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1. 发明授权

US06441090B1 High gloss high impact monovinylidene aromatic polymers 失效
标题翻译：高光泽高冲击单亚乙烯基芳族聚合物
公开(公告)号：US06441090B1
公开(公告)日：2002-08-27
申请号：US09423027
申请日：1999-10-28
申请人： Mehmet Demirors , David Schrader , Steven M. Black
发明人： Mehmet Demirors , David Schrader , Steven M. Black
IPC分类号： C08F27902
CPC分类号： C08L53/00 , C08F279/02 , C08F287/00 , C08L51/04 , C08L55/02 , C08L2666/04 , C08L2666/02 , C08L2666/24
摘要： The present invention is a rubber modified monovinylidene aromatic polymer having a bimodal particle size distribution comprising: a) rubber particles of a star or branched low viscosity rubber having a volume average particle size of from 0.1 to 2&mgr;, and a cellular or core shell morphology or mixture thereof, and b) rubber particles of a star or branched low viscosity rubber, linear diene rubber or block copolymer rubber having a volume average particle size of from 0.5 to 10&mgr;, characterized in that the rubber particles of b) are more dense than the rubber particles of a), having a smaller occluded monovinylidene aromatic polymer content than the particles of a), wherein the particles of a) are from 50 to 99 weight percent of the total diene rubber content
摘要翻译：本发明是具有双峰粒度分布的橡胶改性单亚乙烯基芳族聚合物，其包含：a）体积平均粒度为0.1〜2μm的星形或支链低粘度橡胶的橡胶颗粒，以及细胞或核壳形态或 b）具有体积平均粒径为0.5〜10μm的星形或支链低粘度橡胶，线性二烯橡胶或嵌段共聚物橡胶的橡胶颗粒，其特征在于，b）的橡胶颗粒比 a）的橡胶颗粒，具有比a）的颗粒更小的闭塞的单亚乙烯基芳族聚合物含量，其中a）的颗粒占总二烯橡胶含量的50至99重量％

2. 发明授权

US06444752B1 Monovinylidene aromatic polymers with improved toughness and rigidity and a process for their preparation 失效
标题翻译：具有改善韧性和刚性的单亚乙烯基芳族聚合物及其制备方法
公开(公告)号：US06444752B1
公开(公告)日：2002-09-03
申请号：US09852198
申请日：2001-05-09
申请人： Mehmet Demirors , Dianne J. M. Maughon , Jose M. Rego , David Schrader
发明人： Mehmet Demirors , Dianne J. M. Maughon , Jose M. Rego , David Schrader
IPC分类号： C08F27902
CPC分类号： C08F279/02 , C08F257/02 , C08L51/003 , C08L51/04 , C08F212/08 , C08L2666/02
摘要： Disclosed are rubber-modified monovinylidene aromatic polymers with improved toughness and rigidity as well as a process for the preparation thereof. The polymer comprises: a) a monovinylidene aromatic polymer matrix, b) rubber particles dispersed therein, characterized in that the rubber particles are produced from a diene rubber having I) from 20 to 80 percent, based on the total weight of said rubber particles, of a high solution viscosity component having a viscosity value ranging from 110 to 500 centipoise and II) from 80 to 20 percent, based on the total weight of said rubber particles, of a low solution viscosity component having a viscosity value ranging from 1 to 100 centipoise, further characterized in that the ratio of solution viscosity of high solution viscosity component to the solution viscosity of low solution viscosity ranges from 1.1 to 500, wherein both components I and II have a 1,4 cis content of greater than 30 percent, and III) the rubber is grafted with monovinylidene aromatic polymer to the extent that there is at least 30 percent monovinylidene aromatic polymer present as grafts on the rubber.
摘要翻译：公开了具有改进的韧性和刚性的橡胶改性的单亚乙烯基芳族聚合物以及其制备方法。聚合物包括：a）单亚乙烯基芳族聚合物基体，b）分散在其中的橡胶颗粒，其特征在于，所述橡胶颗粒由二烯橡胶制成，所述二烯橡胶的I）为20-80重量％，基于所述橡胶颗粒的总重量，具有粘度值为110-500厘泊的高溶液粘度组分和II。基于所述橡胶颗粒总重量的80％至20％的粘度值范围为1至100的低溶液粘度组分其特征在于，高溶液粘度组分的溶液粘度与低溶液粘度的溶液粘度的比例为1.1至500，其中组分I和II均具有大于30％的1,4-顺式含量，以及 III）橡胶用单亚乙烯基芳族聚合物接枝至至少30％的单亚乙烯基芳族聚合物作为橡胶上的接枝物存在的程度。

