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    • 3. 发明申请
    • NOVEL SHEAR-RESISTANT POLYMER SYSTEMS, PRODUCTION THEREOF, AND ALSO USE THEREOF AS THICKENERS
    • 新型耐磨聚合物系统,其生产,并且还作为更大的使用者
    • US20140350205A1
    • 2014-11-27
    • US14115539
    • 2012-05-02
    • Alexander LerchManfred SchadeAlexander BurkhartHelmut Ritter
    • Alexander LerchManfred SchadeAlexander BurkhartHelmut Ritter
    • C08F220/58
    • C08F220/58A61K8/8158A61K9/0014A61K2800/10A61K2800/48A61Q19/00C04B24/163C04B24/2652C04B28/04C04B2103/22C04B2103/44C04B2111/00672C08F220/36C08F220/38C08F2220/387C08F2220/585C08F2500/19C09K3/00C09K8/24C08F222/1006C04B14/06C04B24/383
    • The present invention relates to thickener polymers which comprise the following structural elements 1-3: a) as structural feature 1 at least one betainic monomer unit according to the formula below with a proportion by weight of from 0.1 to 99.9% by weight, based on the copolymer in which the mutually independent definitions are as follows: m=integer≧1; R1═H, C1-3 alkyl, —COOH; R2═H, C1-3 alkyl; R3=n- or isoalkylene of the formula —(CxH2x)—, in which x is an integer from 1 to 30; R4=—H, cycloalkyl, n- or isoalkyl, aryl; R5=n- or isoalkylene of the formula —(CyH2y)—, in which y is an integer from 1 to 30; A=—S—, —O—, —NR2, in which R2═H, C1-3 alkyl; b) as structural feature 2 at least one anionically charged monomer unit according to the following formula with a proportion by weight of from 0.1 to 99.9% by weight, based on the copolymer in which the mutually independent definitions are: l=integer≧1; R1═H, C1-3 alkyl, —COOH; R2═H, C1-3 alkyl; R6=—OH, —OOH, —SH, —(CxH2x)—COOH, —(CxH2x)—SO3H, —N (R2)—(CxH2x)—SO3H, in which —(CxH2x)—=n- or isoalkylene and x is an integer from 1 to 30; c) optionally as structural feature 3 one or more non-ionic comonomer units with a proportion by weight of from 0 to 50% by weight, based on the copolymer. When compared with the prior art, the thickener polymers have increased shear resistance in aqueous formulations.
    • 本发明涉及包含以下结构单元1-3的增稠剂聚合物:a)作为结构特征1,根据下式的至少一种甜菜碱单体单元,其重量比为0.1至99.9重量%,基于 其中相互独立定义的共聚物如下:m =整数≧1; R1 = H,C1-3烷基,-COOH; R2 = H,C1-3烷基; R3 =式 - (CxH2x) - 的n-或异亚烷基,其中x为1至30的整数; R4 = -H,环烷基,正或异烷基,芳基; R5 =式 - (CyH2y) - 的n-或异亚烷基,其中y为1至30的整数; A = -S-,-O-,-NR2,其中R2 = H,C1-3烷基; b)结构特征2至少一个根据下式的阴离子带电单体单元,其重量比为0.1至99.9重量%,基于相互独立定义的共聚物:l =整数≥1; R1 = H,C1-3烷基,-COOH; R2 = H,C1-3烷基; R6 = -OH,-OOH,-SH, - (CxH2x)-COOH, - (CxH2x)-SO3H,-N(R2) - (CxH2x)-SO3H,其中 - (CxH2x) - = x是1至30的整数; c)任选地作为结构特征3一种或多种基于共聚物的重量比为0至50重量%的非离子共聚单体单元。 当与现有技术相比时,增稠剂聚合物在水性配方中具有增加的抗剪切性。
    • 4. 发明授权
    • Use of comb copolymers based on acryloyldimethyltaurine acid in cosmetic, pharmaceutical and dermatological products
    • 在化妆品,药​​物和皮肤病学产品中使用基于丙烯酰基二甲基牛磺酸的梳状共聚物
    • US07279154B2
    • 2007-10-09
    • US10433203
    • 2001-11-28
    • Matthias LöfflerRoman MorschhäuserManfred Schade
    • Matthias LöfflerRoman MorschhäuserManfred Schade
    • C08F265/04C08F291/00A61K8/81
    • C08F291/00A61K8/8158A61K8/8182A61K8/86A61K2800/54A61Q5/006A61Q5/02A61Q5/06A61Q5/12A61Q19/00A61Q19/004A61Q19/10C08F265/04C08F271/02C08L51/003Y10S514/937C08L2666/02
    • The invention relates to uses of comb polymers of acryloyldimethyltaurine and/or acryloyldimethyltaurates in cosmetic, pharmaceutical and dermatological applications as thickeners, dispersing agents, suspending agents, emulsifiers, stabilizers, solubilizers, conditioning agents, consistency-giving agents, lubricants, bonding agents and/or conditioners. The comb polymers of the present invention comprise at least one copolymer. The copolymer is obtained by free-radical copolymerization of A) acryloyldimethyltaurine and/or acryloyldimethyltaurates, and B) optionally, one or more further olefinically unsaturated, noncationic comonomers, C) optionally, one or more olefinically unsaturated, cationic comonomers, D) optionally, one or more silicon-containing component(s), E) optionally, one or more fluorine-containing component(s), F) optionally, one or more macromonomers, G) optionally, the copolymerization taking place in the presence of at least one polymeric additive, H) with the proviso that component A) is copolymerized with at least one component selected from one of the groups D) to G).
    • 本发明涉及在化妆品,药​​物和皮肤病学应用中丙烯酰基二甲基牛磺酸和/或丙烯酰基二甲基牛磺酸盐的梳状聚合物用作增稠剂,分散剂,悬浮剂,乳化剂,稳定剂,增溶剂,调理剂,稠度赋予剂,润滑剂,粘合剂和/ 或调理剂。 本发明的梳状聚合物包含至少一种共聚物。 共聚物通过A)丙烯酰基二甲基牛磺酸和/或丙烯酰基二甲基牛磺酸酯的自由基共聚得到,和B)任选的一种或多种其它烯属不饱和非阳离子共聚单体,C)任选的一种或多种烯属不饱和阳离子共聚单体,D) 一种或多种含硅组分,E)任选的一种或多种含氟组分,F)任选的一种或多种大分子单体,G)任选地,所述共聚发生在存在至少一种 聚合物添加剂,H),条件是组分A)与选自D)至G)中的一种组分的至少一种共聚合。