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    • 3. 发明授权
    • Cordierite honeycomb structural body and its production process
    • 堇青石蜂窝结构体及其生产工艺
    • US06589627B1
    • 2003-07-08
    • US09526630
    • 2000-03-16
    • Tomohiko NakanishiMasanori YamadaYosiyasu Andou
    • Tomohiko NakanishiMasanori YamadaYosiyasu Andou
    • B32B312
    • C04B35/6365C04B38/0645C04B2111/0081C08K3/34C08K7/00Y10T428/131Y10T428/1352Y10T428/24149Y10T428/24661Y10T428/24744C04B35/195C04B38/0006
    • There is provided a cordierite honeycomb structural body that allows the thickness of the cell walls to be reduced and heat capacity to be decreased by improving the fluidity of the molding material when passing through a mold for extrusion molding while maintaining the shape retention of the molding material. A water-soluble cellulose ether is used as a binder that is added to a cordierite-converted starting material. This water-soluble cellulose ether contains methoxyl groups substituted for the cellulose hydroxyl groups within the range of a substitution rate of 27.5 to 31.5%, does not contain hydroxypropoxyl groups and hydroxyethoxyl groups in an amount greater than the amount of unavoidable impurities (0.1 wt %), and has a viscosity in a 2 wt % aqueous solution at 20° C. of less than 8000 centipoise. As a result of adding this water-soluble cellulose ether in an amount of 3 wt % to 10 wt % relative to the amount of the cordierite-converted starting material, frictional resistance is decreased allowing improvement of fluidity while maintaining adequate hardness of the molding material.
    • 提供了一种堇青石蜂窝结构体,通过提高成形材料在通过挤出成型用模具时的流动性,能够降低单元壁的厚度,降低热容量,同时保持成型材料的形状保持性 。 使用水溶性纤维素醚作为添加到堇青石转化的原料中的粘合剂。 该水溶性纤维素醚在取代率为27.5〜31.5%的范围内含有取代纤维素羟基的甲氧基,不含羟基丙氧基和羟基乙氧基,其量大于不可避免的杂质(0.1重量% ),并且在20℃的2重量%水溶液中具有小于8000厘泊的粘度。 作为相对于堇青石转化原料的量添加3重量%〜10重量%的水溶性纤维素醚的结果,摩擦阻力降低,从而提高流动性,同时保持成型材料的适当的硬度 。
    • 6. 发明授权
    • Purification catalyst for internal combustion engine exhaust gas
    • 内燃机废气净化催化剂
    • US06713429B1
    • 2004-03-30
    • US09461415
    • 1999-12-16
    • Masakazu TanakaYosiyasu AndouKeiji ItoTakahiro Kida
    • Masakazu TanakaYosiyasu AndouKeiji ItoTakahiro Kida
    • B01J2104
    • F01N3/2828Y02A50/2322
    • A purification catalyst for exhaust gas is provided that uses a hexagonal cell monolithic carrier which is able to demonstrate purification performance that is superior to the case of using a square cell monolithic carrier. This purification catalyst for exhaust gas comprises a monolithic carrier (10) provided with hexagonal cells (15) of 200 cells/in2 or more in which the porosity of partition walls (11) that form the cells (15) is 25% or more; and, a catalyst layer (2) arranged on the surface of the partition walls (11) of the monolithic carrier (10) that contains a catalyst component for purification of exhaust gas. The thickness of catalyst layer (2) is 10-70 &mgr;m at its thin portion (21), and its thick portion (22) has a thickness of no more than 12 times that of thin portion (21).
