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1. 发明申请

US20050172858A1 Preparations containing at least one diformate 审中-公开
标题翻译：含有至少一个二甲酸酯的制剂
公开(公告)号：US20050172858A1
公开(公告)日：2005-08-11
申请号：US10521202
申请日：2003-07-07
申请人： Michael Schonherr , Jorn Karl , Alexander Hauk , Gerd Diebold , Andreas Habich , Robert Lenz , Anna Lohmann , Volker Schmidt , Leif Hjornevik
发明人： Michael Schonherr , Jorn Karl , Alexander Hauk , Gerd Diebold , Andreas Habich , Robert Lenz , Anna Lohmann , Volker Schmidt , Leif Hjornevik
IPC分类号： A23K3/03 , A23K1/00 , A23K1/16 , A23K1/175 , A23K1/18 , A23K3/00 , A23L1/00 , A23P1/04 , C05F11/00 , C05G3/00 , C05G3/02 , C09K3/00
CPC分类号： A23K30/15 , A23K20/10 , A23K20/105 , A23K20/158 , A23K20/28 , A23K30/00 , A23K40/30 , A23P10/30 , C05F11/00 , C05G3/0029 , C05G3/0035 , C05G3/0041
摘要： The present invention relates to coated preparations comprising at least one diformate of the general formula XH(COOH)2, where X is Na, K, Cs, NH4 and to the use thereof.
摘要翻译：本发明涉及包含至少一种通式XH（COOH）2 N的二甲酸酯的涂覆制剂，其中X是Na，K，Cs，NH 4，使用它。

2. 发明申请

US20050249784A1 Preparations containing diformates and short-chain carboxylic acids 审中-公开
标题翻译：含有二甲酸酯和短链羧酸的制剂
公开(公告)号：US20050249784A1
公开(公告)日：2005-11-10
申请号：US10521204
申请日：2003-07-07
申请人： Michael Schonherr , Jorn Karl , Alexander Hauk , Gerd Diebold , Andreas Habich , Robert Lenz , Anna Lohmann , Volker Schmidt
发明人： Michael Schonherr , Jorn Karl , Alexander Hauk , Gerd Diebold , Andreas Habich , Robert Lenz , Anna Lohmann , Volker Schmidt
IPC分类号： C07C51/41 , A23K1/16 , A23K1/18 , A23K3/03 , C05C3/00 , C05F11/00 , A23K1/165 , A23K1/17
CPC分类号： C05F11/00 , A23K20/105 , A23K20/111 , A23K30/15 , A23K50/00 , C05C3/00
摘要： The present invention relates to preparations comprising at least one diformate of the general formula XH(COOH)2, where X=Na, K, Cs, NH4 and at least one short-chain carboxylic acids and/or at least one salt of the short-chain carboxylic acid and/or at least one ester and/or at least one derivative of the short-chain carboxylic acid, and to the use of these preparations.
摘要翻译：本发明涉及包含至少一种通式XH（COOH）2 N的二甲酸酯的制剂，其中X = Na，K，Cs，NH 4和至少一种短链羧酸和/或至少一种短链羧酸盐和/或至少一种酯和/或至少一种短链羧酸的衍生物，以及这些制剂的用途。

3. 发明申请

US20090143618A1 METHOD FOR THE PRODUCTION OF FORMIC ACID FORMATES 审中-公开
标题翻译：用于生产形态酸的方法
公开(公告)号：US20090143618A1
公开(公告)日：2009-06-04
申请号：US10595702
申请日：2004-11-05
申请人： Alexander Hauk , Jorn Karl , Jurgen Paschold , Stefan Gropp , Anna Valeska Lohmann , Robert Lenz , Thomas Letzelter , Robert Heinz
发明人： Alexander Hauk , Jorn Karl , Jurgen Paschold , Stefan Gropp , Anna Valeska Lohmann , Robert Lenz , Thomas Letzelter , Robert Heinz
IPC分类号： C07C53/02
CPC分类号： C07C51/412 , C07C53/06 , C07C53/02
摘要： A process is proposed for preparing acid formates in which a liquid stream I comprising formic acid and a liquid stream II comprising a metal formate are prepared, the liquid streams I and II are fed to a rectification column in such a manner that a higher or identical feed point to the rectification column is chosen for the liquid stream II than for the liquid stream I, the liquid streams I and II are mixed in the rectification column, with water being removed overhead from the rectification column and a bottoms stream comprising the acid formate is taken off from the rectification column, which comprises the bottoms stream being produced as melt comprising less than 0.5% by weight of water.
摘要翻译：提出了一种制备酸甲酯的方法，其中制备了包含甲酸的液体料流I和包含甲酸金属盐的液体料流II，将液体流I和II以更高或相同的方式供入精馏塔对于液流II，对于液流II的进料点选择为液流I，液流I和II在精馏塔中混合，水从精馏塔顶部除去，含有酸甲酯的塔底料流从精馏塔中取出，其包括底部物流作为包含小于0.5重量％水的熔体制成。

