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1. 发明授权

US5395997A Process for the preparation of hydrofluorocarbons having 3 to 7 carbon atoms 失效
标题翻译：制备碳原子数为3〜7的氢氟烃的方法
公开(公告)号：US5395997A
公开(公告)日：1995-03-07
申请号：US99677
申请日：1993-07-29
申请人： Michael Van Der Puy , G. V. Bindu Madhavan , Timothy R. Demmin
发明人： Michael Van Der Puy , G. V. Bindu Madhavan , Timothy R. Demmin
IPC分类号： B01J27/06 , B01J27/10 , B01J27/12 , B01J27/122 , B01J27/135 , C07B61/00 , C07C17/10 , C07C17/20 , C07C17/23 , C07C17/278 , C07C19/08 , C07C19/10 , C07C17/08 , C07C17/28
CPC分类号： C07C17/278 , C07C17/206 , C07C17/23
摘要： The invention relates to a process for preparing hydrofluorocarbons of the formulas CF.sub.3 (CH.sub.2 CF.sub.2).sub.n F comprising reacting at least one reactant selected from CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.n Cl, CCl.sub.3 (CH.sub.2 CF.sub.2).sub.n Cl or CCl.sub.2 [(CH.sub.2 CF.sub.2)Cl].sub.2, where n=1 to 3, with hydrogen fluoride at a temperature of from about 25.degree. to about 200.degree. C.
摘要翻译：本发明涉及一种制备式CF 3（CH 2 CF 2）nF的氢氟烃的方法，包括使至少一种选自CCl 3（CH 2 Cl 2）nCl，CCl 3（CH 2 CF 2）nCl或CCl 2 [（CH 2 CF 2）Cl] 2的反应物反应，其中n = 在约25℃至约200℃的温度下加入氟化氢

2. 发明授权

US5728904A Process for the preparation of 1,1,1,3,3-pentafluoropropane 失效
标题翻译：制备1,1,1,3,3-五氟丙烷的方法
公开(公告)号：US5728904A
公开(公告)日：1998-03-17
申请号：US679938
申请日：1996-07-15
申请人： Michael Van Der Puy , Richard E. Eibeck , Lois A. S. Ellis , G. V. Bindu Madhavan
发明人： Michael Van Der Puy , Richard E. Eibeck , Lois A. S. Ellis , G. V. Bindu Madhavan
IPC分类号： B01J23/44 , B01J27/135 , C07B61/00 , C07C17/20 , C07C17/23 , C07C17/278 , C07C19/08 , C07C17/08
CPC分类号： C07C19/08 , C07C17/206 , C07C17/23 , C07C17/278
摘要： This invention is related to the preparation of hydrofluorocarbons (HFCs). Specifically, it relates to the manufacture of 1,1,1,3,3-pentafluoropropane, CF.sub.3 CH.sub.2 CF.sub.2 H (HFC-245fa) by the steps comprising (1) the formation of CCl.sub.3 CH.sub.2 CCl.sub.3 by the reaction of CCl.sub.4 with vinylidene chloride; (2) the conversion of CCl.sub.3 CH.sub.2 CCl.sub.3 to CF.sub.3 CH.sub.2 CF.sub.2 Cl by reaction with HF in the presence of a fluorination catalyst, selected from TiCl.sub.4, SnCl.sub.4 or mixtures thereof; and (3) reduction of CF.sub.3 CH.sub.2 CF.sub.2 Cl to CF.sub.3l CH.sub.2 CF.sub.2 H.
摘要翻译：本发明涉及氢氟烃（HFCs）的制备。具体地说，本发明涉及通过以下步骤制造1,1,1,3,3-五氟丙烷CF 3 CH 2 CF 2 H（HFC-245fa）：（1）通过CCl 4与偏二氯乙烯的反应形成CCl 3 CH 2 ClCl 3; （2）在选自TiCl 4，SnCl 4或其混合物的氟化催化剂存在下，通过与HF反应，将CCl 3 CH 2 ClCl 3转化为CF 3 CH 2 CF 2 Cl; 和（3）CF 3 CH 2 CF 2 Cl还原成CF 3 I CH 2 CF 2 H.

