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1. 发明授权

US07854508B2 Plastic lens and manufacturing method of plastic lens 有权
标题翻译：塑胶透镜及塑料透镜的制造方法
公开(公告)号：US07854508B2
公开(公告)日：2010-12-21
申请号：US12089519
申请日：2006-09-15
申请人： Mikito Nakajima , Katsuyoshi Takeshita , Yusuke Kutsukake , Jun Kinoshita , Shuji Naito , Koichi Takahama , Hiroshi Yokogawa , Takeyuki Yamaki , Akira Tsujimoto , Ryozo Fukuzaki
发明人： Mikito Nakajima , Katsuyoshi Takeshita , Yusuke Kutsukake , Jun Kinoshita , Shuji Naito , Koichi Takahama , Hiroshi Yokogawa , Takeyuki Yamaki , Akira Tsujimoto , Ryozo Fukuzaki
IPC分类号： G02C7/02 , B29D11/00 , C03C17/00
CPC分类号： G02B1/111 , C09D183/04
摘要： A plastic lens includes: a plastic lens base material; a hard coat layer formed on the plastic lens base material; an organic antireflection film formed on the hard coat layer; and a primer layer between the plastic lens base material and the hard coat layer. The plastic lens base material contains at least a sulfur atom. The hard coat layer contains at least: fine metal oxide particles containing a titanium oxide having a rutile-type crystalline structure; and an organosilicon compound represented by a general formula of R1SiX13. The antireflection film contains a coating composition containing at least: an organosilicon compound represented by a general formula of XmR23−mSi—Y—SiR23−mXm; an epoxy group-containing organic compound containing one or more epoxy group in a molecule; and fine silica particles with average particle size of 1 to 150 nm, the antireflection film having a refractive index lower than that of the hard coat layer by 0.10 or more.
摘要翻译：塑料透镜包括：塑料透镜基材; 塑料透镜基材上形成的硬涂层; 形成在硬涂层上的有机抗反射膜; 以及塑料透镜基材和硬涂层之间的底漆层。塑料透镜基材至少含有硫原子。硬涂层至少含有：含有金红石型结晶结构的氧化钛的金属氧化物微粒; 和由通式R1SiX13表示的有机硅化合物。防反射膜含有至少含有由通式XmR23-mSi-Y-SiR23-mXm表示的有机硅化合物的涂料组合物，分子中含有一个或多个环氧基的含环氧基的有机化合物; 平均粒径为1〜150nm的二氧化硅微粒，折射率比硬涂层的折射率低0.10以上的防反射膜。

2. 发明申请

US20090040457A1 PLASTIC LENS AND MANUFACTURING METHOD OF PLASTIC LENS 有权
标题翻译：塑料镜片塑料镜片及其制造方法
公开(公告)号：US20090040457A1
公开(公告)日：2009-02-12
申请号：US12089519
申请日：2006-09-15
申请人： Mikito Nakajima , Katsuyoshi Takeshita , Yusuke Kutsukake , Jun Kinoshita , Shuji Naito , Koichi Takahama , Hiroshi Yokogawa , Takeyuki Yamaki , Akira Tsujimoto , Ryozo Fukuzaki
发明人： Mikito Nakajima , Katsuyoshi Takeshita , Yusuke Kutsukake , Jun Kinoshita , Shuji Naito , Koichi Takahama , Hiroshi Yokogawa , Takeyuki Yamaki , Akira Tsujimoto , Ryozo Fukuzaki
IPC分类号： G02B1/04 , B05D5/06 , G02B1/11 , G02C7/02
CPC分类号： G02B1/111 , C09D183/04
摘要： A plastic lens includes: a plastic lens base material; a hard coat layer formed on the plastic lens base material; an organic antireflection film formed on the hard coat layer; and a primer layer between the plastic lens base material and the hard coat layer. The plastic lens base material contains at least a sulfur atom. The hard coat layer contains at least: fine metal oxide particles containing a titanium oxide having a rutile-type crystalline structure; and an organosilicon compound represented by a general formula of R1SiX13. The antireflection film contains a coating composition containing at least: an organosilicon compound represented by a general formula of XmR23-mSi—Y—SiR23-mXm; an epoxy group-containing organic compound containing one or more epoxy group in a molecule; and fine silica particles with average particle size of 1 to 150 nm, the antireflection film having a refractive index lower than that of the hard coat layer by 0.10 or more.
摘要翻译：塑料透镜包括：塑料透镜基材; 塑料透镜基材上形成的硬涂层; 形成在硬涂层上的有机抗反射膜; 以及塑料透镜基材和硬涂层之间的底漆层。塑料透镜基材至少含有硫原子。硬涂层至少含有：含有金红石型结晶结构的氧化钛的金属氧化物微粒; 和由通式R1SiX13表示的有机硅化合物。防反射膜含有至少含有由通式XmR23-mSi-Y-SiR23-mXm表示的有机硅化合物的涂料组合物，分子中含有一个或多个环氧基的含环氧基的有机化合物; 平均粒径为1〜150nm的二氧化硅微粒，折射率比硬涂层的折射率低0.10以上的防反射膜。

