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1. 发明授权

US09159991B2 Mixed phosphate-diphosphate electrode materials and methods of manufacturing same 有权
标题翻译：混合磷酸二磷酸盐电极材料及其制造方法
公开(公告)号：US09159991B2
公开(公告)日：2015-10-13
申请号：US13846822
申请日：2013-03-18
申请人： Massachusetts Institute of Technology
发明人： Gerbrand Ceder , Anubhav Jain , Geoffroy Hautier , Jae Chul Kim , Byoungwoo Kang , Robert Daniel
IPC分类号： H01M4/58 , H01M4/131 , C01B25/45 , H01M4/36 , H01M10/052 , B02C17/18 , B02C19/18 , B02C23/06
CPC分类号： H01M4/131 , B02C17/1815 , B02C19/186 , B02C23/06 , C01B25/45 , H01M4/366 , H01M4/58 , H01M4/5805 , H01M4/5825 , H01M10/052 , Y02E60/122 , Y02P70/54
摘要： This invention relates generally to electrode materials, electrochemical cells employing such materials, and methods of synthesizing such materials. The electrode materials have a crystal structure with a high ratio of Li to metal M, which is found to improve capacity by enabling the transfer of a greater amount of lithium per metal, and which is also found to improve stability by retaining a sufficient amount of lithium after charging. Furthermore, synthesis techniques are presented which result in improved charge and discharge capacities and reduced particle sizes of the electrode materials.
摘要翻译：本发明一般涉及电极材料，采用这种材料的电化学电池，以及合成这些材料的方法。电极材料具有Li与金属M的高比例的晶体结构，通过使每个金属能够转移更多量的锂，发现能够提高容量，并且还发现通过保持足够量的充电后锂。此外，提出了合成技术，其导致电极材料的充电和放电容量的提高以及粒径的降低。

2. 发明申请

US20150204809A1 SCREENING SOLID STATE IONIC CONDUCTORS FOR HIGH IONIC CONDUCTIVITY 有权
标题翻译：筛选用于高离子电导率的固体状态离子导体
公开(公告)号：US20150204809A1
公开(公告)日：2015-07-23
申请号：US14536506
申请日：2014-11-07
申请人： Samsung Electronics, Co. Ltd. , Massachusetts Institute of Technology
发明人： Lincoln J. Miara , William Richards , Shyue Ping Ong , Yifei Mo , Gerbrand Ceder
IPC分类号： G01N27/02
CPC分类号： G06F19/704 , H01M10/42 , H01M2300/0065
摘要： Non-normal statistics applied to diffusivity calculations accelerate screening of ionic conductors for electrochemical devices such as electric storage batteries, fuel cells, and sensors. Displacements of atomic species within a crystalline structure for a candidate ionic conductor material are analyzed using a Skellam distribution optionally combined with Gaussian noise to calculate values for the standard deviation, upper error bound, and lower error bound for predicted values of diffusivity (D). When the predicted values of D have sufficient statistical precision, the diffusivity calculation is terminated and the calculated diffusivity is compared to a threshold value of diffusivity. When the threshold has been exceeded, the candidate ionic conductor may be listed as a preferred good conductor. When the calculated diffusivity fails to exceed the threshold, the material may be listed as a poor conductor and may be eliminated from further consideration.
摘要翻译：应用于扩散计算的非正态统计加速了电化学装置（如蓄电池，燃料电池和传感器）的离子导体的筛选。使用可选地与高斯噪声组合的Skellam分布来分析用于候选离子导体材料的晶体结构内的原子物质的位移，以计算扩散系数（D）的标准偏差，上误差界限和下限误差界限的值。当D的预测值具有足够的统计精度时，终止扩散计算，并将计算出的扩散系数与扩散系数的阈值进行比较。当超过阈值时，可将候选离子导体列为优选导体。当计算的扩散系数不能超过阈值时，材料可能被列为不良导体，并可能被进一步考虑。

3. 发明授权

US10957901B2 High-capacity positive electrode active material 有权
公开(公告)号：US10957901B2
公开(公告)日：2021-03-23
申请号：US15691396
申请日：2017-08-30
申请人： Massachusetts Institute of Technology
发明人： Gerbrand Ceder , Jinhyuk Lee , Alexander Urban , Xin Li , Sangtae Kim , Geoffroy Hautier
IPC分类号： H01M4/36 , H01M4/485 , H01M4/525 , H01M4/131 , H01M4/62
摘要： This disclosure provides a positive electrode active lithium-excess metal oxide with composition LixMyO2 (0.6≤y≤0.85 and 0≤x+y≤2) for a lithium secondary battery with a high reversible capacity that is insensitive with respect to cation-disorder. The material exhibits a high capacity without the requirement of overcharge during the first cycles.

