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1. 发明授权

US07041728B2 Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant 失效
标题翻译：具有少量氟化表面活性剂的聚四氟乙烯的水分散体
公开(公告)号：US07041728B2
公开(公告)日：2006-05-09
申请号：US10962633
申请日：2004-10-12
申请人： Tilman Zipplies , Klaus Hintzer , Michael C. Dadalas , Gernot Loehr
发明人： Tilman Zipplies , Klaus Hintzer , Michael C. Dadalas , Gernot Loehr
IPC分类号： C08L27/12 , D06M15/277
CPC分类号： C09D127/18 , C08F6/16 , C08F214/26 , C08L27/18 , C08L71/02 , C08L2666/02 , C08L2666/22
摘要： The present invention provides a method of making an aqueous dispersion of non-melt processible polytetrafluoroethylene, the method comprising:(a) an aqueous emulsion polymerization of an amount of tetrafluoroethylene to produce a final amount of polytetrafluoroethylene solids and optionally up to 1% by weight based on the amount of tetrafluoroethylene of a perfluorinated comonomer, wherein said aqueous emulsion polymerization is initiated with a free radical initiator and the polymerization is carried out in the presence of a fluorinated surfactant, and wherein before completing the feeding of said amount of tetrafluoroethylene but after feeding at least 80% by weight of said amount of tetrafluoroethylene, free radicals capable of introducing ionic end groups or precursors thereof in the polytetrafluoroethylene polymer are caused to be formed at a rate that without counter measures would cause an increase in the polymerization rate of at least 20%;(b) reducing the amount of fluorinated surfactant in the thus obtained aqueous dispersion to an amount of not more than 200 ppm, preferably not more than 100 ppm and more preferably not more than 50 ppm based on the amount of polytetrafluoroethylene solids. The invention further provides an aqueous dispersion of polytetrafluoroethylene particles and the use thereof in coating a substrate.
摘要翻译：本发明提供了一种制备不熔融可加工聚四氟乙烯的水性分散体的方法，该方法包括：（a）一定量的四氟乙烯的水乳液聚合以产生最终量的聚四氟乙烯固体，并且任选地高达1重量％基于全氟化共聚单体的四氟乙烯的量，其中所述水性乳液聚合由自由基引发剂引发，并且聚合在氟化表面活性剂的存在下进行，并且其中在完成所述量的四氟乙烯之前但在加入至少80重量％的所述量的四氟乙烯，使得能够在聚四氟乙烯聚合物中引入离子端基或其前体的自由基以不加对策的方式形成，导致聚四氟乙烯聚合速率的升高至少20％; （b）将由此得到的水性分散体中的氟化表面活性剂的量减少到基于聚四氟乙烯固体量不超过200ppm，优选不超过100ppm，更优选不大于50ppm的量。本发明还提供聚四氟乙烯颗粒的水分散体及其在涂布基材中的用途。

2. 发明授权

US07462667B2 Primer coating of PTFE for metal substrates 有权
标题翻译：用于金属基材的PTFE底漆涂层
公开(公告)号：US07462667B2
公开(公告)日：2008-12-09
申请号：US11172345
申请日：2005-06-30
申请人： Michael C. Dadalas , Klaus Hintzer , Gernot Loehr , Tilman Zipplies
发明人： Michael C. Dadalas , Klaus Hintzer , Gernot Loehr , Tilman Zipplies
IPC分类号： C08L37/12
CPC分类号： C09D179/08 , C08L27/08 , C09D5/002 , C09D177/00 , C09D179/04 , C09D181/06 , Y10T428/3154 , C08L2666/14 , C08L2666/04
摘要： The present invention provides an aqueous coating composition comprising (i) particles of a non-melt processible polymer of tetrafluoroethylene and (ii) a non-fluorinated polymer selected from the group consisting of a polysulfone, a polyamide, a polyimide, a polyamide-imide, a polybismaleimide and mixtures thereof, wherein said particles are core-shell particles whereby the shell comprises a copolymer of tetrafluoroethylene and a partially fluorinated or non-fluorinated comonomer. The aqueous coating composition may be used for providing a primer coating on a substrate such as a metal or glass substrate. Such primer coating may provide good or excellent non-stick coatings combined with good or excellent scratch and wear resistance of the coating. Also, such primer coating may provide for good to excellent PTFE coatings that can resist hot salt water. The aqueous coating composition may also be used to provide other coating layers of a multi-layer coating.
摘要翻译：本发明提供一种水性涂料组合物，其包含（i）四氟乙烯的不可熔融加成聚合物的颗粒和（ii）选自聚砜，聚酰胺，聚酰亚胺，聚酰胺 - 酰亚胺的非氟化聚合物，多双马来酰亚胺及其混合物，其中所述颗粒是核 - 壳颗粒，其中壳包含四氟乙烯和部分氟化或非氟化共聚单体的共聚物。水性涂料组合物可以用于在诸如金属或玻璃基材的基材上提供底漆涂层。这种底漆涂层可以提供良好或优异的不粘涂层，同时具有涂层的良好或优异的耐擦伤性和耐磨性。此外，这种底漆涂层可以提供可耐受热盐水的良好至优异的PTFE涂层。水性涂料组合物也可用于提供多层涂层的其它涂层。

