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    • 1. 发明授权
    • Ink follower
    • 墨水跟随者
    • US07179006B2
    • 2007-02-20
    • US10532091
    • 2003-10-27
    • Masaru MiyamotoYoji TakeuchiKenji Sato
    • Masaru MiyamotoYoji TakeuchiKenji Sato
    • B43K7/08
    • B43K7/02B43K7/08C09D11/18
    • An ink follower which has stable followability regardless of a pen body specification, a flow rate for writing and a writing speed and does not cause back leaking of the ink originating in shortage in the ink follower in the middle of writing and scattering of the ink follower by impact applied to the pen body and which does not flow out from the ink reservoir in storing the pen body at a high temperature and provides a stable flow rate for writing. An ink follower is also provided which prevents the ink from volatilizing by shutting off the ink from the outside air (volatilization preventing property) and which prevents the ink from leaking in writing with the pen turned upward. The ink follower, for example, contains a non-volatile or slightly volatile organic solvent and a non-styrene base thermoplastic elastomer which is soluble or swollen in the organic solvent and showing viscoelasticity which is predominant in elastic response.
    • 一种具有稳定的随动性的墨水随动体,不论笔体规格如何,书写流速和书写速度,并且在油墨跟随器的书写和散射中间不会引起油墨随动体中不足的油墨的反向泄漏 通过施加到笔体的冲击,并且在将笔体储存在高温下不会从墨水储存器流出并提供稳定的书写流量。 还提供了一种墨水随动体,其通过从外部空气中关闭墨水(防止挥发性)防止墨水挥发,并且防止墨水以书写方式向上翻转而泄漏墨水。 墨汁随动体例如含有在有机溶剂中可溶或溶胀的非挥发性或轻微挥发性有机溶剂和非苯乙烯基热塑性弹性体,并且显示出以弹性响应为主的粘弹性。
    • 2. 发明申请
    • Ink following element
    • 墨水追随元素
    • US20060047017A1
    • 2006-03-02
    • US10532091
    • 2003-10-27
    • Masaru MiyamotoYoji TakeuchiKenji Sato
    • Masaru MiyamotoYoji TakeuchiKenji Sato
    • C09D11/00
    • B43K7/02B43K7/08C09D11/18
    • Provided is an ink follower which has stable followability regardless of a pen body specification, a flow rate for writing and a writing speed and does not cause back leaking of the ink originating in shortage in the ink follower in the middle of writing and scattering of the ink follower by impact applied to the pen body and which does not flow out from the ink reservoir in storing the pen body at a high temperature and provides a stable flow rate for writing. Further, provided is an ink follower which prevents the ink from volatilizing by shutting off the ink from the outside air (volatilization preventing property) and which prevents the ink from leaking in writing with the pen turned upward. The above ink follower includes, for example, an ink follower characterized by containing a non-volatile or slightly volatile organic solvent and a non-styrene base thermoplastic elastomer which is soluble or swollen in the organic solvent and showing viscoelasticity which is predominant in elastic response.
    • 提供了一种墨水随动体,不论笔体规格如何,书写流动速度和书写速度都是稳定的随动性,并且在书写和散射的中间不会引起油墨随动体中不足的油墨的反向泄漏 通过冲击施加到笔体上并且在将笔体储存在高温下时不会从墨水容器中流出并提供稳定的写入流量的墨汁随动体。 此外,提供一种墨水随动体,其通过从外部空气中关闭墨水(防止挥发性)防止墨水挥发,并且防止墨水以书写方式向上翻转而泄漏墨水。 上述墨汁随动体包括例如墨汁随动体,其特征在于含有在有机溶剂中溶解或溶胀的非挥发性或轻微挥发性有机溶剂和非苯乙烯基热塑性弹性体,并显示弹性响应中主要的粘弹性 。
    • 4. 发明授权
    • Ink follower for water-based ink ballpoint pen
    • 水性墨水圆珠笔墨水跟随器
    • US07179005B2
    • 2007-02-20
    • US10499966
    • 2002-12-27
    • Masaru MiyamotoYoji Takeuchi
    • Masaru MiyamotoYoji Takeuchi
    • B43K7/08
    • B43K7/08B43K7/01
    • An ink follower for a ballpoint pen using a water-based ink in which a value of the test for oil separation (60° C., 24 hours) according to JIS K 2220-5.7-1993 is 0.5 to 12% and which has a viscoelasticity predominant in an elastic response or a value of tan δ of 0.1 to 1.5 at a temperature of 25° C. and in the full frequency range of an angular frequency of 0.1 to 630 rad/sec, and it contains as a base oil, a non-water-soluble organic solvent having a viscosity of 5 Pas·sec or less at a temperature of 25° C. and a shearing speed of 1 to 400 sec−1. Polybutene, mineral oil and silicone oil can be used as the base oil.
