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1. 发明专利

JP2011140670A Polyolefin composition having variable density and method for manufacturing and using the same 有权
标题翻译：具有可变密度的聚烯烃组合物及其制造和使用方法
公开(公告)号：JP2011140670A
公开(公告)日：2011-07-21
申请号：JP2011095489
申请日：2011-04-21
申请人： Materia Inc , マテリアインコーポレイテッドMateria,Inc.
发明人： GIARDELLO MICHAEL A , CRUCE CHRISTOPHER J , HAAR CHRISTOPHER M , LASCH JONATHAN G , MACLEOD JESSIE G
IPC分类号： C08J5/00 , C08L65/00 , A63B53/04 , A63B53/12 , C08F4/06 , C08F4/80 , C08G61/08 , C08J9/32 , C08K3/00 , C08K5/00 , C08K5/13 , C08K7/02 , C08K7/22
CPC分类号： C08K5/13 , A63B53/04 , A63B53/0487 , A63B53/12 , A63B2053/0408 , A63B2209/00 , C08G61/08
摘要： PROBLEM TO BE SOLVED: To provide a new polyolefin composition having variable density and a method for manufacturing and using the same. SOLUTION: There is provided a composition comprising one or more density modulators dispersed in a polymer matrix, wherein the matrix is prepared by the metathesis of an olefin monomer using a ruthenium or osmium metal carbene catalyst. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供具有可变密度的新的聚烯烃组合物及其制造和使用方法。解决方案：提供了包含分散在聚合物基质中的一种或多种密度调节剂的组合物，其中基质通过使用钌或锇金属卡宾催化剂的烯烃单体的复分解来制备。版权所有（C）2011，JPO＆INPIT

2. 发明申请

WO2012026980A3 VARTM FLOW MODIFICATIONS FOR LOW VISCOSITY RESIN SYSTEMS 审中-公开
标题翻译：用于低粘度树脂体系的VARTM流动修饰
公开(公告)号：WO2012026980A3
公开(公告)日：2012-06-21
申请号：PCT/US2011001488
申请日：2011-08-23
申请人： MATERIA INC , CORRAL SERGIO , CRANE STEPHEN , STEPHEN ANTHONY R , CRUCE CHRISTOPHER J , FLORES EVERARDO GARCIA
发明人： CORRAL SERGIO , CRANE STEPHEN , STEPHEN ANTHONY R , CRUCE CHRISTOPHER J , FLORES EVERARDO GARCIA
IPC分类号： B29C70/44 , B29C70/48
CPC分类号： B29C70/021 , B29C70/443 , B29C70/546 , Y10T428/31924
摘要： A vacuum-assisted resin transfer molding (VARTM) method is disclosed, the method comprising: providing a vacuum-assisted resin transfer mold assembly comprising a mold having a first mold surface and a second mold surface arranged to enclose a laminate assembly within a space between the first and second mold surfaces when the laminate assembly is placed on the first mold surface; providing a laminate assembly comprising a laminate pre-form, a peel ply, and a resin distribution media pervious to the flow of a resin, the laminate pre-form having first and second surfaces, the first surface of the pre-form positioned to be in contact with the first mold surface, the peel ply positioned such that the second surface of the laminate pre-form is in contact with the peel ply, and the resin distribution media positioned to be contained within the first and second mold surfaces; positioning at least one resin flow control structure to modify the flow of resin within the resin distribution media; providing at least one inlet and at least one outlet in the laminate assembly such that the resin can be introduced into the assembly through the inlet; arranging and sealing the second mold surface to enclose the laminate assembly within the space between the first and second mold surfaces such that a vacuum can be pulled on the laminate assembly contained within the space between the first and second mold surfaces; applying a vacuum to the mold assembly; allowing the resin to flow into the laminate assembly through the at least one inlet such that the resin flows into the resin distribution media; allowing the resin to flow out of the laminate assembly through the at least one outlet; and allowing the resin to cure in the laminate assembly to form a laminate material. An article of manufacture made by said VARTM method.
摘要翻译：公开了一种真空辅助树脂传递模塑（VARTM）方法，该方法包括：提供一种真空辅助树脂转移模具组件，其包括具有第一模具表面和第二模具表面的模具，该模具布置成将层压组件包围在当层压组件放置在第一模具表面上时的第一和第二模具表面; 提供层压组件，其包括层压预成型件，剥离层和可透过树脂流动的树脂分配介质，所述层压预成型件具有第一和第二表面，预成型件的第一表面定位为与第一模具表面接触，剥离层定位成使得层压预成型件的第二表面与剥离层接触，并且树脂分配介质定位成容纳在第一和第二模具表面内; 定位至少一个树脂流量控制结构以改变树脂分布介质内的树脂流动; 在所述层叠组件中提供至少一个入口和至少一个出口，使得所述树脂可以通过所述入口被引入到所述组件中; 布置和密封第二模具表面以将层压体组件包围在第一和第二模具表面之间的空间内，使得可以在包含在第一和第二模具表面之间的空间内的层压组件上拉动真空; 向模具组件施加真空; 允许树脂通过至少一个入口流入层压组件，使得树脂流入树脂分布介质; 允许树脂通过至少一个出口流出层压组件; 并且允许树脂在层压组件中固化以形成层压材料。由VARTM方法制造的制品。

