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    • 6. 发明授权
    • Condensation polymer containing copolymerized colorants derived from
indigo and articles produced therefrom
    • 含有衍生自靛蓝的共聚着色剂和由其制备的制品的缩合聚合物
    • US4808677A
    • 1989-02-28
    • US153635
    • 1988-02-08
    • Max A. WeaverClarence A. Coates, Jr.Wayne P. PruettSamuel D. Hilbert
    • Max A. WeaverClarence A. Coates, Jr.Wayne P. PruettSamuel D. Hilbert
    • C08G63/685C09B69/10C08G63/20
    • C09B69/109C08G63/685
    • Disclosed are colored compositions useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising condensation polymer having reacted therewith or copolymerized therein a coloring amount of the residue of a colorant compound having the formula; ##STR1## wherein R.sup.1 is ##STR2## carbonyl halide or an unsubstituted or substituted carbocyclic or hetrocyclic aryl radical;R.sup.2 is hydrogen or an unsubstituted or substituted alkyl or acyl radical;R.sup.3 is any of the substituents which R.sup.1 may represent; andA.sup.1 and A.sup.2 each is the residue of a fused benzene ring; whereinR.sup.4 is hydrogen, allyl or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; andR.sup.5 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; provided the colorant compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived.The colorant compound residues are present in the polymer chain and impart a red color to the polymer. The residues are nonextractable from the polymer and stable at the condition at which the polymers are prepared and processed.
    • 公开了可用于模制成诸如食品容器,饮料瓶,固化的结构塑料等制品的着色组合物,其包含与其反应或与其共聚的具有下式的着色剂化合物的着色量的缩聚物; 或者其中R 1为羰基卤或未取代或取代的碳环或杂环芳基的“IMAGE”或“IMAGE” R2是氢或未取代或取代的烷基或酰基; R3是R1可以表示的任何取代基; A1和A2各自为稠合苯环的残基; 其中R4是氢,烯丙基或未取代或取代的烷基,环烷基或芳基; 并且R 5是氢或未取代或取代的烷基,环烷基或芳基; 只要着色剂化合物具有至少一个与衍生缩合聚合物的单体之一反应的取代基。 着色剂化合物残基存在于聚合物链中并赋予聚合物红色。 残余物不可聚合,并且在制备和加工聚合物的条件下是稳定的。
    • 8. 发明授权
    • Condensation polymers containing methine ultraviolet radiation-absorbing
residues and shaped articles produced therefrom
    • 含有次甲基紫外线辐射吸收残基的冷凝聚合物和由其制备的成型制品
    • US4749773A
    • 1988-06-07
    • US78433
    • 1987-07-27
    • Max A. WeaverWayne P. PruettSamuel D. HilbertClarence A. Coates, Jr.
    • Max A. WeaverWayne P. PruettSamuel D. HilbertClarence A. Coates, Jr.
    • C08G63/44C08G63/54C08G63/685C08G64/04C08G64/12C08G63/76C08G69/44
    • C08G64/12C07C255/00C07C317/00C08G63/54C08G63/6858C08G64/045
    • A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding grade linear or unsaturated polyester or polycarbonate having reacted or copolymerized therein a total of from 100 to about 800 ppm, of the residue of one or a mixture of methine reactants of the formula ##STR1## wherein R.sup.1 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical;A.sup.1 is an unsubstituted or substituted phenylene radical;A.sup.2 is an unsubstituted or substituted 1,4-phenylene radical;R.sup.2 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical;R.sup.3 is cyano or ##STR2## and R.sup.4 is one of the substituents which R.sup.3 can represent or an unsubstituted or substituted carbamoyl, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, aryl or aromatic heterocyclic radicals.The methine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.
    • 可用于模制成诸如食品容器,软饮料瓶,固化的结构塑料等的制品的组合物,其包含在其中反应或共聚合总计为100至约800ppm的残余物的成型级线性或不饱和聚酯或聚碳酸酯 其中R 1是氢或未取代或取代的烷基,链烯基,环烷基或芳基的一种或者下式的次甲基化合物的混合物: A1是未取代或取代的亚苯基; A2是未取代或取代的1,4-亚苯基; R2是氢或未取代或取代的烷基,环烷基或芳基; R 3是氰基或R 4是R 3可以代表的取代基之一或未取代或取代的氨基甲酰基,烷酰基,芳酰基,烷基磺酰基,芳基磺酰基,芳基或芳族杂环基。 次甲基残基作为聚合物链的组成部分存在于聚合物中,并吸收约250至约390nm范围内的紫外线辐射。 残余物不能从聚合物中萃取,并且在制备和加工聚合物的条件下是稳定的。