3. 发明授权

US06323282B1 Bimodal rubbers and rubber modified high impact monovinylidene aromatic polymers produced therefrom 失效
标题翻译：由其制备的双峰橡胶和橡胶改性的高冲击单亚乙烯基芳族聚合物
公开(公告)号：US06323282B1
公开(公告)日：2001-11-27
申请号：US09553298
申请日：2000-04-20
申请人： Mehmet Demirors , David Schrader , Jose M. Rego
发明人： Mehmet Demirors , David Schrader , Jose M. Rego
IPC分类号： C08F25500
CPC分类号： C08F279/04 , C08F36/04 , C08F279/02 , C08F4/48 , C08F212/08
摘要： The present invention is related to a bimodal rubber characterized in that the bimodal rubber is a composition of linear, and branched rubber molecules, and has a broad, yet monomodal Mw distribution and rubber modified polymers produced therefrom.
摘要翻译：本发明涉及双峰橡胶，其特征在于双峰橡胶是直链和支链橡胶分子的组合物，并且具有宽但单峰的Mw分布和由其制备的橡胶改性聚合物。

4. 发明授权

US06545090B1 Monovinylidene aromatic polymers with improved properties and a process for their preparation 失效
标题翻译：具有改进性能的单亚乙烯基芳族聚合物及其制备方法
公开(公告)号：US06545090B1
公开(公告)日：2003-04-08
申请号：US09714306
申请日：2000-11-16
申请人： Mehmet Demirors , David Schrader , Jose M. Rego
发明人： Mehmet Demirors , David Schrader , Jose M. Rego
IPC分类号： C08L5104
CPC分类号： C08L51/04 , C08F279/02 , C08L25/06 , C08L2666/24 , C08L2666/02
摘要： The present invention is a rubber modified monovinylidene aromatic polymer comprising: a) a monovinylidene aromatic polymer matrix, b) rubber particles dispersed therein, characterized in that the rubber particles are produced from a diene rubber having I) a high molecular weight component and II) a low molecular weight component; the high molecular weight component having a weight average molecular weight at least two and one half times greater than the weight average molecular weight of the low molecular weight component, wherein both components I and II have a 1,4 cis content of greater than 70 percent and III) the rubber is grafted with monovinylidene aromatic polymer to the extent that there is at least 30 percent monovinylidene aromatic polymer present as grafts on the rubber.
摘要翻译：本发明是橡胶改性单亚乙烯基芳族聚合物，其包含：a）单亚乙烯基芳族聚合物基体，b）分散在其中的橡胶颗粒，其特征在于橡胶颗粒由具有I）高分子量组分和II）低分子量组分; 高分子量组分的重均分子量比低分子量组分的重均分子量至少大2.5倍，其中组分I和II都具有大于70％的1,4-顺式含量和III），橡胶用单亚乙烯基芳族聚合物接枝至至少30％单亚乙烯基芳族聚合物作为橡胶上的接枝物存在的程度。

5. 发明授权

US06350813B1 High impact monovinylidene aromatic polymers 失效
标题翻译：高冲击单亚乙烯基芳族聚合物
公开(公告)号：US06350813B1
公开(公告)日：2002-02-26
申请号：US09448818
申请日：1999-11-24
申请人： David Schrader , Steven M. Black
发明人： David Schrader , Steven M. Black
IPC分类号： C08F27902
CPC分类号： C08L25/06 , C08F257/02 , C08F279/02 , C08L9/00 , C08L51/003 , C08L51/04 , C08L2666/04 , C08L2666/02
摘要： The present invention refers to a rubber modified monovinylidene aromatic polymer composition wherein the rubber is in the form of discrete, dispersed rubber particles and comprises: a) from 75 to 25 weight percent based on the total weight of rubber, of a star branched diene rubber, having a cis 1,4 structure content of less than 75 percent; and b) from 25 to 75 weight percent, based on the total weight of rubber, of a linear diene rubber, having a cis 1,4 structure content of less than 50 percent.
摘要翻译：本发明涉及一种橡胶改性单亚乙烯基芳族聚合物组合物，其中橡胶是离散的，分散的橡胶颗粒的形式，包括：a）基于橡胶总重量的75至25重量％的星形支链二烯橡胶，顺式1,4结构含量小于75％; 和b）25至75重量％，基于橡胶的总重量，具有小于50％的顺式1,4结构含量的线性二烯橡胶。

6. 发明授权

US5428106A Rubber modified polystyrene 失效
标题翻译：橡胶改性聚苯乙烯
公开(公告)号：US5428106A
公开(公告)日：1995-06-27
申请号：US116163
申请日：1993-09-02
申请人： David Schrader , Mark E. Soderquist , Mark D. Heires
发明人： David Schrader , Mark E. Soderquist , Mark D. Heires
IPC分类号： C08L25/00 , C08F2/44 , C08F285/00 , C08F287/00 , C08L51/00 , C08L51/04
CPC分类号： C08F287/00
摘要： High impact polystyrene resins are provided having a surprisingly good combination of toughness and gloss characteristics. Such resins contain small (i.e., 0.1 to 0.4 micron) capsule morphology rubber particles in combination with relatively small (i.e., 0.25 to 1 micron) entanglement morphology rubber particles. It has been found that such resins are capable of providing Izod impact strength values in the range of 2.5 to 3.5 ft-lb/in (133.4 to 186.7 J/m) and higher at an overall volume average rubber size of less than 0.4 micron with corresponding gloss values in excess of 90 percent.
摘要翻译：提供了高抗冲聚苯乙烯树脂，其具有惊人的良好的韧性和光泽特性组合。这种树脂含有较小（即，0.1至0.4微米）的胶囊形态橡胶颗粒与较小（即0.25至1微米）的缠结形态橡胶颗粒的组合。已经发现，这样的树脂能够在小于0.4微米的总体积平均橡胶尺寸的2.5至3.5ft-lb / in（133.4至186.7J / m）范围内提供艾佐德冲击强度值和更高，相应的光泽值超过90％。

