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1. 发明申请

US20110233042A1 BIOMASS CONVERSION PROCESS 有权
标题翻译：生物量转换过程
公开(公告)号：US20110233042A1
公开(公告)日：2011-09-29
申请号：US13038118
申请日：2011-03-01
申请人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN , Walter WEISSMAN
发明人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN , Walter WEISSMAN
IPC分类号： C10B55/10 , C10B55/00
CPC分类号： C10B55/00 , C10B53/02 , C10B55/10 , C10B57/045 , C10B57/06 , C10G3/00 , C10G3/57 , C10G2300/1014 , C10G2300/1037 , C10G2300/708 , C10L1/00 , Y02E50/14 , Y02P20/145 , Y02P30/20
摘要： Biomass is used as a co-feed for a heavy petroleum oil coking process to improve the operation of the coking process and to utilize biomaterial for the production of transportation fuels. The coking process may be a delayed coking process or a fluidized bed coking process and in each case, the presence of the biomass will decrease the coke drying time so reducing coke handling problems in the unit besides forming a superior coke product. In the case of a fluidized bed coking process using a gasifier for the coke, the addition of an alkali metal salt improves the operation of the gasifier.
摘要翻译：生物质用作重石油炼焦过程的共同进料，以改善焦化过程的运行并利用生物材料生产运输燃料。焦化方法可以是延迟焦化方法或流化床焦化方法，并且在每种情况下，生物质的存在将降低焦炭干燥时间，从而减少除了形成高级焦炭产物之外的单元中的焦炭处理问题。在使用气化炉用于焦炭的流化床焦化方法的情况下，加入碱金属盐改善了气化器的操作。

2. 发明申请

US20110232164A1 BIOMASS OIL CONVERSION PROCESS 有权
标题翻译：生物质油转化过程
公开(公告)号：US20110232164A1
公开(公告)日：2011-09-29
申请号：US13038107
申请日：2011-03-01
申请人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN , Walter WEISSMAN
发明人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN , Walter WEISSMAN
IPC分类号： C10L1/02
CPC分类号： C10G1/02 , C10B57/045 , C10B57/06 , C10G1/002 , C10G9/005 , C10G2300/1014 , Y02P20/145 , Y02P30/20
摘要： A biomass pyrolysis oil is used as a co-feed for a heavy petroleum oil coking process to improve the operation of the coking process and to utilize biomaterial for the production of transportation fuels. The coking process may be a delayed coking process or a fluidized bed coking process and in each case, the presence of the biomass pyrolysis oil will decrease the coke drying time while reducing coke handling problems in the unit besides forming a superior coke product. In the case of a fluidized bed coking process using a gasifier for the coke, the addition of an alkali metal salt improves the operation of the gasifier.
摘要翻译：生物质热解油用作重石油焦化工艺的共同进料，以改善焦化工艺的运行并利用生物材料生产运输燃料。焦化过程可以是延迟焦化方法或流化床焦化方法，并且在每种情况下，除了形成优异的焦炭产物之外，生物质热解油的存在将降低焦炭干燥时间，同时减少该单元中的焦炭处理问题。在使用气化炉用于焦炭的流化床焦化方法的情况下，加入碱金属盐改善了气化器的操作。

3. 发明申请

US20110232161A1 BIOMASS OIL CONVERSION PROCESS 有权
标题翻译：生物质油转化过程
公开(公告)号：US20110232161A1
公开(公告)日：2011-09-29
申请号：US13038010
申请日：2011-03-01
申请人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN
发明人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN
IPC分类号： C10L1/00
CPC分类号： C10G3/40 , C10G2300/1014 , C10G2300/4006 , C10L1/04 , C10L9/086 , Y02P30/20
摘要： Biomass pyrolysis oil is converted into precursors for hydrocarbon transportation fuels by contacting the oil with liquid superheated water or supercritical water to depolymerize and deoxygenate the components of the oil and form the transportation fuel precursors. Temperatures above 200° C. and preferably above 300° C. are preferred with supercritical water at temperatures above 374° C. and pressures above 22 MPA providing the capability for fast conversion rates.
摘要翻译：通过使油与液体过热水或超临界水接触来将生物质热解油转化为烃运输燃料的前体，以解聚和脱氧油组分并形成运输燃料前体。超过200℃，优选高于300℃的温度优选超过374℃的超临界水，高于22MPA的压力提供快速转化率的能力。

