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1. 发明申请

US20050090678A1 Phosphonites, use thereof as ligand in transition metal complexes and method for production of nitriles 失效
标题翻译：亚膦酸酯，其用作过渡金属络合物中的配体以及腈的生产方法
公开(公告)号：US20050090678A1
公开(公告)日：2005-04-28
申请号：US10491918
申请日：2002-10-04
申请人： Michael Bartsch , Robert Baumann , Dagmar Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel , Ferenc Molnar
发明人： Michael Bartsch , Robert Baumann , Dagmar Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel , Ferenc Molnar
IPC分类号： B01J31/22 , B01J31/18 , C07B61/00 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07 , C07F9/48 , C07F9/02
CPC分类号： C07F9/4875 , B01J31/1865 , B01J2231/323 , B01J2231/52 , B01J2531/847 , C07C253/10 , C07C255/04 , C07C255/07
摘要： The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF3 and n is 1 or 2.
摘要翻译：本发明涉及式（1）或（2）的亚膦酸酯I，其中R 1，R 2，R 5，R 6，R 7，R 8，R 9独立地表示氢，具有1至8个碳原子的烷基或亚烷基或烷氧基具有1至8个碳原子; R3是H或甲基; R4是异丙基或叔丁基; X是F，Cl或CF 3，n是1或2。

2. 发明申请

US20050090677A1 Phosphinites 审中-公开
标题翻译：亚磷酸盐
公开(公告)号：US20050090677A1
公开(公告)日：2005-04-28
申请号：US10491911
申请日：2002-10-04
申请人： Michael Bartsch , Robert Baumann , Dagmar Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel , Ferenc Molnar
发明人： Michael Bartsch , Robert Baumann , Dagmar Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel , Ferenc Molnar
IPC分类号： B01J31/22 , B01J31/18 , C07B61/00 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07 , C07F9/46 , C07F15/04 , C07F9/02
CPC分类号： C07F9/46 , B01J31/1875 , B01J2231/323 , B01J2231/52 , B01J2531/847 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07
摘要： Phosphinites I of the formula 1, 2 or 3 where R1, R2, R4 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that at least one of the groups R1, R2, R4 is not H, R3 is H or methyl X is F, Cl or CF3 n is 0, 1 or 2 can be used as catalysts.
摘要翻译：式1,2或3的亚磷酸酯I，其中R 1，R 2，R 4各自独立地为氢，具有1至8个碳原子的烷基或亚烷基或具有1至8个碳原子的烷氧基，条件是基团R 1，R 2，R 4中的至少一个不是H，R 3是H或甲基X是F，Cl或CF 3 n是0,1或2可以被用作催化剂。

3. 发明授权

US07067685B2 Phosphonites, use thereof as ligand in transition metal complexes and method for production of nitriles 失效
标题翻译：亚膦酸酯，其用作过渡金属络合物中的配体以及腈的生产方法
公开(公告)号：US07067685B2
公开(公告)日：2006-06-27
申请号：US10491918
申请日：2002-10-04
申请人： Michael Bartsch , Robert Baumann , Dagmar Pascale Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel , Ferenc Molnar
发明人： Michael Bartsch , Robert Baumann , Dagmar Pascale Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel , Ferenc Molnar
IPC分类号： C07F17/02
CPC分类号： C07F9/4875 , B01J31/1865 , B01J2231/323 , B01J2231/52 , B01J2531/847 , C07C253/10 , C07C255/04 , C07C255/07
摘要： The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF3 and n is 1 or 2
摘要翻译：本发明涉及式（1）或（2）的亚膦酸酯I，其中R 1，R 2，R 5，R 6，R 7，R 8，R 9独立地表示氢，具有1至8个碳原子的烷基或亚烷基或烷氧基具有1至8个碳原子; R3是H或甲基; R4是异丙基或叔丁基; X是F，Cl或CF 3，n是1或2

