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    • 9. 发明申请
    • FLUOROPOLYMER AND SOIL REMOVER
    • 氟聚合物和土壤去除
    • US20090256102A1
    • 2009-10-15
    • US11995225
    • 2006-07-11
    • Norimasa Uesugi
    • Norimasa Uesugi
    • D06M15/263C08F214/18
    • D06M15/277C08F220/24C08F220/28
    • A fluorocopolymer formed from, as essential ingredients, (a) a fluoromonomer represented by the general formula: CH2═C(—X)—C(—O)—Y—[—(CH2)m-Z-]p-(CH2)n—Rf  (1) [wherein X is hydrogen, C1-21 linear or branched alkyl, fluorine, chlorine, bromine, iodine, —CFX1X2 (wherein X1 and X2 each is hydrogen, fluorine, chlorine, bromine, or iodine), cyano, C1-21 linear or branched fluoroalkyl, (un)substituted benzyl, or (un)substituted phenyl; Y is —O— or —NH—; Z is —S— or —SO2—; Rf is C1-21 fluoroalkyl; m is 1-10; n is 0-10; and p is 0 or 1] and (b) a polyalkylene glycol (meth)acrylate. A soil remover containing this fluorocopolymer imparts to a woven fabric, etc. excellent oil repellency, unsusceptibility to fouling, and the property of releasing stains therefrom, while maintaining durability in washing.
    • 作为必要成分的(a)由以下通式表示的含氟单体形成的含氟共聚物:(C)-C( - ) - ( - ) - [ - (CH2)mZ-] p-(CH2)n -Rf(1)[其中X为氢,C1〜21直链或支链烷基,氟,氯,溴,碘,-CFX1X2(其中X1和X2各自为氢,氟,氯,溴或碘),氰基, C 1-12直链或支链氟代烷基,(取代的)取代的苄基或(取代的)取代的苯基; Y是-O-或-NH-; Z是-S-或-SO 2 - ; Rf为C1〜21氟烷基; m为1-10; n为0-10; 和p为0或1]和(b)聚亚烷基二醇(甲基)丙烯酸酯。 含有这种含氟共聚物的去污剂赋予机织物等优异的拒油性,不易污染,以及在保持洗涤时的耐久性的同时释放污渍的性质。