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1. 发明授权

US4376206A N-Alkenylphenylmaleimides and N,N'-[alkenylene phenylene]bismaleimides for the same 失效
标题翻译： N-烯基苯基马来酰亚胺和N，N' - [亚烯基亚苯基]双马来酰亚胺
公开(公告)号：US4376206A
公开(公告)日：1983-03-08
申请号：US131804
申请日：1980-03-19
申请人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
发明人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
IPC分类号： C07D207/44 , C07D207/448 , C07D207/452 , C08G73/12 , C07D207/40
CPC分类号： C07D207/448 , C07D207/452 , C08G73/12
摘要： Disclosed are novel alkenylphenylmaleimide derivatives having the general formula ##STR1## where R is an alkenyl radical of from 3 to 12 carbon atoms, R' is a hydrogen atom, a halogen atom, or a straight-chain or branched alkyl radical of from 1 to 4 carbon atoms, and n is a whole number of from 1 to 4, and linear dimers thereof as well as a process for the preparation of such maleimide compounds.
摘要翻译：公开了具有通式为“IMAGE”的新的烯基苯基马来酰亚胺衍生物，其中R是3至12个碳原子的烯基，R'是氢原子，卤素原子或直链或支链烷基， 4个碳原子，n为1〜4的整数，以及其线性二聚体以及这些马来酰亚胺化合物的制备方法。

2. 发明授权

US4401777A Curable resin composition comprising N-(alkenylphenyl)maleimide and epoxy composition 失效
标题翻译：包含N-（烯基苯基）马来酰亚胺和环氧组合物的可固化树脂组合物
公开(公告)号：US4401777A
公开(公告)日：1983-08-30
申请号：US312959
申请日：1981-10-20
申请人： Hikotada Tsuboi , Motoo Kawamata , Masayuki Oba , Nobuhito Koga
发明人： Hikotada Tsuboi , Motoo Kawamata , Masayuki Oba , Nobuhito Koga
IPC分类号： C08G59/40 , C08G73/12 , C08G59/18 , C08G59/44
CPC分类号： C08G73/126 , C08G59/4042 , C08G73/122
摘要： Disclosed is a curable resin composition comprising (a) at least one maleimide compound selected from the group consisting of N-(alkenylphenyl)maleimide derivatives, and dimers and polymers thereof and (b) one or more kinds of epoxy resins, each having at least one epoxy group in the unit molecule thereof. The resin composition may contain, besides the above two components, an amino compound as a further component (c). The resin composition may comprise a prepolymer of any two components among the three components (a), (b) and (c) and the remaining component. The resin compositions are useful as molding materials, for the fabrication of laminates, and as varnishes, including insulation varnishes and impregnating varnishes.
摘要翻译：公开了一种可固化树脂组合物，其包含（a）至少一种选自N-（烯基苯基）马来酰亚胺衍生物和二聚体及其聚合物的马来酰亚胺化合物和（b）一种或多种环氧树脂，其单体分子中有一个环氧基。除了上述两种成分之外，树脂组合物可以含有作为其他成分（c）的氨基化合物。树脂组合物可以包含三种组分（a），（b）和（c）中的任何两种组分的预聚物和剩余组分。树脂组合物可用作模制材料，用于制造层压材料，以及作为清漆，包括绝缘清漆和浸渍清漆。

3. 发明授权

US4323662A Thermosetting resin compositions comprising bismaleimides and alkenylaniline derivatives 失效
标题翻译：包含双马来酰亚胺和链烯基苯胺衍生物的热固性树脂组合物
公开(公告)号：US4323662A
公开(公告)日：1982-04-06
申请号：US167145
申请日：1980-07-08
申请人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
发明人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
IPC分类号： C08F12/00 , C08F20/00 , C08F20/52 , C08F22/36 , C08F212/14 , C08F222/40 , C08F290/02 , C08F220/52 , C08F122/40 , C08F271/02
CPC分类号： C08F222/40 , C08F290/02
摘要： Disclosed is a thermosetting resin composition comprising (a) a bismaleimide and/or a polymaleimide and (b) at least one member selected from alkenylaniline derivatives, linear dimers thereof, and polymers thereof. In addition to components (a) and (b), this resin composition can contain (c) a polymerizable unsaturated substance.
摘要翻译：公开了一种热固性树脂组合物，其包含（a）双马来酰亚胺和/或聚马来酰亚胺和（b）选自链烯基苯胺衍生物，其线性二聚体及其聚合物中的至少一种。除了组分（a）和（b）之外，该树脂组合物可以含有（c）可聚合不饱和物质。

