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    • 2. 发明授权
    • Process for producing modified polypropylene
    • 生产改性聚丙烯的方法
    • US4483966A
    • 1984-11-20
    • US421243
    • 1982-09-22
    • Takeshi SuzukiHiroshi ShimizuNobutoshi KomoriTakehiro UmenoAtsuyoshi Shimizu
    • Takeshi SuzukiHiroshi ShimizuNobutoshi KomoriTakehiro UmenoAtsuyoshi Shimizu
    • C08F297/00C08F4/42C08F4/64C08F297/08
    • C08F297/083
    • A process for producing ethylene-propylene block copolymer by the use of a catalyst employed for producing isotactic polypropylene is provided. This process is characterized in that a gas phase polymerization of propylene is substantially carried out in the presence of the catalyst obtained by combining a titanium trichloride composition with an average particle size of 10.about.100 .mu. and an organic aluminum to form the propylene polymer segment with a specific surface area more than 0.015 m.sup.2 /g at a yield of more than 3,000 g per 1 g of the titanium trichloride composition in the first step, and then a gas phase polymerization of a mixture of polypropylene and ethylene is successively carried out in the second step to form the copolymer segment with a copolymerization ratio of propylene:ethylene being 5.about.80 weight %:95.about.20 weight %, wherein the polymerized amount of the second step is 10-40% of total polymerized amount and wherein normal hexane extraction ratio (75.degree. C., 1 hour) of the ethylene-propylene block copolymer powders obtained is 1.about.10 weight %. The process of the present invention is one having an extremely high productivity industrially, and the modified polypropylene obtained has a superior low-temperature-impact strength and brittle temperature.
    • 提供了通过使用用于制备全同立构聚丙烯的催化剂制备乙烯 - 丙烯嵌段共聚物的方法。 该方法的特征在于丙烯的气相聚合基本上在通过将平均粒径为10-600微米的三氯化钛组合物和有机铝组合而获得的催化剂的存在下进行,以形成丙烯聚合物链段, 比表面积大于0.015m 2 / g,第一步中每1g三氯化钛组合物的产量大于3,000g,然后在聚丙烯和乙烯的混合物中进行气相聚合 形成共聚物链段的第二步,丙烯:乙烯的共聚比为5分子量80重量%:95重量比20重量%,其中第二步的聚合量为总聚合量的10-40%,其中正常己烷萃取 获得的乙烯 - 丙烯嵌段共聚物粉末的比例(75℃,1小时)为10重量%。 本发明的方法在工业上具有极高的生产率,所得到的改性聚丙烯具有优异的低温冲击强度和脆性温度。
    • 3. 发明授权
    • Deodorized polyolefins and process for the preparation thereof
    • 除臭聚烯烃及其制备方法
    • US4591633A
    • 1986-05-27
    • US752653
    • 1985-07-08
    • Takeshi SuzukiNobutoshi Komori
    • Takeshi SuzukiNobutoshi Komori
    • C08F6/02C08K3/26C08K3/34C08F6/08
    • C08K3/26C08F6/02C08K3/34
    • Purified polyolefins prepared by deactivating Ziegler type catalyst residue contained in polyolefins not purified by use of alkylene oxide and having off-odor are mixed for deodorization with 0.001 to 0.5% by weight of at least one deodorizer selected from the compounds having the following formulas (1) to (6):Al.sub.x Si.sub.y (OH).sub.3x+4y.nH.sub.2 O (1)Mg.sub.x (OH).sub.2y-2x (CO.sub.3).sub.y.nH.sub.2 O (2)Mg.sub.x Ca.sub.y (CO.sub.3).sub.2x+2y/2.nH.sub.2 O (3)M.sub.x Si.sub.y (OH).sub.2x+4y.nH.sub.2 O (4)M.sub.x Al.sub.y Si.sub.z (OH).sub.2x+3y+4z.nH.sub.2 O (5)M.sub.x Al.sub.y (OH).sub.2x+3y-2z (A).nH.sub.2 O (6)where M represents Mg or Ca; A represents CO.sub.3, HPO.sub.4 or SO.sub.4 ; x, y and z represent a positive number; and n represents zero or a positive integer; calcined products therefrom, and hydrates thereof. The deodorizer may be added thereto independently from or concurrently with other additives to be mixed.Another aspect of the present invention is directed to a process for the preparation of deodorized polyolefins which comprises mixing polyolefins purified by deactivating the catalyst residue remained in crude polyolefins obtained by the polymerization of olefins by use of Ziegler type catalyst at least one deodorizer said above.
    • 混合使用0.001〜0.5重量%的至少一种选自具有下式(1)的化合物的除臭剂进行除臭除去通过使未纯化的环氧烷并且具有异味的聚烯烃中所含的齐格勒型催化剂残渣失活而制备的纯化聚烯烃 )至(6):AlxSiy(OH)3x + 4y.nH2O(1)Mgx(OH)2y-2x(CO3)y.nH2O(2)MgxCay(CO3)2x + 2y / 2.nH2O(3)MxSiy OH)2x + 4y.nH2O(4)MxAlySiz(OH)2x + 3y + 4z.nH2O(5)MxAly(OH)2x + 3y-2z(A).nH2O(6)其中M表示Mg或Ca; A表示CO 3,HPO 4或SO 4; x,y和z表示正数; n表示0或正整数; 煅烧产物及其水合物。 除臭剂可以独立于或与其它待混合的添加剂同时加入。 本发明的另一方面涉及一种制备除臭聚烯烃的方法,该方法包括通过使用齐格勒型催化剂使上述至少一种除臭剂将残留在通过烯烃聚合获得的粗聚烯烃中的催化剂残余物失活来纯化。