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1. 发明授权

US09834496B2 Reactivating propane dehydrogenation catalyst 有权
公开(公告)号：US09834496B2
公开(公告)日：2017-12-05
申请号：US14122201
申请日：2012-07-11
申请人： Matthew Pretz , Lin Luo , Susan Domke , Howard W. Clark , Richard A. Pierce , Andrzej M. Malek , Mark W. Stewart , Brien A. Stears , Albert E. Schweizer, Jr. , Guido Capone , Duncan P. Coffey , Isa K. Mbaraka
发明人： Matthew Pretz , Lin Luo , Susan Domke , Howard W. Clark , Richard A. Pierce , Andrzej M. Malek , Mark W. Stewart , Brien A. Stears , Albert E. Schweizer, Jr. , Guido Capone , Duncan P. Coffey , Isa K. Mbaraka
IPC分类号： C07C5/333 , B01J23/62 , B01J23/96 , B01J38/02 , B01J38/12 , B01J38/14 , C07C5/32
CPC分类号： C07C5/3337 , B01J23/62 , B01J23/96 , B01J38/02 , B01J38/12 , B01J38/14 , B01J2523/00 , B01J2523/828 , C07C5/325 , C07C2521/12 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/62 , C07C2527/224 , Y02P20/52 , Y02P20/584 , B01J2523/13 , B01J2523/31 , B01J2523/32 , B01J2523/41 , C07C11/04 , C07C11/06 , C07C11/08 , C07C11/10
摘要： Increase propane dehydrogenation activity of a partially deactivated dehydrogenation catalyst by heating the partially deactivated catalyst to a temperature of at least 660° C., conditioning the heated catalyst in an oxygen-containing atmosphere and, optionally, stripping molecular oxygen from the conditioned catalyst.

2. 发明申请

US20140200385A1 REACTIVATING PROPANE DEHYDROGENATION CATALYST 有权
标题翻译：反应脱氢催化剂
公开(公告)号：US20140200385A1
公开(公告)日：2014-07-17
申请号：US14122201
申请日：2012-07-11
申请人： Matthew T. Pretz , LIn Luo , Susan Domke , Howard W. Clark , Richard A. Pierce , Andrzej M. Malek , Mark W. Stewart , Brien A. Stears , Albert E. Schweizer, JR. , Guido Capore , Duncan P. Coffey , Isa K. Mbaraka
发明人： Matthew T. Pretz , LIn Luo , Susan Domke , Howard W. Clark , Richard A. Pierce , Andrzej M. Malek , Mark W. Stewart , Brien A. Stears , Albert E. Schweizer, JR. , Guido Capore , Duncan P. Coffey , Isa K. Mbaraka
IPC分类号： C07C5/333
CPC分类号： C07C5/3337 , B01J23/62 , B01J23/96 , B01J38/02 , B01J38/12 , B01J38/14 , B01J2523/00 , B01J2523/828 , C07C5/325 , C07C2521/12 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/62 , C07C2527/224 , Y02P20/52 , Y02P20/584 , B01J2523/13 , B01J2523/31 , B01J2523/32 , B01J2523/41 , C07C11/04 , C07C11/06 , C07C11/08 , C07C11/10
摘要： Increase propane dehydrogenation activity of a partially deactivated dehydrogenation catalyst by heating the partially deactivated catalyst to a temperature of at least 660° C, conditioning the heated catalyst in an oxygen-containing atmosphere and, optionally, stripping molecular oxygen from the conditioned catalyst.
摘要翻译：通过将部分失活的催化剂加热到至少660℃的温度，调节部分失活的脱氢催化剂的丙烷脱氢活性，调节加热的催化剂在含氧气氛中，以及任选地从调节的催化剂中汽提分子氧。

