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    • 9. 发明授权
    • Layered inorganic-organic polymer shaped article thereof and process for
producing the same
    • 层状无机 - 有机聚合物成型体及其制造方法
    • US5527871A
    • 1996-06-18
    • US422606
    • 1995-04-12
    • Masaaki TaniYoshiaki FukushimaAkane OkadaKatsuya Mizutani
    • Masaaki TaniYoshiaki FukushimaAkane OkadaKatsuya Mizutani
    • C08G77/00C08G77/58
    • C08G77/58C08G77/00
    • A layered inorganic-organic polymer having the features of both inorganic and organic materials and a coating material produced therefrom. The former is produced, for example, by reacting an organoalkoxysilane having alkoxyl groups and organic groups with a metal salt or alkoxide in an alkaline solution. This reaction yields a layered inorganic-organic polymer composed of one or two sheets of tetrahedrons with a central atom of Si or a metal and a sheet of octahedrons with a central atom of a metal, part or all of the central atoms of the tetrahedrons being covalently bonded to organic groups. If the organic group is one which contains a functional group capable of polymerization, the resulting layered inorganic-organic polymer may be polymerized with a functional group to give a firm coating material. The functional group of the organic group may be bonded to an organic compound. The layered inorganic-organic polymer has both the features of inorganic materials such as high hardness and good heat resistance and the features of organic materials such as flexibility and sheet formability at room temperature. In addition, it has good affinity for organic solvents and organic substances.
    • 具有无机和有机材料特征的层状无机 - 有机聚合物和由其制备的涂料。 前者例如通过在碱性溶液中使具有烷氧基和有机基团的有机烷氧基硅烷与金属盐或醇盐反应来制备。 该反应产生层叠的无机 - 有机聚合物,其由具有Si中心原子或金属的一个或两个四面体组成,并且具有金属的中心原子,四面体的部分或全部中心原子的八面体片是 共价结合到有机基团上。 如果有机基团是含有能够聚合的官能团的有机基团,则所得的层状无机 - 有机聚合物可以与官能团聚合,得到牢固的涂料。 有机基团的官能团可以键合到有机化合物上。 层状无机 - 有机聚合物具有高硬度,良好的耐热性等无机材料的特征,以及室温下的有机材料如柔软性和片材成型性的特征。 此外,它对有机溶剂和有机物质具有良好的亲和力。