7. 发明申请

US20100298486A1 MONOVINYLIDENE AROMATIC POLYMERS CONTAINING NONFUNCTIONALIZED, NONMINERAL OIL 审中-公开
标题翻译：含有非官能化的非金属油的单甲氧基芳族聚合物
公开(公告)号：US20100298486A1
公开(公告)日：2010-11-25
申请号：US12439956
申请日：2007-09-11
申请人： Zenon Lysenko , Amaia Montoya-Goni , David Schrader , Alan K. Schrock , Gregory Chambard
发明人： Zenon Lysenko , Amaia Montoya-Goni , David Schrader , Alan K. Schrock , Gregory Chambard
IPC分类号： C08L51/04 , C08L25/02 , C08L53/00 , C08L55/02
CPC分类号： C08L53/02 , C08K5/103 , C08L51/04 , C08L55/02 , C08L2666/04 , C08L2666/24 , C08L2666/02
摘要： Monovinylidene aromatic polymers, e.g., general purpose polystyrene or high impact polystyrene, are plasticized with a nonfunctionalized, nonmineral oil, e.g., a vegetable oil such as canola oil, cottonseed oil or the like. The mixture of monovinylidene aromatic polymer and oil is typically and preferably free of any significant amount of functionalized nonmineral oil, and it typically contains at least 0.1 weight percent of the nonfunctionalized, nonmineral oil, alone or in combination with a mineral oil, based on the weight of the polymer. The nonmineral oil has an iodine value of less than 120, and a hydroxyl number of less than 20.
摘要翻译：单亚乙烯基芳族聚合物，例如通用聚苯乙烯或高抗冲聚苯乙烯，用非官能化的非矿物油（例如植物油如卡诺拉油，棉籽油等）增塑。单亚乙烯基芳族聚合物和油的混合物通常且优选不含任何显着量的官能化非矿物油，并且其通常包含至少0.1重量％的非官能化非矿物油，单独或与矿物油组合，基于聚合物的重量。非矿物油的碘值小于120，羟基数小于20。

8. 发明申请

US20050149547A1 Method and apparatus for creation and maintenance of database structure 有权
公开(公告)号：US20050149547A1
公开(公告)日：2005-07-07
申请号：US11068424
申请日：2005-02-28
申请人： Robert Wight , Josh Griffin , Timothy Tryzbiak , Anibal Santiago , Dale Couch , Edward Benson , David Crossmier , David Schrader
发明人： Robert Wight , Josh Griffin , Timothy Tryzbiak , Anibal Santiago , Dale Couch , Edward Benson , David Crossmier , David Schrader
IPC分类号： G06Q30/02 , G06Q30/06 , G06F17/00
CPC分类号： G06Q30/02 , G06Q30/0601 , G06Q30/0623 , Y10S707/99933 , Y10S707/99944 , Y10S707/99945
摘要： The invention provides a method for configuring a database system to store information regarding a plurality of items, the method comprising: establishing a database on a computer system; establishing within the database a first object corresponding to a first item of the plurality of items; generating within the first object at least one field; associating a field identifier with each the field; and storing at least a portion of the information within each the field; the database system configured to store information regarding a plurality of items, each item in the plurality of items having at least one item attribute, the database system comprising a computer having memory, a database stored in said memory, a first object in said database corresponding to one item of the plurality of items, said first object corresponding to the first item, at least one field in said first object, a field identifier associated with each said field, and information regarding said first item stored in said first object.

9. 发明授权

US5491195A Rubber modified polystyrene 失效
公开(公告)号：US5491195A
公开(公告)日：1996-02-13
申请号：US360868
申请日：1994-12-21
申请人： David Schrader , Mark E. Soderquist , Mark D. Heires
发明人： David Schrader , Mark E. Soderquist , Mark D. Heires
IPC分类号： C08L25/00 , C08F2/44 , C08F285/00 , C08F287/00 , C08L51/00 , C08L51/04
CPC分类号： C08F287/00
摘要： High impact polystyrene resins are provided having a surprisingly good combination of toughness and gloss characteristics. Such resins contain small (i.e., 0.1 to 0.4 micron) capsule morphology rubber particles in combination with relatively small (i.e., 0.25 to 1 micron) entanglement morphology rubber particles. It has been found that such resins are capable of providing Izod impact strength values in the range of 2.5 to 3.5 ft-lb/in (133.4 to 186.7 J/m) and higher at an overall volume average rubber size of less than 0.4 micron with corresponding gloss values in excess of 90 percent.

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