4. 发明申请

US20060217571A1 Method for producing formic acid formiates 审中-公开
标题翻译：甲酸甲酸酯的生产方法
公开(公告)号：US20060217571A1
公开(公告)日：2006-09-28
申请号：US10556393
申请日：2004-05-14
申请人： Alexander Hauk , Christoph Adami , Jorn Karl , Robert Lenz
发明人： Alexander Hauk , Christoph Adami , Jorn Karl , Robert Lenz
IPC分类号： C07C51/15
CPC分类号： C07C51/412 , C07C53/06
摘要： A process is proposed for preparing acid formates by providing a liquid stream I containing formic acid and a liquid stream II containing a metal formate, and mixing the liquid stream I with the liquid stream II, obtaining the corresponding acid formate, which comprises feeding, to the liquid stream I or a precursor thereof, to the liquid stream II or a precursor thereof, or to the mixture of the liquid streams I and II, a liquid stream III containing the following components at contents of in each case >0.1% by weight: metal formate, metal methoxide, methanol and MeFo (MeFo), which is produced in a process for preparing MeFo by carbonylating methanol in a reactor at a pressure up to 50 MPa absolute in the presence of a metal methoxide as homogeneous catalyst.
摘要翻译：提出了通过提供含有甲酸的液体流I和含有金属甲酸盐的液体流II以及将液体流I与液体流II混合的方法来制备酸性甲酸酯，得到相应的酸式甲酸酯，其包括进料至液体流I或其前体，液体流II或其前体，或液体流I和II的混合物，含有以下组分的液体流III，其含量为> 0.1重量％：金属甲酸盐，金属甲醇盐，甲醇和MeFo（MeFo），其是在金属甲醇钠作为均相催化剂存在下，在反应器中以绝对压力达到绝对压力为50MPa的条件下通过羰基化甲醇制备MeFo的方法制备的。

5. 发明申请

US20050256338A1 Method and device for producing formates and the use thereof 失效
标题翻译：用于生产甲酸盐的方法和装置及其用途
公开(公告)号：US20050256338A1
公开(公告)日：2005-11-17
申请号：US10524202
申请日：2003-07-30
申请人： Christoph Adami , Jorn Karl , Alexander Hauk , Ralf Bohling , Jorg Pastre , Robert Lenz
发明人： Christoph Adami , Jorn Karl , Alexander Hauk , Ralf Bohling , Jorg Pastre , Robert Lenz
IPC分类号： C07C51/09 , C07C51/43 , C07C51/44 , C07C53/02
CPC分类号： C07C51/43 , C07C51/09 , C07C51/44 , C07C53/02 , C07C53/06
摘要： A process for preparing acid formates which comprises (a) partially hydrolyzing methyl formates with water; (b) separating off by distillation methyl formate and methanol from the reaction mixture obtained in process stage (a), forming a stream comprising formic acid and water; and (c) combining the stream comprising formic acid and water from the process stage (b) and the corresponding formate, forming a mixture comprising the acid formate and water, an apparatus for their preparation and their use.
摘要翻译：一种制备酸甲酯的方法，其包括（a）用水部分水解甲酸甲酯; （b）通过蒸馏甲酸甲酯和甲醇从工艺阶段（a）中获得的反应混合物分离，形成包含甲酸和水的流; 和（c）将来自加工阶段（b）的甲酸和水的流与相应的甲酸酯混合，形成含有甲酸和水的混合物，其制备及其用途的装置。