4. 发明授权

US07022866B2 Phosphonites 失效
标题翻译：亚膦酸盐
公开(公告)号：US07022866B2
公开(公告)日：2006-04-04
申请号：US10491964
申请日：2002-10-01
申请人： Michael Bartsch , Robert Baumann , Dagmar Pascale Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel , Ferenc Molnar
发明人： Michael Bartsch , Robert Baumann , Dagmar Pascale Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel , Ferenc Molnar
IPC分类号： C07F15/04 , C07F9/02 , B01J31/00 , C07C253/00
CPC分类号： C07F9/4875 , B01J31/1865 , B01J2231/323 , B01J2231/52 , B01J2531/847 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07
摘要： Phosphonites I of the formula 1 or 2 where R1, R2 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that R1 and R2 are not simultaneously H, R3 is H or methyl, R4 is t-butyl, R5, R6, R7, R8, R9 are each, independently of one another, H or an alkyl or alkylene group having from 1 to 8 carbon atoms.
摘要翻译：式1或2的亚膦酸酯I其中R 1，R 2各自独立地为氢，具有1至8个碳原子的烷基或亚烷基或具有1至8个碳原子的烷氧基，条件是 R1和R2不同时为H，R3为H或甲基，R4为叔丁基，R5，R6，R7，R8，R9各自独立地为H或具有1至8个碳原子的烷基或亚烷基原子

5. 发明申请

US20080071105A1 NI(0) -CONTAINING CATALYST SYSTEM 有权
标题翻译： NI（0）-CONTAINING催化剂体系
公开(公告)号：US20080071105A1
公开(公告)日：2008-03-20
申请号：US11860972
申请日：2007-09-25
申请人： Michael BARTSCH , Robert Baumann , Dagmar Kumsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel
发明人： Michael BARTSCH , Robert Baumann , Dagmar Kumsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel
IPC分类号： C07C253/00
CPC分类号： B01J31/185 , B01J23/755 , B01J31/1865 , B01J31/1875 , B01J2231/323 , B01J2531/847 , C07C253/10 , C07C255/07 , C07C255/04
摘要： A system comprising a) Ni(0) b) from 4 to 10 mol per mol of Ni(0) in a) of a compound (I) of the formula P(X1R1)(X2R2)(X3R3) (I) where X1, X2, X3 are each, independently of one another, oxygen or a single bond, R1, R2, R3 are, independently of one another, identical or different organic radicals and c) from 1 to 4 mol per mol of Ni(0) in a) of a compound (II) of the formula where X11, X12, X13 X21, X22, X23 are each, independently of one another, oxygen or a single bond, R11, R12 are identical or different, individual or bridged organic radicals, R21, R22 are identical or different, individual or bridged organic radicals and Y is a bridging group is suitable as catalyst for preparing mixtures of monoolefinic C5 mononitriles having nonconjugated C═C and C═N bonds by hydrocyanation of a 1,3-butadiene-containing hydrocarbon mixture and for preparing a dinitrile by hydrocyanation of a mixture of monoolefinic C5 mononitriles having nonconjugated C═C and C═N bonds.
摘要翻译：一种系统，其包含a）式（I）中的式（ⅰ）中的每一摩尔Ni（0）中的Ni（0）b）4至10摩尔的式（ⅰ）的线性式描述=“在线式” 结束=“铅”→P（X 1> 1 ）（X 2 2 R 2）（X （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中X <1> 2，R 3彼此独立地为相同或不同的有机基团，c）1至4摩尔每摩尔a）化合物中的Ni（0） II），其中X 11，X 12，X 13，X 21，X 22 X 23，X 23各自彼此独立地为氧或单键，R 11，R 12和R 12相同或相同，不同的单个或桥连的有机基团，R 21，R 22和R 22相同或不同，单个或桥接的有机基团和 Y是桥联基团，适合作为通过含1,3-丁二烯的烃混合物的氢氰化制备具有非共轭CC和CN键的单烯键式C 5 H 5单体的混合物的催化剂，并通过氢氰化制备二腈的具有非共轭CC和CN键的单烯烃C 5 H 5单体的混合物。