3. 发明授权

US5481050A Processes for the preparation of fluorinated olefins and hydrofluorocarbons using fluorinated olefin 失效
标题翻译：使用氟化烯烃制备氟化烯烃和氢氟烃的方法
公开(公告)号：US5481050A
公开(公告)日：1996-01-02
申请号：US412476
申请日：1995-03-28
申请人： Michael Van Der Puy , G. V. Bindu Madhavan , Alagappan Thenappan , Hsueh S. Tung
发明人： Michael Van Der Puy , G. V. Bindu Madhavan , Alagappan Thenappan , Hsueh S. Tung
IPC分类号： C07B61/00 , C07C17/00 , C07C17/087 , C07C17/25 , C07C17/275 , C07C19/08 , C07C19/10 , C07C19/14 , C07C21/18 , C07C19/01
CPC分类号： C07C21/18 , C07C17/00 , C07C17/087 , C07C17/25 , C07C17/275
摘要： The invention relates to a cost effective and convenient process for the manufacture of fluorinated olefins of the formula RCF.sub.2 CH=CH.sub.2 where R is C.sub.x Cl.sub.y F.sub.z and y+z=2.times.+1. The invention is also directed to a lo practical process for converting these olefins to hydrofluorocarbons via the catalyzed fluorination with hydrogen fluoride. Hydrofluorocarbons produced via this process have application as solvents among other uses.
摘要翻译：本发明涉及用于制造式RCF 2 CH = CH 2的氟化烯烃的成本有效和方便的方法，其中R是C x Cly F z且y + z = 2x + 1。本发明还涉及通过氟化氢的催化氟化将这些烯烃转化为氢氟烃的实际方法。通过该方法生产的氢氟烃可用作其他用途的溶剂。

4. 发明授权

US5532419A Processes for the preparation of fluorinated olefins and hydrofluorocarbons using fluorinated olefin 失效
公开(公告)号：US5532419A
公开(公告)日：1996-07-02
申请号：US528846
申请日：1995-09-15
申请人： Michael Van Der Puy , G. V. Bindu Madhavan , Alagappan Thenappan , Hsueh S. Tung
发明人： Michael Van Der Puy , G. V. Bindu Madhavan , Alagappan Thenappan , Hsueh S. Tung
IPC分类号： C07B61/00 , C07C17/00 , C07C17/087 , C07C17/25 , C07C17/275 , C07C19/08 , C07C19/10 , C07C19/14 , C07C21/18 , C07C19/01
CPC分类号： C07C21/18 , C07C17/00 , C07C17/087 , C07C17/25 , C07C17/275
摘要： The invention relates to a cost effective and convenient process for the manufacture of fluorinated olefins of the formula RCF.sub.2 CH.dbd.CH.sub.2 where R is C.sub.x Cl.sub.y F.sub.z and y+z=2x+1. The invention is also directed to a practical process for converting these olefins to hydrofluorocarbons via the catalyzed fluorination with hydrogen fluoride. Hydrofluorocarbons produced via this process have application as solvents among other uses.

5. 发明授权

US5446217A Processes for the preparation of fluorinated olefins and hydrofluorocarbons using fluorinated olefin 失效
标题翻译：使用氟化烯烃制备氟化烯烃和氢氟烃的方法
公开(公告)号：US5446217A
公开(公告)日：1995-08-29
申请号：US242899
申请日：1994-05-16
申请人： Michael Van Der Puy , G. V. Bindu Madhavan , Alagappan Thenappan , Hsueh S. Tung
发明人： Michael Van Der Puy , G. V. Bindu Madhavan , Alagappan Thenappan , Hsueh S. Tung
IPC分类号： C07B61/00 , C07C17/00 , C07C17/087 , C07C17/25 , C07C17/275 , C07C19/08 , C07C19/10 , C07C19/14 , C07C21/18 , C07C17/20 , C07C17/266
CPC分类号： C07C21/18 , C07C17/00 , C07C17/087 , C07C17/25 , C07C17/275
摘要： The invention relates to a cost effective and convenient process for the manufacture of fluorinated olefins of the formula RCF.sub.2 CH=CH.sub.2 where R is C.sub.x Cl.sub.y F.sub.z and y+z=2x+1. The invention is also directed to a practical process for converting these olefins to hydrofluorocarbons via the catalyzed fluorination with hydrogen fluoride. Hydrofluorocarbons produced via this process have application as solvents among other uses.
摘要翻译：本发明涉及用于制造式RCF 2 CH = CH 2的氟化烯烃的成本有效和方便的方法，其中R是C x Cly F z且y + z = 2x + 1。本发明还涉及通过氟化氢的催化氟化将这些烯烃转化成氢氟烃的实际方法。通过该方法生产的氢氟烃可用作其他用途的溶剂。