3. 发明授权

US07342066B2 Aqueous dispersions of polytetrafluoroethylene particles 有权
标题翻译：聚四氟乙烯颗粒的水分散体
公开(公告)号：US07342066B2
公开(公告)日：2008-03-11
申请号：US10957898
申请日：2004-10-04
申请人： Michael C. Dadalas , Klaus Hintzer , Gernot Loehr , Tilman Zipplies
发明人： Michael C. Dadalas , Klaus Hintzer , Gernot Loehr , Tilman Zipplies
IPC分类号： C08L27/12
CPC分类号： C09D127/18 , C08L2666/28
摘要： The present invention provides an aqueous non-melt processible polytetrafluoroethylene dispersion comprising non-melt processible polytetrafluoroethylene particles in an amount between 30 and 70% by weight based on the total weight of the dispersion and one or more non-ionic surfactants and wherein at least a part of said non-melt processible polytetrafluoroethylene particles comprise polytetrafluoroethylene polymer chains having repeating units comprising ionic groups. The invention further provides a method for obtaining the dispersions.
摘要翻译：本发明提供了一种含水不可熔融加工的聚四氟乙烯分散体，其包含基于分散体和一种或多种非离子表面活性剂的总重量为30-70重量％的不可熔融加工的聚四氟乙烯颗粒，并且其中至少一个所述不可熔融加工的聚四氟乙烯颗粒的一部分包括具有包含离子基团的重复单元的聚四氟乙烯聚合物链。本发明还提供了获得分散体的方法。

4. 发明申请

US20060128872A1 Aqueous Dispersions of Polytetrafluoroethylene Having a Low Amount of Fluorinated Surfactant 有权
标题翻译：具有少量氟化表面活性剂的聚四氟乙烯的水性分散体
公开(公告)号：US20060128872A1
公开(公告)日：2006-06-15
申请号：US11275959
申请日：2006-02-07
申请人： Tilman Zipplies , Klaus Hintzer , Michael Dadalas , Gernot Loehr
发明人： Tilman Zipplies , Klaus Hintzer , Michael Dadalas , Gernot Loehr
IPC分类号： C08G18/62
CPC分类号： C09D127/18 , C08F6/16 , C08F214/26 , C08L27/18 , C08L71/02 , C08L2666/02 , C08L2666/22
摘要： An aqueous non-melt processible polytetrafluoroethylene dispersion having non-melt processible polytetrafluoroethylene particles in an amount of 30 to 70% by weight and an amount of non-ionic surfactant between 2 and 15% by weight based on the weight of polytetrafluoroethylene solids. The dispersion is free of fluorinated surfactant or contains fluorinated surfactant in amounts of not more than 200 ppm based on the amount of polytetrafluoroethylene solids. At least part of the non-melt processible polytetrafluoroethylene particles comprise an effective amount of ionic end groups in the polytetrafluoroethylene polymer chains.
摘要翻译：一种水溶性可熔融加工的聚四氟乙烯分散体，其具有30至70重量％的非熔体加工的聚四氟乙烯颗粒和基于聚四氟乙烯固体重量的2至15重量％的非离子表面活性剂的量。该分散体不含氟化表面活性剂，或含有基于聚四氟乙烯固体量不大于200ppm的含氟表面活性剂。至少部分不可熔融加工的聚四氟乙烯颗粒在聚四氟乙烯聚合物链中包含有效量的离子端基。