4. 发明申请

US20110232163A1 BIOMASS OIL CONVERSION USING CARBON MONOXIDE AND WATER 有权
标题翻译：使用一氧化碳和水的生物质油转化
公开(公告)号：US20110232163A1
公开(公告)日：2011-09-29
申请号：US13038093
申请日：2011-03-01
申请人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN
发明人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN
IPC分类号： C10L1/00
CPC分类号： C10G1/002 , C10G1/02 , C10G3/40 , C10G2300/1014 , C10G2300/4006 , C10G2300/4012 , C10G2300/805 , Y02P30/20
摘要： A pyrolysis oil derived from a lignocellulosic biomass material is converted into precursors for liquid hydrocarbon transportation fuels by contacting the oil with water and carbon monoxide at elevated temperature, typically from 280 to 350° C., an elevated pressure, typically a total system pressure of 12 to 30 MPa and a CO partial pressure from 5 to 10 MPa and a weight ratio of water:biomass oil from 0.5:1 to 5.0:1, to dissolve the oil into the reaction mixture and depolymerize, deoxygenate and hydrogenate the oil, so converting it into liquid transportation fuel precursors.
摘要翻译：衍生自木质纤维素生物质材料的热解油通过使油与水和一氧化碳在升高的温度（通常为280至350℃）下接触而转化为液体烃运输燃料的前体，升高的压力通常为 12〜30MPa，CO分压为5〜10MPa，水：生物质油的重量比为0.5：1〜5.0：1，将油溶解于反应混合物中，对油进行脱氧，氢化，将其转化为液体运输燃料前体。

5. 发明申请

US20110232162A1 BIOMASS CONVERSION USING CARBON MONOXIDE AND WATER 有权
标题翻译：使用一氧化碳和水的生物量转换
公开(公告)号：US20110232162A1
公开(公告)日：2011-09-29
申请号：US13038060
申请日：2011-03-01
申请人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN
发明人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN
IPC分类号： C10L1/00
CPC分类号： C10G1/00 , C10G1/04 , C10G1/083 , C10G2300/1014 , Y02P30/20
摘要： A lignocellulosic biomass material is converted into precursors for liquid hydrocarbon transportation fuels by contacting the biomass material with water and carbon monoxide at elevated temperature, typically from 280 to 350° C., an elevated pressure, typically a total system pressure of 12 to 30 MPa and a CO partial pressure from 5 to 10 MPa and a weight ratio of water:biomass material from 0.5:1 to 5.0:1, to dissolve the biomass material into the reaction mixture and depolymerize, deoxygenate and hydrogenate the lignocellulose biomass material, so converting the biomass material into liquid transportation fuel precursors.
摘要翻译：木质纤维素生物质材料通过使生物质材料与水和一氧化碳在升高的温度（通常为280-350℃），升高的压力（通常为12-30MPa的总体系压力）接触而转化为液体烃运输燃料的前体和5〜10MPa的CO分压和水：生物质材料的重量比为0.5:1至5.0:1，将生物质材料溶解到反应混合物中，解聚，脱氧和氢化木质纤维素生物质材料，从而转化生物质材料成为液体运输燃料前体。

6. 发明申请

US20110232160A1 BIOMASS CONVERSION PROCESS 审中-公开
标题翻译：生物量转换过程
公开(公告)号：US20110232160A1
公开(公告)日：2011-09-29
申请号：US13037938
申请日：2011-03-01
申请人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN
发明人： Michael SISKIN , Glen E. PHILLIPS , Simon R. KELEMEN
IPC分类号： C10L1/10
CPC分类号： C10L1/04 , C10G3/40 , C10G2300/1003 , C10G2300/1014 , C10G2300/4006 , Y02P30/20
摘要： Biomass material is converted into precursors for hydrocarbon transportation fuels by contacting the biomass with liquid superheated water or supercritical water to depolymerize and deoxygenate the biomass into the transportation fuel precursors. Temperatures above 200° C. and preferably above 300° C. are preferred with supercritical water at temperatures above 374° C. and pressures above 22 MPa providing a capability for higher conversion rates.
摘要翻译：生物质材料通过使生物质与液体过热水或超临界水接触，将生物质解聚和脱氧转化为运输燃料前体，将其转化为烃运输燃料的前体。超过200℃，优选高于300℃的温度优选超过374℃的超临界水，高于22MPa的压力提供更高转化率的能力。