    • 提供了一种废气净化催化剂,其使用能够表现出优于使用方形电池单片载体的情况的纯化性能的六边形单元整体载体。 这种废气净化催化剂包括一个整体式载体(10),该整体载体(10)具有200个/ in 2或更多的六边形单元(15),其中形成单元(15)的隔壁(11)的孔隙率为25% 或者更多; 以及布置在整体式载体(10)的分隔壁(11)的表面上的催化剂层(2),其包含用于净化废气的催化剂组分。 催化剂层(2)的厚度在其薄部分(21)为10-70μm,其厚部分(22)的厚度不超过薄部分(21)的厚度的12倍。
    • 7. 发明授权
    • Production process of a hexagonal honeycomb structure
    • 六角蜂窝结构的生产工艺
    • US06309590B1
    • 2001-10-30
    • US09372124
    • 1999-08-11
    • Takasi ObataYosiyasu AndouKazuhiko Yasuda
    • Takasi ObataYosiyasu AndouKazuhiko Yasuda
    • B28B320
    • B28B3/269B01J35/04F01N3/2828F01N2330/34
    • The present invention provides a production process of a hexagonal honeycomb structure having low deformation of hexagonal cells. This process comprises an extrusion step for obtaining moldings (7) in which partitions (71) are provided in the form of a hexagonal matrix by extrusion molding of a mixed raw material using a horizontal extruder having an extrusion die provided with slits in the form of a hexagonal matrix and in which the direction of extruding is substantially the horizontal direction, a drying step for drying moldings (7), and a baking step for baking moldings (7). The extrusion step is performed such that c axis (700) parallel to two parallel sides (702) and (705) of the six sides (701) through (706) of each hexagon formed by partitions (71) of extruded moldings (7) is substantially vertical relative to the horizontal plane.
    • 本发明提供六方晶胞形变小的六边形蜂窝结构体的制造方法。 该方法包括用于获得模制品(7)的挤出步骤,其中通过使用具有挤出模头的卧式挤出机挤出成型六边形矩形形式的隔板(71),该挤出模具具有以下形式的狭缝: 六边形基体,其中挤出方向基本上是水平方向,干燥模制品(7)的干燥步骤和用于烘烤模制品(7)的烘烤步骤。 进行挤出步骤,使得平行于由挤压成形品(7)的间隔(71)形成的每个六边形的六个边(701)至(706)的两个平行边(702)和(705)的c轴(700) 相对于水平面基本垂直。
    • 8. 发明授权
    • Process for producing cordierite honeycomb structural body and honeycomb structural body molding aid
    • 堇青石蜂窝结构体和蜂窝结构体成型助剂的生产工艺
    • US06284188B1
    • 2001-09-04
    • US09348013
    • 1999-07-06
    • Yosiyasu AndouKazuhiko KoikeTomohiko Nakanishi
    • Yosiyasu AndouKazuhiko KoikeTomohiko Nakanishi
    • C04B35195
    • C04B38/0006C04B35/195C04B35/632C04B35/63488
    • There is provided a process for obtaining a cordierite honeycomb structural body with thin cell walls and no molding defects such as cell breakage or the like. Cell breakage is prevented by limiting the maximum particle size of the cordierite starting material powder to no greater than 85% of the slit width of the extrusion molding die so that the starting material particles will not clog inside the slits or the introduction port of the slits. As one cordierite starting material, talc with a mean particle size of 5 &mgr;m or greater is used to give a honeycomb structural body with a void volume of greater than 30%, for production of a honeycomb structural body, with good moldability, having a small thickness and a low heat capacity. It is preferred to add to the starting material at least a lubricant/humectant, a binder and/or a mixture of a water-soluble polyhydric alcohol derivative and a polyhydric alcohol.
    • 提供了一种获得具有细胞壁的堇青石蜂窝结构体并且没有诸如细胞破裂等的成型缺陷的方法。 通过将堇青石原料粉末的最大粒径限制在挤出成型模具的狭缝宽度的不大于85%的方式防止细胞破裂,使得原料颗粒不会堵塞狭缝或缝隙的引入口 。 作为一种堇青石原料,使用平均粒径为5μm以上的滑石,得到空孔体积大于30%的蜂窝结构体,制造蜂窝结构体,成形性好,成型性小 厚度和低热容量。 优选至少添加润滑剂/保湿剂,粘合剂和/或水溶性多元醇衍生物和多元醇的混合物的原料。