4. 发明授权

US4506042A Curable resin composition comprising N-(alkenylphenyl)maleimide, epoxy composition and polyamine 失效
标题翻译：包含N-（烯基苯基）马来酰亚胺，环氧组合物和多胺的可固化树脂组合物
公开(公告)号：US4506042A
公开(公告)日：1985-03-19
申请号：US471204
申请日：1983-04-04
申请人： Hikotada Tsuboi , Motoo Kawamata , Masayuki Oba , Nobuhito Koga
发明人： Hikotada Tsuboi , Motoo Kawamata , Masayuki Oba , Nobuhito Koga
IPC分类号： C08G59/40 , C08G73/12 , C08L63/00 , C08L67/00 , C08L77/00
CPC分类号： C08G73/122 , C08G59/4042 , C08G73/126
摘要： Disclosed is a curable resin composition comprising (a) at least one maleimide compound selected from the group consisting of N-(alkenylphenyl)maleimide derivatives, and dimers and polymers thereof and (b) one or more kinds of epoxy resins, each having at least one epoxy group in the unit molecule thereof. The resin composition may contain, besides the above two components, an amino compound as a further component (c). The resin composition may comprise a prepolymer of any two components among the three components (a), (b) and (c) and the remaining component. The resin compositions are useful as molding materials, for the fabrication of laminates, and as varnishes, including insulation varnishes and impregnating varnishes.
摘要翻译：公开了一种可固化树脂组合物，其包含（a）至少一种选自N-（烯基苯基）马来酰亚胺衍生物和二聚体及其聚合物的马来酰亚胺化合物和（b）一种或多种环氧树脂，其单体分子中有一个环氧基。除了上述两种成分之外，树脂组合物可以含有作为其他成分（c）的氨基化合物。树脂组合物可以包含三种组分（a），（b）和（c）中的任何两种组分的预聚物和剩余组分。树脂组合物可用作模制材料，用于制造层压材料，以及作为清漆，包括绝缘清漆和浸渍清漆。

5. 发明授权

US4400521A N-Substituted phenyl maleimides 失效
标题翻译： N-取代的苯基马来酰亚胺
公开(公告)号：US4400521A
公开(公告)日：1983-08-23
申请号：US201901
申请日：1980-10-29
申请人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
发明人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
IPC分类号： C07D207/44 , C07D207/452
CPC分类号： C07D207/452
摘要： Maleimide compounds represented by the general formula (I) ##STR1## where R and R' are a hydrogen atom, a halogen atom, or an alkyl radical of from 1 to 4 carbon atoms, and n and n' are a whole number of from 1 to 4; and a process for the preparation of the maleimide compounds, in which a maleamic acid represented by the general formula (II) ##STR2## where R and R' are a hydrogen atom, a halogen atom, or an alkyl radical of from 1 to 4 carbon atoms, and n and n' are a whole number of from 1 to 4, is contacted with a dehydrating agent in an organic solvent.
摘要翻译：由通式（I）表示的马来酰亚胺化合物其中R和R'是氢原子，卤素原子或1至4个碳原子的烷基，n和n'是整数数字从1到4; 以及制备马来酰亚胺化合物的方法，其中由通式（II）表示的马来酰胺酸（II）其中R和R'是氢原子，卤素原子或 1〜4个碳原子，n和n'为1〜4的整数，与脱水剂在有机溶剂中接触。