6. 发明申请

US20120296118A1 SODIUM DIFORMATE PRODUCTION AND USE 有权
标题翻译： SODIUM DIFORMATE生产和使用
公开(公告)号：US20120296118A1
公开(公告)日：2012-11-22
申请号：US13566376
申请日：2012-08-03
申请人： Robert Heinz , Otto Machhammer , Stefan Gropp , Alexander Hauk , Gerd Diebold , Anna Valeska Lohmann , Dieter Feuerstein , Robert Rühle , Rüdiger Schmitt
发明人： Robert Heinz , Otto Machhammer , Stefan Gropp , Alexander Hauk , Gerd Diebold , Anna Valeska Lohmann , Dieter Feuerstein , Robert Rühle , Rüdiger Schmitt
IPC分类号： C07C51/41
CPC分类号： C07C53/06 , A23K20/105 , A23K20/22 , A23K30/00 , A23K30/15 , A23K50/00 , A23K50/30 , A23K50/75 , A23V2002/00 , C05F11/00 , C07C51/02 , C07C51/412 , Y02P20/582 , A23V2200/06
摘要： The invention relates to a method for producing and using a solid sodium diformate having a high formic acid content, to the use thereof in animal foods in the form of an acidifier, preservatives, ensilage auxiliary agents, fertilizers, and a growth and productivity-stimulating agent and the inventive animal food additives containing sodium diformate.
摘要翻译：本发明涉及一种用于生产和使用具有高甲酸含量的固体二甲酸钠的方法，其用于在酸化剂，防腐剂，青贮助剂，肥料和生长和生产力刺激的形式的动物食品中的用途药剂和含有二甲酸钠的本发明动物食品添加剂。

7. 发明申请

US20080317934A1 Production of Acid Propionates 有权
标题翻译：酸丙酸酯的生产
公开(公告)号：US20080317934A1
公开(公告)日：2008-12-25
申请号：US12159513
申请日：2006-12-29
申请人： Alexander Hauk , Stefan Gropp , Gerd Diebold , Florian Weigel , Gerhard Laux
发明人： Alexander Hauk , Stefan Gropp , Gerd Diebold , Florian Weigel , Gerhard Laux
IPC分类号： A23K1/16
CPC分类号： C07C51/412 , A23K20/105 , A23K20/22 , A23K20/24 , A23K40/10 , A23K50/00 , A23K50/30 , A23K50/75 , C07C53/122
摘要： The present invention relates to propionic acid-comprising compositions in solid and essentially pure form comprising at least one compound according to formula (I) (Mn+)(H+)x(CH3CH2C(O)O−)(n+x) (I), where Mn+ is an n-valent alkali metal cation or alkaline earth metal cation, n being equal to 1 or 2; and x is a number in the range from 0.25 to 5; with the proviso that x is not in the range from 0.75 to 1.75 when Mn+ is potassium; a method for producing such propionic acid-comprising compositions; and also the use of such compositions as silage additive, preservative, acidifier, food supplement, feedstuff or feedstuff additive for animal feed.
摘要翻译：本发明涉及固体和基本上纯的形式的含丙酸的组合物，其包含至少一种根据式（I）的化合物<？in-line-formula description =“In-line Formulas”end =“lead”→（ Mn +）（H +）x（CH3CH2C（O）O - ）（n + x）（I），<？in-line-formula description =“In-line Formulas”end =“tail”？>其中Mn + 碱金属阳离子或碱土金属阳离子，n等于1或2; x为0.25〜5的数; 条件是当Mn +为钾时x不在0.75至1.75的范围内; 制备这种含丙酸的组合物的方法; 以及使用这些组合物作为动物饲料的青贮添加剂，防腐剂，酸化剂，食品添加剂，饲料或饲料添加剂。

