部分, 通过扫描型电子显微镜在通过仅混合汽车而获得的活性物质层重量为6〜20mg / cm 2的电极之后, 通过横截面研磨机切割带状颗粒(A)和粘合树脂,同时按压至1.2至1.8g / cm 2的活性物质密度或未压制,因此测量的各个主要直径和小直径的平均值为大直径 (a)和小直径(b)。