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1. 发明授权

US09334609B2 Leather-like sheet and process for producing the same 有权
标题翻译：皮革样片材及其制造方法
公开(公告)号：US09334609B2
公开(公告)日：2016-05-10
申请号：US12675573
申请日：2008-08-28
申请人： Masaru Makimura , Hidekazu Andoh , Michinori Fujisawa , Yasunori Murate , Yoshiyuki Ando , Yoshiki Nobuto , Norio Makiyama
发明人： Masaru Makimura , Hidekazu Andoh , Michinori Fujisawa , Yasunori Murate , Yoshiyuki Ando , Yoshiki Nobuto , Norio Makiyama
IPC分类号： D06N3/00 , D04H1/4382 , D04H13/00
CPC分类号： D06N3/0004 , D04H1/4382 , D04H3/016 , D04H3/12 , D04H13/002 , D06N3/0013 , Y10T428/24438 , Y10T442/2377
摘要： A leather-like sheet containing a microfine long-fiber nonwoven fabric containing an entangled web structure made of bundles of microfine long fibers and an elastic polymer impregnated in the microfine long-fiber nonwoven fabric. The leather-like sheet has a machine direction/transverse direction ratio of breaking strength of 1/1 to 1.3/1, an elongation at break in each of the machine direction and the transverse direction of 80% or more, and a machine direction/transverse direction ratio of elongation at break of 1/1 to 1/1.5. The leather-like sheet has a natural dense feeling, a soft hand, a small difference of mechanical properties in the machine direction and the transverse direction, a moderate resistance to elongation and a durable recovery.
摘要翻译：包含含有由超细长纤维束构成的缠结网状结构的微细长纤维无纺布和浸渍在超细长纤维无纺织物中的弹性聚合物的皮革状片材。皮革状片材的断裂强度的纵向/横向比为1/1〜1.3 / 1，纵向和横向的断裂伸长率为80％以上，机器方向/ 断裂伸长率的横向方向比为1/1至1 / 1.5。皮革状片材具有自然的感觉，柔软的手感，机器方向和横向上的机械性能差异小，伸长率适中，耐久恢复。

2. 发明申请

US20100239817A1 LEATHER-LIKE SHEET AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：皮革类似物及其生产方法
公开(公告)号：US20100239817A1
公开(公告)日：2010-09-23
申请号：US12675573
申请日：2008-08-28
申请人： Masaru Makimura , Hidekazu Andoh , Michinori Fujisawa , Yasunori Murate , Yoshiyuki Ando , Yoshiki Nobuto , Norio Makiyama
发明人： Masaru Makimura , Hidekazu Andoh , Michinori Fujisawa , Yasunori Murate , Yoshiyuki Ando , Yoshiki Nobuto , Norio Makiyama
IPC分类号： D06N3/00 , B32B27/04 , B32B5/02 , B05D3/02
CPC分类号： D06N3/0004 , D04H1/4382 , D04H3/016 , D04H3/12 , D04H13/002 , D06N3/0013 , Y10T428/24438 , Y10T442/2377
摘要： A leather-like sheet comprising a microfine long-fiber nonwoven fabric comprising an entangled web structure made of bundles of microfine long fibers and an elastic polymer impregnated in the microfine long-fiber nonwoven fabric. The leather-like sheet has the following features: (1) each of the bundles of microfine long fibers comprises 5 to 70 microfine long fibers having an average single fiber fineness of 0.5 dtex or less; (2) the bundles of microfine long fibers have an average fineness of 3 dtex or less; (3) the entangle web structure comprises superposed webs each comprising the bundles of microfine long fibers; (4) a ratio of the microfine long fibers and the elastic polymer is 70/30 to 40/60 by mass; (5) the elastic polymer is substantially continuous; and (6) a machine direction/transverse direction ratio of breaking strength is 1/1 to 1.3/1, an elongation at break in each of the machine direction and the transverse direction is 80% or more, and a machine direction/transverse direction ratio of elongation at break is 1/1 to 1/1.5. With these features, the leather-like sheet has a natural dense feeling resembling natural leathers, a soft hand a small difference of mechanical properties in the machine direction and the transverse direction, a moderate resistance to elongation and a durable recovery.
摘要翻译：一种皮革状片材，其特征在于，包括由超细长纤维束构成的缠结网状结构体和浸渍在所述超细长纤维无纺布中的弹性聚合物构成的超细长纤维无纺布。皮革状片材具有以下特征：（1）每根超细长纤维束包含平均单纤维细度为0.5dtex以下的5〜70个超细长纤维，（2）超细长纤维束的平均细度为3分特以下，（3）缠结纤维网结构包括每个包含超细长纤维束的重叠腹板; （4）微细长纤维与弹性聚合物的比例为70/30〜40/60质量％（5）弹性聚合物基本连续; （6）断裂强度的机器方向/横向方向比为1/1〜1.3 / 1，纵向和横向各自的断裂伸长率为80％以上，机器方向/横向断裂伸长率为1/1〜1 / 1.5。具有这些特征，皮革状片材具有类似于天然皮革的天然致密感，柔软的手在机器方向和横向方向上的机械性能的差异小，伸长率适中，耐久恢复。

