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1. 发明申请

US20070287845A1 Hydroxymethylfurfural Reduction Methods and Methods of Producing Furandimethanol 有权
标题翻译：羟甲基糠醛还原方法和生产呋喃二甲醇的方法
公开(公告)号：US20070287845A1
公开(公告)日：2007-12-13
申请号：US11760634
申请日：2007-06-08
申请人： Michael Lilga , Richard Hallen , Todd Werpy , James White , Johnathan Holladay , John Frye , Alan Zacher
发明人： Michael Lilga , Richard Hallen , Todd Werpy , James White , Johnathan Holladay , John Frye , Alan Zacher
IPC分类号： C07D307/02
CPC分类号： C07D307/42 , C07D307/46
摘要： A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250° C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30° C. A method of producing tetrahydrofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
摘要翻译：提供一种还原羟甲基糠醛（HMF）的方法，其中含有HMF的原料在包含水的溶剂中。 H 2被提供到反应器中，起始材料与含有至少一种选自Ni，Co，Cu，Pd，Pt，Ru，Ir，Re和Rh的金属的催化剂接触，温度小于或等于250℃。氢化HMF的方法包括提供含有HMF和果糖的水溶液。 H 2 H 2和氢化催化剂。 HMF在等于或高于30℃的温度下相对于果糖选择性地氢化。制备四氢呋喃二甲醇（THFDM）的方法包括提供具有第一和第二催化剂的连续流动反应器，并向反应器中提供包含HMF的进料。进料与第一催化剂接触以产生与第二催化剂接触以产生THFDM的呋喃二甲醇（FDM）。

2. 发明申请

US20070173643A1 Process for Producing Cyclic Compounds 有权
标题翻译：生产环状化合物的方法
公开(公告)号：US20070173643A1
公开(公告)日：2007-07-26
申请号：US11688022
申请日：2007-03-19
申请人： Todd Werpy , John Frye , James White , Johnathan Holladay , Alan Zacher
发明人： Todd Werpy , John Frye , James White , Johnathan Holladay , Alan Zacher
IPC分类号： C07D207/267 , C07D223/10 , C07D205/02
CPC分类号： C07D207/404
摘要： The invention includes methods of processing an initial di-carbonyl compound by conversion to a cyclic compound. The cyclic compound is reacted with an alkylating agent to form a derivative having an alkylated ring nitrogen. The invention encompasses a method of producing an N-alkyl product. Ammonia content of a solution is adjusted to produce a ratio of ammonia to di-carboxylate compound of from about 1:1 to about 1.5:1. An alkylating agent is added and the initial compound is alkylated and cyclized. The invention includes methods of making N-methyl pyrrolidinone (NMP). Aqueous ammonia and succinate is introduced into a vessel and ammonia is adjusted to provide a ratio of ammonia to succinate of less than 2:1. A methylating agent is reacted with succinate at a temperature of from greater than 100° C. to about 400° C. to produce N-methyl succinimide which is purified and hydrogenated to form NMP.
摘要翻译：本发明包括通过转化为环状化合物来处理初始二羰基化合物的方法。环状化合物与烷基化剂反应形成具有烷基化环氮的衍生物。本发明包括生产N-烷基产物的方法。调节溶液的氨含量以产生约1：1至约1.5：1的氨与二羧酸酯化合物的比例。加入烷基化剂并将该初始化合物烷基化并环化。本发明包括制备N-甲基吡咯烷酮（NMP）的方法。将氨水和琥珀酸钠引入容器中，并调节氨以提供小于2:1的氨与琥珀酸的比例。甲基化剂与琥珀酸酯在大于100℃至约400℃的温度下反应，生成N-甲基琥珀酰亚胺，将其纯化并氢化形成NMP。

3. 发明申请

US20070219397A1 Method for conversion of beta-hydroxy carbonyl compounds 审中-公开
标题翻译： β-羟基羰基化合物转化方法
公开(公告)号：US20070219397A1
公开(公告)日：2007-09-20
申请号：US11376936
申请日：2006-03-15
申请人： Johnathan Holladay , Alan Zacher , Michael Lilga , James White , Danielle Muzatko , Rick Orth , Paraskevas Tsobanakis , Xiangsheng Meng , Timothy Abraham
发明人： Johnathan Holladay , Alan Zacher , Michael Lilga , James White , Danielle Muzatko , Rick Orth , Paraskevas Tsobanakis , Xiangsheng Meng , Timothy Abraham
IPC分类号： C07C51/00
CPC分类号： C07C231/14 , C07C51/377 , Y02P20/127 , C07C57/04 , C07C233/09
摘要： A process is disclosed for conversion of ammonium salts of β-hydroxy carbonyl compounds forming useful conversion products including, e.g., α, β-unsaturated carbonyl compounds and/or ammonium salts of α, β-unsaturated carbonyl compounds recovered at a high molar yield. Conversion products find use, e.g., as feedstock and/or end-use chemicals.
摘要翻译：公开了用于转化形成有用转化产物的β-羟基羰基化合物的铵盐的方法，包括例如以高摩尔收率回收的α，β-不饱和羰基化合物和/或α，β-不饱和羰基化合物的铵盐。转化产物可用作例如原料和/或最终用途的化学品。