6. 发明授权

US07345006B2 Catalyst system containing Ni(0) for hydrocyanation 有权
标题翻译：含有Ni（0）氢化氰化催化体系
公开(公告)号：US07345006B2
公开(公告)日：2008-03-18
申请号：US10484169
申请日：2002-07-16
申请人： Michael Bartsch , Robert Baumann , Dagmar Pascale Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel
发明人： Michael Bartsch , Robert Baumann , Dagmar Pascale Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel
IPC分类号： B01J27/185
CPC分类号： B01J31/185 , B01J23/755 , B01J31/1865 , B01J31/1875 , B01J2231/323 , B01J2531/847 , C07C253/10 , C07C255/07 , C07C255/04
摘要： A system comprising a) Ni(0) b) from 4 to 10 mol per mol of Ni(0) in a) of a compound (I) of the formula P(X1R1)(X2R2)(X3R3) (I) where X1, X2, X3 are each, independently of one another, oxygen or a single bond, R1, R2, R3 are, independently of one another, identical or different organic radicals and c) from 1 to 4 mol per mol of Ni(0) in a) of a compound (II) of the formula where X11, X12, X13 X21, X22, X23 are each, independently of one another, oxygen or a single bond, R11, R12 are identical or different, individual or bridged organic radicals, R21, R22 are identical or different, individual or bridged organic radicals and Y is a bridging group is suitable as catalyst for preparing mixtures of monoolefinic C5 mononitriles having nonconjugated C═C and C═N bonds by hydrocyanation of a 1,3-butadiene-containing hydrocarbon mixture and for preparing a dinitrile by hydrocyanation of a mixture of monoolefinic C5 mononitriles having nonconjugated C═C and C═N bonds.
摘要翻译：一种系统，其包含a）式（I）中的式（ⅰ）中的每一摩尔Ni（0）中的Ni（0）b）4至10摩尔的式（ⅰ）的线性式描述=“在线式” 结束=“铅”→P（X 1> 1 ）（X 2 2 R 2）（X （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中X <1> 2，R 3彼此独立地为相同或不同的有机基团，c）1至4摩尔每摩尔a）化合物中的Ni（0） II），其中X 11，X 12，X 13，X 21，X 22 X 23，X 23各自彼此独立地为氧或单键，R 11，R 12和R 12相同或相同，不同的单个或桥接的有机基团，R 21，R 22和R 22相同或不同，单个或桥接的有机基团和Y 桥联基团适合作为通过含1,3-丁二烯的烃混合物的氢氰化制备具有非共轭CC和CN键的单烯烃C 5 H 5单体的混合物的催化剂，并通过氢化氰化反应制备二腈具有非共轭CC和CN键的单烯烃C 5 H 5单体的混合物。

7. 发明授权

US07777068B2 Ni(0) -containing catalyst system 有权
标题翻译：含Ni（0）的催化剂体系
公开(公告)号：US07777068B2
公开(公告)日：2010-08-17
申请号：US11860972
申请日：2007-09-25
申请人： Michael Bartsch , Robert Baumann , Dagmar Pascale Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel
发明人： Michael Bartsch , Robert Baumann , Dagmar Pascale Kunsmann-Keitel , Gerd Haderlein , Tim Jungkamp , Marco Altmayer , Wolfgang Siegel
IPC分类号： C07C255/01
CPC分类号： B01J31/185 , B01J23/755 , B01J31/1865 , B01J31/1875 , B01J2231/323 , B01J2531/847 , C07C253/10 , C07C255/07 , C07C255/04
摘要： A system comprising a) Ni(0) b) from 4 to 10 mol per mol of Ni(0) in a) of a compound (I) of the formula P(X1R1)(X2R2)(X3R3) (I) where X1, X2, X3 are each, independently of one another, oxygen or a single bond, R1, R2, R3 are, independently of one another, identical or different organic radicals and c) from 1 to 4 mol per mol of Ni(0) in a) of a compound (II) of the formula where X11, X12, X13 X21, X22, X23 are each, independently of one another, oxygen or a single bond, R11, R12 are identical or different, individual or bridged organic radicals, R21, R22 are identical or different, individual or bridged organic radicals and Y is a bridging group is suitable as catalyst for preparing mixtures of monoolefinic C5 mononitriles having nonconjugated C═C and C═N bonds by hydrocyanation of a 1,3-butadiene-containing hydrocarbon mixture and for preparing a dinitrile by hydrocyanation of a mixture of monoolefinic C5 mononitriles having nonconjugated C═C and C═N bonds.
摘要翻译：一种系统，其包含a）式（I）化合物（I）的式（I）化合物（I）中的每摩尔Ni（0）的每摩尔Ni（0）的Ni（0）b）4至10摩尔（X 2 R 2）（X 3 R 3），X2，X3各自独立地为氧或单键，R 1，R 2，R 3彼此独立地为相同或不同的有机基团，c）每摩尔Ni（0）为1〜4摩尔，其中X 11，X 12，X 13 X 21，X 22，X 23各自独立地为氧或单键，R 11，R 12相同或不同，单个或桥接的有机基团 R21，R22相同或不同，单个或桥接的有机基团和Y是桥连基团，适合作为具有非共轭C = C和C = N键的单烯烃C5单腈混合物的催化剂，通过1,3-丁二烯的氢氰化的含烃混合物，并通过氢化氰化得到具有非共轭C = C和C = N键的单烯烃C5单腈混合物来制备二腈。