3. 发明授权

US09752260B2 Base material for artificial leather and process for producing the same 有权
公开(公告)号：US09752260B2
公开(公告)日：2017-09-05
申请号：US12988563
申请日：2008-06-25
申请人： Michinori Fujisawa , Jiro Tanaka , Norio Makiyama , Yoshiyuki Ando , Yoshiki Nobuto
发明人： Michinori Fujisawa , Jiro Tanaka , Norio Makiyama , Yoshiyuki Ando , Yoshiki Nobuto
IPC分类号： D04H3/105 , D04H3/016 , D06N3/00
CPC分类号： D04H3/105 , D04H3/016 , D06N3/0004 , Y10T428/2395 , Y10T442/2352 , Y10T442/613
摘要： A substrate for artificial leather comprising a nonwoven fabric of bundles of microfine filaments. The substrate for artificial leather simultaneously satisfies the following requirements 1 to 4: (1) the bundle of microfine filaments comprises 8 to 70 microfine filaments having a cross-sectional shape of nearly circle; (2) the bundle of microfine filaments has a cross-sectional area of 170 to 700 μm2 and a flatness of 4.0 or less; (3) on a cross section parallel to a thickness direction of the nonwoven fabric body, cross sections of the microfine fiber bundles exist in a density of 1500 to 3000/mm2; and (4) on a cross section parallel to a thickness direction of the nonwoven fabric body, gaps between the microfine fiber bundles have a size of 70 μm or less. By satisfying the requirements, the substrate for artificial leather combines high level of sensuous qualities and high level of physical properties which have been considered to be mutually exclusive.

4. 发明申请

US20110039055A1 BASE MATERIAL FOR ARTIFICIAL LEATHER AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：人造革用基材及其制造方法
公开(公告)号：US20110039055A1
公开(公告)日：2011-02-17
申请号：US12988563
申请日：2008-06-25
申请人： Michinori Fujisawa , Jiro Tanaka , Norio Makiyama , Yoshiyuki Ando , Yoshiki Nobuto
发明人： Michinori Fujisawa , Jiro Tanaka , Norio Makiyama , Yoshiyuki Ando , Yoshiki Nobuto
IPC分类号： D06N3/00 , D04H3/00 , D01H13/30
CPC分类号： D04H3/105 , D04H3/016 , D06N3/0004 , Y10T428/2395 , Y10T442/2352 , Y10T442/613
摘要： A substrate for artificial leather comprising a nonwoven fabric of bundles of microfine filaments. The substrate for artificial leather simultaneously satisfies the following requirements 1 to 4: (1) the bundle of microfine filaments comprises 8 to 70 microfine filaments having a cross-sectional shape of nearly circle; (2) the bundle of microfine filaments has a cross-sectional area of 170 to 700 μm2 and a flatness of 4.0 or less; (3) on a cross section parallel to a thickness direction of the nonwoven fabric body, cross sections of the microfine fiber bundles exist in a density of 1500 to 3000/mm2; and (4) on a cross section parallel to a thickness direction of the nonwoven fabric body, gaps between the microfine fiber bundles have a size of 70 μm or less. By satisfying the requirements, the substrate for artificial leather combines high level of sensuous qualities and high level of physical properties which have been considered to be mutually exclusive.
摘要翻译：一种人造革用基材，其特征在于，包含超细丝束的无纺布。人造皮革基材同时满足以下要求1〜4：（1）超细丝束包含截面形状近似圆形的8〜70个细长丝; （2）所述超细丝束的截面积为170〜700μm2，平坦度为4.0以下; （3）在与无纺布体的厚度方向平行的截面上，超细纤维束的截面以1500〜3000 / mm 2的密度存在; 和（4）在与无纺布体的厚度方向平行的截面上，超细纤维束之间的间隙为70μm以下。通过满足要求，用于人造革的基材结合了高水平的感官品质和高水平的物理性能，被认为是相互排斥的。

