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1. 发明授权

US5314748A Radiation-curable silicone elastomers and pressure sensitive adhesives 失效
标题翻译：可辐射固化的硅氧烷弹性体和压敏粘合剂
公开(公告)号：US5314748A
公开(公告)日：1994-05-24
申请号：US109004
申请日：1993-08-16
申请人： Mieczyslaw H. Mazurek , Steven S. Kantner , Charles M. Leir , Yvan A. Bogaert , Robert K. Galkiewicz , Audrey A. Sherman
发明人： Mieczyslaw H. Mazurek , Steven S. Kantner , Charles M. Leir , Yvan A. Bogaert , Robert K. Galkiewicz , Audrey A. Sherman
IPC分类号： C07F7/08 , C07F7/12 , C08F299/08 , C08G77/26 , C08G77/388 , C09J7/02 , C09J155/00 , C09J183/08 , B32B7/12 , B32B9/04
CPC分类号： C07F7/12 , C07F7/0854 , C08F299/08 , C08G77/26 , C08G77/388 , C09J155/005 , C09J183/08 , C09J7/0207 , Y10T428/2809 , Y10T428/2852 , Y10T428/2896 , Y10T428/31663
摘要： A composition which is curable to an elastomer comprising:A polymer or mixture of polymers of the formula ##STR1## wherein: X are monovalent moieties having ethylenic unsaturation which can be the same or different;Y are divalent linking groups which can be the same or different;m is an integer of 0 to 1;D are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, an alkyl group of 1 to about 10 carbon atoms, aryl, and substituted aryl;R are divalent hydrocarbon groups which can be the same or different;R.sup.1 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl;R.sup.2 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl;R.sup.3 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl;R.sup.4 are monovalent moieties which can be the same or different selenited from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; andn is an integer of about 270 to about 1000.A composition which is curable to a pressure sensitive adhesive comprising the above polymer and a sufficient amount of tackifier. The invention also relates to fluorosilane compounds useful in the preparation of silicone macromonomer, their preparation and the preparation of silicone macromonomer.
摘要翻译：可固化成弹性体的组合物，其包含：下式的聚合物或聚合物的混合物，其中：X是具有烯属不饱和度的单价部分，其可以相同或不同; Y是可以相同或不同的二价连接基团; m为0〜1的整数; D是可以相同或不同的一价部分，其选自氢，1至约10个碳原子的烷基，芳基和取代的芳基; R是可以相同或不同的二价烃基; R1是可以相同或不同的一价部分，其选自烷基，取代的烷基，芳基和取代的芳基; R2是可以相同或不同的一种选自烷基，取代的烷基，芳基和取代的芳基的一价部分; R3是可以相同或不同的一种选自烷基，取代的烷基，乙烯基，芳基和取代的芳基的一价部分; R4是可以与由烷基，取代的烷基，乙烯基，芳基和取代的芳基组成的组相同或不同的一价部分; 并且n是约270至约1000的整数。可包含上述聚合物和足够量的增粘剂的压敏粘合剂可固化的组合物。本发明还涉及可用于制备硅氧烷大分子单体的氟硅烷化合物，其制备和硅氧烷大分子单体的制备。