3. 发明申请

WO2012174502A3 ADHESION PROMOTERS AND GEL-MODIFIERS FOR OLEFIN METATHESIS COMPOSITIONS 审中-公开
标题翻译：粘合剂组合物的粘合促进剂和凝胶改性剂
公开(公告)号：WO2012174502A3
公开(公告)日：2013-03-07
申请号：PCT/US2012042850
申请日：2012-06-17
申请人： MATERIA INC , WANG LI-SHENG , STEPHEN ANTHONY R , BOOTHE PAUL W , SCHULZE TESSA , GIARDELLO MICHAEL A , TRIMMER MARK S , CRUCE CHRISTOPHER J , MOTAMEDI FARSHAD J , EDGECOMBE BRIAN
发明人： WANG LI-SHENG , STEPHEN ANTHONY R , BOOTHE PAUL W , SCHULZE TESSA , GIARDELLO MICHAEL A , TRIMMER MARK S , CRUCE CHRISTOPHER J , MOTAMEDI FARSHAD J , EDGECOMBE BRIAN
IPC分类号： C08L45/00 , C08F32/02 , C08K5/14 , C08K5/16 , C08L65/00
CPC分类号： C03C25/30 , C08F32/02 , C08G61/08 , C08G2261/3325 , C08G2261/418 , C08K5/0025 , C08K5/14 , C08K5/29 , C08K2201/014 , C08L65/00
摘要： This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials, pre-treating substrate materials to improve the adhesion of resin compositions to the substrate materials, and/or controlling gel formation of resin compositions. More particularly, the invention relates to compositions and methods for improving the adhesion of ring opening metathesis polymerization (ROMP) compositions to substrate materials using adhesion promoters containing isocyariate groups in a resin composition. The invention also relates to methods for improving the adhesion of resin compositions to substrate materials by pre-treating substrate materials with adhesion promoters containing isocyanate groups. The invention further relates to a method of providing a gel- modified ROMP composition, in which a hydroperoxide is added to a ROMP polymerizable resin composition in order to control gel formation of the polymerizing resin. An improved ROMP composition is further disclosed, comprising a cyclic olefin, a ROMP metathesis catalyst, an adhesion promoter, and an added hydroperoxide gel modifier. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.
摘要翻译：本发明涉及用于改善树脂组合物与基材的粘合性，预处理基材以提高树脂组合物与基材的粘合性和/或控制树脂组合物凝胶形成的组合物和方法。更具体地，本发明涉及使用在树脂组合物中含有异质基团的粘合促进剂来改善开环易位聚合（ROMP）组合物与基材的粘合性的组合物和方法。本发明还涉及通过用含有异氰酸酯基团的粘合促进剂预处理底物材料来改善树脂组合物对基材的粘附性的方法。本发明还涉及提供凝胶改性的ROMP组合物的方法，其中向ROMP可聚合树脂组合物中加入过氧化氢以控制聚合树脂的凝胶形成。进一步公开了改进的ROMP组合物，其包含环烯烃，ROMP复分解催化剂，粘合促进剂和加入的氢过氧化物凝胶改性剂。通过本发明的ROMP反应生产的聚合物产品可用于广泛的材料和复合材料应用。本发明可用于催化，有机合成，聚合物和材料的化学和制造领域。