5. 发明授权

US08778126B2 Base material for artificial leather and grained artificial leather 有权
标题翻译：人造皮革和人造革人造革的基础材料
公开(公告)号：US08778126B2
公开(公告)日：2014-07-15
申请号：US13667752
申请日：2012-11-02
申请人： Michinori Fujisawa , Jiro Tanaka , Yoshiyuki Ando , Norio Makiyama
发明人： Michinori Fujisawa , Jiro Tanaka , Yoshiyuki Ando , Norio Makiyama
IPC分类号： D06C19/00
CPC分类号： D06N3/0004 , D04H3/016 , D04H3/018 , D04H3/12 , D06N3/0077 , D06N3/14 , Y10T442/614
摘要： A method of producing a substrate suitable for artificial leathers. The substrate is composed of an entangled nonwoven fabric made of microfine fibers and a binder resin. At least one surface of the substrate is a densified layer which is made of the microfine fibers and which is substantially free from the binder resin. The binder resin is impregnated into a portion of the substrate other than the densified layer. The densified layer prevents the binder resin impregnated into the entangled nonwoven fabric from migrating into the surface of the entangled nonwoven fabric, thereby providing the substrate having the surface substantially free from the binder resin. The peeling strength between the substrate and a grain layer formed on the surface thereof is drastically improved because the surface of the substrate is substantially free from the binder resin.
摘要翻译：一种适用于人造皮革的基材的制造方法。基材由由超细纤维和粘合剂树脂制成的缠结无纺布构成。基材的至少一个表面是由微细纤维制成并且基本上不含粘合剂树脂的致密层。粘合剂树脂浸渍在除了致密化层之外的基材的一部分中。致密层防止浸渍到缠结非织造织物中的粘合剂树脂迁移到缠结非织造织物的表面，从而提供具有基本上不含粘合剂树脂的表面的基材。由于基材的表面基本上不含粘合剂树脂，所以基材和形成在其表面上的颗粒层之间的剥离强度显着提高。

6. 发明申请

US20090053948A1 BASE FOR SYNTHETIC LEATHER AND SYNTHETIC LEATHERS MADE BY USING THE SAME 有权
标题翻译：使用合成皮革和合成皮革的基础
公开(公告)号：US20090053948A1
公开(公告)日：2009-02-26
申请号：US12097659
申请日：2006-12-13
申请人： Michinori Fujisawa , Jiro Tanaka , Tsuyoshi Yamasaki , Norio Makiyama , Yoshiyuki Ando
发明人： Michinori Fujisawa , Jiro Tanaka , Tsuyoshi Yamasaki , Norio Makiyama , Yoshiyuki Ando
IPC分类号： B32B27/04 , D01F8/04
CPC分类号： D06N3/0004 , Y10S428/904 , Y10T442/2861 , Y10T442/614 , Y10T442/682 , Y10T442/689
摘要： A substrate for artificial leathers, comprising a nonwoven fabric body made of microfine fiber bundles and an elastic polymer impregnated therein. The substrate for artificial leathers simultaneously satisfies the following requirements 1 to 4: (1) each of the microfine fiber bundles contains 6 to 150 bundled microfine long fibers in average; (2) a cross-sectional area of the microfine long fibers constituting the microfine fiber bundles is 27 μm2 or less, and 80% or more of the microfine long fibers has a cross-sectional area of from 0.9 to 25 μm2; (3) an average cross-sectional area of the microfine fiber bundles is from 15 to 150 μm2; and (4) on a cross section parallel to a thickness direction of the nonwoven fabric body, cross sections of the microfine fiber bundles exist in a density of from 1000 to 3000/mm2 in average. The raised artificial leathers and grain-finished artificial leathers made from the substrate for artificial leathers are excellent in the properties which are hitherto difficult to be combined.
摘要翻译：一种人造革用基材，其特征在于，包括由超细纤维束构成的无纺布体和浸渍在其中的弹性聚合物。人造革用基材同时满足以下要求1〜4：（1）每个超细纤维束平均含有6〜150个捆束的超细长纤维; （2）构成超细纤维束的微细长纤维的截面积为27mum2以下，超微细长纤维的80％以上的截面积为0.9〜25mum2; （3）超细纤维束的平均截面积为15〜150μm2; 和（4）在与无纺布体的厚度方向平行的截面上，超细纤维束的截面的平均密度为1000〜3000 / mm 2。由人造革用基材制成的人造革和人造革人造皮革，迄今为止难以组合的性能优异。