2. 发明授权

US5091483A Radiation-curable silicone elastomers and pressure sensitive adhesives 失效
标题翻译：可辐射固化的硅氧烷弹性体和压敏粘合剂
公开(公告)号：US5091483A
公开(公告)日：1992-02-25
申请号：US671172
申请日：1991-03-15
申请人： Mieczyslaw H. Mazurek , Steven S. Kantner , Charles M. Leir , Yvan A. Bogaert , Robert K. Galkiewicz , Audrey A. Sherman
发明人： Mieczyslaw H. Mazurek , Steven S. Kantner , Charles M. Leir , Yvan A. Bogaert , Robert K. Galkiewicz , Audrey A. Sherman
IPC分类号： C07F7/08 , C07F7/12 , C08F299/08 , C08G77/26 , C08G77/388 , C09J7/02 , C09J155/00 , C09J183/08
CPC分类号： C08F299/08 , C07F7/0854 , C07F7/12 , C08G77/26 , C08G77/388 , C09J155/005 , C09J183/08 , C09J7/0207
摘要： A composition which is curable to an elastomer comprising:A polymer or mixture of polymers of the formula ##STR1## wherein: X are monovalent moieties having ethylenic unsaturation which can be the same or different;Y are divalent linking groups which can be the same or different;m is an integer of 0 to 1;D are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, an alkyl group of 1 to about 10 carbon atoms, aryl, and substituted aryl;R are divalent hydrocarbon groups which can be the same or different;R.sup.1 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl;R.sup.2 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl;R.sup.3 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl;R.sup.4 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; andn is an integer of about 270 to about 1000.A composition which is curable to a pressure sensitive adhesive comprising the above polymer and a sufficient amount of tackifier. Thhe invention also relates to fluorosilane compounds useful in the preparation of silicone macromonomer, their preparation and the preparation of silicone macromonomer.
摘要翻译：可固化成弹性体的组合物，其包含：下式的聚合物或聚合物的混合物，其中：X是具有烯属不饱和度的单价部分，其可以相同或不同; Y是可以相同或不同的二价连接基团; m为0〜1的整数; D是可以相同或不同的一价部分，其选自氢，1至约10个碳原子的烷基，芳基和取代的芳基; R是可以相同或不同的二价烃基; R1是可以相同或不同的一价部分，其选自烷基，取代的烷基，芳基和取代的芳基; R2是可以相同或不同的一种选自烷基，取代的烷基，芳基和取代的芳基的一价部分; R3是可以相同或不同的一种选自烷基，取代的烷基，乙烯基，芳基和取代的芳基的一价部分; R4是可以相同或不同的一种选自烷基，取代的烷基，乙烯基，芳基和取代的芳基的一价部分; 并且n是约270至约1000的整数。可包含上述聚合物和足够量的增粘剂的压敏粘合剂可固化的组合物。本发明还涉及可用于制备硅氧烷大分子单体的氟硅烷化合物，它们的制备和硅氧烷大分子单体的制备。

3. 发明授权

US5475124A Radiation-curable silicone elastomers and pressure sensitive adhesives 失效
标题翻译：可辐射固化的硅氧烷弹性体和压敏粘合剂
公开(公告)号：US5475124A
公开(公告)日：1995-12-12
申请号：US247023
申请日：1994-05-20
申请人： Mieczyslaw H. Mazurek , Steven S. Kantner , Charles M. Leir , Audrey A. Sherman
发明人： Mieczyslaw H. Mazurek , Steven S. Kantner , Charles M. Leir , Audrey A. Sherman
IPC分类号： C07F7/08 , C07F7/12 , C08F299/08 , C08G77/26 , C08G77/388 , C09J7/02 , C09J155/00 , C09J183/08 , C07F7/10
CPC分类号： C07F7/12 , C07F7/0854 , C08F299/08 , C08G77/26 , C08G77/388 , C09J155/005 , C09J183/08 , C09J7/0207 , Y10T428/2809 , Y10T428/2852 , Y10T428/2896 , Y10T428/31663
摘要： A composition which is curable to an elastomer comprising:A polymer or mixture of polymers of the formula ##STR1## A composition which is curable to a pressure sensitive adhesive comprising the above polymer and a sufficient amount of tackifier. The invention also relates to fluorosilane compounds useful in the preparation of silicone macromonomer, their preparation and the preparation of silicone macromonomer.
摘要翻译：可固化到弹性体的组合物，其包含：下式的聚合物或聚合物的混合物：可固化到包含上述聚合物的压敏粘合剂和足量的增粘剂的组合物。本发明还涉及可用于制备硅氧烷大分子单体的氟硅烷化合物，其制备和硅氧烷大分子单体的制备。