4. 发明申请

WO2013040519A3 IMPROVED ELECTROLYTIC CELL COVERS COMPRISING A RESIN COMPOSITION POLYMERIZED WITH A GROUP 8 OLEFIN METATHESIS CATALYST 审中-公开
标题翻译：改进的包含与第8族烯烃甲基化催化剂聚合的树脂组合物的电解池盖
公开(公告)号：WO2013040519A3
公开(公告)日：2013-06-27
申请号：PCT/US2012055663
申请日：2012-09-14
申请人： MATERIA INC , GIARDELLO MICHAEL A , TRIMMER MARK S , CRUCE CHRISTOPHER J , STEPHEN ANTHONY R , TONER STUART A M , PAPPANO ALBERT E
发明人： GIARDELLO MICHAEL A , TRIMMER MARK S , CRUCE CHRISTOPHER J , STEPHEN ANTHONY R , TONER STUART A M , PAPPANO ALBERT E
IPC分类号： C25B9/00 , C08J5/00 , G12B9/04
CPC分类号： C25B9/00 , B29C39/003 , B29C67/246 , B29K2023/00 , B29K2023/38 , B29K2105/0014 , B29K2995/0029 , B29L2031/7146 , C08G61/02 , C08G2120/00 , C08G2261/3325 , C08G2261/418 , C08G2261/58 , C25B1/34
摘要： Articles of manufacture possessing corrosion resistance characteristics are described, in particular for use in the chlor-alkali and other industries. The articles are formed from a resin composition, e.g., a cyclic olefin composition, polymerized with a Group 8 olefin metathesis catalyst. In particular aspects, an electrolytic cell component, such as a cell cover for use in the electrolysis of brine, may be formed from the resin composition. Among other benefits, such articles provide improved corrosion resistance compared to articles molded from other resin compositions, such as Fiberglass reinforced polyesters and vinyl esters, and two-component dicyclopentadiene (DCPD) resins comprising molybdenum or tungsten pre-catalysts.
摘要翻译：描述了具有耐腐蚀特性的制品，特别是用于氯碱和其他工业。制品由与第8族烯烃复分解催化剂聚合的树脂组合物例如环烯烃组合物形成。在具体的方面，可以由树脂组合物形成电解池组件，例如用于电解盐水的电池盖。除了其它益处之外，与由其它树脂组合物例如玻璃纤维增强聚酯和乙烯基酯以及包含钼或钨预催化剂的双组分双环戊二烯（DCPD）树脂模制的制品相比，此类制品提供改进的耐腐蚀性。

5. 发明公开

EP3092204A4 METHOD AND COMPOSITION FOR IMPROVING ADHESION OF METATHESIS COMPOSITIONS TO SUBSTRATES 审中-实审
公开(公告)号：EP3092204A4
公开(公告)日：2017-12-20
申请号：EP15735525
申请日：2015-01-12
申请人： MATERIA INC
发明人： STEPHEN ANTHONY R , CRUCE CHRISTOPHER J , TRIMMER MARK S , GIARDELLO MICHAEL A
IPC分类号： C03C25/30 , C08G61/08 , C08J5/04 , C08J5/08 , C08J5/22 , C08J5/24 , C08K3/36 , C08K3/40 , C08K5/14 , C08K5/5419 , C08K5/5425 , C08K7/14 , C08K7/28 , C08L65/00
CPC分类号： C08G61/02 , B29B15/122 , B29K2309/08 , C03C17/328 , C03C25/30 , C08G61/08 , C08G2261/3325 , C08G2261/964 , C08J5/043 , C08J2323/20 , C08K3/36 , C08K3/40 , C08K5/14 , C08K5/5419 , C08K5/5425 , C08K7/14 , C08K7/28 , C08L65/00 , C09D165/00
摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter.