7. 发明申请

US20090124156A1 BASE MATERIAL FOR ARTIFICIAL LEATHER AND GRAINED ARTIFICIAL LEATHER 审中-公开
标题翻译：人造皮革和人造人造革的基材
公开(公告)号：US20090124156A1
公开(公告)日：2009-05-14
申请号：US12302813
申请日：2007-05-22
申请人： Michinori Fujisawa , Jiro Tanaka , Yoshiyuki Ando , Norio Makiyama
发明人： Michinori Fujisawa , Jiro Tanaka , Yoshiyuki Ando , Norio Makiyama
IPC分类号： D04H13/00 , B29C43/00
CPC分类号： D06N3/0004 , D04H3/016 , D04H3/018 , D04H3/12 , D06N3/0077 , D06N3/14 , Y10T442/614
摘要： A substrate for artificial leathers composed of an entangled nonwoven fabric made of microfine fibers and a binder resin. At least one surface of the substrate for artificial leathers is a densified layer which is made of the microfine fibers and which is substantially free from the binder resin. The binder resin is impregnated into a portion of the substrate for artificial leathers other than the densified layer. The densified layer prevents the binder resin impregnated into the entangled nonwoven fabric from migrating into the surface of the entangled nonwoven fabric, thereby providing the substrate for artificial leathers having the surface substantially free from the binder resin. The peeling strength between the substrate for artificial leathers and a grain layer formed on the surface thereof is drastically improved because the surface of the substrate for artificial leathers is substantially free from the binder resin.
摘要翻译：一种人造革用基材，其由由超细纤维制成的缠结无纺布和粘合剂树脂组成。用于人造革的基材的至少一个表面是由微细纤维制成并且基本上不含粘合剂树脂的致密层。粘合剂树脂浸渍在除了致密层以外的用于人造革的基材的一部分中。致密层防止浸渍到缠结非织造织物中的粘合剂树脂迁移到缠结非织造织物的表面，从而提供具有基本上不含粘合剂树脂的表面的人造革用基材。用于人造革的基材和形成在其表面上的颗粒层之间的剥离强度由于用于人造革的基材的表面基本上不含粘合剂树脂而显着改善。

8. 发明申请

US20130055535A1 BASE MATERIAL FOR ARTIFICIAL LEATHER AND GRAINED ARTIFICIAL LEATHER 有权
标题翻译：人造皮革和人造人造革的基材
公开(公告)号：US20130055535A1
公开(公告)日：2013-03-07
申请号：US13667752
申请日：2012-11-02
申请人： Michinori FUJISAWA , Jiro Tanaka , Yoshiyuki Ando , Norio Makiyama
发明人： Michinori FUJISAWA , Jiro Tanaka , Yoshiyuki Ando , Norio Makiyama
IPC分类号： D06C29/00
CPC分类号： D06N3/0004 , D04H3/016 , D04H3/018 , D04H3/12 , D06N3/0077 , D06N3/14 , Y10T442/614
摘要： A method of producing a substrate suitable for artificial leathers. The substrate is composed of an entangled nonwoven fabric made of microfine fibers and a binder resin. At least one surface of the substrate is a densified layer which is made of the microfine fibers and which is substantially free from the binder resin. The binder resin is impregnated into a portion of the substrate other than the densified layer. The densified layer prevents the binder resin impregnated into the entangled nonwoven fabric from migrating into the surface of the entangled nonwoven fabric, thereby providing the substrate having the surface substantially free from the binder resin. The peeling strength between the substrate and a grain layer formed on the surface thereof is drastically improved because the surface of the substrate is substantially free from the binder resin.
摘要翻译：一种适用于人造皮革的基材的制造方法。基材由由超细纤维和粘合剂树脂制成的缠结无纺布构成。基材的至少一个表面是由微细纤维制成并且基本上不含粘合剂树脂的致密层。粘合剂树脂浸渍在除了致密化层之外的基材的一部分中。致密层防止浸渍到缠结非织造织物中的粘合剂树脂迁移到缠结非织造织物的表面，从而提供具有基本上不含粘合剂树脂的表面的基材。由于基材的表面基本上不含粘合剂树脂，所以基材和形成在其表面上的颗粒层之间的剥离强度显着提高。

