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    • 1. 发明申请
    • FLUORO-RUBBER COMPOSITION AND BLADDER FOR TIRE FABRICATION
    • 氟橡胶组合物和轮胎制造用刀片
    • US20130225758A1
    • 2013-08-29
    • US13817965
    • 2010-08-25
    • Masashi YanoDaisuke OtaShuichi Okutsu
    • Masashi YanoDaisuke OtaShuichi Okutsu
    • C08K3/04
    • C08K3/04B29D22/02B29D30/0654B29D2030/665C08K5/0025C08L27/12C08K5/14
    • A fluoro rubber composition which is able to make both a high tensile strength and a high elongation at break after vulcanization compatible with each other and from which favorable mechanical characteristics are obtained even in a high-temperature environment; and a bladder for tire fabrication, which is manufactured using the same are provided. The fluoro rubber composition includes a rubber component containing a fluoro rubber and carbon black, wherein in a dynamic viscoelasticity test of an unvulcanized rubber by a rubber process analyzer (RPA) (measurement temperature: 100° C., measurement frequency: 1 Hz), a difference δGA′ (G′(1%)−G′(100%)) between a shear modulus G′ (1%) at the time of a dynamic strain of 1% and a shear modulus G′ (100%) at the time of a dynamic strain of 100% is 120 kPa or more and not more than 3,000 kPa.
    • 能够使硫化后的拉伸强度高,断裂伸长率高的氟橡胶组合物,即使在高温环境下也能获得良好的机械特性, 并且提供了使用其制造的用于轮胎制造的气囊。 氟橡胶组合物包括含有氟橡胶和炭黑的橡胶组分,其中在橡胶过程分析仪(RPA)(测量温度:100℃,测量频率:1Hz)的未硫化橡胶的动态粘弹性试验中, 在1%的动态应变时的剪切模量G'(1%)和剪切模量G'(100%)之间的差ΔGA'(G'(1%)-G'(100%)) 100%的动态应变时间为120kPa以上且3000kPa以下。
    • 2. 发明授权
    • Fluorine rubber composition and bladder for tire production
    • 氟橡胶组合物和用于轮胎生产的膀胱
    • US09068064B2
    • 2015-06-30
    • US13817894
    • 2010-08-25
    • Masashi YanoDaisuke OtaShuichi Okutsu
    • Masashi YanoDaisuke OtaShuichi Okutsu
    • C08L15/02C08L27/16B29D22/02B29D30/06B29D30/66C08K5/00
    • C08L15/02B29D22/02B29D30/0654B29D2030/665C08K5/0025C08K3/04C08L27/16
    • A fluorine rubber composition that provides high tensile strength and high elongation after vulcanization mutually compatible and from which favorable mechanical characteristics are obtained even in a high-temperature environment; and a bladder for tire production, which is manufactured using the same are provided. The fluorine rubber composition includes a rubber component containing a fluorine rubber and carbon black, wherein the carbon black has a specific surface area by nitrogen adsorption (N2SA) of 25 m2/g or more and not more than 180 m2/g and a dibutyl phthalate (DBP) absorption amount of 60 mL/100 g or more and not more than 180 mL/100 g; and in a kneading step (A) of compounding the carbon black in the rubber component, an average shear rate of a rotor surface of a kneading machine is 100 (1/sec) or more, and a kneading maximum temperature Tm is 120° C. or higher and not higher than 200° C.