6. 发明授权

US4500719A Process for the preparation of N-alkenylphenylmaleimides and N,N'-[alkenylenephenylene]bismalemides 失效
标题翻译：制备N-烯基苯基马来酰亚胺和N，N' - [亚烯基亚苯基]双马来酰亚胺的方法
公开(公告)号：US4500719A
公开(公告)日：1985-02-19
申请号：US408042
申请日：1982-08-13
申请人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
发明人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
IPC分类号： C07D207/44 , C07D207/448 , C07D207/452 , C07D207/40
CPC分类号： C07D207/448 , C07D207/452
摘要： Disclosed are novel alkenylphenylmaleimide derivatives having the general formula ##STR1## where R is an alkenyl radical of from 3 to 12 carbon atoms, R' is a hydrogen atom, a halogen atom, or a straight-chain or branched alkyl radical of from 1 to 4 carbon atoms, and n is a whole number of from 1 to 4, and linear dimers thereof as well as a process for the preparation of such maleimide compounds.
摘要翻译：公开了具有通式为“IMAGE”的新的烯基苯基马来酰亚胺衍生物，其中R是3至12个碳原子的烯基，R'是氢原子，卤素原子或直链或支链烷基， 4个碳原子，n为1〜4的整数，以及其线性二聚体以及这些马来酰亚胺化合物的制备方法。

7. 发明授权

US4289699A Process for the production of N-(hydroxyphenyl) maleimides 失效
标题翻译：制备N-（羟基苯基）马来酰亚胺的方法
公开(公告)号：US4289699A
公开(公告)日：1981-09-15
申请号：US88825
申请日：1979-10-26
申请人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
发明人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
IPC分类号： C07D207/44 , C07D207/448 , C07D207/452
CPC分类号： C07D207/448
摘要： N-(hydroxyphenyl) maleimides of the general formula ##STR1## where R' stands for H, CH.sub.3, C.sub.2 H.sub.5, F, Cl, Br or I and n is an integer of 1-5 are produced by treating the corresponding maleamic acid or by treating the ester of said N-(hydroxyphenyl) maleimide at a temperature of 0.degree.-150.degree. C. in the presence of at least one dehydrating agent selected for the group consisting of oxides and oxyacids of sulfur or phosphorus and alkali metal and alkaline earth metal salts of the said oxyacids. The corresponding maleamic acid can be obtained by reacting an aminophenol having one or more hydroxyl groups on its phenyl nucleus with maleic anhydride. The esters of the N-(hydroxyphenyl maleimide) can be obtained by reacting said aminophenol and said maleic anhydride in the presence of a conventional acid anhydride dehydrating agent and a conventional imide-forming cyclization catalyst.
摘要翻译：其中R'代表H，CH 3，C 2 H 5，F，Cl，Br或I并且n是1-5的整数的N-（羟基苯基）马来酰亚胺，其中R'代表H，CH 3，C 2 H 5，F，Cl，Br或I，并且n是通过处理相应的马来酰胺酸或在选自硫或磷的氧化物和含氧基团以及碱金属和碱土金属的至少一种脱水剂存在下，在0-150℃的温度下处理所述N-（羟基苯基）马来酰亚胺的酯所述含氧酸的金属盐。相应的马来酰胺酸可以通过使苯基上具有一个或多个羟基的氨基苯酚与马来酸酐反应来获得。 N-（羟基苯基马来酰亚胺）的酯可以通过在常规的酸酐脱水剂和常规的形成酰亚胺的环化催化剂的存在下使所述氨基苯酚和所述马来酸酐反应来获得。

8. 发明授权

US4231934A Process for the production of N-(hydroxyphenyl) maleimides 失效
标题翻译：制备N-（羟基苯基）马来酰亚胺的方法
公开(公告)号：US4231934A
公开(公告)日：1980-11-04
申请号：US956971
申请日：1978-11-02
申请人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
发明人： Masayuki Oba , Motoo Kawamata , Hikotada Tsuboi , Nobuhito Koga
IPC分类号： C07D207/44 , C07D207/448
CPC分类号： C07D207/448
摘要： N-(hydroxyphenyl) maleimides of the general formula ##STR1## where R' stands for H, CH.sub.3, C.sub.2 H.sub.5, F, Cl, Br or I and n is an integer of 1-5 are produced by treating the corresponding maleamic acid or by treating the ester of said N-(hydroxyphenyl) maleimide at a temperature of 0-150.degree. C. in the presence of at least one dehydrating agent selected from the group consisting of oxides and oxyacids of sulfur or phosphorus and alkali metal and alkaline earth metal salts of the said oxyacids. The corresponding maleamic acid can be obtained by reacting an aminophenol having one or more hydroxyl groups on its phenyl nucleus with maleic anhydride. The esters of the N-(hydroxyphenyl maleimide) can be obtained by reacting said aminophenol and said maleic anhydride in the presence of a conventional acid anhydride dehydrating agent and a conventional imide-forming cyclization catalyst.
摘要翻译：其中R'代表H，CH 3，C 2 H 5，F，Cl，Br或I并且n是1-5的整数的N-（羟基苯基）马来酰亚胺，其中R'代表H，CH 3，C 2 H 5，F，Cl，Br或I，并且n是通过处理相应的马来酰胺酸或在选自硫或磷的氧化物和含氧基团以及碱金属和碱土金属的至少一种脱水剂的存在下，在0-150℃的温度下处理所述N-（羟基苯基）马来酰亚胺的酯所述含氧酸的盐。相应的马来酰胺酸可以通过使苯基上具有一个或多个羟基的氨基苯酚与马来酸酐反应来获得。 N-（羟基苯基马来酰亚胺）的酯可以通过在常规的酸酐脱水剂和常规的形成酰亚胺的环化催化剂的存在下使所述氨基苯酚和所述马来酸酐反应来获得。