    • 一种使用水性油墨的圆珠笔用墨汁随动体,其中根据JIS K 2220-5.7-1993的油分离试验值(60℃,24小时)为0.5〜12%,其具有 在25℃的温度和角频率为0.1〜630弧度/秒的全频率范围内,以弹性响应为主的粘弹性或tanδ为0.1〜1.5的值,并且含有基油, 在25℃的温度和1〜400秒-1的剪切速度下粘度为5Pa·sec以下的非水溶性有机溶剂。 聚丁烯,矿物油和硅油可用作基础油。
    • 7. 发明授权
    • Water based ink for ball point pen
    • 圆珠笔水性墨水
    • US06261351B1
    • 2001-07-17
    • US09530506
    • 2000-04-27
    • Masaru MiyamotoShigeru MiyazakiYoji Takeuchi
    • Masaru MiyamotoShigeru MiyazakiYoji Takeuchi
    • C09D1116
    • C09D11/18
    • An action of the preventing drying at a pen tip without using water-soluble organic solvents such as glycols, glycerin and glycol ethers which have so far been used for a water based ink for a ball point pen is allotted to at least one selected from the group consisting of a reducing sugar comprising maltitol as a principal component, a reducing sugar comprising sorbitol as a principal component, reducing dextrin, reducing maltodextrin, &agr;-cyclodextrin, &bgr;-cyclodextrin and maltosylcyclodextrin, and the actions of inhibiting feathering of the drawn lines, improving discharge stability of the ink and maintaining the lubricity are allotted to at least one selected from the group consisting of an alkylene oxide adduct of polyglycerin, an alkylene oxide adduct of glycerin and an alkylene oxide adduct of trimethylolpropane. Further, a viscosity-controlling agent is added thereto to thereby prepare a water based ink for a ball point pen which has feathering resistance, good writing feeling and high discharge stability and which is excellent in drying prevention effect at a pen tip.
    • 使用迄今为止用于圆珠笔的水性墨水的水溶性有机溶剂如乙二醇,甘油和二醇醚的笔尖防止干燥的作用被分配到选自以下的至少一种: 由麦芽糖醇作为主要成分的还原糖组成的还原糖,以山梨糖醇为主要成分的还原糖,还原糊精,还原麦芽糖糊精,α-环糊精,β-环糊精,麦芽糖基环糊精等,还有抑制拉伸线羽化的作用, 提高油墨的排出稳定性并保持润滑性被分配到选自聚甘油的烯化氧加合物,甘油的烯化氧加合物和三羟甲基丙烷的烯化氧加成物中的至少一种。 此外,向其中加入粘度调节剂,由此制备了具有耐羽毛,具有良好的书写感和高放电稳定性的圆珠笔用水性油墨,其笔尖的防干燥效果优异。
    • 8. 发明申请
    • Ink follow-up material for water-base ball pen
    • 水底球笔油墨后续材料
    • US20050074273A1
    • 2005-04-07
    • US10499966
    • 2002-12-27
    • Masaru MiyamotoYoji Takeuchi
    • Masaru MiyamotoYoji Takeuchi
    • B43K7/01B43K7/08B43K7/00
    • B43K7/08B43K7/01
    • Provided is an ink follower for a ballpoint pen using a water-based ink in which a value of the test for oil separation (60° C., 24 hours) according to JIS K 2220-5.7-1993 is 0.5 to 12% and which has a viscoelasticity predominant in an elastic response or a value of tan δ of 0.1 to 1.5 at a temperature of 25° C. and in the full frequency range of an angular frequency of 0.1 to 630 rad/sec, and it contains as a base oil, a non-water-soluble organic solvent having a viscosity of 5 Pas·sec or less at a temperature of 25° C. and a shearing speed of 1 to 400 sec−1. Polybutene, mineral oil and silicone oil can be used as the base oil.
    • 本发明提供一种使用水性油墨的圆珠笔用墨汁随动体,其中根据JIS K 2220-5.7-1993的油分离试验值(60℃,24小时)为0.5〜12%,其中 在25℃的温度和0.1〜630弧度/秒的角频率的全频率范围内,弹性响应中具有优异的粘弹性或tanδ的值为0.1至1.5的粘弹性,并且其包含作为基底 油,在25℃的温度和1〜400秒-1的剪切速度下粘度为5Pa·sec以下的非水溶性有机溶剂。 聚丁烯,矿物油和硅油可用作基础油。
    • 9. 发明授权
    • Water-based ink composition for writing utensil
    • 用于书写用具的水性油墨组合物
    • US06776829B2
    • 2004-08-17
    • US10297063
    • 2002-12-02
    • Masaru MiyamotoTadashi KamagataYoji TakeuchiShigeru Miyazaki
    • Masaru MiyamotoTadashi KamagataYoji TakeuchiShigeru Miyazaki
    • C09D1116
    • C09D11/16C09D11/18
    • Provided is a water based ink composition for a writing instrument comprising at least one of nonionic surfactants comprising polyhydric alcohol fatty acid esters, ethylene oxide adducts of polyhydric alcohol fatty acid esters, ethylene oxide adducts of higher alcohols and alkylphenols, ethylene oxide and propylene oxide adducts of higher alcohols, ethylene oxide adducts of castor oil or hardened castor oil, ethylene oxide adducts of hardened castor oil fatty acid esters and ethylene oxide adducts of higher alkylamines and fatty acid amides and further comprising a colorant, a perfume and water. It is less liable to cause feathering of the lines and has durability of fragrance, in which a perfume is dispersed and retained in an aqueous medium in a stable state.
    • 提供一种书写用水性油墨组合物,其包括至少一种包含多元醇脂肪酸酯的非离子表面活性剂,多元醇脂肪酸酯的环氧乙烷加合物,高级醇的环氧乙烷加成物和烷基酚,环氧乙烷和环氧丙烷加成物 高级醇,蓖麻油或硬化蓖麻油的环氧乙烷加成物,硬化蓖麻油脂肪酸酯的环氧乙烷加合物和高级烷基胺和脂肪酸酰胺的环氧乙烷加成物,并且还包含着色剂,香料和水。 不易引起线的羽化,并且具有香料的耐久性,其中香料分散并保持在稳定状态的水性介质中。