8. 发明授权

US08293793B2 Production of acid propionates 有权
标题翻译：生产酸丙酸酯
公开(公告)号：US08293793B2
公开(公告)日：2012-10-23
申请号：US12159513
申请日：2006-12-29
申请人： Alexander Hauk , Stefan Gropp , Gerd Diebold , Florian Weigel , Gerhard Laux
发明人： Alexander Hauk , Stefan Gropp , Gerd Diebold , Florian Weigel , Gerhard Laux
IPC分类号： A61K31/19 , C07C53/00
CPC分类号： C07C51/412 , A23K20/105 , A23K20/22 , A23K20/24 , A23K40/10 , A23K50/00 , A23K50/30 , A23K50/75 , C07C53/122
摘要： The present invention relates to propionic acid-comprising compositions in solid and essentially pure form comprising at least one compound according to formula (I) (Mn+)(H+)x(CH3CH2C(O)O−)(n+x) (I), where Mn+ is an n-valent alkali metal cation or alkaline earth metal cation, n being equal to 1 or 2; and x is a number in the range from 0.25 to 5; with the proviso that x is not in the range from 0.75 to 1.75 when Mn+ is potassium; a method for producing such propionic acid-comprising compositions; and also the use of such compositions as silage additive, preservative, acidifier, food supplement, feedstuff or feedstuff additive for animal feed.
摘要翻译：本发明涉及包含至少一种根据式（I）的化合物（Mn +）（H +）x（CH 3 CH 2 C（O）O - ）（n + x）（I））的固体和基本上纯的形式的含丙酸的组合物，其中Mn +为n价碱金属阳离子或碱土金属阳离子，n等于1或2; x为0.25〜5的数; 条件是当Mn +为钾时x不在0.75至1.75的范围内; 制备这种含丙酸的组合物的方法; 以及使用这些组合物作为动物饲料的青贮添加剂，防腐剂，酸化剂，食品添加剂，饲料或饲料添加剂。

9. 发明授权

US08497394B2 Sodium diformate production and use 有权
公开(公告)号：US08497394B2
公开(公告)日：2013-07-30
申请号：US13566376
申请日：2012-08-03
申请人： Robert Heinz , Otto Machhammer , Stefan Gropp , Alexander Hauk , Gerd Diebold , Anna Valeska Lohmann , Dieter Feuerstein , Robert Rühle , Rüdiger Schmitt
发明人： Robert Heinz , Otto Machhammer , Stefan Gropp , Alexander Hauk , Gerd Diebold , Anna Valeska Lohmann , Dieter Feuerstein , Robert Rühle , Rüdiger Schmitt
IPC分类号： C07C53/00
CPC分类号： C07C53/06 , A23K20/105 , A23K20/22 , A23K30/00 , A23K30/15 , A23K50/00 , A23K50/30 , A23K50/75 , A23V2002/00 , C05F11/00 , C07C51/02 , C07C51/412 , Y02P20/582 , A23V2200/06
摘要： The invention relates to a method for producing and using a solid sodium diformate having a high formic acid content, to the use thereof in animal foods in the form of an acidifier, preservatives, ensilage auxiliary agents, fertilizers, and a growth and productivity-stimulating agent and the inventive animal food additives containing sodium diformate.

10. 发明申请

US20080182001A1 Sodium Diformate Production and Use 审中-公开
标题翻译：钠形态生产和使用
公开(公告)号：US20080182001A1
公开(公告)日：2008-07-31
申请号：US11911292
申请日：2006-04-12
申请人： Robert Heinz , Otto Machhammer , Stefan Gropp , Alexander Hauk , Gerd Diebold , Anna Valeska Lohmann , Dieter Feuerstein , Robert Ruhle , Rudiger Schmitt
发明人： Robert Heinz , Otto Machhammer , Stefan Gropp , Alexander Hauk , Gerd Diebold , Anna Valeska Lohmann , Dieter Feuerstein , Robert Ruhle , Rudiger Schmitt
IPC分类号： A23K1/00 , C07C53/06
CPC分类号： C07C53/06 , A23K20/105 , A23K20/22 , A23K30/00 , A23K30/15 , A23K50/00 , A23K50/30 , A23K50/75 , A23V2002/00 , C05F11/00 , C07C51/02 , C07C51/412 , Y02P20/582 , A23V2200/06
摘要： The invention relates to a method for producing and using a solid sodium diformate having a high formic acid content, to the use thereof in animal foods in the form of an acidifier, preservatives, ensilage auxiliary agents, fertilizers, and a growth and productivity-stimulating agent and the inventive animal food additives containing sodium diformate.
摘要翻译：本发明涉及一种用于生产和使用具有高甲酸含量的固体二甲酸钠的方法，其用于在酸化剂，防腐剂，青贮助剂，肥料和生长和生产力刺激的形式的动物食品中的用途药剂和含有二甲酸钠的本发明动物食品添加剂。

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