3. 发明授权

US08653317B2 Dehydrogenation process and catalyst 有权
标题翻译：脱氢方法和催化剂
公开(公告)号：US08653317B2
公开(公告)日：2014-02-18
申请号：US12717453
申请日：2010-03-04
申请人： Richard A. Pierce , Lin Luo , Michael M. Olken , Susan Domke , Howard W. Clark
发明人： Richard A. Pierce , Lin Luo , Michael M. Olken , Susan Domke , Howard W. Clark
IPC分类号： C07C5/333
CPC分类号： B01J23/62 , B01J23/96 , B01J35/1019 , C07C5/3337 , C07C2521/04 , C07C2523/04 , C07C2523/08 , C07C2523/42 , Y02P20/584 , C07C15/44 , C07C15/46 , C07C11/02
摘要： A supported catalyst and process for dehydrogenating a hydrocarbon, the catalyst comprising a first component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium, and compounds thereof; a second component selected from the group consisting of metals of Group 8 of the Periodic Table of the Elements and compounds thereof, and a support comprising alumina in the gamma crystalline form. The catalysts are especially active and efficient when employed in concurrent flow in a dehydrogenation reactor having an average contact time between the hydrocarbon and catalyst of from 0.5 to 10 seconds.
摘要翻译：一种负载催化剂和用于使烃脱氢的方法，所述催化剂包含选自锡，锗，铅，铟，镓，铊及其化合物的第一组分; 选自元素周期表第8族的金属和其化合物的第二组分和包含γ-晶体形式的氧化铝的载体。当在具有0.5至10秒的烃和催化剂之间的平均接触时间的脱氢反应器中同时流动时，催化剂是特别活泼和有效的。

4. 发明申请

US20100236985A1 DEHYDROGENATION PROCESS AND CATALYST 有权
标题翻译：脱氢工艺和催化剂
公开(公告)号：US20100236985A1
公开(公告)日：2010-09-23
申请号：US12717453
申请日：2010-03-04
申请人： Lin Luo , Susan Domke , Howard W. Clark , Richard A. Pierce , Michael M. Olken
发明人： Lin Luo , Susan Domke , Howard W. Clark , Richard A. Pierce , Michael M. Olken
IPC分类号： C10G35/06 , B01J23/58
CPC分类号： B01J23/62 , B01J23/96 , B01J35/1019 , C07C5/3337 , C07C2521/04 , C07C2523/04 , C07C2523/08 , C07C2523/42 , Y02P20/584 , C07C15/44 , C07C15/46 , C07C11/02
摘要： A supported catalyst and process for dehydrogenating a hydrocarbon, the catalyst comprising a first component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium, and compounds thereof; a second component selected from the group consisting of metals of Group 8 of the Periodic Table of the Elements and compounds thereof, and a support comprising alumina in the gamma crystalline form. The catalysts are especially active and efficient when employed in concurrent flow in a dehydrogenation reactor having an average contact time between the hydrocarbon and catalyst of from 0.5 to 10 seconds
摘要翻译：一种负载催化剂和用于使烃脱氢的方法，所述催化剂包含选自锡，锗，铅，铟，镓，铊及其化合物的第一组分; 选自元素周期表第8族的金属和其化合物的第二组分和包含γ-晶体形式的氧化铝的载体。当催化剂在烃和催化剂的平均接触时间为0.5至10秒的脱氢反应器中同时流动时使用时，催化剂是特别活泼和有效的