4. 发明授权

US10324138B2 Computing system for identification of solid-solid interphase products 有权
公开(公告)号：US10324138B2
公开(公告)日：2019-06-18
申请号：US15352400
申请日：2016-11-15
申请人： Samsung Electronics Co., Ltd. , Massachusetts Institute of Technology
发明人： William D. Richards , Lincoln J. Miara , Yan E. Wang , Jae Chul Kim , Gerbrand Ceder
IPC分类号： H01M10/42 , G01R31/367 , H01M10/0525 , H01M10/0562
摘要： Embodiments of a method, a system, and non-transitory computer readable storage media evaluating electrochemical qualities for interphase products. The disclosed embodiments perform a selection of a plurality of chemical phases for a solid electrolyte and at least one of the anode and cathode to be received. Thermodynamic data is received for the plurality of chemical phases. The retrieved thermodynamic data is received to evaluate a respective electrochemical quality for at least one of an interface between the solid electrolyte and the anode, and an interface between the solid electrolyte and the cathode.

5. 发明申请

US20180294533A1 Liquid Metal Alloy Energy Storage Device 审中-公开
公开(公告)号：US20180294533A1
公开(公告)日：2018-10-11
申请号：US16003681
申请日：2018-06-08
申请人： Massachusetts Institute of Technology
发明人： David J. Bradwell , Gerbrand Ceder , Luis A. Ortiz , Donald R. Sadoway
IPC分类号： H01M10/39 , H01M4/38 , H01M10/654 , H01M10/6554 , H01M10/658 , H01M2/02 , H01M2/04 , H01M4/70 , H01M4/66 , H01M4/46 , H01M10/617 , H01M4/134 , H01M2/12 , H01M2/10 , H01M10/6571 , H01M4/76 , H01M4/02
摘要： An energy storage device configured to exchange energy with an external device includes a container having walls, a lid covering the container and having a safety pressure valve, a negative electrode disposed away from the walls of the container, a positive electrode in contact with at least a portion of the walls of the container, and an electrolyte contacting the negative electrode and the positive electrode at respective electrode/electrolyte interfaces. The negative electrode, the positive electrode and the electrolyte include separate liquid materials within the container at an operating temperature of the battery.

6. 发明授权

US09966629B2 Sodium-conducting solid electrolyte 有权
公开(公告)号：US09966629B2
公开(公告)日：2018-05-08
申请号：US14698691
申请日：2015-04-28
申请人： Samsung Electronics, Co. Ltd. , Massachusetts Institute of Technology
发明人： William D. Richards , Shyue Ping Ong , Yifei Mo , Gerbrand Ceder , Lincoln Miara , Tomoyuki Tsujimura , Yan Wang , Young-Gyoon Ryu , Naoki Suzuki , Ichiro Uechi
IPC分类号： H01M10/39 , H01M10/0562 , C01B25/14 , H01M4/38 , H01M10/05
CPC分类号： H01M10/0562 , C01B25/14 , C01P2002/30 , C01P2002/72 , C01P2006/40 , H01M4/381 , H01M10/05 , H01M2300/0068
摘要： A sodium-conductive solid-state electrolyte material includes a compound of the composition Na10MP2S12, wherein M is selected from Ge, Si, and Sn. The material may have a conductivity of at least 1.0×10−5 S/cm at a temperature of about 300K and may have a tetragonal microstructure, e.g., a skewed P1 crystallographic structure. Also provided are an electrochemical cell that includes the sodium-conductive solid-state electrolyte material and a method for producing the sodium-conductive solid electrolyte material via controlled thermal processing parameters.

7. 发明授权

US09905852B2 Sodium transition metal oxide electroactive compounds 有权
公开(公告)号：US09905852B2
公开(公告)日：2018-02-27
申请号：US14839524
申请日：2015-08-28
申请人： Massachusetts Institute of Technology
发明人： Xin Li , Gerbrand Ceder
IPC分类号： H01M4/525 , C01G53/00 , H01M4/505 , C01G45/12 , C01G49/00 , C01G51/00 , H01M10/054 , H01M4/02
CPC分类号： H01M4/525 , C01G45/1221 , C01G45/1228 , C01G49/0027 , C01G51/42 , C01G53/42 , C01G53/44 , C01G53/50 , C01P2002/72 , C01P2002/80 , C01P2006/40 , H01M4/505 , H01M10/054 , H01M2004/028
摘要： Embodiments related to electroactive compounds, their methods of manufacture, and use are described. In one embodiment, an electroactive compound may include Na(FeaX1-a)O2. X includes at least one of Ti, V, Cr, Mn, Co, Ni, and a is greater than 0 and less than or equal to 0.4. In another embodiment, an electroactive compound may include Na(MnwFexCoyNiz)O2, where w, x, y, and z are greater than 0. Further, a sum of w, x, y, and z is equal to 1 in some cases.