8. 发明申请

US20060178537A1 Method for producing a-(3-arylthio)-acetophenones 失效
标题翻译： α-（3-芳硫基） - 苯乙酮的制备方法
公开(公告)号：US20060178537A1
公开(公告)日：2006-08-10
申请号：US10547342
申请日：2004-02-20
申请人： Marco Altmayer , Wolfgang Siegel
发明人： Marco Altmayer , Wolfgang Siegel
IPC分类号： C07C319/08
CPC分类号： C07C319/14 , C07C323/22
摘要： A process for preparing α-(3-arylthio)acetophenones of the general formula I where the substituents R1 and R2 are each independently C1-C6-alkyl or an optionally substituted phenyl or benzyl radical, which comprises A) reacting acetophenones of the general formula II where the substituent R1 is as defined above with sulfuryl chloride and subsequently hydrolyzing, and B) reacting the reaction mixture obtained in this way with a thiophenol of the general formula III where the substituent R2 is as defined above
摘要翻译：制备通式I的α-（3-芳硫基）苯乙酮的方法，其中取代基R 1和R 2各自独立地为C 1〜 C 1 -C 6 - 烷基或任选取代的苯基或苄基，其包括A）使通式II的苯乙酮其中取代基R 1如上所定义的上述与磺酰氯并随后水解，和B）使由此获得的反应混合物与通式III的苯硫酚反应，其中取代基R 2定义如上

9. 发明授权

US07385087B2 Method for producing a-(3-arylthio)-acetophenones 失效
标题翻译： α-（3-芳硫基） - 苯乙酮的制备方法
公开(公告)号：US07385087B2
公开(公告)日：2008-06-10
申请号：US10547342
申请日：2004-02-20
申请人： Marco Altmayer , Wolfgang Siegel
发明人： Marco Altmayer , Wolfgang Siegel
IPC分类号： C07C319/00 , C07C321/00 , C07C323/00 , C07C381/00
CPC分类号： C07C319/14 , C07C323/22
摘要： A process for preparing α-(3-arylthio)acetophenones of the general formula I where the substituents R1 and R2 are each independently C1-C6-alkyl or an optionally substituted phenyl or benzyl radical, which comprises A) reacting acetophenones of the general formula II where the substituent R1 is as defined above with sulfuryl chloride and subsequently hydrolyzing, and B) reacting the reaction mixture obtained in this way with a thiophenol of the general formula III where the substituent R2 is as defined above
摘要翻译：制备通式I的α-（3-芳硫基）苯乙酮的方法，其中取代基R 1和R 2各自独立地为C 1〜 C 1 -C 6 - 烷基或任选取代的苯基或苄基，其包括A）使通式II的苯乙酮其中取代基R 1如上所定义的上述与磺酰氯并随后水解，和B）使由此获得的反应混合物与通式III的苯硫酚反应，其中取代基R 2定义如上

10. 发明申请

US20070060776A1 Method for the production of alpha-(3-arylthio)-acetophenones 审中-公开
标题翻译： α-（3-芳硫基） - 苯乙酮的制备方法
公开(公告)号：US20070060776A1
公开(公告)日：2007-03-15
申请号：US10575539
申请日：2004-10-14
申请人： Marco Altmayer , Wolfgang Siegel
发明人： Marco Altmayer , Wolfgang Siegel
IPC分类号： C07C323/22
CPC分类号： C07C319/14 , C07C323/22
摘要： A process for preparing α-(3-arylthio)acetophenones of the general formula I in which the substituents R1 and R2 are each independently C1-C6-alkyl, SiR33 where the substituent R3 is a C1-C6-alkyl radical, or an optionally substituted phenyl or benzyl radical, which comprises reacting, in methanol acetophenones of the general formula II in which the substituent X is Cl or Br with a thiolate of the general formula III in which M is an alkali metal.
摘要翻译：制备通式I的α-（3-芳硫基）苯乙酮的方法，其中取代基R 1和R 2各自独立地为C 1〜其中取代基R 3是C 1 -C 6烷基，其中取代基R 3是C 1 -C 6烷基，其中包括使通式II的甲基苯乙酮（其中取代基X为Cl或Br）的甲苯和/或其取代的苯基或苄基其中M是碱金属的通式III的硫醇盐。

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