4. 发明授权

US5514730A Radiation-curable acrylate/silicone pressure-sensitive adhesive compositions 失效
标题翻译：可辐射固化的丙烯酸酯/硅氧烷压敏粘合剂组合物
公开(公告)号：US5514730A
公开(公告)日：1996-05-07
申请号：US279718
申请日：1994-07-25
申请人： Mieczyslaw H. Mazurek , Steven S. Kantner , David J. Kinning , Yvan A. Bogaert
发明人： Mieczyslaw H. Mazurek , Steven S. Kantner , David J. Kinning , Yvan A. Bogaert
IPC分类号： C08F299/08 , C08F290/00 , C09J4/00 , C09J4/06 , C09J7/02 , C09J183/00 , C09J183/02 , C09J183/08 , C09J183/10 , C09J183/07
CPC分类号： C09J183/08 , C09J183/10 , C09J4/06 , Y10S525/925 , Y10S526/931
摘要： The present invention provides a radiation curable vinyl-silicone pressure-sensitive adhesive composition which combines the advantages of silicone and acrylate pressure-sensitive adhesives and which does not experience gross phase separation problems. The composition comprises at least about 20 weight percent of a certain telechelic silicone polymer, about 0.5 to about 80 weight percent of monofunctional free-radically polymerizable vinyl monomer copolymerizable with the silicone polymer, and a sufficient amount of a silicate MQ tackifying resin to impart a degree of adhesive tack to the cured composition at the use temperature, wherein the weight percentages of the silicone polymer and the monomer are based upon the total weight of the silicone polymer and monomer.
摘要翻译：本发明提供了可聚合有机硅和丙烯酸酯压敏粘合剂的优点并且不经历总相分离问题的可辐射固化的乙烯基 - 硅氧烷压敏粘合剂组合物。组合物包含至少约20重量％的某些遥爪硅氧烷聚合物，约0.5至约80重量％的可与硅氧烷聚合物共聚的单官能可自由基聚合的乙烯基单体，以及足够量的硅酸盐MQ增粘树脂，以赋予在使用温度下对固化的组合物的粘合程度，其中硅氧烷聚合物和单体的重量百分比是基于有机硅聚合物和单体的总重量。

5. 发明申请

US20080023890A1 METHODS FOR CHANGING THE SHAPE OF A SURFACE OF A SHAPE MEMORY POLYMER ARTICLE 有权
标题翻译：改变形状记忆聚合物表面形状的方法
公开(公告)号：US20080023890A1
公开(公告)日：2008-01-31
申请号：US11460682
申请日：2006-07-28
申请人： Audrey A. Sherman , William J. Bryan , Robert K. Galkiewicz , Mieczyslaw H. Mazurek , James R. Starkey , Wendi J. Winkler , Haiyan Zhang , Jeffrey M. Olofson
发明人： Audrey A. Sherman , William J. Bryan , Robert K. Galkiewicz , Mieczyslaw H. Mazurek , James R. Starkey , Wendi J. Winkler , Haiyan Zhang , Jeffrey M. Olofson
IPC分类号： C04B33/32
CPC分类号： B29C59/18 , B29C37/0053 , B29C43/26 , B29C59/02 , B29C2059/023 , B29C2791/001
摘要： Methods for changing the shape of a surface of an article are disclosed. The methods may include providing a liquid polymer precursor, casting the precursor against a first tool assembly, curing the precursor to form a shape memory polymer substrate, deforming one or more surfaces of the substrate, and mobilizing the shape memory polymer to shift the deformed surface of the substrate from a deformed shape to a pre-set shape.
摘要翻译：公开了改变制品表面形状的方法。所述方法可以包括提供液体聚合物前体，将前体相对于第一工具组件浇铸，固化前体以形成形状记忆聚合物基质，使基底的一个或多个表面变形，以及移动形状记忆聚合物以使变形表面从变形的形状到预设的形状。