6. 发明授权

US5421971A Hydrochlorofluorocarbons and hydrofluorocarbons and methods for producing the same 失效
标题翻译：氢氯氟烃和氢氟碳化物及其制备方法
公开(公告)号：US5421971A
公开(公告)日：1995-06-06
申请号：US116935
申请日：1993-09-03
申请人： Michael Van Der Puy , Alagappan Thenappan , G. V. Bindu Madhavan
发明人： Michael Van Der Puy , Alagappan Thenappan , G. V. Bindu Madhavan
IPC分类号： C07C17/10 , C07C17/23 , C07C17/269 , C07C19/10 , C07B39/00
CPC分类号： C07C19/10 , C07C17/10 , C07C17/23 , C07C17/269
摘要： A process for the preparation of compounds of the formula, F(CF.sub.2).sub.a CC1.sub.2 CC1.sub.2 (CF.sub.2).sub.b F where a and b are the same or different and are each an integer .gtoreq.1 (including the novel compound CF.sub.3 CF.sub.2 CC1.sub.2 CC1.sub.2 CF.sub.2 CF.sub.3), which comprises chlorination in the presence of irradiation, of at least one compound of the formula, F(CF.sub.2).sub.n CH.sub.x C1.sub.3-x where n is an integer .gtoreq.1 and x is an integer .ltoreq.3. There is also disclosed a process for utilizing the F(CF.sub.2).sub.a CC1.sub.2 CC1.sub.2 (CF.sub.2).sub.b F compounds to produce F(CF.sub.2).sub.a CH.sub.2 CH.sub.2 (CF.sub.2).sub.b F.sub.3 compounds which comprises contacting hydrogen and the F(CF.sub.2).sub.a CC1.sub.2 CC1.sub.2 (CF.sub.2).sub.b F compounds in the presence of a catalysis which includes at least one Group VIII transition metal. A further aspect of the invention is a novel group of compounds, F(CF.sub.2).sub.a CC1.sub.2 CC1.sub.2 (CF.sub.2).sub.b F, wherein a and b are the same or different and are each an integer from 2 to 10, particularly 3,3,4,4-tetrachloroperfluorohexane (i.e., CF.sub.3 CF.sub.2 CC1.sub.2 CC1.sub.2 CF.sub.2 CF.sub.3), whose corresponding hydrofluorocarbons can be used as cleaning solvents.
摘要翻译：其中a和b相同或不同并且各自为整数> / = 1（包括新化合物CF 3 CF 2 CCl 2 CCl 2 CF 2 CF 3）的式（F（CF 2）aCC 12 CCl 2（CF 2）b F）化合物的方法，其包括在至少一种下式的化合物F（CF 2）n CH x C 13-x其中n是整数> / = 1且x是整数3的照射的存在。还公开了一种利用F（CF2）aCC12CC12（CF2）bF化合物制备F（CF 2）aCH 2 CH 2（CF 2）bF 3化合物的方法，其包括在存在下使氢和F（CF2）aCC12CC12（CF2）bF化合物接触的催化剂，其包括至少一种第VIII族过渡金属。本发明的另一方面是新的一组化合物F（CF2）aCC12CC12（CF2）bF，其中a和b相同或不同，各自为2-10的整数，特别是3,3,4,4 四氯全氟己烷（即CF3CF2CC12CC12CF2CF3），其相应的氢氟烃可用作清洁溶剂。

