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    • 1. 发明授权
    • Method for processing a silver halide photographic material
    • 卤化银照相材料的处理方法
    • US5194367A
    • 1993-03-16
    • US384913
    • 1989-07-25
    • Minoru YamadaTakashi ToyodaNaoki Arai
    • Minoru YamadaTakashi ToyodaNaoki Arai
    • G03C5/30
    • G03C5/30Y10S430/145
    • A method for processing a silver halide photographic material for infrared laser scanner is described, comprising developing the silver halide photographic material which comprises a support having thereon at least one hydrophilic colloidal layer including at least one silver halide emulsion layer with an automatic developing machine, wherein the silver halide emulsion layer contains silver chloroiodobromide grains having a silver iodide content of 0 to 2 mol% and a silver chloride content of 0 to 30 mol%, the hydrophilic colloidal layer has a swelling percentage of 200% or less, and as a developing solution for the development step in the automatic developing machine, a single developing solution containing a 3-pyrazolidone developing agent represented by formula (I) is used therein: ##STR1## wherein R.sub.0 represents a substituted or unsubstituted aryl group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aralkyl group, with the proviso that when R.sub.0 represents an unsubstituted phenyl group, at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aralkyl group.
    • 描述了一种处理用于红外激光扫描仪的卤化银照相材料的方法,其包括显影所述卤化银照相材料,所述卤化银照相材料包括其上具有至少一个包含至少一个卤化银乳剂层的亲水性胶体层的载体,所述亲水胶体层具有自动显影机,其中 卤化银乳剂层含有碘化银含量为0〜2摩尔%,氯化银含量为0〜30摩尔%的氯碘溴化银粒子,亲水性胶体层的膨润率为200%以下,作为显色剂 在自动显影机中用于显影步骤的溶液,其中使用含有由式(I)表示的3-吡唑烷酮显影剂的单一显影液:其中R 0表示取代或未取代的芳基; 可以相同或不同的R 1,R 2,R 3和R 4各自表示氢原子,取代或未取代的烷基,取代或未取代的芳基或取代或未取代的芳烷基,条件是当 R 0表示未取代的苯基,R 1,R 2,R 3和R 4中的至少一个表示取代或未取代的烷基,取代或未取代的芳基或取代或未取代的芳烷基。
    • 2. 发明授权
    • Method of formation of photographic images
    • 形成摄影图像的方法
    • US5198327A
    • 1993-03-30
    • US812857
    • 1991-12-23
    • Minoru YamadaNaoki AraiKazuo Kagawa
    • Minoru YamadaNaoki AraiKazuo Kagawa
    • G03C5/29
    • G03C5/29Y10S430/164Y10S430/167
    • For formation of a photographic image by development of a silver halide photographic material with an automatic developing machine, a certain period of time or not longer than 15 seconds is set as the time of the development step and a silver halide photographic material is used which, when developed for a period of one-half of said certain period of time after such an exposure that the exposed silver halide photographic material, when developed for said certain period of time, would give a value of (Dmax-fog).times.1/2, gives a value of (D-fog) having 70% or more of the value of (Dmax-fog).times.1/2. The silver halide photographic material comprises at least one of a combination of (1), (2) and (3) or (2) and (4): where: (1) represents a silver halide emulsion containing a water-soluble iridium salt; (2) represents a silver halide emulsion layer with a silver amount from 1 to 3.5 grams/m.sup.2 coated on one surface of said emulsion layer; (3) represents silver halide grains wherein the mean grain size is 1.0 .mu. or less; and (4) represents tabular silver halide grains having an aspect ratio of 4 or more. By the rapid development procedure, a sharp image with no development unevenness (drag streaks) can be obtained and the automatic developing machine to be used may be made small-sized and compact.
    • 为了通过用自动显影机开发卤化银照相材料形成摄影图像,设定一段时间或不长于15秒的时间作为显影步骤的时间,并使用卤化银照相材料, 当暴露的卤化银照相材料在这样的一段时间内显影时会产生(Dmax-fog)x1 / 2的值,在曝光之后的所述特定时间段的一半时间内, 给出具有(Dmax-fog)x1 / 2的值的70%以上的(D-fog)的值。 卤化银照相材料包括(1),(2)和(3)或(2)和(4)的组合中的至少一种:其中:(1)代表含有水溶性铱盐的卤化银乳剂 ; (2)表示涂布在所述乳剂层的一个表面上的银量为1至3.5克/平方米的卤化银乳剂层; (3)表示平均粒径为1.0μm以下的卤化银粒子, 和(4)表示长宽比为4以上的片状卤化银颗粒。 通过快速显影程序,可以获得没有显影不均匀(阻力条纹)的清晰图像,并且可以使使用的自动显影机小型化和紧凑。
    • 4. 发明授权
    • Process for the development of silver halide photographic material
    • 用于开发卤化银照相材料的方法
    • US4839273A
    • 1989-06-13
    • US103874
    • 1987-10-02
    • Minoru YamadaTakashi ToyodaKunio Seto
    • Minoru YamadaTakashi ToyodaKunio Seto
    • G03D3/06G03C5/26G03C7/30G03C7/42
    • G03C5/26
    • In a process for development, fixing, and washing or stabilization of a silver halide photographic light-sensitive material by means of an automatic developing machine, is provided, which process comprises supplying to a developing bath and/or a fixing bath a concentrated developing solution and/or a concentrated solution having a fixing capacity, respectively, and water which has been treated by at least one antifungal means selected from the group consisting of irradiation with ultraviolet rays, irradiation with magnetic fields, processing with ion exchange resins, and incorporation of at least one compound selected from the group consisting of aminopolycarboxylic acids and phosphonic acids. In a preferred embodiment, the amount of wash water or stabilizing sollution to be refilled is 3 l or less (including 0 l) per 1 m.sup.2 of light-sensitive material, and the water processed by antifungal means contained in the stock tank is also used as the wash water or stabilizing solution.
