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    • 1. 发明申请
    • ION-CONDUCTING CERAMIC APPARATUS, METHOD, FABRICATION, AND APPLICATIONS
    • 离子陶瓷装置,方法,制造和应用
    • US20110192727A1
    • 2011-08-11
    • US13083737
    • 2011-04-11
    • Matthew YatesDongxia Liu
    • Matthew YatesDongxia Liu
    • C25D5/50C30B15/14
    • C30B29/14H01M8/1004H01M8/1016H01M2008/1293
    • A c-axis-oriented HAP thin film synthesized by seeded growth on a palladium hydrogen membrane substrate. An exemplary synthetic process includes electrochemical seeding on the substrate, and secondary and tertiary hydrothermal treatments under conditions that favor growth along c-axes and a-axes in sequence. By adjusting corresponding synthetic conditions, an HAP this film can be grown to a controllable thickness with a dense coverage on the underlying substrate. The thin films have relatively high proton conductivity under hydrogen atmosphere and high temperature conditions. The c-axis oriented films may be integrated into fuel cells for application in the intermediate temperature range of 200-600° C. The electrochemical-hydrothermal deposition technique may be applied to create other oriented crystal materials having optimized properties, useful for separations and catalysis as well as electronic and electrochemical applications, electrochemical membrane reactors, and in chemical sensors.
    • 通过在钯氢膜底物上接种生长合成的c轴取向的HAP薄膜。 示例性的合成方法包括在基板上的电化学接种,以及在有利于沿c轴和a轴的顺序生长的条件下的二次和三次水热处理。 通过调整相应的合成条件,HAP可以将该膜生长到可控的厚度,并在下面的基底上具有致密的覆盖。 在氢气氛和高温条件下,薄膜具有较高的质子传导性。 c轴取向膜可以集成到燃料电池中,用于200-600℃的中间温度范围。电化学 - 水热沉积技术可用于产生具有优化性能的其他定向晶体材料,可用于分离和催化 以及电子和电化学应用,电化学膜反应器和化学传感器。
    • 2. 发明授权
    • Ion-/proton-conducting apparatus and method
    • 离子/质子传导装置和方法
    • US07943269B2
    • 2011-05-17
    • US12392150
    • 2009-02-25
    • Matthew YatesDongxia Liu
    • Matthew YatesDongxia Liu
    • H01M8/10C01B15/16
    • C30B29/14H01M8/1004H01M8/1016H01M2008/1293
    • A c-axis-oriented HAP thin film synthesized by seeded growth on a palladium hydrogen membrane substrate. An exemplary synthetic process includes electrochemical seeding on the substrate, and secondary and tertiary hydrothermal treatments under conditions that favor growth along c-axes and a-axes in sequence. By adjusting corresponding synthetic conditions, an HAP this film can be grown to a controllable thickness with a dense coverage on the underlying substrate. The thin films have relatively high proton conductivity under hydrogen atmosphere and high temperature conditions. The c-axis oriented films may be integrated into fuel cells for application in the intermediate temperature range of 200-600° C. The electrochemical-hydrothermal deposition technique may be applied to create other oriented crystal materials having optimized properties, useful for separations and catalysis as well as electronic and electrochemical applications, electrochemical membrane reactors, and in chemical sensors.
    • 通过在钯氢膜底物上接种生长合成的c轴取向的HAP薄膜。 示例性的合成方法包括在基板上的电化学接种,以及在有利于沿c轴和a轴的顺序生长的条件下的二次和三次水热处理。 通过调整相应的合成条件,HAP可以将该膜生长到可控的厚度,并在下面的基底上具有致密的覆盖。 在氢气氛和高温条件下,薄膜具有较高的质子传导性。 c轴取向膜可以集成到燃料电池中,用于200-600℃的中间温度范围。电化学 - 水热沉积技术可用于产生具有优化性能的其他定向晶体材料,可用于分离和催化 以及电子和电化学应用,电化学膜反应器和化学传感器。
    • 4. 发明授权
    • Ion-conducting ceramic apparatus, method, fabrication, and applications
    • 离子导电陶瓷装置,方法,制造和应用
    • US08129072B2
    • 2012-03-06
    • US13083737
    • 2011-04-11
    • Matthew YatesDongxia Liu
    • Matthew YatesDongxia Liu
    • H01M8/10C01B15/16B05D5/12
    • C30B29/14H01M8/1004H01M8/1016H01M2008/1293
    • A c-axis-oriented HAP thin film synthesized by seeded growth on a palladium hydrogen membrane substrate. An exemplary synthetic process includes electrochemical seeding on the substrate, and secondary and tertiary hydrothermal treatments under conditions that favor growth along c-axes and a-axes in sequence. By adjusting corresponding synthetic conditions, an HAP this film can be grown to a controllable thickness with a dense coverage on the underlying substrate. The thin films have relatively high proton conductivity under hydrogen atmosphere and high temperature conditions. The c-axis oriented films may be integrated into fuel cells for application in the intermediate temperature range of 200-600° C. The electrochemical-hydrothermal deposition technique may be applied to create other oriented crystal materials having optimized properties, useful for separations and catalysis as well as electronic and electrochemical applications, electrochemical membrane reactors, and in chemical sensors.