3. 发明申请

US20060251884A1 Plastic lens and method of manufacturing a plastic lens 有权
标题翻译：塑料透镜及塑料透镜的制造方法
公开(公告)号：US20060251884A1
公开(公告)日：2006-11-09
申请号：US11413017
申请日：2006-04-28
申请人： Shuji Naito , Hidenori Komai , Jun Kinoshita , Yusuke Kutsukake , Katsuyoshi Takeshita
发明人： Shuji Naito , Hidenori Komai , Jun Kinoshita , Yusuke Kutsukake , Katsuyoshi Takeshita
IPC分类号： B32B27/40 , B32B27/36 , B05D5/06
CPC分类号： G02B1/041 , Y10T428/256 , Y10T428/259 , Y10T428/31551 , Y10T428/31598 , Y10T428/31663 , Y10T428/31667 , Y10T428/31786
摘要： A plastic lens includes a plastic lens substrate and a hard coat layer on the plastic lens substrate, and an organic antireflection film on the hard coat layer, the plastic lens substrate including at least a sulfur atom, the hard coat layer being a coating film formed with a coating composition which includes at least the following Component A and Component B, the organic antireflection film being a coating film which includes at least the following Component C and Component D, and has a refractive index that is lower than the refractive index of the hard coat layer by 0.10 or more, and the plastic lens including a primer layer between the plastic lens substrate and the hard coat layer: Component A: metal oxide fine particles including titanium oxide having a rutile crystal structure, Component B: an organic silicon compound represented by the general formula: R1SiX13 (wherein, R1 represents an organic group having a polymerizable reactive group and having two or more carbon atoms; and X1 represents a hydrolytic group), Component C: an organic silicon compound represented by the general formula: R2nR3mSiX24-n-m (wherein, R2 represents an organic group having a polymerizable reactive group; R3 represents a hydrocarbon group having 1 to 6 carbon atoms; X2 represents a hydrolytic group; n represents 0 or 1; and m represents 0 or 1), and Component D: silica fine particles having a mean particle diameter of 1 to 150 nm.
摘要翻译：塑料透镜包括在塑料透镜基板上的塑料透镜基板和硬涂层，以及硬涂层上的有机抗反射膜，塑料透镜基板至少包含硫原子，硬涂层是形成的涂膜至少包含以下组分A和组分B的涂料组合物，所述有机抗反射膜是至少包含以下组分C和组分D的涂膜，并且其折射率低于硬涂层0.10以上，塑料透镜基材和硬涂层之间的底漆层的塑料透镜：成分A：具有金红石型结晶结构的氧化钛的金属氧化物微粒，成分B：有机硅化合物由以下通式表示：其中，R 1表示具有下式的有机基团：其中R 1，R 2，可聚合反应性具有两个或多个碳原子; 和X 1表示水解基团），组分C：由以下通式表示的有机硅化合物：R 2 N 3 2 S 2 4-nm（其中，R 2表示有机基团，其具有可聚合反应性基团; R 3表示碳原子数1〜6的烃基; X 2表示水解基团，n表示0或1，m表示0或1 ），成分D：平均粒径为1〜150nm的二氧化硅微粒。