7. 发明申请

US20100320120A1 HIGH TEMPERATURE HYDROPYROLYSIS OF CARBONACEOUS MATERIALS 审中-公开
标题翻译：碳酸盐材料的高温水解
公开(公告)号：US20100320120A1
公开(公告)日：2010-12-23
申请号：US12773499
申请日：2010-05-04
申请人： Michael SISKIN , Ramesh VARADARAJ , Walter WEISSMAN , Mark A. GREANEY
发明人： Michael SISKIN , Ramesh VARADARAJ , Walter WEISSMAN , Mark A. GREANEY
IPC分类号： C10B53/06 , C10B53/00 , C10G1/00
CPC分类号： C10G1/06 , C10G47/22
摘要： Heat from nuclear reactor as a source of thermal energy is applied to the conversion of carbonaceous materials such as heavy petroleum crude oils, coals and biomass to liquid hydrocarbons. The heat is applied to provide at least a portion of the process heat used in the high temperature, short contact time hydropyrolysis of the carbonaceous material which is supplied with hydrogen generated by a high temperature process such as high temperature steam electrolysis, the sulfur-iodine cycle, the hybrid sulfur cycle, the zinc-zinc oxide cycle, a solid oxide fuel cell or by methane steam cracking. The heat from the nuclear reactor may be used to generate electricity to operate high temperature steam electrolysis used in generation of the hydrogen. By the use of nuclear thermal energy, hydrocarbon resource utilization for process heat is eliminated along with carbon dioxide evolution associated with burning of the hydrocarbon resource to generate process heat. The substitution of zero carbon emission sources therefore offers the potential for significant carbon emission reductions in refinery operations where external process heat can be applied and effectively utilized.
摘要翻译：作为热能来源的核反应堆的热量被应用于碳质材料如重质石油原油，煤和生物质向液态烃的转化。施加热量以提供在由高温蒸汽电解产生的氢气产生的碳质材料的高温，短接触时间加氢热解中使用的工艺热量的至少一部分，硫 - 碘循环，杂化硫循环，锌 - 锌氧化物循环，固体氧化物燃料电池或甲烷蒸汽裂解。可以使用来自核反应堆的热量来发电以操作用于产生氢的高温蒸汽电解。通过使用核热能，消除了用于工艺热的碳氢化合物资源利用以及与碳氢化合物资源的燃烧相关的二氧化碳排放以产生工艺热。因此，替代零碳排放源可提供炼油作业中显着的碳排放减少的潜力，其中可以应用和有效利用外部过程热。

8. 发明申请

US20100314235A1 HIGH TEMPERATURE HYDROPYROLYSIS OF CARBONACEOUS MATERIALS 审中-公开
标题翻译：碳酸盐材料的高温水解
公开(公告)号：US20100314235A1
公开(公告)日：2010-12-16
申请号：US12773518
申请日：2010-05-04
申请人： Ramesh VARADARAJ , Michael SISKIN , Walter WEISSMAN , Mark A. GREANEY
发明人： Ramesh VARADARAJ , Michael SISKIN , Walter WEISSMAN , Mark A. GREANEY
IPC分类号： C10B57/12 , C10B57/04 , C10B21/00 , C10B57/00
CPC分类号： C10G47/22 , C01B3/384 , C01B2203/0233 , C01B2203/0283 , C01B2203/067 , C01B2203/0855 , C01B2203/1241 , C01B2203/86 , C10G1/06 , C25B1/04 , C25B9/10 , H01M8/04007 , H01M2008/1293 , H01M2250/40 , Y02E60/366 , Y02E60/56 , Y02E60/566 , Y02E70/10 , Y02E70/20 , Y02P20/134 , Y02P30/30
摘要： Heat from a concentrated solar power source is applied to the conversion of carbonaceous materials such as heavy petroleum crude oils, coals and biomass to liquid hydrocarbons. The solar heat is applied to provide at least a portion of the process heat used in the high temperature, short contact time hydropyrolysis of the carbonaceous material which is supplied with hydrogen generated by a high temperature process such as high temperature steam electrolysis, the sulfur-iodine cycle, the hybrid sulfur cycle, the zinc-zinc oxide cycle or by methane steam cracking. The heat from the solar source may be used to generate electricity to operate high temperature steam electrolysis used in generation of the hydrogen. By the use of solar thermal energy sources, hydrocarbon resource utilization for process heat is eliminated along with carbon dioxide evolution associated with burning of the hydrocarbon resource to generate process heat. The substitution of zero carbon emission sources therefore offers the potential for significant carbon emission reductions in refinery operations where external process heat can be applied and effectively utilized.
摘要翻译：来自集中太阳能发电源的热量用于将重质石油原油，煤和生物质等碳质材料转化为液态烃。施加太阳能热量以提供在通过高温蒸汽电解的高温过程产生的氢气的碳质材料的高温，短接触时间加氢热解中使用的工艺热量的至少一部分，碘循环，杂化硫循环，锌 - 锌氧化物循环或甲烷蒸汽裂解。来自太阳能源的热可以用于发电以操作用于产生氢的高温蒸汽电解。通过使用太阳能热能源，可以消除用于过程热的碳氢化合物资源利用以及与碳氢化合物资源燃烧相关的二氧化碳排放以产生过程热量。因此，替代零碳排放源可提供炼油作业中显着的碳排放减少的潜力，其中可以应用和有效利用外部过程热。