    • 在通过自动显影机进行显影,定影和洗涤或稳定卤化银摄影感光材料的方法中,该方法包括向显影浴和/或定影液供应浓缩显影液 和/或分别具有定影能力的浓缩溶液和已经通过至少一种选自紫外线照射,磁场照射,离子交换树脂加工以及离子交换树脂加工的至少一种抗真菌剂处理的水 至少一种选自氨基多羧酸和膦酸的化合物。 在优选的实施方案中,每1m 2的感光材料的洗涤水或重新填充的稳定溶剂的量为3l以下(包括0l),并且也使用由储存罐中所含的防真菌装置加工的水 作为洗涤水或稳定溶液。
    • 6. 发明授权
    • Method for processing silver halide photographic material with an
alkaline black and white developer
    • 用碱性黑白显影剂处理卤化银照相材料的方法
    • US4810622A
    • 1989-03-07
    • US69144
    • 1987-07-02
    • Minoru YamadaTakashi Toyoda
    • Minoru YamadaTakashi Toyoda
    • G03C5/30G03C5/305G03C5/38
    • G03C5/305G03C5/30Y10S430/167
    • A method of processing a silver halide photographic material is described, comprising developing an exposed silver halide photographic material with an alkaline black-and-white developer having a pH value of 9.2 to 10 comprising:(1) at least one of hydroquinones, (2) at least one of 3-pyrazolidone-based developing agents, (3) at least one of dialdehyde-based hardening agents, (4) at least one antifoggant selected from the group consisting essentially of indazole-, benzimidazole-, benztriazole- and mercaptothiadiazole-based antifoggants, (5) at least one compound selected from the group consisting essentially of diethylenetriaminepentaacetic acid, triethylenetetraminehexaacetic acid, 1,3-diamino-2-propanoltetraacetic acid, ethylenediaminetetramethylenephosphonic acid, aminotrimethylenephosphonic acid and alkali metal salts thereof, (6) at least one of silver halide solvents, and (7) at least one compound selected from the group consisting essentially of sulfite, bisulfite, and metabisulfite.
    • 描述了一种处理卤化银照相材料的方法,包括用碱性黑白显影剂将pH值为9.2至10的曝光的卤化银照相材料显影,其包括:(1)至少一种氢醌,(2 )至少一种3-吡唑烷酮类显影剂,(3)至少一种二醛类硬化剂,(4)至少一种选自以下的防灰雾剂:基本上由吲唑,苯并咪唑,苯并三唑和巯基噻二唑 (5)至少一种选自二亚乙基三胺五乙酸,三亚乙基四胺六乙酸,1,3-二氨基-2-丙醇四乙酸,乙二胺四亚甲基膦酸,氨基三亚甲基膦酸及其碱金属盐的化合物,(6)在 至少一种卤化银溶剂,和(7)至少一种选自亚硫酸盐,亚硫酸氢盐和代谢物的化合物 lfite。
    • 8. 发明授权
    • Method for automatic processing of silver halide photographic material
    • 卤化银照相材料的自动处理方法
    • US5187050A
    • 1993-02-16
    • US830527
    • 1992-02-04
    • Minoru YamadaTakashi ToyodaSumito Yamada
    • Minoru YamadaTakashi ToyodaSumito Yamada
    • G03C1/035G03C1/00G03C1/005G03C1/047G03C1/30G03C5/00G03C5/16G03C5/30G03C5/31
    • G03C5/31G03C1/0051G03C1/047G03C1/30G03C5/3035G03C2001/0476
    • A method for processing a silver halide photographic material is described, comprising the steps of:(a) developing a silver halide photographic material comprising a support having thereon at least one hydrophilic colloidal layer, including at least one light-sensitive emulsion layer containing tabular silver halide grains having an aspect ratio of at least about 4, the total number of hydrophilic colloidal layers having a degree of swelling of about 250% or less; and(b) after developing a predetermined amount of said silver halide photographic material, adding a single replenisher of the developer comprising a 3-pyrazolidone developing agent represented by formula (I): ##STR1## wherein R.sub.o represents a substituted or unsubstituted aryl group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group, provided that when R.sub.o represents an unsubstituted phenyl group, at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group.
    • 描述了一种用于处理卤化银照相材料的方法,其包括以下步骤:(a)显影卤化银照相材料,其包括其上具有至少一个亲水性胶体层的载体,其包含至少一种含有片状银的感光乳剂层 具有至少约4的纵横比的卤化物颗粒,具有约250%或更小的膨胀度的亲水胶体层的总数; (b)在显影预定量的所述卤化银照相材料之后,加入包含由式(I)表示的3-吡唑烷酮显影剂的显影剂的单次补充剂:其中Ro表示取代或未取代的 芳基; 可以相同或不同的R 1,R 2,R 3和R 4各自表示氢原子,取代或未取代的烷基,取代或未取代的芳基或取代或未取代的芳烷基,条件是当R a表示 未取代的苯基,R 1,R 2,R 3和R 4中的至少一个表示取代或未取代的烷基,取代或未取代的芳基或取代或未取代的芳烷基。