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1. 发明授权

US5516932A Halogenated cinnamic acids and esters thereof, processes for the preparation thereof and halogenated aryldiazonium salts 失效
标题翻译：卤化肉桂酸及其酯，其制备方法和卤代芳基重氮盐
公开(公告)号：US5516932A
公开(公告)日：1996-05-14
申请号：US178089
申请日：1994-01-06
申请人： Matthias Beller , Hartmut Fischer , Laurent Weisse , Klaus Forstinger , Ralf Pfirmann , Heinz Strutz
发明人： Matthias Beller , Hartmut Fischer , Laurent Weisse , Klaus Forstinger , Ralf Pfirmann , Heinz Strutz
IPC分类号： B01J23/44 , C07B61/00 , C07C57/60 , C07C67/333 , C07C67/343 , C07C69/65 , C07C245/20 , C07C69/76
CPC分类号： C07C245/20 , C07C57/60 , C07C67/343 , C07C69/65
摘要： The present invention relates to compounds of the formula ##STR1## in which R.sup.1 and R.sup.2 are identical or different and are hydrogen or an alkyl radical having 1 to 18 carbon atoms and optionally containing oxygen, nitrogen or halogen, the radicals X, Y and Z are identical and are a fluorine, bromine or iodine atom or if two of the radicals X, Y or Z are identical or all of the radicals X, Y, Z are different from each other, X, Y and Z are a fluorine, chlorine, bromine or iodine atom. The invention further relates to a process for the preparation of the compounds, by reacting an aryldiazonium salt of the formula ##STR2## in which the radicals X, Y and Z are identical and are a fluorine, bromine or iodine atom or, if two of the radicals X, Y and Z are identical or all of the radicals X, Y, Z are different from each other, X, Y and Z are a fluorine, chlorine, bromine or iodine atom and A.sup.(-) is an anion of an acid having a pK.sub.a
摘要翻译：本发明涉及式（I）的化合物，其中R 1和R 2相同或不同并且是氢或具有1至18个碳原子并且任选地含有氧，氮或卤素的烷基，基团X， Y和Z相同并且是氟，溴或碘原子，或者如果基团X，Y或Z中的两个相同或基团X，Y，Z的全部彼此不同，则X，Y和Z是氟，氯，溴或碘原子。本发明还涉及通过使基团X，Y和Z相同且为氟，溴或碘原子的式（II）的芳基重氮盐与式如果基团X，Y和Z中的两个相同或全部基团X，Y，Z彼此不同，X，Y和Z是氟，氯，溴或碘原子，并且A（ - ）是具有pKa <7的酸的阴离子与式（III）的化合物反应，其中R 1和R 2相同或不同，并且是氢或具有1至18个碳原子的烷基，并且任选地含有氧，氮或卤素，在含钯催化剂的存在下，如果合适，加入碱，和式（II）的芳基重氮盐。

2. 发明授权

US5675034A Process for preparing 2-(p-fluorophenyl)-2 methyl-propionic acid and 3-(p-fluorophenyl)-2-methylpropionic acid derivatives 失效
标题翻译：制备2-（对氟苯基）-2甲基 - 丙酸和3-（对氟苯基）-2-甲基丙酸衍生物的方法
公开(公告)号：US5675034A
公开(公告)日：1997-10-07
申请号：US581757
申请日：1996-01-02
申请人： Matthias Beller , Hartmut Fischer , Heinz Strutz
发明人： Matthias Beller , Hartmut Fischer , Heinz Strutz
IPC分类号： B01J31/16 , C07B61/00 , C07C67/303 , C07C67/343 , C07C67/347 , C07C69/65 , C07C69/76
CPC分类号： C07C69/65 , C07C67/303 , C07C67/343
摘要： Process for preparing 3-(p-fluorophenyl)-2-methylpropionic acid and derivatives thereof of the formula (I), ##STR1## in which R is a hydroxy group, a linear or branched (C.sub.1 -C.sub.8)-alkoxy group, an aryloxygroup, an amino group or a (C.sub.1 -C.sub.8)-alkylamino group or a (C.sub.1 -C.sub.8)-dialkylamino group, by a) converting p-fluoroaniline into the p-fluorophenyldiazonium salt of the formula (II) ##STR2## in which X is the equivalent of an anion of an organic or inorganic acid having a pKa value of less than 7, b) reacting the diazonium salt of the formula (II) with a methacrylic acid derivative of the formula (III) ##STR3## in which R is as defined above in the presence of a palladium catalyst, if desired in the presence of a base and/or a solvent, to give the compounds of the formulae (IV) and (V) in which R is as defined above, ##STR4## and c) hydrogenating the resulting compounds of the formulae (IV) and (V) in the presence of a palladium catalyst with hydrogen.
摘要翻译：制备式（I）的3-（对氟苯基）-2-甲基丙酸及其衍生物的方法，其中R是羟基，直链或支链（C1-C8） - 烷氧基基团，芳氧基，氨基或（C1-C8） - 烷基氨基或（C1-C8） - 二烷基氨基，通过a）将对氟苯胺转化为式（II）的对氟苯基重氮盐