7. 发明授权

US06548719B1 Process for producing fluoroolefins 有权
标题翻译：制备氟烯烃的方法
公开(公告)号：US06548719B1
公开(公告)日：2003-04-15
申请号：US09962974
申请日：2001-09-25
申请人： Haridasan K. Nair , Michael Van Der Puy , David Nalewajek , Timothy R. Demmin , Andrew J. Poss , David E. Bradley , Ian R. Shankland
发明人： Haridasan K. Nair , Michael Van Der Puy , David Nalewajek , Timothy R. Demmin , Andrew J. Poss , David E. Bradley , Ian R. Shankland
IPC分类号： C07C1725
CPC分类号： C07C17/04 , C07C17/25 , C07C19/14 , C07C21/18
摘要： A process for producing a fluoroolefin of the formula: CF3CY═CXnHp wherein Y is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); X is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); n and p are integers independently equal to 0, 1 or 2, provided that (n+p)=2; comprising contacting, in the presence of a phase transfer catalyst, a compound of the formula: CF3C(R1aR2b)C(R3cR4d), wherein R1, R2, R3, and R4 are independently a hydrogen atom or a halogen selected from the group consisting of fluorine, chlorine, bromine and iodine, provided that at least one of R1, R2, R3, and R4 is halogen and there is at least one hydrogen and one halogen on adjacent carbon atoms; a and b are independently=0, 1 or 2 and (a+b)=2; and c and d are independently=0, 1, 2 or 3 and (c+d)=3; and at least one alkali metal hydroxide. The alkali metal hydroxide can be, for example, potassium or sodium hydroxide and the phase transfer catalyst can be, for example, at least one: crown ether such as 18-crown-6 and 15-crown-5; or onium salt such as, quaternary phosphonium salt and quaternary ammonium salt. The olef in is useful, for example, as an intermediate for producing other industrial chemicals and as a monomer for producing oligomers and polymers.
摘要翻译：制备下式的氟代烯烃的方法：CF 3 CY = CXnHp其中Y是氢原子或卤素原子（即氟，氯，溴或碘）; X是氢原子或卤素原子（即氟，氯，溴或碘）; n和p是独立地等于0,1或2的整数，条件是（n + p）= 2; 包括在相转移催化剂存在下使下式化合物：其中R 1，R 2，R 3和R 4独立地为氢原子或选自以下的卤素：式中：CF 3 C（R 1a R 2b）C（R 3 c R 4d）氟，氯，溴和碘，条件是R 1，R 2，R 3和R 4中的至少一个是卤素，并且在相邻碳原子上具有至少一个氢和一个卤素; a和b独立地为0,1或2，（a + b）= 2; 且c和d独立地为0,1,2或3和（c + d）= 3; 和至少一种碱金属氢氧化物。碱金属氢氧化物可以是例如氢氧化钾或氢氧化钠，相转移催化剂可以是例如至少一种：冠醚如18-冠-6和15-冠-5; 或鎓盐如季鏻盐和季铵盐。烯烃可用作例如生产其它工业化学品的中间体，以及用作生产低聚物和聚合物的单体。

8. 发明授权

US06551469B1 Photochlorination of 1,1,1,3,3-pentafluoropropane 有权
标题翻译： 1,1,1,3,3-五氟丙烷的光氯化
公开(公告)号：US06551469B1
公开(公告)日：2003-04-22
申请号：US09994438
申请日：2001-11-27
申请人： Haridasan K. Nair , Michael Van Der Puy , David Nalewajek , Timothy R. Demmin , Andrew J. Poss , David E. Bradley , Ian R. Shankland , Martin E. Cheney
发明人： Haridasan K. Nair , Michael Van Der Puy , David Nalewajek , Timothy R. Demmin , Andrew J. Poss , David E. Bradley , Ian R. Shankland , Martin E. Cheney
IPC分类号： C07C1700
CPC分类号： C07C17/10 , C07C19/10
摘要： A process for preparing 1-chloro-1,1,3,3,3-pentafluoropropane, CF3CH2CF2Cl, comprising contacting in a reaction zone in the substantial absence of oxygen, reactants comprising chlorine and 1,1,1,3,3-pentafluoropropane, CF3CH2CHF2 (also referred to as HFC-245fa), and subjecting the reactants to actinic radiation, such as UV light at about 2,000 to 4,000 Angstroms, wherein: (1) inert gas is present at a concentration equal to or less than about 5 wt. % of the total weight of reactants; (2) the molar ratio of chlorine to CF3CH2CHF2 is from about 0.2:1 to about 1.5:1; and (3) the concentration of chlorinated product produced having greater than one chlorine present in the molecule is less than or equal to about 10 wt. %.
摘要翻译：制备1-氯-1,1,3,3,3-五氟丙烷CF 3 CH 2 CF 2 Cl的方法，包括在基本不存在氧的反应区中接触，包含氯的反应物和1,1,1,3,3-五氟丙烷，CF 3 CH 2 CHF 2（也称为HFC-245fa），并使反应物进行光化辐射，例如约2,000至4,000埃的紫外光，其中：（1）惰性气体的存在浓度等于或小于约5 重量反应物总重量的百分比; （2）氯与CF 3 CH 2 CHF 2的摩尔比为约0.2:1至约1.5:1; 和（3）分子中存在的具有大于一个氯的氯化产物的浓度小于或等于约10wt。％。