5. 发明申请

US20060003168A1 Primer coating of PTFE for metal substrates 有权
标题翻译：用于金属基材的PTFE底漆涂层
公开(公告)号：US20060003168A1
公开(公告)日：2006-01-05
申请号：US11172345
申请日：2005-06-30
申请人： Michael Dadalas , Klaus Hintzer , Gernot Loehr , Tilman Zipplies
发明人： Michael Dadalas , Klaus Hintzer , Gernot Loehr , Tilman Zipplies
IPC分类号： B32B27/00
CPC分类号： C09D179/08 , C08L27/08 , C09D5/002 , C09D177/00 , C09D179/04 , C09D181/06 , Y10T428/3154 , C08L2666/14 , C08L2666/04
摘要： The present invention provides an aqueous coating composition comprising (i) particles of a non-melt processible polymer of tetrafluoroethylene and (ii) a non-fluorinated polymer selected from the group consisting of a polysulfone, a polyamide, a polyimide, a polyamide-imide, a polybismaleimide and mixtures thereof, wherein said particles are core-shell particles whereby the shell comprises a copolymer of tetrafluoroethylene and a partially fluorinated or non-fluorinated comonomer. The aqueous coating composition may be used for providing a primer coating on a substrate such as a metal or glass substrate. Such primer coating may provide good or excellent non-stick coatings combined with good or excellent scratch and wear resistance of the coating. Also, such primer coating may provide for good to excellent PTFE coatings that can resist hot salt water. The aqueous coating composition may also be used to provide other coating layers of a multi-layer coating.
摘要翻译：本发明提供一种水性涂料组合物，其包含（i）四氟乙烯的不可熔融加成聚合物的颗粒和（ii）选自聚砜，聚酰胺，聚酰亚胺，聚酰胺 - 酰亚胺的非氟化聚合物，多双马来酰亚胺及其混合物，其中所述颗粒是核 - 壳颗粒，其中壳包含四氟乙烯和部分氟化或非氟化共聚单体的共聚物。水性涂料组合物可以用于在诸如金属或玻璃基材的基材上提供底漆涂层。这种底漆涂层可以提供良好或优异的不粘涂层，同时具有涂层的良好或优异的耐擦伤性和耐磨性。此外，这种底漆涂层可以提供可耐受热盐水的良好至优异的PTFE涂层。水性涂料组合物也可用于提供多层涂层的其它涂层。

6. 发明授权

US07294668B2 Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant 有权
标题翻译：具有少量氟化表面活性剂的聚四氟乙烯的水分散体
公开(公告)号：US07294668B2
公开(公告)日：2007-11-13
申请号：US11275959
申请日：2006-02-07
申请人： Tilman Zipplies , Klaus Hintzer , Michael C. Dadaias , Gernot Loehr
发明人： Tilman Zipplies , Klaus Hintzer , Michael C. Dadaias , Gernot Loehr
IPC分类号： C08J3/00
CPC分类号： C09D127/18 , C08F6/16 , C08F214/26 , C08L27/18 , C08L71/02 , C08L2666/02 , C08L2666/22
摘要： An aqueous non-melt processible polytetrafluoroethylene dispersion having non-melt processible polytetrafluoroethylene particles in an amount of 30 to 70% by weight and an amount of non-ionic surfactant between 2 and 15% by weight based on the weight of polytetrafluoroethylene solids. The dispersion is free of fluorinated surfactant or contains fluorinated surfactant in amounts of not more than 200 ppm based on the amount of polytetrafluoroethylene solids. At least part of the non-melt processible polytetrafluoroethylene particles comprise an effective amount of ionic end groups in the polytetrafluoroethylene polymer chains.
摘要翻译：一种水溶性可熔融加工的聚四氟乙烯分散体，其具有30至70重量％的非熔体加工的聚四氟乙烯颗粒和基于聚四氟乙烯固体重量的2至15重量％的非离子表面活性剂的量。该分散体不含氟化表面活性剂，或含有基于聚四氟乙烯固体量不大于200ppm的含氟表面活性剂。至少部分不可熔融加工的聚四氟乙烯颗粒在聚四氟乙烯聚合物链中包含有效量的离子端基。