3. 发明授权

US5360924A Process for preparing aromatic olefins 失效
标题翻译：芳烃烯烃的制备方法
公开(公告)号：US5360924A
公开(公告)日：1994-11-01
申请号：US177945
申请日：1994-01-06
申请人： Matthias Beller , Hartmut Fischer , Heinz Strutz
发明人： Matthias Beller , Hartmut Fischer , Heinz Strutz
IPC分类号： B01J23/44 , C07B37/04 , C07B61/00 , C07C37/11 , C07C39/19 , C07C47/542 , C07C47/55 , C07C67/343 , C07C69/76 , C07C69/86 , C07C69/92 , C07C201/12 , C07C205/06 , C07C233/05 , C07C233/11 , C07C233/20 , C07C235/34 , C07C237/06 , C07C253/30 , C07C255/32 , C07C255/50 , C07C255/51 , C07C255/54 , C07C255/55 , C07C255/57 , C07C255/58
CPC分类号： C07C67/343
摘要： Process for preparing aromatic olefins of the formula (1) ##STR1## in which R.sup.1 -R.sup.3 are hydrogen, alkyl (C.sub.1 -C.sub.8) , alkoxy-(C.sub.1 -C.sub.5), phenyl, fluorine, chlorine, bromine, --OH, --NO.sub.2, --CN, --CHO, --COalkyl(C.sub.1 -C.sub.4) , --COphenyl, --COOalkyl (C.sub.1 -C.sub.4) , --OCOalkyl(C.sub.1 -C.sub.4), --NHCOalkyl(C.sub.1 -C.sub.4) , --CF.sub.3, --NH.sub.2, --NH--alkyl(C.sub.1 -C.sub.4) or --N(alkyl(C.sub.1 -C.sub.4)).sub.2 and R.sup.4 is hydrogen, alkyl(C.sub.1 -C.sub.8), phenyl, fluorine, chlorine, bromine, --OH, --NO.sub.2, --CN, --CHO or --OCOalkyl (C.sub.1 -C.sub.4) , and X is, inter alia, alkenyl(C.sub.2 -C.sub.12) or cycloalkenyl(C.sub.4 -C.sub.8) or the group ##STR2## in which R.sup.5 and R.sup.6 are, independently of one another, hydrogen or methyl, and Y is --phenyl, --CN, --COOH, --COOalkyl(C.sub.1 -C.sub.12), --COOphenyl, ##STR3## --CON (phenyl).sub.2, --COalkyl(C.sub.1 -C.sub.12), --COphenyl, --Oalkyl(C.sub.1 -C.sub.12) , --Ophenyl or the radical ##STR4## in which R.sup.1 -R.sup.4 are as defined above, by reacting an aryldiazonium salt of the formula (2) ##STR5## in which R.sup.1 -R.sup.4 are as defined and Z is the equivalent of an anion of an acid having a pK.sub.a of less than 7, with an olefin of the formula (3)HX (3)
摘要翻译：制备式（1）的芳族烯烃的方法其中R1-R3是氢，烷基（C1-C8），烷氧基 - （C1-C5），苯基，氟，氯，溴，-OH ，-NO 2，-CN，-CHO，-CO烷基（C1-C4），-CO苯基，-COO烷基（C1-C4），-OCO烷基（C1-C4），-NHCO烷基（C1-C4），-NH-烷基（C1-C4）或-N（烷基（C1-C4））2，R4是氢，烷基（C1-C8），苯基，氟，氯，溴，-OH，-NO2，-CN ，-CHO或-OCO烷基（C1-C4），X特别是链烯基（C2-C12）或环烯基（C4-C8）或其中R5和R6彼此独立的基团氢或甲基，Y是 - 苯基，-CN，-COOH，-COO烷基（C1-C12），-COO苯基，-CON（苯基）2，-CO-烷基（C1-C12）（2）的芳基重氮盐（其中R1-R4如上所定义）的基团（C1-C12）， - 苯基或其中R1-R4如上所定义的基团 Z是相当于pKa小于7的酸的阴离子与下式的烯烃（3）HX（3）