4. 发明授权

US07981506B2 Plastic lens and method of manufacturing a plastic lens 有权
标题翻译：塑料透镜及塑料透镜的制造方法
公开(公告)号：US07981506B2
公开(公告)日：2011-07-19
申请号：US11413017
申请日：2006-04-28
申请人： Shuji Naito , Hidenori Komai , Jun Kinoshita , Yusuke Kutsukake , Katsuyoshi Takeshita
发明人： Shuji Naito , Hidenori Komai , Jun Kinoshita , Yusuke Kutsukake , Katsuyoshi Takeshita
IPC分类号： B32B27/40 , B32B27/18 , B32B5/16
CPC分类号： G02B1/041 , Y10T428/256 , Y10T428/259 , Y10T428/31551 , Y10T428/31598 , Y10T428/31663 , Y10T428/31667 , Y10T428/31786
摘要： The plastic lens has the hard coat layer on a plastic lens base material containing at least sulfur atom and the organic anti-reflection film on the hard coat layer and further has a primer layer between the plastic lens base material and the hard coat layer. The hard coat layer comprises metal oxide particulates at least containing titanium oxide with rutile-type crystal structure and an organic silicon compound expressed by general Formula: R1SiX13. The organic anti-reflection film comprises a coating composition at least containing an organic silicon compound expressed by general Formula: R2nR3 mSiX24-n-m and silica system particulates of 1 to 150 nm mean particle diameter and has a refractive index which is lower than that of that of the hard coat layer by 0.10 or more.
摘要翻译：该塑料透镜在至少含有硫原子的塑料透镜基材和硬涂层上的有机抗反射膜上具有硬涂层，并且在塑料透镜基材和硬涂层之间还具有底漆层。硬涂层包含至少含有金红石型晶体结构的氧化钛和通式R 1 SiX 13表示的有机硅化合物的金属氧化物微粒。有机防反射膜包括至少含有由通式R2nR3 mSiX24-nm表示的有机硅化合物和平均粒径为1〜150nm的二氧化硅系微粒的涂料组合物，折射率低于的硬涂层为0.10以上。

5. 发明申请

US20090029153A1 PLASTIC LENS AND METHOD FOR PRODUCING PLASTIC LENS 审中-公开
标题翻译：塑料镜片及其制造方法
公开(公告)号：US20090029153A1
公开(公告)日：2009-01-29
申请号：US11908375
申请日：2005-10-28
申请人： Shuji Naito , Jun Kinoshita , Yusuke Kutsukake , Katsuyoshi Takeshita , Hitoshi Mizuno , Hirokazu Tanaka , Eiko Tanaka
发明人： Shuji Naito , Jun Kinoshita , Yusuke Kutsukake , Katsuyoshi Takeshita , Hitoshi Mizuno , Hirokazu Tanaka , Eiko Tanaka
IPC分类号： B32B5/16 , B05D5/06
CPC分类号： B29D11/00865 , Y10T428/256
摘要： Disclosed herein is a plastic lens which exhibits outstanding weather resistance and light resistance with a minimum of deteriorating effect on the organic antireflection thin film formed thereon. The plastic lens is composed of a plastic lens base material, a hard coating layer formed on the plastic lens base material, and an antireflection film formed on the hard coating layer, wherein the hard coating layer is one which is formed from a coating composition comprising inorganic oxide fine particles containing titanium oxide with a rutile-type crystallite and an organosilicon compound as a binder.
摘要翻译：本文公开了一种塑料透镜，其具有优异的耐候性和耐光性，对其上形成的有机抗反射薄膜具有最小的劣化作用。塑料透镜由塑料透镜基材，形成在塑料透镜基材上的硬涂层和形成在硬涂层上的抗反射膜组成，其中硬涂层是由涂料组合物形成的涂料组合物，其包含含有金红石型微晶的氧化钛和有机硅化合物作为粘合剂的无机氧化物微粒。