9. 发明授权

US5633413A Continuous process for the production of vinylidene chloride telomers 失效
标题翻译：用于生产偏二氯乙烯调节剂的连续方法
公开(公告)号：US5633413A
公开(公告)日：1997-05-27
申请号：US512575
申请日：1995-08-08
申请人： Michael Van Der Puy , Timothy R. Demmin , David E. Bradley
发明人： Michael Van Der Puy , Timothy R. Demmin , David E. Bradley
IPC分类号： C07C17/278 , C07C17/08 , C07C17/266 , C07C17/275
CPC分类号： C07C17/278
摘要： A process for the continuous production of telomers CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.n Cl where n=1-3 (Formula I) by the continuous reaction of CCl.sub.4 and vinylidene chloride in the presence of a solvent and a catalyst. The reaction to form CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl proceeds at a reaction rate constant k.sub.1. If n=1, CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl is continuously removed from the reactor. If n=2, the removed CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl reacts similarly with CCl.sub.4 and CH.sub.2 .dbd.CCl.sub.2 in a second reactor to form and remove CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl under conditions to have a reaction rate constant k.sub.2, wherein the ratio of the molar amounts of CCl.sub.4 to CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl reacted is greater than the ratio k.sub.2 /k.sub.1. If n=3, the removed CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl similarly reacts in a third reactor with CCl.sub.4 and CH.sub.2 .dbd.CCl.sub.2 to form CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.3 Cl under conditions to have a reaction rate constant k.sub.3, wherein the ratio of the molar amounts of CCl.sub.4 to CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl reacted is greater than the ratio k.sub.3 /k.sub.2.
摘要翻译：在溶剂和催化剂存在下，通过CCl4和偏二氯乙烯的连续反应连续生产调节剂CCl 3（CH 2 Cl 2）n Cl，其中n = 1-3（式I）的方法。形成CCl 3（CH 2 Cl 2）Cl的反应以反应速率常数k1进行。如果n = 1，则从反应器中连续除去CCl 3（CH 2 Cl 2））Cl。如果n = 2，则在第二反应器中除去的CCl 3（CH 2 Cl 2 Cl 2）Cl类似地与CCl 4和CH 2 = CCl 2反应，以在具有反应速率常数k2的条件下形成和除去CCl 3（CH 2 Cl 2）2 Cl，其中摩尔量的CCl4至CCl3（CH2Cl2）Cl反应的比值大于k2 / k1的比例。如果n = 3，则除去的CCl 3（CH 2 Cl 2）2 Cl类似地在第三反应器中与CCl 4和CH 2 = CCl 2反应以在具有反应速率常数k 3的条件下形成CCl 3（CH 2 Cl 2）3 Cl，其中CCl 4的摩尔量至CCl 3（CH 2 Cl 2）2 Cl反应的比例大于k3 / k2的比例。

10. 发明授权

US06927312B2 Method of removing water from hydrofluorocarbon manufacturing processes 失效
公开(公告)号：US06927312B2
公开(公告)日：2005-08-09
申请号：US10706250
申请日：2003-11-12
申请人： Jason T. Stuck , Hsueh Sung Tung , Michael Van Der Puy , Timothy R. Demmin , Franklin S. Wong , Andrew J. Poss , Matthew H. Luly
发明人： Jason T. Stuck , Hsueh Sung Tung , Michael Van Der Puy , Timothy R. Demmin , Franklin S. Wong , Andrew J. Poss , Matthew H. Luly
IPC分类号： C07B39/00 , C07C17/38 , C07C17/395 , C07C17/42 , C07C17/00
CPC分类号： C07B39/00 , Y02P20/582
摘要： Disclosed are improved fluorination processes and fluorine-containing compositions which involve introducing to one or more fluorination process compositions a water reactive agent in an amount and under conditions effective to decrease the amount of water in that composition. The water reactive agent is preferably introduced to the fluorination reaction process at a location proximate to the site of the fluorination reaction, or upstream of the fluorination reaction, in amounts and under conditions effective to produce a relatively lower concentration of water in the composition, and preferably throughout the fluorination process.

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