4. 发明授权

US5475176A Process for preparing vinyl-substituted aromatic compounds from arylamines 失效
标题翻译：从芳基胺制备乙烯基取代的芳族化合物的方法
公开(公告)号：US5475176A
公开(公告)日：1995-12-12
申请号：US222325
申请日：1994-04-04
申请人： Matthias Beller , Heinz Strutz
发明人： Matthias Beller , Heinz Strutz
IPC分类号： B01J23/44 , B01J31/28 , C07B37/04 , C07B61/00 , C07C2/86 , C07C15/44 , C07C15/58 , C07C15/60 , C07C41/30 , C07C1/00 , C07C2/66 , C07C15/46
CPC分类号： C07C41/30 , C07B37/04 , C07C2/86
摘要： The present invention relates to a process for preparing vinyl-substituted aromatic compounds of the formula (I) Ar--CH.dbd.CH.sub.2, where Ar is a phenyl group that may bear 1 to 5 substituents, naphthyl or anthryl or a naphthyl radical bearing 1 to 7 substituents or an anthryl radical bearing 1 to 8 substituents, or a mononuclear five-, six- or seven-membered heterocyclic aromatic group which contains an oxygen atom and/or one or two nitrogen atoms in the ring and may bear 1 to 5 substituents, wherein an arylamine of the formula (II) Ar--NH.sub.2, where Ar has the aforementioned meaning, is reacted in an organic acid with an organic nitrite of the formula (III) R--ONO, where R is an alkyl group having 1 to 18 carbon atoms, a phenyl radical which may bear 1 to 3 alkyl groups each having 1 to 4 carbon atoms, or is an alkylcarbonyl group having 2 to 5 carbon atoms, and ethylene in an organic solvent in the presence of a palladium(0) of palladium(II) compound at temperatures of 0.degree. to 35.degree. C.
摘要翻译：本发明涉及制备式（I）所示的乙烯基取代的芳族化合物的方法Ar-CH = CH 2，其中Ar是可以带有1至5个取代基的苯基，含有1至5个取代基的萘基或蒽基或萘基 7个取代基或含有1至8个取代基的蒽基，或在环中含有氧原子和/或一个或两个氮原子的单核五，六或七元杂环芳族基团，并且可以具有1至5个取代基其中式（II）Ar-NH 2的芳基胺（其中Ar具有上述含义）在有机酸与式（III）的有机亚硝酸酯R-ONO反应，其中R是具有1〜 18个碳原子，可具有1至3个具有1至4个碳原子的烷基或者是具有2至5个碳原子的烷基羰基的苯基，以及在有机溶剂中的钯（0）存在下的乙烯，的钯（II）化合物在0℃至35℃的温度下进行。

5. 发明授权

US08664444B2 Method for producing primary aliphatic amines from aldehydes 有权
标题翻译：从醛生产伯脂肪族胺的方法
公开(公告)号：US08664444B2
公开(公告)日：2014-03-04
申请号：US13817155
申请日：2011-08-18
申请人： Kurt Schalapski , Norman Nowotny , Matthias Eisenacher , Dirk Bermann , Thorsten Kreickmann , Peter Heymanns , Heinz Strutz
发明人： Kurt Schalapski , Norman Nowotny , Matthias Eisenacher , Dirk Bermann , Thorsten Kreickmann , Peter Heymanns , Heinz Strutz
IPC分类号： C07C209/26
CPC分类号： C07B43/04 , B01J21/08 , B01J23/40 , B01J23/70 , B01J23/866 , C07C209/26 , C07C211/07
摘要： A continuous process for producing primary aliphatic amines having 9 to 18 carbon atoms by reaction of corresponding aliphatic aldehydes with ammonia and hydrogen in the presence of a hydrogenation catalyst in the liquid phase, characterized in that the reaction is carried out solventlessly at a molar ratio of aliphatic aldehyde:ammonia of at least 1:30, at a temperature of 100 to 200° C. and at a pressure of 6 to 11 MPa.
摘要翻译：在液相中在氢化催化剂存在下，通过相应的脂族醛与氨和氢的反应制备具有9至18个碳原子的伯脂肪族胺的连续方法，其特征在于该反应以脂肪醛：氨至少1:30，温度为100〜200℃，压力为6〜11MPa。