9. 发明授权

US5753407A Polyamic acid composition 失效
标题翻译：聚酰胺酸组成
公开(公告)号：US5753407A
公开(公告)日：1998-05-19
申请号：US653319
申请日：1996-05-24
申请人： Masayuki Oba
发明人： Masayuki Oba
IPC分类号： C08G73/10 , C08L79/08 , G02F1/1337 , G03F7/023
CPC分类号： G03F7/0233 , C08G73/1007 , C08G73/1025 , C08L79/08 , G02F1/133723 , G02F1/133753
摘要： Disclosed herein is a polyamic acid composition which comprises an aromatic carboxylic acid compound having phenolic hydroxyl groups, polyamic acid, and a photosensitizer made of a diazide compound, and which can form a polyimide film pattern having a high resolution and capable of firmly adhering to a substrate.
摘要翻译：本文公开了一种聚酰胺酸组合物，其包含具有酚羟基的芳族羧酸化合物，聚酰胺酸和由重氮化合物制成的光敏剂，并且其可以形成具有高分辨率并能够牢固粘附于基质。\！

10. 发明授权

US06159654A Negative photosensitive polymer composition of a thermosetting polymer precursor curable by cyclodehydration upon heating 失效
标题翻译：通过加热时通过环化脱水可固化的热固性聚合物前体的负光敏聚合物组合物
公开(公告)号：US06159654A
公开(公告)日：2000-12-12
申请号：US221113
申请日：1998-12-28
申请人： Shigeru Machida , Yoshiaki Kawamonzen , Masayuki Oba
发明人： Shigeru Machida , Yoshiaki Kawamonzen , Masayuki Oba
IPC分类号： G03F7/004 , C08G73/10 , C08K5/04 , C08K5/16 , C08K5/34 , C08K5/36 , C08K5/51 , C08L79/04 , C08L79/08 , C08L101/00 , C09K9/00 , G03F7/028 , G03F7/037 , G03F7/038 , G03F7/38 , H01L21/027 , G03C1/73
CPC分类号： G03F7/037 , H01L2224/48091 , H01L2224/48247 , H01L2224/48465 , H01L2224/8592 , H01L2924/181 , H01L2924/00014 , H01L2924/00012 , H01L2924/00
摘要： A negative photosensitive polymer composition, which comprises a thermosetting polymer precursor which can be cured through cyclodehydration upon heating, and a photosensitive heat cure accelerator which is capable of accelerating a curing upon irradiation of light (cyclodehydration accelerating property). This photosensitive heat cure accelerator may be a compound which is capable of increasing molecular weight and raising volatilization temperature upon irradiation of light, or a compound which is capable of generating a carboxyl group upon irradiation of light thereby exhibiting a heat cure-accelerating property, and is formed of an aromatic hydrocarbon or aromatic heterocyclic compound having at least one hydroxyl group, substituted or unsubstituted amino group or mercapto group.
摘要翻译：一种负型光敏聚合物组合物，其包含可通过加热时通过环化脱水固化的热固性聚合物前体，以及能够在照射光时加速固化的光敏热固化促进剂（环化脱水加速性）。该感光性热固化促进剂可以是能够增加分子量并且在照射光时提高挥发温度的化合物，或能够在光照射下产生羧基的化合物，从而表现出热固化促进性的化合物，以及由具有至少一个羟基，取代或未取代的氨基或巯基的芳族烃或芳族杂环化合物形成。

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