    • 通过在钯氢膜底物上接种生长合成的c轴取向的HAP薄膜。 示例性的合成方法包括在基板上的电化学接种,以及在有利于沿c轴和a轴的顺序生长的条件下的二次和三次水热处理。 通过调整相应的合成条件,HAP可以将该膜生长到可控的厚度,并在下面的基底上具有致密的覆盖。 在氢气氛和高温条件下,薄膜具有较高的质子传导性。 c轴取向膜可以集成到燃料电池中,用于200-600℃的中间温度范围。电化学 - 水热沉积技术可用于产生具有优化性能的其他定向晶体材料,可用于分离和催化 以及电子和电化学应用,电化学膜反应器和化学传感器。
    • 5. 发明授权
    • Ion/proton-conducting apparatus and method
    • 离子/质子传导装置和方法
    • US08916311B2
    • 2014-12-23
    • US13213566
    • 2011-08-19
    • Matthew YatesWei Xue
    • Matthew YatesWei Xue
    • H01M8/10B05D5/12C30B29/14H01M8/12
    • C30B29/14H01M8/1004H01M8/1016H01M2008/1293H01M2300/0068Y02E60/521Y02E60/525
    • A c-axis-oriented HAP thin film synthesized by seeded growth on a palladium hydrogen membrane substrate. An exemplary synthetic process includes electrochemical seeding on the substrate, and secondary and tertiary hydrothermal treatments under conditions that favor growth along c-axes and a-axes in sequence. By adjusting corresponding synthetic conditions, an HAP this film can be grown to a controllable thickness with a dense coverage on the underlying substrate. The thin films have relatively high proton conductivity under hydrogen atmosphere and high temperature conditions. The c-axis oriented films may be integrated into fuel cells for application in the intermediate temperature range of 200-600° C. The electrochemical-hydrothermal deposition technique may be applied to create other oriented crystal materials having optimized properties, useful for separations and catalysis as well as electronic and electrochemical applications, electrochemical membrane reactors, and in chemical sensors. Additional high-density and gas-tight HAP film compositions may be deposited using a two-step deposition method that includes an electrochemical deposition method followed by a hydrothermal deposition method. The two-step method uses a single hydrothermal deposition solution composition. The method may be used to deposit HAP films including but not limited to at least doped HAP films, and more particularly including carbonated HAP films. In addition, the high-density and gas-tight HAP films may be used in proton exchange membrane fuel cells.
    • 通过在钯氢膜底物上接种生长合成的c轴取向的HAP薄膜。 示例性的合成方法包括在基板上的电化学接种,以及在有利于沿c轴和a轴的顺序生长的条件下的二次和三次水热处理。 通过调整相应的合成条件,HAP可以将该膜生长到可控的厚度,并在下面的基底上具有致密的覆盖。 在氢气氛和高温条件下,薄膜具有较高的质子传导性。 c轴取向膜可以集成到燃料电池中,用于200-600℃的中间温度范围。电化学 - 水热沉积技术可用于产生具有优化性能的其他定向晶体材料,可用于分离和催化 以及电子和电化学应用,电化学膜反应器和化学传感器。 可以使用包括电化学沉积法和水热沉积法的两步沉积方法来沉积另外的高密度和气密HAP膜组合物。 两步法使用单一的热液沉积溶液组合物。 该方法可以用于沉积HAP膜,包括但不限于至少掺杂的HAP膜,更具体地包括碳酸化的HAP膜。 另外,高密度和气密的HAP膜可以用于质子交换膜燃料电池。
    • 7. 发明申请
    • ION/PROTON-CONDUCTING APPARATUS AND METHOD
    • 离子/导体装置和方法
    • US20120040269A1
    • 2012-02-16
    • US13213566
    • 2011-08-19
    • Matthew YatesWei Xue
    • Matthew YatesWei Xue
    • H01M8/10B05D5/12
    • C30B29/14H01M8/1004H01M8/1016H01M2008/1293H01M2300/0068Y02E60/521Y02E60/525