6. 发明申请

US20130131391A1 Method for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the side-streams in trimethylolpropane production 有权
公开(公告)号：US20130131391A1
公开(公告)日：2013-05-23
申请号：US13810723
申请日：2011-07-28
申请人： Thorsten Kreickmann , Guido D. Frey , Norman Nowotny , Heinz Strutz
发明人： Thorsten Kreickmann , Guido D. Frey , Norman Nowotny , Heinz Strutz
IPC分类号： C07C29/74 , C07C41/34
CPC分类号： C07C29/74 , C07C29/10 , C07C29/80 , C07C29/90 , C07C41/34 , C07C41/42 , C07C41/44 , C07C31/22 , C07C43/132
摘要： The present invention relates to a process for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the high-boiling fractions and residues which are obtained in the distillative purification of trimethylolpropane, wherein an aqueous solution of these fractions and residues is catalytically hydrogenated in the presence of an acidic compound and, after removing solids, contacted both with basic and with acidic ion exchangers. A trimethylolpropane-enriched product stream can be distilled out of the aqueous eluate obtained, leaving ditrimethylolpropane as the distillation residue.

7. 发明申请

US20130116467A1 Process for Aftertreating Polyolesters 有权
标题翻译：后置聚酯的工艺
公开(公告)号：US20130116467A1
公开(公告)日：2013-05-09
申请号：US13805693
申请日：2011-06-29
申请人： Guido D. Frey , Heyko Jürgen Schultz , Heinz Strutz
发明人： Guido D. Frey , Heyko Jürgen Schultz , Heinz Strutz
IPC分类号： C07C67/48
CPC分类号： C07C67/60 , C07C69/28
摘要： A process for aftertreatment of polyol esters prepared by reacting polyols of the general formula H—(—O—[—CR1R2—]m—)o—OH in which R1 and R2 are each independently hydrogen, an alkyl radical having 1 to 5 carbon atoms, or a hydroxyalkyl radical having 1 to 5 carbon atoms, m is an integer of 1 to 10, o is an integer of 2 to 15, with linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms in the presence of an adsorbent and in the presence of metal compounds selected from the group of titanium compounds, zirconium compounds, tin compounds, zinc compounds, iron compounds and aluminium compounds as a catalyst while removing the water formed and subsequently treating with steam, characterized in that the polyol ester obtained is aftertreated first with an oxidizing or reducing compound and immediately thereafter with steam at a temperature of 150 to 250° C. and over a period of 0.5 to 5 hours.
摘要翻译：一种通过使通式为H - （ - O - [ - CR 1 R 2 - ] m - ）o-OH的多元醇反应制备的多元醇酯的方法，其中R 1和R 2各自独立地为氢，具有1至5个碳原子的烷基原子或具有1至5个碳原子的羟烷基，m是1至10的整数，o是2至15的整数，在吸附剂存在下具有3至20个碳原子的直链或支链脂肪族单羧酸在选择钛化合物，锆化合物，锡化合物，锌化合物，铁化合物和铝化合物作为催化剂的金属化合物的存在下，同时除去形成的水并随后用蒸汽处理，其特征在于获得的多元醇酯首先用氧化或还原化合物进行后处理，然后立即用蒸汽在150至250℃的温度和0.5至5小时的时间内进行处理。