6. 发明授权

US07572513B2 Lens and method of manufacturing lens 有权
标题翻译：透镜和制造镜片的方法
公开(公告)号：US07572513B2
公开(公告)日：2009-08-11
申请号：US11246631
申请日：2005-10-11
申请人： Yusuke Kutsukake , Jun Kinoshita
发明人： Yusuke Kutsukake , Jun Kinoshita
IPC分类号： B32B9/04 , B05D5/06 , B32B5/18 , G11B5/706
CPC分类号： G02B1/111 , Y10T428/24876 , Y10T428/249953 , Y10T428/249967 , Y10T428/249987 , Y10T428/31515
摘要： A lens including a lens base material, a hard coat layer that is laminated on the lens base material directly or via a primer layer and includes a metal oxide fine particle, an organic silicon compound and a polyfunctional epoxy compound as principal components, and an antireflection layer that is laminated on the hard coat layer and includes a porous silica fine particle and a second organic silicon compound as principal components.
摘要翻译：包括透镜基材的透镜，直接或经由底漆层层压在透镜基材上并包含金属氧化物细颗粒，有机硅化合物和多官能环氧化合物作为主要成分的硬涂层和抗反射层叠在硬涂层上，并且包括多孔二氧化硅微粒和第二有机硅化合物作为主要成分。

7. 发明申请

US20060078723A1 Lens and method of manufacturing lens 有权
公开(公告)号：US20060078723A1
公开(公告)日：2006-04-13
申请号：US11246631
申请日：2005-10-11
申请人： Yusuke Kutsukake , Jun Kinoshita
发明人： Yusuke Kutsukake , Jun Kinoshita
IPC分类号： B32B3/26 , B05D5/06 , B32B27/38
CPC分类号： G02B1/111 , Y10T428/24876 , Y10T428/249953 , Y10T428/249967 , Y10T428/249987 , Y10T428/31515
摘要： A lens including a lens base material, a hard coat layer that is laminated on the lens base material directly or via a primer layer and includes a metal oxide fine particle, an organic silicon compound and a polyfunctional epoxy compound as principal components, and an antireflection layer that is laminated on the hard coat layer and includes a porous silica fine particle and a second organic silicon compound as principal components.

8. 发明申请

US20050041298A1 Plastic lens and method production thereof 审中-公开
标题翻译：塑胶镜片及其制法
公开(公告)号：US20050041298A1
公开(公告)日：2005-02-24
申请号：US10495548
申请日：2003-11-18
申请人： Mitsuhiro Toda , Jun Kinoshita , Katsuyoshi Takeshita
发明人： Mitsuhiro Toda , Jun Kinoshita , Katsuyoshi Takeshita
IPC分类号： G02C7/02 , G02B1/10 , G02B1/11 , G02B3/00
CPC分类号： G02B1/14 , G02B1/105 , G02B1/11 , G02B1/115
摘要： The present invention includes a plastic lens having a plastic lens base material, a primer layer formed on the plastic lens base material, and a hard coat layer formed on the primer layer, the hard coat layer being formed from a hard coat composition having (A) an inorganic fine particle having a particle diameter of 1 to 100 millimicrons, (B) an organic silicon compound expressed in terms of a specified Formula (1), (C) a multi-functional epoxy compound, and (D) a curing catalyst. Such a plastic lens is excellent in shock impact resistance by including the primer layer and also shows improvements in scratch resistance, water resistance, and permanence properties while keeping the coloring properties of the hard coat layer of a colorable type.
摘要翻译：本发明包括具有塑料透镜基材的塑料透镜，形成在塑料透镜基材上的底漆层和形成在底漆层上的硬涂层，硬涂层由具有（A ）具有1〜100毫微米粒径的无机细颗粒，（B）以规定的式（1）表示的有机硅化合物，（C）多官能环氧化合物和（D）固化催化剂。这样的塑料透镜通过包含底漆层而具有优异的抗冲击性，并且在保持着色性的硬涂层的着色性的同时，也显示出耐划伤性，耐水性和耐久性的提高。