9. 发明授权

US07932192B2 Base for synthetic leather and synthetic leathers made by using the same 有权
标题翻译：用于合成皮革和合成皮革的基础使用它
公开(公告)号：US07932192B2
公开(公告)日：2011-04-26
申请号：US12097659
申请日：2006-12-13
申请人： Michinori Fujisawa , Jiro Tanaka , Tsuyoshi Yamasaki , Norio Makiyama , Yoshiyuki Ando
发明人： Michinori Fujisawa , Jiro Tanaka , Tsuyoshi Yamasaki , Norio Makiyama , Yoshiyuki Ando
IPC分类号： B32B27/02 , D01F8/00
CPC分类号： D06N3/0004 , Y10S428/904 , Y10T442/2861 , Y10T442/614 , Y10T442/682 , Y10T442/689
摘要： A substrate for artificial leathers, comprising a nonwoven fabric body made of microfine fiber bundles and an elastic polymer impregnated therein. The substrate for artificial leathers simultaneously satisfies the following requirements 1 to 4: (1) each of the microfine fiber bundles contains 6 to 150 bundled microfine long fibers in average; (2) a cross-sectional area of the microfine long fibers constituting the microfine fiber bundles is 27 μm2 or less, and 80% or more of the microfine long fibers has a cross-sectional area of from 0.9 to 25 μm2; (3) an average cross-sectional area of the microfine fiber bundles is from 15 to 150 μm2; and (4) on a cross section parallel to a thickness direction of the nonwoven fabric body, cross sections of the microfine fiber bundles exist in a density of from 1000 to 3000/mm2 in average. The raised artificial leathers and grain-finished artificial leathers made from the substrate for artificial leathers are excellent in the properties which are hitherto difficult to be combined.
摘要翻译：一种人造革用基材，其特征在于，包括由超细纤维束构成的无纺布体和浸渍在其中的弹性聚合物。人造革用基材同时满足以下要求1〜4：（1）每个超细纤维束平均含有6〜150个捆束的超细长纤维; （2）构成超细纤维束的微细长纤维的截面积为27μm2以下，超细长纤维的80％以上的截面积为0.9〜25μm2; （3）超细纤维束的平均截面积为15〜150μm2; 和（4）在与无纺布体的厚度方向平行的截面上，超细纤维束的截面的平均密度为1000〜3000 / mm 2。由人造革用基材制成的人造革和人造革人造皮革，迄今为止难以组合的性能优异。

10. 发明授权

US08053060B2 Base material for artificial leathers and method of producing the same 失效
标题翻译：人造革用基材及其制造方法
公开(公告)号：US08053060B2
公开(公告)日：2011-11-08
申请号：US11917665
申请日：2006-06-14
申请人： Michinori Fujisawa , Jiro Tanaka , Yoshiyuki Ando
发明人： Michinori Fujisawa , Jiro Tanaka , Yoshiyuki Ando
IPC分类号： D06N7/04 , B32B27/04 , B32B27/12 , B32B5/02
CPC分类号： D06N3/0004 , D04H1/46 , D04H1/74 , D06N3/14 , Y10T428/24438 , Y10T442/2377 , Y10T442/614 , Y10T442/637 , Y10T442/64
摘要： A substrate for artificial leathers which is composed of a nonwoven fabric made of fiber bundles of microfine fibers having an average single fiber fineness of 0.5 dtex or less and an elastic polymer impregnated into the nonwoven fabric. The substrate for artificial leathers satisfies the following requirements 1 and 2: (1) the number of fiber bundles which are oriented to a thickness direction of the nonwoven fabric is 75 to 300 per 1 cm of width which is perpendicular to the thickness direction, when measured on a cross section parallel to the thickness direction; and (2) the number of cross sections of the fiber bundles which are oriented to the thickness direction is 30 to 800 per 1 mm2, when measured on a cross section perpendicular to the thickness direction. The substrate for artificial leathers is suitable for the production of a grain-finished artificial leather which combines a non-repulsive softness and firm hand resembling natural sheep leathers and has fine buckling wrinkles, and a suede-finished or nubuck artificial leather having a surface touch with fine texture and a grace writing effect each being hitherto not obtained.
摘要翻译：一种人造革用基材，其由平均单纤维纤度为0.5dtex以下的超细纤维纤维束制成的无纺布和浸渍在该无纺布中的弹性聚合物构成。人造革用基材满足以下要求1和2：（1）与无纺布的厚度方向取向的纤维束的数量为与厚度方向垂直的每1cm宽度为75〜300，当在平行于厚度方向的横截面上测量; 和（2）当在与厚度方向垂直的截面上测量时，沿厚度方向取向的纤维束的横截面数为30〜800mm / 1mm 2。用于人造革的基材适用于生产一种结合非排斥柔软度的坚硬手感和类似于天然羊皮的坚固手感并具有细小皱纹皱纹的精制人造皮革，以及具有表面触感的麂皮绒或正绒面革人造皮革具有精细的纹理和宽限的写作效果，每个都是迄今未获得的。

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