    • 一种在硫化后提供高拉伸强度和高伸长率的氟橡胶组合物相互兼容并且即使在高温环境中也获得了有利的机械特性; 并且提供了使用其制造的用于轮胎生产的气囊。 氟橡胶组合物包括含有氟橡胶和炭黑的橡胶组分,其中炭黑通过氮吸附比(N2SA)为25m 2 / g以上且不大于180m 2 / g的比表面积和邻苯二甲酸二丁酯 (DBP)吸收量为60mL / 100g以上且不大于180mL / 100g; 在橡胶成分中混合炭黑的捏合工序(A)中,捏合机的转子表面的平均剪切速度为100(1 / sec)以上,捏合最高温度Tm为120℃ 以上且不高于200℃。
    • 3. 发明申请
    • FLUORINE RUBBER COMPOSITION AND BLADDER FOR TIRE PRODUCTION
    • 氟橡胶组合物和轮胎生产用叶片
    • US20130217816A1
    • 2013-08-22
    • US13817894
    • 2010-08-25
    • Masashi YanoDaisuke OtaShuichi Okutsu
    • Masashi YanoDaisuke OtaShuichi Okutsu
    • C08L15/02
    • C08L15/02B29D22/02B29D30/0654B29D2030/665C08K5/0025C08K3/04C08L27/16
    • A fluorine rubber composition that provides high tensile strength and high elongation after vulcanization mutually compatible and from which favorable mechanical characteristics are obtained even in a high-temperature environment; and a bladder for tire production, which is manufactured using the same are provided. The fluorine rubber composition includes a rubber component containing a fluorine rubber and carbon black, wherein the carbon black has a specific surface area by nitrogen adsorption (N2SA) of 25 m2/g or more and not more than 180 m2/g and a dibutyl phthalate (DBP) absorption amount of 60 mL/100 g or more and not more than 180 mill 00 g; and in a kneading step (A) of compounding the carbon black in the rubber component, an average shear rate of a rotor surface of a kneading machine is 100 (1/sec) or more, and a kneading maximum temperature Tm is 120° C. or higher and not higher than 200° C.
    • 一种在硫化后提供高拉伸强度和高伸长率的氟橡胶组合物相互兼容并且即使在高温环境中也获得了有利的机械特性; 并且提供了使用其制造的用于轮胎生产的气囊。 氟橡胶组合物包括含有氟橡胶和炭黑的橡胶组分,其中炭黑通过氮吸附比(N2SA)为25m 2 / g以上且不大于180m 2 / g的比表面积和邻苯二甲酸二丁酯 (DBP)吸收量为60mL / 100g以上且不大于180 mill 00g; 在橡胶成分中混合炭黑的捏合工序(A)中,捏合机的转子表面的平均剪切速度为100(1 / sec)以上,捏合最高温度Tm为120℃ 以上且不高于200℃。
    • 9. 发明授权
    • Fuel management systems having a fluororubber article in contact with biodiesel fuel
    • 具有与生物柴油燃料接触的氟橡胶制品的燃料管理系统
    • US07964001B2
    • 2011-06-21
    • US12423100
    • 2009-04-14
    • Shuichi OkutsuBunichi Rai
    • Shuichi OkutsuBunichi Rai
    • C10L1/19
    • C08K5/11C08L27/16
    • Disclosed herein is a fuel management system having at least one fluororubber article in contact with biodiesel fuel wherein said fluororubber article comprises i) a polyhydroxy cured fluoroelastomer comprising copolymerized units of vinylidene fluoride and at least one other fluoromonomer, and ii) 1 to 10 parts by weight of a diester of a dicarboxylic acid per hundred parts fluoroelastomer. Also disclosed is a method for reducing volume swell of a polyhydroxy cured fluororubber article in contact with biodiesel fuel wherein 1 to 10 parts by weight of a diester of a dicarboxylic acid is incorporated into said article.
    • 本文公开了一种燃料管理系统,其具有与生物柴油燃料接触的至少一个氟橡胶制品,其中所述氟橡胶制品包括i)包含偏二氟乙烯和至少一种其它含氟单体的共聚单元的多羟基固化含氟弹性体,和ii)1至10份 二羧酸二酯的重量每百份含氟弹性体。 还公开了一种减少与生物柴油燃料接触的多羟基固化的氟橡胶制品的体积膨胀的方法,其中将1至10重量份的二羧酸的二酯掺入所述制品中。