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    • 3. 发明授权
    • Porous film material comprising at least one carbonaceous semimetal oxide phase, and use thereof as a separator material for electrochemical cells
    • 包含至少一种碳质半金属氧化物相的多孔膜材料及其作为电化学电池用隔板材料的用途
    • US08603681B2
    • 2013-12-10
    • US12824656
    • 2010-06-28
    • Nicole HildebrandtArno LangeKlaus LeitnerPhillip HanefeldClaudia Staudt
    • Nicole HildebrandtArno LangeKlaus LeitnerPhillip HanefeldClaudia Staudt
    • H01M2/16B23B3/26C08J9/26C08G77/00C08F6/00
    • H01M2/166H01M2/1646H01M10/0525Y10T428/249979
    • The present invention relates to a novel porous film material which comprises at least one carbonaceous semimetal oxide phase, and to a process for production thereof. The invention also relates to the use of these porous film materials as a separator layer or for production of such separator layers in electrochemical cells, particularly in lithium cells and especially in lithium secondary cells.The inventive porous film material comprises: a) at least one carbonaceous (semi)metal oxide phase A of silicon, of aluminum, of titanium or of zirconium, which has hydrocarbon groups bonded covalently to the (semi)metal of said (semi)metal oxide phase A; b) optionally one or more organic polymer phases B, said carbonaceous (semi)metal oxide phase A forming essentially continuous phase domains in which the pore phase present in the film material and the optionally present organic polymer phase(s) B are intercalated, the mean distance between two phase boundaries of adjacent domains of identical phases being not more than 50 nm, preferably not more than 10 nm, particularly not more than 5 nm and especially not more than 2 nm.
    • 本发明涉及包含至少一种碳质半金属氧化物相的新型多孔膜材料及其生产方法。 本发明还涉及这些多孔膜材料作为隔离层或在电化学电池中,特别是在锂电池中,特别是在锂二次电池中制备这种隔离层的用途。 本发明的多孔膜材料包括:a)至少一种碳,铝,钛或锆的碳质(半)金属氧化物相A,其具有与所述(半)金属的(半)金属共价键合的烃基 氧化物相A; b)任选的一个或多个有机聚合物相B,所述碳质(半)金属氧化物相A形成基本上连续的相域,其中存在于膜材料中的孔相和任选存在的有机聚合物相B被插入, 相同相位的相邻畴的两相边界之间的平均距离不大于50nm,优选不大于10nm,特别是不大于5nm,特别是不大于2nm。
    • 4. 发明申请
    • POROUS FILM MATERIAL COMPRISING AT LEAST ONE CARBONACEOUS SEMIMETAL OXIDE PHASE, AND USE THEREOF AS A SEPARATOR MATERIAL FOR ELECTROCHEMICAL CELLS
    • 包含至少一个碳氧化物半氧化物相的多孔膜材料,以及作为电化学细胞的分离材料的用途
    • US20110003189A1
    • 2011-01-06
    • US12824656
    • 2010-06-28
    • Nicole HildebrandtArno LangeKlaus LeitnerPhillip HanefeldClaudia Staudt
    • Nicole HildebrandtArno LangeKlaus LeitnerPhillip HanefeldClaudia Staudt
    • H01M2/14C08J9/00
    • H01M2/166H01M2/1646H01M10/0525Y10T428/249979
    • The present invention relates to a novel porous film material which comprises at least one carbonaceous semimetal oxide phase, and to a process for production thereof. The invention also relates to the use of these porous film materials as a separator layer or for production of such separator layers in electrochemical cells, particularly in lithium cells and especially in lithium secondary cells.The inventive porous film material comprises: a) at least one carbonaceous (semi)metal oxide phase A of silicon, of aluminum, of titanium or of zirconium, which has hydrocarbon groups bonded covalently to the (semi)metal of said (semi)metal oxide phase A; b) optionally one or more organic polymer phases B, said carbonaceous (semi)metal oxide phase A forming essentially continuous phase domains in which the pore phase present in the film material and the optionally present organic polymer phase(s) B are intercalated, the mean distance between two phase boundaries of adjacent domains of identical phases being not more than 50 nm, preferably not more than 10 nm, particularly not more than 5 nm and especially not more than 2 nm.
    • 本发明涉及包含至少一种碳质半金属氧化物相的新型多孔膜材料及其生产方法。 本发明还涉及这些多孔膜材料作为隔离层或在电化学电池中,特别是在锂电池中,特别是在锂二次电池中制备这种隔离层的用途。 本发明的多孔膜材料包括:a)至少一种碳,铝,钛或锆的碳质(半)金属氧化物相A,其具有与所述(半)金属的(半)金属共价键合的烃基 氧化物相A; b)任选的一个或多个有机聚合物相B,所述碳质(半)金属氧化物相A形成基本上连续的相域,其中存在于膜材料中的孔相和任选存在的有机聚合物相B被插入, 相同相位的相邻畴的两相边界之间的平均距离不大于50nm,优选不大于10nm,特别是不大于5nm,特别是不大于2nm。