4. 发明申请

US20070219390A1 Method and apparatus for conversion of beta-hydroxy carbonyl compounds 审中-公开
标题翻译：转化β-羟基羰基化合物的方法和装置
公开(公告)号：US20070219390A1
公开(公告)日：2007-09-20
申请号：US11377052
申请日：2006-03-15
申请人： Alan Zacher , Johnathan Holladay , Michael Lilga , James White , Danielle Muzatko , Rick Orth , Paraskevas Tsobanakis , Xiangsheng Meng , Timothy Abraham
发明人： Alan Zacher , Johnathan Holladay , Michael Lilga , James White , Danielle Muzatko , Rick Orth , Paraskevas Tsobanakis , Xiangsheng Meng , Timothy Abraham
IPC分类号： C07C69/52
CPC分类号： C07C51/377 , C07C57/04
摘要： A process and apparatus are disclosed for conversion of β-hydroxy carbonyl compounds forming useful conversion products including, e.g., acrylic acid [CAS No. 79-10-7], acrylates, and acrylamide [CAS No. 79-06-01]. Conversion products find use, e.g., as feedstock and/or end-use chemicals.
摘要翻译：公开了用于转化形成有用的转化产物的β-羟基羰基化合物的方法和装置，包括例如丙烯酸[CAS No.79-10-7]，丙烯酸酯和丙烯酰胺[CAS No.79-06-01]。转化产物可用作例如原料和/或最终用途的化学品。

5. 发明申请

US20070219391A1 Method for conversion of beta-hydroxy carbonyl compounds 失效
标题翻译： β-羟基羰基化合物转化方法
公开(公告)号：US20070219391A1
公开(公告)日：2007-09-20
申请号：US11377096
申请日：2006-03-15
申请人： Michael Lilga , James White , Johnathan Holladay , Alan Zacher , Danielle Muzatko , Rick Orth
发明人： Michael Lilga , James White , Johnathan Holladay , Alan Zacher , Danielle Muzatko , Rick Orth
IPC分类号： C07C69/52
CPC分类号： C07C51/377 , C07C51/41 , C07C57/04
摘要： A process is disclosed for conversion of salts of β-hydroxy carbonyl compounds forming useful conversion products including, e.g., α,β-unsaturated carbonyl compounds and/or salts of α,β-unsaturated carbonyl compounds. Conversion products find use, e.g., as feedstock and/or end-use chemicals.
摘要翻译：公开了用于转化形成有用的转化产物的β-羟基羰基化合物的盐的方法，包括例如α，β-不饱和羰基化合物和/或α，β-不饱和羰基化合物的盐。转化产物可用作例如原料和/或最终用途的化学品。

6. 发明申请

US20070173652A1 Method of forming a dianhydrosugar alcohol 失效
标题翻译：形成二脱水糖醇的方法
公开(公告)号：US20070173652A1
公开(公告)日：2007-07-26
申请号：US11341961
申请日：2006-01-26
申请人： Johnathan Holladay , Jianli Hu , Yong Wang , Todd Werpy , Xinjie Zhang
发明人： Johnathan Holladay , Jianli Hu , Yong Wang , Todd Werpy , Xinjie Zhang
IPC分类号： C07D311/22
CPC分类号： C07D307/20 , C07D493/04 , Y02P20/127
摘要： The invention includes methods of producing dianhydrosugars. A polyol is reacted in the presence of a first catalyst to form a monocyclic sugar. The monocyclic sugar is transferred to a second reactor where it is converted to a dianhydrosugar alcohol in the presence of a second catalyst. The invention includes a process of forming isosorbide. An initial reaction is conducted at a first temperature in the presence of a solid acid catalyst. The initial reaction involves reacting sorbitol to produce 1,4-sorbitan, 3,6-sorbitan, 2,5-mannitan and 2,5-iditan. Utilizing a second temperature, the 1,4-sorbitan and 3,6-sorbitan are converted to isosorbide. The invention includes a method of purifying isosorbide from a mixture containing isosorbide and at least one additional component. A first distillation removes a first portion of the isosorbide from the mixture. A second distillation is then conducted at a higher temperature to remove a second portion of isosorbide from the mixture.
摘要翻译：本发明包括生产二脱水甘油糖的方法。多元醇在第一催化剂存在下反应形成单环糖。将单环糖转移到第二反应器中，在第二反应器中，在第二催化剂的存在下将其转化为二脱水甘油醇。本发明包括形成异山梨醇的方法。在固体酸催化剂存在下，在第一温度下进行初始反应。初始反应包括使山梨醇反应生成1,4-脱水山梨糖醇，3,6-脱水山梨糖醇，2,5-甘露聚糖和2,5-己烷。利用第二温度，将1,4-脱水山梨醇和3,6-脱水山梨醇转化为异山梨醇。本发明包括从含有异山梨醇和至少一种另外的组分的混合物中纯化异山梨醇的方法。第一蒸馏从混合物中除去第一部分的异山梨醇。然后在较高温度下进行第二次蒸馏以从混合物中除去第二部分的异山梨醇。