9. 发明申请

US20110005911A1 DELAYED COKING PROCESS 审中-公开
标题翻译：延迟炼焦工艺
公开(公告)号：US20110005911A1
公开(公告)日：2011-01-13
申请号：US12828405
申请日：2010-07-01
申请人： Fritz A. BERNATZ , Michael SISKIN , Christopher P. EPPIG , Craig Y. SABOTTKE , Eric W. FRYATT
发明人： Fritz A. BERNATZ , Michael SISKIN , Christopher P. EPPIG , Craig Y. SABOTTKE , Eric W. FRYATT
IPC分类号： C10B57/04
CPC分类号： C10G9/005 , C10B55/00 , C10B57/06 , C10G2300/107 , C10G2300/1077 , C10G2300/308 , C10G2300/80
摘要： The morphology of petroleum cokes produced by the delayed coking of feeds produced from extra-heavy crude sources such as those from the Venezuela Orinoco Heavy Oil Belt can be controlled to produce a less dense coke which is less likely to inflame in the coke pit or in subsequent handling. An aqueous solution of an alkali metal or alkaline earth metal carbonate salt when added to a feed of this type which would normally produce a dense coke product is effective to produce a quenchable coke product of lower density and higher porosity, usually in compact, granular form permitting it to be readily discharged from the drum.
摘要翻译：由超重原油（如委内瑞拉奥里诺科重油带）生产的饲料的延迟焦化产生的石油焦炭的形态可以被控制以产生较不致密的焦炭，其在焦炭坑或不太可能发生火焰后续处理。当加入通常产生致密焦炭产品的这种类型的进料中时，碱金属或碱土金属碳酸盐的水溶液是有效的，以生产具有较低密度和更高孔隙率的可淬火焦炭产品，通常为紧凑的颗粒形式使其容易从鼓中排出。

10. 发明申请

US20130310623A1 AMINE GAS TREATMENT SOLUTIONS 审中-公开
标题翻译：氨气处理解决方案
公开(公告)号：US20130310623A1
公开(公告)日：2013-11-21
申请号：US13471758
申请日：2012-05-15
申请人： Michael SISKIN , Robert B. FEDICH , Michel A. DAAGE
发明人： Michael SISKIN , Robert B. FEDICH , Michel A. DAAGE
IPC分类号： C07C7/11 , C09K3/00
CPC分类号： C07C7/11 , B01D53/1456 , B01D53/18 , B01D2252/20426 , B01D2252/20478 , B01D2252/604 , B01D2256/24 , B01D2257/304 , B01D2257/306 , B01D2257/308 , B01D2257/408 , B01D2257/504 , C09K3/00
摘要： A process for the selective absorption of acidic components from normally gaseous hydrocarbon mixtures using an aqueous amine absorbent solution comprising an antioxidant and a non-detergent co-solvent for the amine and the antioxidant.
摘要翻译：使用包含用于胺和抗氧化剂的抗氧化剂和非洗涤剂助溶剂的含水胺吸收剂溶液从常规气态烃混合物中选择性吸收酸性组分的方法。

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