6. 发明授权

US07951319B2 Methods for changing the shape of a surface of a shape memory polymer article 有权
标题翻译：改变形状记忆聚合物制品表面形状的方法
公开(公告)号：US07951319B2
公开(公告)日：2011-05-31
申请号：US11460682
申请日：2006-07-28
申请人： Audrey A. Sherman , William J Bryan , Robert K. Galkiewicz , Mieczyslaw H. Mazurek , James R. Starkey , Wendi J. Winkler , Haiyan Zhang , Jeffrey M. Olofson
发明人： Audrey A. Sherman , William J Bryan , Robert K. Galkiewicz , Mieczyslaw H. Mazurek , James R. Starkey , Wendi J. Winkler , Haiyan Zhang , Jeffrey M. Olofson
IPC分类号： B29C59/18
CPC分类号： B29C59/18 , B29C37/0053 , B29C43/26 , B29C59/02 , B29C2059/023 , B29C2791/001
摘要： Methods for changing the shape of a surface of an article are disclosed. The methods may include providing a liquid polymer precursor, casting the precursor against a first tool assembly, curing the precursor to form a shape memory polymer substrate, deforming one or more surfaces of the substrate, and mobilizing the shape memory polymer to shift the deformed surface of the substrate from a deformed shape to a pre-set shape.
摘要翻译：公开了改变制品表面形状的方法。所述方法可以包括提供液体聚合物前体，将前体相对于第一工具组件浇铸，固化前体以形成形状记忆聚合物基质，使基底的一个或多个表面变形，以及移动形状记忆聚合物以使变形表面从变形的形状到预设的形状。

7. 发明申请

US20120058305A1 SHAPE MEMORY POLYMER ARTICLES WITH A MICROSTRUCTURED SURFACE 审中-公开
标题翻译：具有微结构表面的形状记忆聚合物文章
公开(公告)号：US20120058305A1
公开(公告)日：2012-03-08
申请号：US13296362
申请日：2011-11-15
申请人： Mieczyslaw H. Mazurek , Robert K. Galkiewicz , Audrey A. Sherman , James R. Starkey , Wendi J. Winkler , Halyan Zhang , Jeffrey M. Olofson
发明人： Mieczyslaw H. Mazurek , Robert K. Galkiewicz , Audrey A. Sherman , James R. Starkey , Wendi J. Winkler , Halyan Zhang , Jeffrey M. Olofson
IPC分类号： B32B3/00
CPC分类号： A61L15/26 , A61L15/24 , A61L24/046 , A61L24/06 , A61L2400/16 , C08F283/00 , C08F283/12 , C08F290/068 , C08F290/148 , Y10T428/24355 , C08L33/08 , C08L83/04
摘要： A shape memory polymer article is disclosed. The article may include a surface having a microstructure and it may include a shape memory polymer. The shape memory polymer may include a copolymer network. The copolymer network may be formed from the reaction product of a free radically polymerizable siloxane having greater than one functional free radically polymerizable group and at least one (meth)acrylate monomer.
摘要翻译：公开了形状记忆聚合物制品。制品可以包括具有微结构的表面，并且其可以包括形状记忆聚合物。形状记忆聚合物可以包括共聚物网络。共聚物网络可以由具有大于一个官能的可自由基聚合基团的自由基可聚硅氧烷和至少一种（甲基）丙烯酸酯单体的反应产物形成。