8. 发明申请

US20170025705A1 SOLID ELECTROLYTE AND/OR ELECTROACTIVE MATERIAL 审中-公开
标题翻译：固体电解质和/或电解材料
公开(公告)号：US20170025705A1
公开(公告)日：2017-01-26
申请号：US15155354
申请日：2016-05-16
申请人： Samsung Electronic, Co. Ltd. , Massachusetts Institute of Technology
发明人： Lincoln J. Miara , William D. Richards , Yan E. Wang , Jae Chul Kim , Gerbrand Ceder
IPC分类号： H01M10/0562 , H01M10/0525
CPC分类号： H01M10/0562 , H01M10/0525 , H01M2300/0071
摘要： Solid electrolyte materials as well as their applications and methods of manufacture are disclosed. In one embodiment, a solid electrolyte material has a formula of A3+δCl1−δBδO, where δ is greater than 0. In the above formula, A is at least one of Li and Na, and B is at least one of S, Se, and N. In another embodiment, a solid electrolyte material is a crystal structure having the general formula A3XO, where A is at least one of Li and Na. Additionally, X is Cl, at least a portion of which is substituted with at least one of S, Se, and N. The solid electrolyte material also includes interstitial lithium ions and/or interstitial sodium ions located in the crystal structure.
摘要翻译：公开了固体电解质材料及其应用和制造方法。在一个实施方案中，固体电解质材料具有式A3 +δCl1-δBδO，其中δ大于0.在上式中，A是Li和Na中的至少一种，B是S，Se中的至少一种和N.在另一个实施方案中，固体电解质材料是具有通式A3XO的晶体结构，其中A是Li和Na中的至少一种。此外，X是Cl，其至少一部分被S，Se和N中的至少一个取代。固体电解质材料还包括位于晶体结构中的间隙锂离子和/或间隙钠离子。

9. 发明申请

US20160064734A1 SODIUM TRANSITION METAL OXIDE ELECTROACTIVE COMPOUNDS 有权
标题翻译：过渡金属氧化物电解质化合物
公开(公告)号：US20160064734A1
公开(公告)日：2016-03-03
申请号：US14839524
申请日：2015-08-28
申请人： Massachusetts Institute of Technology
发明人： Xin Li , Gerbrand Ceder
IPC分类号： H01M4/525 , H01M4/505 , C01G51/00 , C01G49/00 , C01G53/00 , C01G45/12
CPC分类号： H01M4/525 , C01G45/1221 , C01G45/1228 , C01G49/0027 , C01G51/42 , C01G53/42 , C01G53/44 , C01G53/50 , C01P2002/72 , C01P2002/80 , C01P2006/40 , H01M4/505 , H01M10/054 , H01M2004/028
摘要： Embodiments related to electroactive compounds, their methods of manufacture, and use are described. In one embodiment, an electroactive compound may include Na(FeaX1-a)O2. X includes at least one of Ti, V, Cr, Mn, Co, Ni, and a is greater than 0 and less than or equal to 0.4. In another embodiment, an electroactive compound may include Na(MnwFexCoyNiz)O2, where w, x, y, and z are greater than 0. Further, a sum of w, x, y, and z is equal to 1 in some cases.
摘要翻译：描述了与电活性化合物相关的实施方案，其制造方法和用途。在一个实施方案中，电活性化合物可包括Na（FeaX1-a）O 2。 X包括Ti，V，Cr，Mn，Co，Ni中的至少一种，a大于0且小于或等于0.4。在另一个实施方案中，电活性化合物可以包括Na（MnwFexCoyNiz）O 2，其中w，x，y和z大于0.此外，在某些情况下，w，x，y和z的和等于1。

10. 发明申请

US20150303525A1 Liquid Metal Alloy Energy Storage Device 有权
标题翻译：液态金属合金储能装置
公开(公告)号：US20150303525A1
公开(公告)日：2015-10-22
申请号：US14755685
申请日：2015-06-30
申请人： Massachusetts Institute of Technology
发明人： David J. Bradwell , Gerbrand Ceder , Luis Ortiz , Donald R. Sadoway
IPC分类号： H01M10/39 , H01M4/38 , H01M4/134 , H01M4/46 , H01M2/12 , H01M2/04
CPC分类号： H01M10/399 , H01M2/0252 , H01M2/0447 , H01M2/0456 , H01M2/1094 , H01M2/12 , H01M4/134 , H01M4/38 , H01M4/381 , H01M4/387 , H01M4/466 , H01M4/661 , H01M4/662 , H01M4/663 , H01M4/70 , H01M4/76 , H01M10/617 , H01M10/654 , H01M10/6554 , H01M10/6571 , H01M10/658 , H01M2004/027 , H01M2300/0054 , H01M2300/0057
摘要： An energy storage device configured to exchange energy with an external device includes a container having walls, a lid covering the container and having a safety pressure valve, a negative electrode disposed away from the walls of the container, a positive electrode in contact with at least a portion of the walls of the container, and an electrolyte contacting the negative electrode and the positive electrode at respective electrode/electrolyte interfaces. The negative electrode, the positive electrode and the electrolyte include separate liquid materials within the container at an operating temperature of the battery.
摘要翻译：构造成与外部设备交换能量的能量存储装置包括具有壁的容器，覆盖容器的盖子，并具有安全压力阀，远离容器壁设置的负极，与至少接触的正电极容器的壁的一部分，以及在相应的电极/电解质界面处与负极和正电极接触的电解质。在电池的工作温度下，负极，正极和电解质包括在容器内的分离的液体材料。

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