7. 发明申请

US20050192397A1 Method of coating a substrate with a fluoropolymer dispersion 审中-公开
标题翻译：用含氟聚合物分散体涂布基材的方法
公开(公告)号：US20050192397A1
公开(公告)日：2005-09-01
申请号：US11040513
申请日：2005-01-21
申请人： Michael Dadalas , Klaus Hintzer , Gernot Loehr , Tilman Zipplies
发明人： Michael Dadalas , Klaus Hintzer , Gernot Loehr , Tilman Zipplies
IPC分类号： B05D5/08 , B05D7/16 , C03C17/32 , C03C25/30 , C03C25/32 , C08K3/00
CPC分类号： B05D5/083 , B05D7/16 , B05D2203/35 , C03C17/32 , C03C25/305 , C03C25/32
摘要： The present invention provides a method of coating a substrate having a surface defined by a layer of fluoropolymer. The method utilizes an aqueous dispersion that includes: particles of melt-processible fluoropolymer in an amount of 30 to 70% by weight; a fluorinated surfactant in an amount of not more than 250 ppm based on fluoropolymer solids of the aqueous dispersion; and a non-ionic surfactant comprising an ethoxylated aliphatic alcohol in an amount of 2 to 15% by weight based on total solids of the aqueous dispersion. The aqueous dispersion is free or substantially free of aromatic group containing non-ionic surfactants. The aqueous dispersion may be optionally diluted and/or modified with additional components to obtain a coating composition. The coating composition may then be applied on at least part of the surface of the substrate to define the fluoropolymer layer.
摘要翻译：本发明提供一种涂覆具有由含氟聚合物层限定的表面的基材的方法。该方法使用水分散体，其包括：可熔融加工的含氟聚合物的颗粒，其量为30至70重量％; 基于含水分散体的含氟聚合物固体的量不超过250ppm的氟化表面活性剂; 和非离子表面活性剂，其包含相对于水性分散体的总固体为2〜15重量％的乙氧基化脂肪醇。水性分散体是游离的或基本上不含含芳族基团的非离子表面活性剂。水性分散体可以任选地用另外的组分稀释和/或改性以获得涂料组合物。然后将涂料组合物施加到基材的至少部分表面上以限定含氟聚合物层。

8. 发明申请

US20050107518A1 Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant 失效
标题翻译：具有少量氟化表面活性剂的聚四氟乙烯的水分散体
公开(公告)号：US20050107518A1
公开(公告)日：2005-05-19
申请号：US10962633
申请日：2004-10-12
申请人： Tilman Zipplies , Klaus Hintzer , Michael Dadalas , Gernot Loehr
发明人： Tilman Zipplies , Klaus Hintzer , Michael Dadalas , Gernot Loehr
IPC分类号： C08F6/16 , C08F214/26 , C08L27/18 , C08L71/02 , C09D127/18 , C08J3/00
CPC分类号： C09D127/18 , C08F6/16 , C08F214/26 , C08L27/18 , C08L71/02 , C08L2666/02 , C08L2666/22
摘要： The present invention provides a method of making an aqueous dispersion of non-melt processible polytetrafluoroethylene, the method comprising: (a) an aqueous emulsion polymerization of an amount of tetrafluoroethylene to produce a final amount of polytetrafluoroethylene solids and optionally up to 1% by weight based on the amount of tetrafluoroethylene of a perfluorinated comonomer, wherein said aqueous emulsion polymerization is initiated with a free radical initiator and the polymerization is carried out in the presence of a fluorinated surfactant, and wherein before completing the feeding of said amount of tetrafluoroethylene but after feeding at least 80% by weight of said amount of tetrafluoroethylene, free radicals capable of introducing ionic end groups or precursors thereof in the polytetrafluoroethylene polymer are caused to be formed at a rate that without counter measures would cause an increase in the polymerization rate of at least 20%; (b) reducing the amount of fluorinated surfactant in the thus obtained aqueous dispersion to an amount of not more than 200 ppm, preferably not more than 100 ppm and more preferably not more than 50 ppm based on the amount of polytetrafluoroethylene solids. The invention further provides an aqueous dispersion of polytetrafluoroethylene particles and the use thereof in coating a substrate.
摘要翻译：本发明提供了一种制备不熔融可加工聚四氟乙烯的水性分散体的方法，该方法包括：（a）一定量的四氟乙烯的水乳液聚合以产生最终量的聚四氟乙烯固体，并且任选地高达1重量％基于全氟化共聚单体的四氟乙烯的量，其中所述水性乳液聚合由自由基引发剂引发，并且聚合在氟化表面活性剂的存在下进行，并且其中在完成所述量的四氟乙烯之前但之后加入至少80重量％的所述量的四氟乙烯，使得能够在聚四氟乙烯聚合物中引入离子端基或其前体的自由基以不加对策的方式形成，导致聚四氟乙烯聚合速率的升高至少20％; （b）将由此得到的水性分散体中的氟化表面活性剂的量减少到基于聚四氟乙烯固体量不超过200ppm，优选不超过100ppm，更优选不大于50ppm的量。本发明还提供聚四氟乙烯颗粒的水分散体及其在涂布基材中的用途。