8. 发明授权

US08236226B2 Methods for changing the shape of a surface of a shape memory polymer article 有权
标题翻译：改变形状记忆聚合物制品表面形状的方法
公开(公告)号：US08236226B2
公开(公告)日：2012-08-07
申请号：US13092165
申请日：2011-04-22
申请人： Audrey A. Sherman , William J Bryan , Robert K. Galkiewicz , Mieczyslaw H. Mazurek , James R. Starkey , Wendi J. Winkler , Haiyan Zhang , Jeffrey M. Olofson
发明人： Audrey A. Sherman , William J Bryan , Robert K. Galkiewicz , Mieczyslaw H. Mazurek , James R. Starkey , Wendi J. Winkler , Haiyan Zhang , Jeffrey M. Olofson
IPC分类号： B29C43/26
CPC分类号： B29C59/18 , B29C37/0053 , B29C43/26 , B29C59/02 , B29C2059/023 , B29C2791/001
摘要： Methods for changing the shape of a surface of an article are disclosed. The methods may include providing a liquid polymer precursor, casting the precursor against a first tool assembly, curing the precursor to form a shape memory polymer substrate, deforming one or more surfaces of the substrate, and mobilizing the shape memory polymer to shift the deformed surface of the substrate from a deformed shape to a pre-set shape.
摘要翻译：公开了改变制品表面形状的方法。所述方法可以包括提供液体聚合物前体，将前体相对于第一工具组件浇铸，固化前体以形成形状记忆聚合物基质，使基底的一个或多个表面变形，以及移动形状记忆聚合物以使变形表面从变形的形状到预设的形状。

9. 发明授权

US10279069B2 Shape memory polymer articles with a microstructured surface 有权
公开(公告)号：US10279069B2
公开(公告)日：2019-05-07
申请号：US13296362
申请日：2011-11-15
申请人： Mieczyslaw H. Mazurek , Robert K. Galkiewicz , Audrey A. Sherman , James R. Starkey , Wendi J. Winkler , Haiyan Zhang , Jeffrey M. Olofson
发明人： Mieczyslaw H. Mazurek , Robert K. Galkiewicz , Audrey A. Sherman , James R. Starkey , Wendi J. Winkler , Haiyan Zhang , Jeffrey M. Olofson
IPC分类号： C08G77/00 , A61L15/26 , A61L15/24 , A61L24/04 , A61L24/06 , C08F283/00 , C08F283/12 , C08F290/06 , C08F290/14
摘要： A shape memory polymer article is disclosed. The article may include a surface having a microstructure and it may include a shape memory polymer. The shape memory polymer may include a copolymer network. The copolymer network may be formed from the reaction product of a free radically polymerizable siloxane having greater than one functional free radically polymerizable group and at least one (meth)acrylate monomer.

10. 发明申请

US20110198781A1 METHODS FOR CHANGING THE SHAPE OF A SURFACE OF A SHAPE MEMORY POLYMER ARTICLE 有权
标题翻译：改变形状记忆聚合物表面形状的方法
公开(公告)号：US20110198781A1
公开(公告)日：2011-08-18
申请号：US13092165
申请日：2011-04-22
申请人： Audrey A. Sherman , William J. Bryan , Robert K. Galkiewicz , Mieczyslaw H. Mazurek , James R. Starkey , Wendi J. Winkler , Haiyan Zhang , Jeffrey M. Olofson
发明人： Audrey A. Sherman , William J. Bryan , Robert K. Galkiewicz , Mieczyslaw H. Mazurek , James R. Starkey , Wendi J. Winkler , Haiyan Zhang , Jeffrey M. Olofson
IPC分类号： B29C43/26
CPC分类号： B29C59/18 , B29C37/0053 , B29C43/26 , B29C59/02 , B29C2059/023 , B29C2791/001
摘要： Methods for changing the shape of a surface of an article are disclosed. The methods may include providing a liquid polymer precursor, casting the precursor against a first tool assembly, curing the precursor to form a shape memory polymer substrate, deforming one or more surfaces of the substrate, and mobilizing the shape memory polymer to shift the deformed surface of the substrate from a deformed shape to a pre-set shape.
摘要翻译：公开了改变制品表面形状的方法。所述方法可以包括提供液体聚合物前体，将前体相对于第一工具组件浇铸，固化前体以形成形状记忆聚合物基质，使基底的一个或多个表面变形，以及移动形状记忆聚合物以使变形表面从变形的形状到预设的形状。

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