9. 发明授权

US6057039A Coating composition 失效
标题翻译：涂料组成
公开(公告)号：US6057039A
公开(公告)日：2000-05-02
申请号：US981226
申请日：1998-07-06
申请人： Katsuyoshi Takeshita , Jun Kinoshita
发明人： Katsuyoshi Takeshita , Jun Kinoshita
IPC分类号： C09D163/00 , C09D183/04 , C09D201/00 , G02B1/10 , G02B1/115 , G02B1/14 , G02B1/11
CPC分类号： C09D201/00 , Y10T428/31507 , Y10T428/31598 , Y10T428/31663 , Y10T428/31667
摘要： The present invention relates to a coating composition characterized in that an acetylacetonate having as the central metallic atom thereof Fe, Al, Sn or Ti, or a perchlorate, or a carboxylic acid or an anhydride thereof, and an acetylacetonate having as the central metallic atom thereof Li, Cu or Mn are incorporated in combination as curing catalysts; and to a composite structure characterized in that an antireflection film is provided on the surface of a coating film that is obtained from the above composition.According to the present invention, a coating film which is drastically improved in transparency, optical properties and durability can be obtained. Moreover, this coating film has both high adhesion to an antireflection film made from an inorganic material, and durability. Further, according to the present invention, the pot life of a coating liquid when preserved at room temperature can be prolonged to 3 weeks or longer.
摘要翻译： PCT No.PCT / JP97 / 01349 Sec。 371日期：1998年7月6日 102（e）日期1998年7月6日PCT 1997年4月18日PCT PCT。公开号WO97 / 41185 PCT 日期：1997年11月6日本发明涉及一种涂料组合物，其特征在于具有作为其中心金属原子Fe，Al，Sn或Ti，或高氯酸盐或其羧酸或其酸酐和乙酰丙酮化物的乙酰丙酮化物，其具有作为其中心金属原子，将Li，Cu或Mn组合加入作为固化催化剂; 以及复合结构，其特征在于，在由上述组成获得的涂膜的表面上设置防反射膜。根据本发明，可以获得透明性，光学性能和耐久性显着提高的涂膜。此外，该涂膜对由无机材料制成的防反射膜具有高粘合性和耐久性。此外，根据本发明，在室温下保存时的涂布液的适用期可以延长至3周以上。

10. 发明申请

US20090011255A1 Method for Producing Product Having Stain-Proofing Layer and Product Having Stain-Proofing Layer 审中-公开
标题翻译：具有防污层的产品的制造方法和具有防污层的产品
公开(公告)号：US20090011255A1
公开(公告)日：2009-01-08
申请号：US12278258
申请日：2007-03-14
申请人： Hidenori Komai , Jun Kinoshita
发明人： Hidenori Komai , Jun Kinoshita
IPC分类号： B32B9/00
CPC分类号： G02B1/111 , C09D4/00 , G02B1/105 , G02B1/18 , Y10T428/31663 , C08G77/00 , C08G77/04
摘要： A production method, which is a production method for a product having a stain-proofing layer, containing a step of forming the stain-proofing layer by using a fluorine-containing composition on a surface of an organic anti-reflection layer which is a lower layer of the stain-reflection layer is provided. The fluorine-containing composition includes at least one type of fluorosilane compound selected from the group consisting of fluorosilane compounds each having a molecular weight in the range of from 1000 to 10000 and at least one type of fluorosilane compound selected from the group consisting of fluorosilane compounds each having a molecular weight in the range of from 100 to 700. By these arrangements, the stain-proofing layer having sufficient durability can be formed on the organic anti-reflection layer.
摘要翻译：一种生产方法，它是具有防污层的产品的生产方法，该方法包括在有机抗反射层的表面上使用含氟组合物形成防污层的步骤设置着色反射层的层。含氟组合物包括选自分子量为1000〜10000的氟硅烷化合物和选自氟硅烷化合物中的至少一种氟硅烷化合物中的至少一种氟硅烷化合物各自的分子量在100〜700的范围内。通过这些布置，可以在有机抗反射层上形成具有足够的耐久性的防污层。

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