    • A c-axis-oriented HAP thin film synthesized by seeded growth on a palladium hydrogen membrane substrate. An exemplary synthetic process includes electrochemical seeding on the substrate, and secondary and tertiary hydrothermal treatments under conditions that favor growth along c-axes and a-axes in sequence. By adjusting corresponding synthetic conditions, an HAP this film can be grown to a controllable thickness with a dense coverage on the underlying substrate. The thin films have relatively high proton conductivity under hydrogen atmosphere and high temperature conditions. The c-axis oriented films may be integrated into fuel cells for application in the intermediate temperature range of 200-600° C. The electrochemical-hydrothermal deposition technique may be applied to create other oriented crystal materials having optimized properties, useful for separations and catalysis as well as electronic and electrochemical applications, electrochemical membrane reactors, and in chemical sensors. Additional high-density and gas-tight HAP film compositions may be deposited using a two-step deposition method that includes an electrochemical deposition method followed by a hydrothermal deposition method. The two-step method uses a single hydrothermal deposition solution composition. The method may be used to deposit HAP films including but not limited to at least doped HAP films, and more particularly including carbonated HAP films. In addition, the high-density and gas-tight HAP films may be used in proton exchange membrane fuel cells.
    • 通过在钯氢膜底物上接种生长合成的c轴取向的HAP薄膜。 示例性的合成方法包括在基板上的电化学接种,以及在有利于沿c轴和a轴的顺序生长的条件下的二次和三次水热处理。 通过调整相应的合成条件,HAP可以将该膜生长到可控的厚度,并在下面的基底上具有致密的覆盖。 在氢气氛和高温条件下,薄膜具有较高的质子传导性。 c轴取向膜可以集成到燃料电池中,用于200-600℃的中间温度范围。电化学 - 水热沉积技术可用于产生具有优化性能的其他定向晶体材料,可用于分离和催化 以及电子和电化学应用,电化学膜反应器和化学传感器。 可以使用包括电化学沉积法和水热沉积法的两步沉积方法来沉积另外的高密度和气密HAP膜组合物。 两步法使用单一的热液沉积溶液组合物。 该方法可以用于沉积HAP膜,包括但不限于至少掺杂的HAP膜,更具体地包括碳酸化的HAP膜。 另外,高密度和气密的HAP膜可以用于质子交换膜燃料电池。
    • 9. 发明申请
    • Ion-Conducting Ceramic Apparatus, Method, Fabrication, and Applications
    • 离子导电陶瓷装置,方法,制造和应用
    • US20100015494A1
    • 2010-01-21
    • US12392150
    • 2009-02-25
    • Matthew YatesDongxia Liu
    • Matthew YatesDongxia Liu
    • H01M8/10B05D5/12C23C28/00
    • C30B29/14H01M8/1004H01M8/1016H01M2008/1293
    • A c-axis-oriented HAP thin film synthesized by seeded growth on a palladium hydrogen membrane substrate. An exemplary synthetic process includes electrochemical seeding on the substrate, and secondary and tertiary hydrothermal treatments under conditions that favor growth along c-axes and a-axes in sequence. By adjusting corresponding synthetic conditions, an HAP this film can be grown to a controllable thickness with a dense coverage on the underlying substrate. The thin films have relatively high proton conductivity under hydrogen atmosphere and high temperature conditions. The c-axis oriented films may be integrated into fuel cells for application in the intermediate temperature range of 200-600° C. The electrochemical-hydrothermal deposition technique may be applied to create other oriented crystal materials having optimized properties, useful for separations and catalysis as well as electronic and electrochemical applications, electrochemical membrane reactors, and in chemical sensors.
    • 通过在钯氢膜底物上接种生长合成的c轴取向的HAP薄膜。 示例性的合成方法包括在基板上的电化学接种,以及在有利于沿c轴和a轴的顺序生长的条件下的二次和三次水热处理。 通过调整相应的合成条件,HAP可以将该膜生长到可控的厚度,并在下面的基底上具有致密的覆盖。 在氢气氛和高温条件下,薄膜具有较高的质子传导性。 c轴取向膜可以集成到燃料电池中,用于200-600℃的中间温度范围。电化学 - 水热沉积技术可用于产生具有优化性能的其他定向晶体材料,可用于分离和催化 以及电子和电化学应用,电化学膜反应器和化学传感器。