8. 发明授权

US08357824B2 Process for preparing neopentyl glycol by cracking high boilers occurring in the production process 有权
标题翻译：通过裂解在生产过程中发生的高锅炉来制备新戊二醇的方法
公开(公告)号：US08357824B2
公开(公告)日：2013-01-22
申请号：US12737388
申请日：2009-06-25
申请人： Rolf-Peter Schulz , Horst Scholz , Thomas Hupperich , Peter Heymanns , Tonia Weber , Alexander Kaufmann , Kurt Schalapski , Heinz Strutz
发明人： Rolf-Peter Schulz , Horst Scholz , Thomas Hupperich , Peter Heymanns , Tonia Weber , Alexander Kaufmann , Kurt Schalapski , Heinz Strutz
IPC分类号： C07C31/18
CPC分类号： C07C29/132 , C07C29/149 , C07C31/20
摘要： The present invention relates to a process for obtaining neopentyl glycol by hydrogenating cracking of high-boilers occurring in the production process in the presence of copper-chromite catalysts. The hydrogenating cracking proceeds in the absence of solvent at a temperature of 140 to 220° C. and at pressures of 7 to 28 MPa.
摘要翻译：本发明涉及通过在亚铬酸铜催化剂的存在下，在生产过程中发生的高锅炉的氢化氢化获得新戊二醇的方法。在不存在溶剂的情况下，在140〜220℃的温度和7〜28MPa的压力下进行氢化裂化。

9. 发明授权

US06423856B1 Process for preparing ester plasticizers 有权
标题翻译：酯增塑剂的制备方法
公开(公告)号：US06423856B1
公开(公告)日：2002-07-23
申请号：US09644913
申请日：2000-08-24
申请人： Helmut Springer , Klaus-Dieter Merscher , Rudolf Heumuller , Klaus Schimmer , Heinz Strutz
发明人： Helmut Springer , Klaus-Dieter Merscher , Rudolf Heumuller , Klaus Schimmer , Heinz Strutz
IPC分类号： C07C5100
CPC分类号： C07C67/08 , B32B17/10605 , C07C69/28 , C07C69/75
摘要： The present invention relates to a process for preparing ester plasticizers from ethylene glycol or the dimers, trimers or tetramers of this compound and linear or branched aliphatic monocarboxylic acids having from 3 to 20 carbon atoms. The reaction is carried out in the presence of organic substances having a boiling point of
摘要翻译：本发明涉及一种由乙二醇或该化合物的二聚体，三聚体或四聚物和具有3-20个碳原子的直链或支链脂族一元羧酸制备酯增塑剂的方法。反应在沸点<112℃的有机物质，特别是环己烷存在下，作为除去反应水的共沸物（夹带剂）进行。

10. 发明授权

US5591893A Process for the preparation of polycarboxylic acids and derivatives thereof 失效
标题翻译：多羧酸及其衍生物的制备方法
公开(公告)号：US5591893A
公开(公告)日：1997-01-07
申请号：US146429
申请日：1993-10-27
申请人： J urgen Kulpe , Heinz Strutz
发明人： J urgen Kulpe , Heinz Strutz
IPC分类号： C07C51/34 , C07C55/22 , C07C55/24 , C07C61/06
CPC分类号： C07C51/34
摘要： The invention relates to a process for the preparation of polycarboxylic acids and derivatives thereof, the polycarboxylic acids prepared containing at least three carboxyl groups, comprising the steps(A) introducing one or more organic compounds, which contain nonaromatic carbon-carbon (C--C) double bonds, into water,(B) ozonolysis of the organic compounds in water by passing in an ozone-containing carrier gas,(C) addition of an aqueous hydrogen peroxide solution, to oxidatively work up the ozonolysis products produced in step (B), which comprises, in step (A), introducing the organic compound(s) into water having a pH of 7 or less than 7 and, in step (C), adding hydrogen peroxide in water without adding an organic solvent.
摘要翻译：本发明涉及一种制备多元羧酸及其衍生物的方法，所述多羧酸制备含有至少三个羧基，包括步骤（A）引入一种或多种含有非芳香碳 - 碳（CC）双键的有机化合物（B）通过使含有臭氧的载气中的有机化合物在水中的臭氧分解，（C）加入过氧化氢水溶液以氧化处理步骤（B）中产生的臭氧分解产物，其包括在步骤（A）中将有机化合物引入pH7或小于7的水中，并且在步骤（C）中，在水中加入过氧化氢而不添加有机溶剂。

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