5. 发明授权

US07002052B2 Integrated process for producing an alkenyl-substituted aromatic compound 有权
标题翻译：用于制备烯基取代的芳族化合物的综合方法
公开(公告)号：US07002052B2
公开(公告)日：2006-02-21
申请号：US10181106
申请日：2001-01-24
申请人： Simon Hamper , William M. Castor , Richard A. Pierce
发明人： Simon Hamper , William M. Castor , Richard A. Pierce
IPC分类号： C07C15/46 , C07C11/04 , C07C5/333
CPC分类号： C07C15/46 , C07C2/66 , C07C5/3332 , C07C5/3337 , C07C6/126 , C07C15/44 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/10 , C07C2523/14 , C07C2523/26 , C07C2523/40 , C07C2523/42 , C07C2523/745 , C07C2523/78 , C07C2523/83 , C07C2529/08 , C07C2529/18 , C07C2529/22 , C07C2529/40 , C07C2529/50 , C07C2529/60 , C07C2529/70 , Y02P20/125 , Y02P20/127 , Y02P20/132 , C07C15/02 , C07C11/02 , C07C15/40
摘要： An integrated process of preparing a C2-5 alkenyl-substituted aromatic compound using a C6-12 aromatic compound and a C2-5 alkane as raw materials. The process involves feeding a C2-5 alkane, for example ethane, and a C2-5 alkyl-substituted aromatic compound, for example ethylbenzene, to a dehydrogenation reactor for concurrent dehydrogenation to a C2-5 alkene, for example ethylene, and a C2-5 alkenyl-substituted aromatic compound, for example stryrene; separating the dehydrogenation effluent to recover a gaseous stream containing alkene, hydrogen, and alkane, and to recover the aromatics with high efficiency; feeding the gas stream and a C6-12 aromatic compound to an alkylation reactor to obtain the corresponding C2-5 alkyl-substituted aromatic compound, which is recycled to the dehydrogenation reactor; subjecting the alkylation unit vent stream containing alkane and hydrogen to a separation step to recover alkane, which is recycled to the dehydrogenation unit; hydrogen, which is recovered at 99% chemical grade purity and energy.
摘要翻译：使用C 6-12芳族化合物和C 2-5烷基取代的芳族化合物制备C 2-5烯基取代的芳族化合物的整合方法，烷烃为原料。该方法包括将C 2-5烷烃（例如乙烷）和C 2-5烷基取代的芳族化合物（例如乙苯）加入到脱氢反应器中同时脱氢至C 5-12烯烃，例如乙烯和C 2-5烯基取代的芳族化合物，例如苯乙烯; 分离脱氢流出物以回收含有烯烃，氢气和烷烃的气流，并以高效率回收芳族化合物; 将气流和C 6-12芳族化合物加入到烷基化反应器中以获得相应的C 2-5烷基取代的芳族化合物，其被再循环到脱氢反应堆; 使含有烷烃和氢的烷基化单元排放流进行分离步骤以回收被再循环到脱氢单元的烷烃; 氢气以99％的化学级纯度和能量回收。

6. 发明授权

US4932656A Foot positioning training aid 失效
标题翻译：脚定位训练辅助
公开(公告)号：US4932656A
公开(公告)日：1990-06-12
申请号：US411222
申请日：1989-09-22
申请人： Richard A. Pierce
发明人： Richard A. Pierce
IPC分类号： A63B69/00 , A63B69/36
CPC分类号： A63B69/3667 , A63B69/0002 , A63B69/3661
摘要： A foot positioning training aid for training and instructing individuals in the proper positioning of their feet when engaged in various activities in which the position and movement of the feet are critical to proper execution of desired functions. The training aid includes a generally rectangular panel which can be supported on various supporting surfaces and is provided with a raised rear edge portion and raised side edge portions to position the feet but not form barriers to movement. The side edges of the training include progress numerical indicia and VELCRO alongside of the indicia together with positionable indicators on the VELCRO to provide indicators for initial position of the feet and also indicators to indicate movement or secondary positions of the feet for optimum performance of certain functions.
摘要翻译：一种足部定位训练辅助，用于训练和指导个人在进行各种活动时适当定位脚，其中脚的位置和运动对于正确执行所需功能至关重要。训练辅助装置包括可以支撑在各种支撑表面上的大致矩形的面板，并且设置有凸起的后边缘部分和凸起的侧边缘部分以定位脚部但不形成移动障碍物。培训的侧边包括进度数字标记和VELCRO以及标记之间的位置以及VELCRO上的可定位指标，以提供足部初始位置的指示，以及指示脚的运动或次要位置以最佳地执行某些功能的指标。