7. 发明申请

US20070173651A1 Two-stage dehydration of sugars 有权
标题翻译：糖两步脱水
公开(公告)号：US20070173651A1
公开(公告)日：2007-07-26
申请号：US11341930
申请日：2006-01-26
申请人： Johnathan Holladay , Jianli Hu , Yong Wang , Todd Werpy
发明人： Johnathan Holladay , Jianli Hu , Yong Wang , Todd Werpy
IPC分类号： C07D311/22
CPC分类号： C07D493/04
摘要： The invention includes methods for producing dianhydrosugar alcohol by providing an acid catalyst within a reactor and passing a starting material through the reactor at a first temperature. At least a portion of the staring material is converted to a monoanhydrosugar isomer during the passing through the column. The monoanhydrosugar is subjected to a second temperature which is greater than the first to produce a dianhydrosugar. The invention includes a method of producing isosorbide. An initial feed stream containing sorbitol is fed into a continuous reactor containing an acid catalyst at a temperature of less than 120° C. The residence time for the reactor is less than or equal to about 30 minutes. Sorbitol converted to 1,4-sorbitan in the continuous reactor is subsequently provided to a second reactor and is dehydrated at a temperature of at least 120° C. to produce isosorbide.
摘要翻译：本发明包括通过在反应器内提供酸催化剂并使原料在第一温度下通过反应器来生产二脱水甘油的方法。在通过色谱柱期间，至少一部分起始物质被转化为单一脱氢葡萄糖异构体。单糖酐经受大于第一温度的第二温度以产生二脱水糖。本发明包括一种生产异山梨醇的方法。含有山梨醇的初始进料流在小于120℃的温度下进料到含有酸催化剂的连续反应器中。反应器的停留时间小于或等于约30分钟。随后将连续反应器中转化为1,4-脱水山梨醇的山梨糖醇提供给第二反应器，并在至少120℃的温度下脱水以制备异山梨醇。

8. 发明申请

US20070173654A1 Methods for dehydration of sugars 有权
标题翻译：糖脱水方法
公开(公告)号：US20070173654A1
公开(公告)日：2007-07-26
申请号：US11341968
申请日：2006-01-26
申请人： Johnathan Holladay , Jianli Hu , Xinjie Zhang , Yong Wang
发明人： Johnathan Holladay , Jianli Hu , Xinjie Zhang , Yong Wang
IPC分类号： C07D493/02
CPC分类号： C07D493/04
摘要： The invention includes a method of dehydration of a sugar using a dehydration catalyst and a co-catalyst within a reactor. A sugar is introduced and H2 is flowed through the reactor at a pressure of less than or equal to about 300 psig to convert at least some of the sugar into an anhydrosugar product. The invention includes a process for producing isosorbide. A starting material comprising sorbitol is flowed into a reactor. H2 is counter flowed through the reactor. The starting material is exposed to a catalyst in the presence of a co-catalyst which comprises at least one metal. The exposing is conducted at a hydrogen pressure of less than or equal to 300 psig within the reactor and the hydrogen removes at least some of any water present during the exposing and inhibits formation of colored byproducts.
摘要翻译：本发明包括使用反应器内的脱水催化剂和助催化剂使糖脱水的方法。引入糖，并且H 2 O 2以小于或等于约300psig的压力流过反应器，以将至少一些糖转化为脱水糖产物。本发明包括制备异山梨醇的方法。将含有山梨醇的原料流入反应器。 H 2反向流过反应器。在包含至少一种金属的助催化剂的存在下，将原料暴露于催化剂。暴露在反应器内在小于或等于300psig的氢气压力下进行，并且氢去除暴露期间存在的任何水中的至少一些，并且抑制着色副产物的形成。