6. 发明公开

EP2970522A4 IN-MOLD COATING OF ROMP POLYMERS 审中-实审
标题翻译：模内涂层VON ROMP-POLYMEREN
公开(公告)号：EP2970522A4
公开(公告)日：2016-11-16
申请号：EP14762532
申请日：2014-03-14
申请人： MATERIA INC
发明人： STEPHEN ANTHONY R , CRUCE CHRISTOPHER J , TRIMMER MARK S , GIARDELLO MICHAEL A
IPC分类号： B29C37/00 , C08F4/80 , C08G61/08
CPC分类号： C08G61/08 , B29C37/0032 , B29C41/00 , B29C41/22 , B29K2075/00 , C08G2261/3325 , C08G2261/418 , C08K5/05 , C08K5/053 , C08K5/101 , C08L65/00 , Y10T428/31938

7. 发明公开

EP2961778A4 METAL CARBENE OLEFIN METATHESIS TWO CATALYST COMPOSITION 审中-实审
标题翻译：与两种催化剂金属CARBEN，烯烃复分解成分
公开(公告)号：EP2961778A4
公开(公告)日：2016-10-05
申请号：EP14757631
申请日：2014-02-27
申请人： MATERIA INC
发明人： STEPHEN ANTHONY R , CRUCE CHRISTOPHER J , GIARDELLO MICHAEL A
IPC分类号： C08F4/80 , C08F132/08 , C08G61/08 , C08K9/06 , C08L65/00
CPC分类号： C08F32/00 , C08F4/80 , C08F132/08 , C08G61/08 , C08G2261/3325 , C08G2261/418
摘要： This invention relates to olefin metathesis catalysts and methods for controlling olefin metathesis reactions. More particularly, the present invention relates to methods and compositions for catalyzing and controlling ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. This invention also relates to olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a ROMP composition comprising a resin composition comprising at least one cyclic olefin, and an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a method of making an article comprising combining an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts with a resin composition comprising at least one cyclic olefin, thereby forming a ROMP composition, and subjecting the ROMP composition to conditions effective to polymerize the ROMP composition. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

8. 发明专利

CA2903574C IN-MOLD COATING OF ROMP POLYMERS 未知
公开(公告)号：CA2903574C
公开(公告)日：2021-07-27
申请号：CA2903574
申请日：2014-03-14
申请人： MATERIA INC
发明人： STEPHEN ANTHONY R , CRUCE CHRISTOPHER J , TRIMMER MARK S , GIARDELLO MICHAEL A
IPC分类号： C08F32/00 , B29C41/02 , C08F4/80 , C08L45/00 , C09D7/40
摘要： The present invention relates to in-mold coating of a cyclic olefin polymer. More particularly, the present invention relates to methods and compositions for in-mold coating cyclic olefin polymers prepared by ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and material chemistry and manufacture.

9. 发明专利

AU2014228926B2 In-mold coating of ROMP polymers 未知
公开(公告)号：AU2014228926B2
公开(公告)日：2017-11-30
申请号：AU2014228926
申请日：2014-03-14
申请人： MATERIA INC
发明人： STEPHEN ANTHONY R , CRUCE CHRISTOPHER J , TRIMMER MARK S , GIARDELLO MICHAEL A
IPC分类号： C08F4/80
摘要： The present invention relates to in-mold coating of a cyclic olefin polymer. More particularly, the present invention relates to methods and compositions for in-mold coating cyclic olefin polymers prepared by ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and material chemistry and manufacture.

10. 发明专利

AU2014285077B2 Liquid molding compositions 未知
公开(公告)号：AU2014285077B2
公开(公告)日：2017-09-14
申请号：AU2014285077
申请日：2014-07-03
申请人： MATERIA INC
发明人： CRUCE CHRISTOPHER J , GIARDELLO MICHAEL A , TRIMMER MARK S , STEPHEN ANTHONY R , BOOTHE PAUL W , EDGECOMBE BRIAN , MOORE JASON L
IPC分类号： C08G61/08 , C08F4/80
摘要： The present invention relates to methods and compositions for olefin metathesis. More particularly, the present invention relates to methods and compositions for ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles and/or polymer composite articles via ROMP Polymer products produced via the metathesis reactions of the invention may be utilized in a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.

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