7. 发明授权

US4792360A Workable cement composition of low water content containing a hydroxyalkyl (meth)acrylate polymer 失效
标题翻译：含有（甲基）丙烯酸羟烷基酯聚合物的低含水量的可水泥组合物
公开(公告)号：US4792360A
公开(公告)日：1988-12-20
申请号：US67915
申请日：1987-06-30
申请人： Richard A. Pierce , Tipton T. Masterson , David A. Grilli
发明人： Richard A. Pierce , Tipton T. Masterson , David A. Grilli
IPC分类号： C04B24/16 , C04B24/26 , C04B28/02 , C04B24/00
CPC分类号： C04B24/2641 , C04B24/16 , C04B28/02 , C04B2111/00525
摘要： Cement compositions having better and longer lasting workability have been made by adding to said compositions a polymer or copolymer of a hydroxyalkyl(meth)acrylate, e.g. hydroxyethyl acrylate or methacrylate. Further improvement is achieved by adding a water reducer, e.g. sulfonated polystyrene, and an antifoam agent, e.g. a polyalkylenepolyol.
摘要翻译：通过向所述组合物中加入（甲基）丙烯酸羟烷基酯，聚（甲基）丙烯酸羟烷基酯等的聚合物或共聚物，已经制备了具有更好和更持久的可加工性的水泥组合物。丙烯酸羟乙酯或甲基丙烯酸羟乙酯。通过添加减水剂，例如，磺化聚苯乙烯和消泡剂，例如，聚亚烷基多元醇。

8. 发明授权

US4643839A Silicone reaction products and glycol compositions containing the products 失效
标题翻译：硅酮反应产物和含有该产品的二醇组合物
公开(公告)号：US4643839A
公开(公告)日：1987-02-17
申请号：US600933
申请日：1984-04-16
申请人： Richard A. Pierce , David A. Wilson
发明人： Richard A. Pierce , David A. Wilson
IPC分类号： C07F9/38 , C09K5/20 , C09K5/00 , C07F7/10
CPC分类号： C09K5/20 , C07F9/3808
摘要： The reaction product of phosphorous acid, formaldehyde, and monomeric or polymeric alkoxysilanes having one or more aminoalkylene groups are useful as gelation inhibitors for aqueous glycol solutions.
摘要翻译：具有一个或多个氨基亚烷基的亚磷酸，甲醛和单体或聚合烷氧基硅烷的反应产物可用作水性二醇溶液的凝胶抑制剂。

9. 发明授权

US4612134A Polyalkylhydrosiloxanes as inorganic silicate stabilizers 失效
标题翻译：聚烷基氢硅氧烷作为无机硅酸盐稳定剂
公开(公告)号：US4612134A
公开(公告)日：1986-09-16
申请号：US763572
申请日：1985-08-08
申请人： Richard A. Pierce , Robert T. Jernigan
发明人： Richard A. Pierce , Robert T. Jernigan
IPC分类号： C09K5/20 , C09K5/00
CPC分类号： C09K5/20
摘要： Polyalkylhydrosiloxanes that are soluble in glycol are used to stabilize antifreeze/coolant formulations that contain inorganic silicate corrosion inhibitors. The stabilizers have the following formulaMe.sub.3 Si--O--[Si(Me).sub.2 --O].sub.x --[SiHMe--O].sub.y --SiMe.sub.3where the ratio of x to y is from 0 to about 10.
摘要翻译：可溶于二醇的聚烷基氢硅氧烷用于稳定含有无机硅酸盐腐蚀抑制剂的防冻液/冷却剂配方。稳定剂具有以下分子式Me 3 Si-O- [Si（Me）2-O] x- [SiHMe-O] y-SiMe 3，其中x与y的比例为0至约10。

10. 发明授权

US4704415A High efficiency superplasticizer comprising a sulfonated copolymer of styrene and alpha-mestyrene for cement compositions 失效
标题翻译：包括苯乙烯和α-甲基苯乙烯的磺化共聚物用于水泥组合物的高效率增塑剂
公开(公告)号：US4704415A
公开(公告)日：1987-11-03
申请号：US873900
申请日：1986-06-13
申请人： Richard A. Pierce , Tipton T. Masterson
发明人： Richard A. Pierce , Tipton T. Masterson
IPC分类号： C04B24/22 , C04B28/04 , C04B7/02 , C04B7/35 , C08G75/24
CPC分类号： C04B24/22 , C04B28/04 , C04B2103/30 , Y02W30/92
摘要： Sulfonated copolymers of styrene alpha-methylstyrene are added to cement compositions to improve the workability and strength characteristics of the concrete, mortar or grout product derived therefrom.
摘要翻译：将苯乙烯α-甲基苯乙烯的磺化共聚物加入到水泥组合物中以改善由其衍生的混凝土，砂浆或水泥浆产品的可加工性和强度特性。

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