9. 发明申请

US20060058557A1 Bis-chelating ligand and use thereof in carbonylation processes 有权
标题翻译：双螯合配体及其在羰基化过程中的应用
公开(公告)号：US20060058557A1
公开(公告)日：2006-03-16
申请号：US10527568
申请日：2003-09-26
申请人： Wei-Jun Peng , Johnathan Holladay
发明人： Wei-Jun Peng , Johnathan Holladay
IPC分类号： C07C45/49 , C07F9/02
CPC分类号： C07F15/008 , B01J31/1608 , B01J31/185 , B01J2231/321 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , C07C45/50 , C07F9/65746 , C07C47/42
摘要： A novel bis-chelating composition characterized by formula I: wherein M is a Group VB element; RI and R2 are each independently selected from hydrogen and monovalent hydrocarbyl radicals; or R1 and R2 are bonded together to form a diradical; or one of RI or R2 is hydrogen or a monovalent hydrocarbyl radical, while the other of R1 or R2 is a hydrocarbyl radical bonded to an atom in Ar; wherein Ar is selected from 1,2-arylenes; Q is selected from 1,2-arylenes, 2,2′-bisarylenes and alkyl diradicals; and W is selected from II, III, IV, or V: wherein M is as defined hereinbefore; each R is independently selected from hydrogen and monovalent hydrocarbyl radicals; X is selected from alkyl and aryl diradicals; Ar1 and Ar2 are each independently selected from 1,2-arylenes; Ar3 and Ar4 are each independently selected from monovalent aryl radicals; and n in formula IV is 0 or 1. The composition finds utility as a ligand in catalysts for carbonylation processes.
摘要翻译：特征在于式I的新型双螯合组合物：其中M是VB族元素; R 1和R 2各自独立地选自氢和一价烃基; 或者R 1和R 2结合在一起形成双基; 或R 1或R 2中的一个为氢或一价烃基，而R 1或R 2中的另一个为与Ar中的原子键合的烃基; 其中Ar选自1,2-亚芳基; Q选自1,2-亚芳基，2,2'-双芳烯和烷基双基; W选自II，III，IV或V：其中M如上所定义; 每个R独立地选自氢和一价烃基; X选自烷基和芳基双基; Ar 1和Ar 2各自独立地选自1,2-亚芳基; Ar 3和Ar 4各自独立地选自单价芳基; 式IV中的n为0或1.该组合物用作羰基化反应催化剂中的配体

10. 发明申请

US20070173653A1 Method of performing sugar dehydration and catalyst treatment 失效
标题翻译：糖脱水和催化剂处理方法
公开(公告)号：US20070173653A1
公开(公告)日：2007-07-26
申请号：US11342146
申请日：2006-01-26
申请人： Jianli Hu , Johnathan Holladay , Xinjie Zhang , Yong Wang
发明人： Jianli Hu , Johnathan Holladay , Xinjie Zhang , Yong Wang
IPC分类号： C07D311/22
CPC分类号： C07H1/00
摘要： The invention includes a method of treating a solid acid catalyst. After exposing the catalyst to a mixture containing a sugar alcohol, the catalyst is washed with an organic solvent and is then exposed to a second reaction mixture. The invention includes a process for production of anhydrosugar alcohol. A solid acid catalyst is provided to convert sugar alcohol in a first sample to an anhydrosugar alcohol. The catalyst is then washed with an organic solvent and is subsequently utilized to expose a second sample. The invention includes a method for selective production of an anhydrosugar. A solid acid catalyst is provided within a reactor and anhydrosugar alcohol is formed by flowing a starting sugar alcohol into the reactor. The acid catalyst is then exposed to an organic solvent which allows a greater amount of additional anhydrosugar to be produced than would occur without exposing the acid catalyst to the organic solvent.
摘要翻译：本发明包括一种处理固体酸催化剂的方法。在将催化剂暴露于含有糖醇的混合物之后，用有机溶剂洗涤催化剂，然后暴露于第二反应混合物。本发明包括生产脱水葡萄糖醇的方法。提供固体酸催化剂以将第一样品中的糖醇转化为脱水葡萄糖醇。然后将催化剂用有机溶剂洗涤，随后用于暴露第二个样品。本发明包括选择性生产脱水糖的方法。在反应器内提供固体酸催化剂，通过将起始糖醇流入反应器而形成脱水葡萄糖醇。然后将酸催化剂暴露于有机溶剂，其允许比不会将酸催化剂暴露于有机溶剂而产生更多量的额外的脱水糖。

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