9. 发明申请

US20050090601A1 Aqueous dispersions of polytetrafluoroethylene particles 有权
标题翻译：聚四氟乙烯颗粒的水分散体
公开(公告)号：US20050090601A1
公开(公告)日：2005-04-28
申请号：US10957898
申请日：2004-10-04
申请人： Michael Dadalas , Klaus Hintzer , Gernot Loehr , Tilman Zipplies
发明人： Michael Dadalas , Klaus Hintzer , Gernot Loehr , Tilman Zipplies
IPC分类号： C08F2/24 , C08F214/26 , C09D127/18 , C08J3/00
CPC分类号： C09D127/18 , C08L2666/28
摘要： The present invention provides an aqueous non-melt processible polytetrafluoroethylene dispersion comprising non-melt processible polytetrafluoroethylene particles in an amount between 30 and 70% by weight based on the total weight of the dispersion and one or more non-ionic surfactants and wherein at least a part of said non-melt processible polytetrafluoroethylene particles comprise polytetrafluoroethylene polymer chains having repeating units comprising ionic groups. The invention further provides a method for obtaining the dispersions.
摘要翻译：本发明提供了一种含水不可熔融加工的聚四氟乙烯分散体，其包含基于分散体和一种或多种非离子表面活性剂的总重量为30-70重量％的不可熔融加工的聚四氟乙烯颗粒，并且其中至少一个所述不可熔融加工的聚四氟乙烯颗粒的一部分包括具有包含离子基团的重复单元的聚四氟乙烯聚合物链。本发明还提供了获得分散体的方法。

10. 发明授权

US06693164B2 High purity fluoropolymers 失效
标题翻译：高纯度氟聚合物
公开(公告)号：US06693164B2
公开(公告)日：2004-02-17
申请号：US09864649
申请日：2001-05-23
申请人： Thomas J. Blong , Denis Duchesne , Gernot Loehr , Albert Killich , Tilman Zipplies , Ralph Kaulbach , Herbert Strasser
发明人： Thomas J. Blong , Denis Duchesne , Gernot Loehr , Albert Killich , Tilman Zipplies , Ralph Kaulbach , Herbert Strasser
IPC分类号： C08F616
CPC分类号： C08F6/06 , C08F6/22 , C08L27/12
摘要： The invention relates to high purity fluoropolymers and processes for making such materials. These polymers are particularly suited for applications in the semiconductor industry. The process comprises removal of unstable polymer end groups by fluorination and removal of heavy metal impurities by extraction with an aqueous acid medium.
摘要翻译：本发明涉及高纯度氟聚合物及其制备方法。这些聚合物特别适用于半导体工业中的应用。该方法包括通过用含水酸性介质萃取氟化和除去重金属杂质来除去不稳定的聚合物端基。

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